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    • 81. 发明申请
    • Apparatus for producing group III element nitride semiconductor and method for producing the semiconductor
    • III族元素氮化物半导体的制造装置及其制造方法
    • US20090126623A1
    • 2009-05-21
    • US12289739
    • 2008-11-03
    • Shiro Yamazaki
    • Shiro Yamazaki
    • C30B19/08
    • C30B29/403C30B19/02C30B19/062Y10T117/1024
    • The present invention provides an apparatus for producing a Group III nitride semiconductor, which enables production of a uniform Si-doped GaN crystal. In one embodiment of the invention, an apparatus for producing a Group III nitride semiconductor includes a supply tube for supplying nitrogen and silane, a Ga-supplying apparatus for supplying Ga melt to a crucible, and an Na-supplying apparatus for supplying Na melt to the crucible. Nitrogen and a dopant is mixed together, and the gas mixture is supplied through one single supply tube without provision of a conventionally employed supply tube for only supplying a dopant. Thus, dead space in a reaction vessel is reduced, and vaporization of Na is suppressed, whereby a high-quality, Si-doped GaN crystal can be produced.
    • 本发明提供一种用于制造III族氮化物半导体的装置,其能够生产均匀的Si掺杂的GaN晶体。 在本发明的一个实施例中,用于制造III族氮化物半导体的装置包括供氮和硅烷的供应管,用于向坩埚供应Ga熔体的Ga供应装置,以及供应Na熔体的Na供应装置 坩埚。 将氮和掺杂剂混合在一起,并且气体混合物通过一个单独的供应管供应,而不需要仅供给掺杂剂的常规使用的供应管。 因此,反应容器中的死空间减小,并且Na的蒸发被抑制,由此可以生产出高品质的Si掺杂的GaN晶体。
    • 84. 发明授权
    • Light-emitting semiconductor device using gallium nitride group compound
    • 使用氮化镓族化合物的发光半导体装置
    • US06362017B1
    • 2002-03-26
    • US09586607
    • 2000-06-02
    • Katsuhide ManabeAkira MabuchiHisaki KatoMichinari SassaNorikatsu KoideShiro YamazakiMasafumi HashimotoIsamu Akasaki
    • Katsuhide ManabeAkira MabuchiHisaki KatoMichinari SassaNorikatsu KoideShiro YamazakiMasafumi HashimotoIsamu Akasaki
    • H01L2100
    • H01L33/32H01L33/007H01L33/025
    • Disclosed herein are (1) a light-emitting semiconductor device that uses a gallium nitride compound semiconductor (AlxGa1−xN) in which the n-layer of n-type gallium nitride compound semiconductor (AlxGa1−xN) is of double-layer structure including an n-layer of low carrier concentration and an n+-layer of high carrier concentration, the former being adjacent to the i-layer of insulating gallium nitride compound semiconductor (AlxGa1−xN); (2) a light-emitting semiconductor device of similar structure as above in which the i-layer is of double-layer structure including an iL-layer of low impurity concentration containing p-type impurities in comparatively low concentration and an iH-layer of high impurity concentration containing p-type impurities in comparatively high concentration, the former being adjacent to the n-layer; (3) a light-emitting semiconductor device having both of the above-mentioned features and (4) a method of producing a layer of an n-type gallium nitride compound semiconductor (AlxGa1−xN) having a controlled conductivity from an organometallic compound by vapor phase epitaxy, by feeding a silicon-containing gas and other raw material gases together at a controlled mixing ratio.
    • 这里公开的是(1)使用其中n型氮化镓化合物半导体(Al x Ga 1-x N)的n层是双层结构的氮化镓化合物半导体(Al x Ga 1-x N)的发光半导体器件,包括 低载流子浓度的n层和高载流子浓度的n +层,前者与绝缘的氮化镓化合物半导体(Al x Ga 1-x N)的i层相邻; (2)具有上述类似结构的发光半导体器件,其中i层是双层结构,其包括含有较低浓度的p型杂质的低杂质浓度的iL层和iH层 含有较高浓度的p型杂质的高杂质浓度,前者与n层相邻; (3)具有上述特征的发光半导体器件和(4)由有机金属化合物具有受控导电性的n型氮化镓系化合物半导体(Al x Ga 1-x N)的层的制造方法, 通过以受控的混合比将含硅气体和其它原料气体一起供给到气相外延。
    • 85. 发明授权
    • Effervescent granular preparation for keeping cut flower freshness
    • 用于保持切花新鲜度的泡腾颗粒制剂
    • US6083535A
    • 2000-07-04
    • US930995
    • 1997-12-29
    • Tadahiko ChibaShiro YamazakiToshihide Saishoji
    • Tadahiko ChibaShiro YamazakiToshihide Saishoji
    • A01N3/02A01N43/653A61K9/14
    • A01N3/02A01N43/653
    • An effervescent granular preparation for keeping cut flower freshness includes an azole-substituted cyclopentanol derivative represented by formula (I) (set forth below) and 2-bromo-2-nitro-1, 3-propanediol as effective components and to a process for producing the same. The effervescent granular preparation is produced by granulation of a mixture containing at least one of glucose, D-mannitol and sucrose as an excipient by incorporating an organic acid such as citric acid or malic acid and a hydrogen carbonate such as sodium hydrogen carbonate. ##STR1## wherein A represents a nitrogen atom or a CH group, R.sup.1 and R.sup.2 represent each independently a hydrogen or a C.sub.1 -C.sub.3 alkyl group, and X represents a hydrogen atom or a halogen atom.
