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81. 发明授权

US07205442B2 Method of making high purity phenol 失效
标题翻译：制备高纯度苯酚的方法
公开(公告)号：US07205442B2
公开(公告)日：2007-04-17
申请号：US10761591
申请日：2004-01-21
申请人： Larry Wayne Payne
发明人： Larry Wayne Payne
IPC分类号： C07C37/68
CPC分类号： C07C37/86 , C07C37/08 , C07C39/04
摘要： A method of manufacturing a phenol product having a reduced concentration of a contaminating reaction by-product. The method includes contacting a phenol stream, having a concentration of the contaminating by-product, by contacting the phenol stream with an acidic catalyst under suitable purification reaction conditions. Also included is a composition comprising a sec-butyl benzene derived phenol product that has been purified by the removal of certain undesirable reaction by-products.
摘要翻译：一种制造具有降低的污染反应副产物浓度的苯酚产物的方法。该方法包括在合适的纯化反应条件下使苯酚流与酸性催化剂接触，使苯酚流具有污染副产物的浓度。还包括一种组合物，其包含通过除去某些不希望的反应副产物而被纯化的仲丁基苯衍生的苯酚产物。

82. 发明授权

US07186866B1 Process for recovery of cumene hydroperoxide decomposition products by distillation 有权
标题翻译：通过蒸馏回收氢过氧化枯烯产物的方法
公开(公告)号：US07186866B1
公开(公告)日：2007-03-06
申请号：US11273411
申请日：2005-11-14
申请人： Scott R. Keenan , Amber R. Harach , James G. Skipworth
发明人： Scott R. Keenan , Amber R. Harach , James G. Skipworth
IPC分类号： C07C49/20 , C07C37/68
CPC分类号： C07C45/53 , C07C37/08 , C07C37/72 , C07C37/74 , C07C37/82 , C07C45/80 , C07C45/82 , C07C39/04
摘要： Products from the decomposition of cumene hydroperoxide (CHP) are recovered by distillation. The majority of the undesirable by-product acetol (hydroxyacetone) is removed from the phenol stream by distillation wherein the majority of the acetol is carried with an overheads stream comprising acetone, cumene and alphamethylstyrene (AMS). Acetol is subsequently separated from acetone by distillation wherein acetone is taken as an overheads stream and acetol remains with a bottoms stream comprising cumene, AMS and phenol. The acetol, along with residual phenol, is extracted from the cumene and AMS by counter-current washing with an aqueous alkali metal hydroxide. The phenol stream is then distilled to separate phenol from cumene, alphamethylstyrene and higher boiling compounds. The phenol, containing only a small amount of acetol, can then be treated to remove methylbenzofuran by treatment with an acidic resin or solid superacid catalyst without formation of significant amounts of additional methylbenzofuran.
摘要翻译：通过蒸馏回收氢过氧化枯烯（CHP）的分解产物。通过蒸馏从苯酚流中除去大部分不合需要的副产物丙酮醇（羟基丙酮），其中大部分丙酮醇与包含丙酮，枯烯和α-甲基苯乙烯（AMS）的塔顶馏出物携带。 Acetol随后通过蒸馏与丙酮分离，其中将丙酮作为塔顶馏出物流，并且丙酮醇与含有异丙基苯，AMS和苯酚的塔底物流保留。通过用碱金属氢氧化物水溶液逆流洗涤，从异丙苯和AMS中提取丙酮醇和残留的苯酚。然后将苯酚流蒸馏以将苯酚与枯烯，α-甲基苯乙烯和较高沸点化合物分离。然后可以用酸性树脂或固体超强酸催化剂处理除苯甲呋喃，只含少量丙酮醇，除去甲基苯并呋喃，不形成显着量的甲基苯并呋喃。