    • PCT No.PCT / JP96 / 00445 Sec。 371日期1997年12月29日第 102(e)日期1997年12月29日PCT提交1996年2月27日PCT公布。 出版物WO96 / 32012 PCT 日期1996年10月17日用于保持切花新鲜度的泡腾颗粒制剂包括由式(I)表示的唑类取代的环戊醇衍生物(下文)和作为有效成分的2-溴-2-硝基-1,3-丙二醇, 涉及其制造方法。 通过掺入有机酸如柠檬酸或苹果酸和碳酸氢钠如碳酸氢钠,通过造粒含有葡萄糖,D-甘露糖醇和蔗糖中的至少一种作为赋形剂的混合物来制备泡腾颗粒制剂。 其中A表示氮原子或CH基团,R 1和R 2各自独立地表示氢或C 1 -C 3烷基,X表示氢原子或卤素原子。
    • 88. 发明授权
    • Herbicidal composition containing a derivative of 1,2,4-triazole as an
active ingredient
    • 含有1,2,4-三唑衍生物作为活性成分的除草组合物
    • US4795484A
    • 1989-01-03
    • US858531
    • 1986-04-24
    • Katsumichi AokiTakafumi ShidaTakeo WatanabeKeigo SatakeHiroyasu ShinkawaShiro Yamazaki
    • Katsumichi AokiTakafumi ShidaTakeo WatanabeKeigo SatakeHiroyasu ShinkawaShiro Yamazaki
    • A01N43/653C07D249/10
    • A01N43/653C07D249/10
    • Disclosed herein is herbicidal composition comprising a derivative of 1,2,4-triazole as an active ingredient, represented by the general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom, a halogen atom or a C.sub.1 -C.sub.2) alkyl group; R.sup.2 represents a hydrogen atom, a halogen atom, a (C.sub.1 -C.sub.2) alkyl group fluoromethyl group (--CH.sub.2 F),3,3,3-trifluoropopyl group, methoxy group, cyano group, methoxymethyl group, methylthio group, methoxycarbonyl group or isopropoxycarbonyl group and R.sup.3 represents a thiocarbamoyl group or a group represented by the general formula (II): ##STR2## wherein R.sup.4 represents a hydrogen atom, a (C.sub.1 -C.sub.2) alkyl group or a hydroxy (C.sub.1 -C.sub.2) alkyl group and R.sup.5 represents a hydrogen atom, a C.sub.1 -C.sub.2) alkyl group, halogeno (C.sub.1 -C.sub.2) alkyl group, hydroxy (C.sub.1 -C.sub.2) alkyl group, cyanomethyl group, acetyl group, halogenoacetyl group, methoxyacetyl group, amino group, phenyl group, methoxy group, hydroxyl group, (C.sub.2 -C.sub.3) alkenyl group, halogeno (C.sub.2 -C.sub.3) alkenyl group, isopropylcarbonyl group, methylthiocarbamoyl group or 2-methoxyethyl group, the proviso that R.sup.2 is not a hydrogen atom, halogen atom or (C.sub.1 -C.sub.2) alkyl group when both of R.sup.4 and R.sup.5 represent hydrogen atoms, and herbicidally acceptable carrier(s) or diluent(s).
    • 本文公开了包含由通式(I)表示的1,2,4-三唑衍生物作为活性成分的除草组合物:其中R1表示氢原子,卤素原子或C1- C2)烷基; R2表示氢原子,卤素原子,(C1-C2)烷基氟甲基(-CH2F),3,3,3-三氟戊酰基,甲氧基,氰基,甲氧基甲基,甲硫基,甲氧基羰基或异丙氧基羰基 基团,R 3表示硫代氨基甲酰基或由通式(II)表示的基团:其中R 4表示氢原子,(C 1 -C 2)烷基或羟基(C 1 -C 2)烷基) R5为氢原子,C1-C2)烷基,卤代(C1-C2)烷基,羟基(C1-C2)烷基,氰基甲基,乙酰基,卤代乙酰基,甲氧基乙酰基,氨基,苯基 ,甲氧基,羟基,(C2-C3)烯基,卤代(C2-C3)烯基,异丙基羰基,甲硫基氨基甲酰基或2-甲氧基乙基,条件是R2不是氢原子,卤素原子或(C1 -C 2)烷基,当R4和R5都表示氢原子,除草可接受的载体或稀释剂( s)。