83. 发明授权

US07109385B2 Process for producing phenol 有权
标题翻译：苯酚生产工艺
公开(公告)号：US07109385B2
公开(公告)日：2006-09-19
申请号：US11092078
申请日：2005-03-29
申请人： Prashant Anil Tatake , Pramod Shankar Kumbhar , Bharat Singh , John William Fulmer , Sabyasachi Mandal , Arun N. Kumar , Rupesh Pawar
发明人： Prashant Anil Tatake , Pramod Shankar Kumbhar , Bharat Singh , John William Fulmer , Sabyasachi Mandal , Arun N. Kumar , Rupesh Pawar
IPC分类号： C07C37/08
CPC分类号： C07C37/08 , C07C39/04
摘要： A process for producing a phenol product generally comprises a first step comprising reacting in a first reactor a feed stream comprising cumene hydroperoxide and water with an acid catalyst to produce an effluent comprising the phenol product, acetone, and at least 1% by weight residual cumene hydroperoxide, and a second step comprising passing the effluent into a second reactor and decomposing the residual cumene hydroperoxide, wherein during said process the ratio of phenol to acetone is maintained at a molar ratio of greater than 1:1, and wherein the water in each of the first and second steps is present in an amount more than 0 and less than or equal to 5 weight percent based on the total weight of the feed stream or effluent, and wherein the process is continuous.
摘要翻译：一种生产酚产物的方法通常包括第一步骤，包括在第一反应器中使含有氢过氧化枯烯和水的进料流与酸催化剂反应以产生包含苯酚产物，丙酮和至少1重量％的残余枯烯的流出物氢过氧化物，第二步骤包括使流出物流入第二反应器并分解残留的氢过氧化枯烯，其中在所述方法期间，苯酚与丙酮的比例保持在大于1:1的摩尔比，并且其中每个基于进料流或流出物的总重量，第一步和第二步的存在量大于0且小于或等于5重量％，并且其中该方法是连续的。

84. 发明授权

US07038093B2 Integrated process for the preparation of phenol from benzene with recycling of the by-products 有权
标题翻译：从苯中制备苯酚的副产物回收综合工艺
公开(公告)号：US07038093B2
公开(公告)日：2006-05-02
申请号：US10716460
申请日：2003-11-20
申请人： Daniele Bianchi , Rossella Bortolo , Roberto Buzzoni , Alberto Cesana , Leonardo Dalloro , Rino D'Aloisio
发明人： Daniele Bianchi , Rossella Bortolo , Roberto Buzzoni , Alberto Cesana , Leonardo Dalloro , Rino D'Aloisio
IPC分类号： C07C37/00
CPC分类号： C07C37/60 , B01J29/89 , B01J2229/30 , Y02P20/125 , Y02P20/52 , C07C39/04
摘要： The invention relates to a process for the preparation of phenol comprising the following phases: 1) preparation in continuous of phenol by means of the direct oxidation of benzene with hydrogen peroxide operating with an H2O2/benzene ratio ranging from 10 to 70%, in a three-phase reaction system comprising a first liquid phase consisting of benzene and an organic solvent, a second liquid phase consisting of water, a solid phase consisting of an activated catalyst based on titanium silicalite TS-1; 2) separation of the phenol and non-reacted benzene from the reaction mixture of the oxidation section (1), by means of fractionated distillation; 3) separation of the solvent and by-products from the mixture coming from the distillation tail (2), by means of basic extraction; 4) transformation of the by-products obtain in section (3) to phenol by means of hydrodeoxygenation with hydrogen operating in continuous, in aqueous solution, at a temperature ranging from 250 to 500° C., at pressures of 1-100 bar and in the presence of a catalyst based on elements of group VIB or their mixtures or group VIII of the periodic table or their mixtures; 5) recycling of the phenol obtained in section (4) to the distillation section (2).
摘要翻译：本发明涉及一种制备苯酚的方法，包括以下阶段：1）通过苯与氧化氢的直接氧化制备苯酚连续操作，所述过氧化氢用H 2 O 2 在含有由苯和有机溶剂组成的第一液相的三相反应体系中，第二液相由水组成，固相由活化的基于钛硅沸石TS-1的催化剂; 2）通过分级蒸馏从氧化段（1）的反应混合物中分离苯酚和未反应的苯; 3）通过碱性萃取法从蒸馏尾料（2）中分离出溶剂和副产物与混合物; 4）将第（3）部分获得的副产物转化为苯酚，通过加氢脱氧，氢气在连续的水溶液中，在250-500℃的温度，1-100巴的压力和在基于元素周期表VIB族元素或它们的混合物或VIII族元素或其混合物的催化剂的存在下; 5）将第（4）节中得到的酚再循环至蒸馏段（2）。

85. 发明申请

US20060020047A1 Processes for the production of cumene, polyetherimides, and polycarbonates 有权
标题翻译：枯烯，聚醚酰亚胺和聚碳酸酯的生产方法
公开(公告)号：US20060020047A1
公开(公告)日：2006-01-26
申请号：US10897732
申请日：2004-07-22
申请人： James Wilkerson
发明人： James Wilkerson
IPC分类号： C08G61/02 , C07C27/26
CPC分类号： C07C2/64 , C07C15/085 , C07C37/08 , C07C37/20 , C07C45/53 , C07C409/08 , C08G64/20 , C08G64/24 , C08G64/307 , C08G73/1003 , C08G73/1028 , C07C49/08 , C07C39/04 , C07C39/16 , C07C407/00 , C07C409/10
摘要： A method for the manufacture of polycarbonate by combining methane and inlet water to produce methanol, converting the methanol to propylene, gasoline aromatics, and gasoline olefins, converting the propylene and gasoline olefins to hydrogen, first benzene, and toluene, reacting the first benzene with propylene to form cumene, reacting the cumene with oxygen to form cumene hydroperoxide, cleaving the cumene hydroperoxide to produce acetone and phenol, reacting the phenol, additional phenol, and acetone to produce a dihydric aromatic compound, and reacting the dihydric aromatic compound with a carbonate precursor to form polycarbonate.
摘要翻译：通过将甲烷和入口水结合以生产甲醇，将甲醇转化为丙烯，汽油芳族化合物和汽油烯烃，将丙烯和汽油烯烃转化为氢气，首先是苯和甲苯，制备聚碳酸酯的方法，使第一个苯与丙烯以形成异丙基苯，使异丙基苯与氧反应形成氢过氧化枯烯，裂解氢过氧化枯烯以产生丙酮和苯酚，使苯酚，另外的苯酚和丙酮反应，生成二元芳族化合物，并使二元芳族化合物与碳酸酯反应形成聚碳酸酯的前体。

86. 发明授权

US06972345B2 Extraction of phenol-containing effluent streams 失效
标题翻译：提取含苯酚的流出物流
公开(公告)号：US06972345B2
公开(公告)日：2005-12-06
申请号：US11108237
申请日：2005-04-18
申请人： Ulrich Blaschke , Stefan Westernacher
发明人： Ulrich Blaschke , Stefan Westernacher
IPC分类号： C02F1/04 , C02F1/26 , C02F1/28 , C07C37/72 , C07C37/74 , C07C37/82 , C07C39/16
CPC分类号： C02F1/26 , C02F1/04 , C02F1/283 , C02F2101/345 , C02F2103/36 , C07C37/685 , C07C37/72 , C07C37/74 , C07C37/82 , C07C39/04
摘要： A process for extracting phenol from a phenol-containing aqueous solution is disclosed. The process entails contacting the aqueous solution with an extracting agent that comprise a mixture of 60 to 99% of methyl isobutyl ketone, 1 to 40% of anisole and 0 to 20% of mesitylene.
摘要翻译：公开了一种从含苯酚的水溶液中提取苯酚的方法。该方法使水溶液与包含60-99％的甲基异丁基酮，1至40％的苯甲醚和0至20％的均三甲苯的混合物的萃取剂接触。

87. 发明授权

US06936738B2 Process for the preparation of phenol by means of the hydrodeoxygenation of benzene-diols 有权
标题翻译：通过苯二醇的加氢脱氧制备苯酚的方法
公开(公告)号：US06936738B2
公开(公告)日：2005-08-30
申请号：US10683403
申请日：2003-10-14
申请人： Leonardo Dalloro , Alberto Cesana , Roberto Buzzoni , Franco Rivetti
发明人： Leonardo Dalloro , Alberto Cesana , Roberto Buzzoni , Franco Rivetti
IPC分类号： C07C37/88 , B01J23/28 , B01J23/30 , B01J23/42 , B01J23/60 , B01J23/75 , B01J23/88 , B01J23/881 , B01J23/882 , B01J23/888 , B01J27/188 , C07B61/00 , C07C29/60 , C07C37/00 , C07C39/04 , C07C39/06 , C07C39/00
CPC分类号： B01J23/60 , B01J23/28 , B01J23/30 , B01J23/42 , B01J23/75 , B01J23/881 , B01J23/882 , B01J23/8885 , B01J27/188 , C07C37/00 , Y02P20/52 , C07C39/04
摘要： A process is described for the preparation of phenol characterized in that the phenol is obtained by means of the hydrodeoxygenation of benzene-diols with hydrogen, operating in continuous, in an aqueous solution, at temperatures ranging from 250 to 500° C., at pressures of 1-100 bar and in the presence of a catalyst based on elements of group VIB or group VIII of the periodic table.
摘要翻译：描述了一种用于制备苯酚的方法，其特征在于通过苯二醇与氢在水溶液中在250-500℃的温度下在压力下连续操作，在氢气中进行加氢脱氧，得到苯酚。在基于元素周期表VIB族或VIII族元素的催化剂的存在下进行。

88. 发明申请

US20040158106A1 Method of purifying phenol 失效
标题翻译：酚的纯化方法
公开(公告)号：US20040158106A1
公开(公告)日：2004-08-12
申请号：US10762027
申请日：2004-01-21
发明人： Larry Wayne Payne
IPC分类号： C07C029/74
CPC分类号： C07C37/86 , Y02P20/52 , C07C39/04
摘要： A method of purifying a phenol stream that contains a concentration of a contaminating compound is provided. The phenol stream is treated or purified by contacting the stream, under suitable process conditions, with a treatment catalyst that has a low silica content but comprises alumina and a Group VIA metal.
摘要翻译：提供了一种纯化含有污染化合物浓度的苯酚流的方法。通过在合适的工艺条件下使料流与具有低二氧化硅含量但包含氧化铝和VIA族金属的处理催化剂接触来处理或纯化苯酚流。

89. 发明申请

US20040158105A1 Method of making high purity phenol 失效
标题翻译：制备高纯度苯酚的方法
公开(公告)号：US20040158105A1
公开(公告)日：2004-08-12
申请号：US10761591
申请日：2004-01-21
发明人： Larry Wayne Payne
IPC分类号： C07C029/74
CPC分类号： C07C37/86 , C07C37/08 , C07C39/04
摘要： A method of manufacturing a phenol product having a reduced concentration of a contaminating reaction by-product. The method includes contacting a phenol stream, having a concentration of the contaminating by-product, by contacting the phenol stream with an acidic catalyst under suitable purification reaction conditions. Also included is a composition comprising a sec-butyl benzene derived phenol product that has been purified by the removal of certain undesirable reaction by-products.
摘要翻译：一种制造具有降低的污染反应副产物浓度的苯酚产物的方法。该方法包括在合适的纯化反应条件下使苯酚流与酸性催化剂接触，使苯酚流具有污染副产物的浓度。还包括一种组合物，其包含通过除去某些不希望的反应副产物而被纯化的仲丁基苯衍生的苯酚产物。

90. 发明申请

US20040110995A1 Reaction method utilizing diaphram type catalyst and apparatus therefor 有权
标题翻译：利用二价型催化剂的反应方法及其设备
公开(公告)号：US20040110995A1
公开(公告)日：2004-06-10
申请号：US10451624
申请日：2003-12-10
发明人： Fujio Mizukami , Shuichi Niwa , Makoto Toba , Naotsugu Itoh , Tomonari Saito , Takemi Nanba , Hiroshi Shoji , Kazuhiko Haba
IPC分类号： C07C027/00
CPC分类号： C07D213/63 , B01J8/009 , B01J10/007 , B01J12/007 , B01J14/005 , B01J19/2475 , B01J23/44 , B01J35/065 , B01J2219/00063 , B01J2219/00094 , B01J2219/00099 , C07C29/50 , C07C37/58 , C07C37/60 , C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C45/40 , C07C2601/14 , Y02P20/52 , C07C49/08 , C07C47/22 , C07C35/08 , C07C39/04 , C07C39/07 , C07C39/14 , C07C35/36
摘要： A method for carrying out a reaction of one substance capable of being activated by a catalyst with another substance capable of reacting with said one substance activated, characterized in that the substance capable of being activated is activated by passing the substance through a diaphragm type catalyst and the reaction is thus performed in one reaction step; a method for producing an aromatic alcohol utilizing the above method; and a reaction apparatus suitable for these reactions. In the method, one substance is activated by passing through a diaphragm type catalyst and an objective reaction is carried out by using the activated substance, and the reaction can be performed in one reaction step and with safety. Moreover, the contact of the above activated substance with a compound to be reacted therewith can be freely controlled, and therefore, over-reaction can be prevented and an objective product can be produced in high yield. The method is thus markedly advantageous from an economical view point as a commercial process for producing oxygen-containing organic compounds such as an aromatic alcohol, a ketone, an aldehyde, a carboxylic acid and an epoxide.
摘要翻译：一种能够使一种能够被催化剂活化的物质与能够与所述一种活化物质反应的物质进行反应的方法，其特征在于，通过使该物质通过隔膜型催化剂而活化，因此在一个反应步骤中进行反应; 利用上述方法制备芳族醇的方法; 和适用于这些反应的反应装置。在该方法中，通过隔膜型催化剂活化一种物质，并通过使用活性物质进行目标反应，反应可以在一个反应步骤和安全性下进行。此外，可以自由地控制上述活性物质与其反应的化合物的接触，因此可以防止过度反应，并且可以高产率制备目标产物。因此，作为用于生产含氧有机化合物如芳族醇，酮，醛，羧酸和环氧化物的商业方法，从经济角度看，该方法显着是有利的。

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