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1. 发明授权

US4795484A Herbicidal composition containing a derivative of 1,2,4-triazole as an active ingredient 失效
标题翻译：含有1,2,4-三唑衍生物作为活性成分的除草组合物
公开(公告)号：US4795484A
公开(公告)日：1989-01-03
申请号：US858531
申请日：1986-04-24
申请人： Katsumichi Aoki , Takafumi Shida , Takeo Watanabe , Keigo Satake , Hiroyasu Shinkawa , Shiro Yamazaki
发明人： Katsumichi Aoki , Takafumi Shida , Takeo Watanabe , Keigo Satake , Hiroyasu Shinkawa , Shiro Yamazaki
IPC分类号： A01N43/653 , C07D249/10
CPC分类号： A01N43/653 , C07D249/10
摘要： Disclosed herein is herbicidal composition comprising a derivative of 1,2,4-triazole as an active ingredient, represented by the general formula (I): ##STR1## wherein R.sup.1 represents a hydrogen atom, a halogen atom or a C.sub.1 -C.sub.2) alkyl group; R.sup.2 represents a hydrogen atom, a halogen atom, a (C.sub.1 -C.sub.2) alkyl group fluoromethyl group (--CH.sub.2 F),3,3,3-trifluoropopyl group, methoxy group, cyano group, methoxymethyl group, methylthio group, methoxycarbonyl group or isopropoxycarbonyl group and R.sup.3 represents a thiocarbamoyl group or a group represented by the general formula (II): ##STR2## wherein R.sup.4 represents a hydrogen atom, a (C.sub.1 -C.sub.2) alkyl group or a hydroxy (C.sub.1 -C.sub.2) alkyl group and R.sup.5 represents a hydrogen atom, a C.sub.1 -C.sub.2) alkyl group, halogeno (C.sub.1 -C.sub.2) alkyl group, hydroxy (C.sub.1 -C.sub.2) alkyl group, cyanomethyl group, acetyl group, halogenoacetyl group, methoxyacetyl group, amino group, phenyl group, methoxy group, hydroxyl group, (C.sub.2 -C.sub.3) alkenyl group, halogeno (C.sub.2 -C.sub.3) alkenyl group, isopropylcarbonyl group, methylthiocarbamoyl group or 2-methoxyethyl group, the proviso that R.sup.2 is not a hydrogen atom, halogen atom or (C.sub.1 -C.sub.2) alkyl group when both of R.sup.4 and R.sup.5 represent hydrogen atoms, and herbicidally acceptable carrier(s) or diluent(s).
摘要翻译：本文公开了包含由通式（I）表示的1,2,4-三唑衍生物作为活性成分的除草组合物：其中R1表示氢原子，卤素原子或C1- C2）烷基; R2表示氢原子，卤素原子，（C1-C2）烷基氟甲基（-CH2F），3,3,3-三氟戊酰基，甲氧基，氰基，甲氧基甲基，甲硫基，甲氧基羰基或异丙氧基羰基基团，R 3表示硫代氨基甲酰基或由通式（II）表示的基团：其中R 4表示氢原子，（C 1 -C 2）烷基或羟基（C 1 -C 2）烷基） R5为氢原子，C1-C2）烷基，卤代（C1-C2）烷基，羟基（C1-C2）烷基，氰基甲基，乙酰基，卤代乙酰基，甲氧基乙酰基，氨基，苯基，甲氧基，羟基，（C2-C3）烯基，卤代（C2-C3）烯基，异丙基羰基，甲硫基氨基甲酰基或2-甲氧基乙基，条件是R2不是氢原子，卤素原子或（C1 -C 2）烷基，当R4和R5都表示氢原子，除草可接受的载体或稀释剂（ s）。

2. 发明授权

US4624697A Derivatives of tetrahydrobenzothiazole and herbicidal compositions containing the same as an active ingredient 失效
标题翻译：四氢苯并噻唑的衍生物和含有其作为活性成分的除草组合物
公开(公告)号：US4624697A
公开(公告)日：1986-11-25
申请号：US597451
申请日：1984-04-06
申请人： Katsumichi Aoki , Takafumi Shida , Hideo Arabori , Satoru Kumazawa , Susumu Shimizu , Takeo Watanabe , Yohichi Kanda , Keigo Satake , Shiro Yamazaki , Hiroyasu Shinkawa , Tsuneaki Chida
发明人： Katsumichi Aoki , Takafumi Shida , Hideo Arabori , Satoru Kumazawa , Susumu Shimizu , Takeo Watanabe , Yohichi Kanda , Keigo Satake , Shiro Yamazaki , Hiroyasu Shinkawa , Tsuneaki Chida
IPC分类号： A01N43/78 , A01N43/82 , C07D233/00 , C07D271/00 , C07D277/00 , C07D417/04
CPC分类号： C07D417/04 , A01N43/78 , A01N43/82
摘要： Disclosed herein are a derivative of tetrahydrobenzothiazole represented by the formula (I): ##STR1## wherein R represents a methyl group, ethyl group or propyl group; R.sup.1 represents a hydrogen atom, a hydroxyl group methoxy group, acetoxy group, propionyloxy group, butylyloxy group, chloroacetoxy group, methoxyacetoxy group, C.sub.1 to C.sub.4 -alkylamino group or di(C.sub.1 to C.sub.4)-alkylamino group, or represents O.dbd.together with R.sup.2 ; R.sup.2 represents a hydrogen atom or represents O.dbd.together with R.sup.1 ; and X represents a methylene group, hydroxymethylene group, carbonyl group or --O--, and a herbicidal composition containing the same as an active ingredient.
摘要翻译：本文公开了由式（I）表示的四氢苯并噻唑的衍生物：其中R表示甲基，乙基或丙基; R1表示氢原子，羟基甲氧基，乙酰氧基，丙酰氧基，丁酰氧基，氯乙酰氧基，甲氧基乙酰氧基，C1〜C4烷基氨基或二（C1〜C4） - 烷基氨基，或表示O = R2; R2代表氢原子或代表O =与R1一起; X表示亚甲基，羟基亚甲基，羰基或-O-，以及含有该活性成分的除草组合物。

3. 发明授权

US4549902A Salts of derivatives of N-(tetrahydrobenzothiazolylcarbamoyl)oxamic acid and herbicidal composition containing the same as active ingredient 失效
标题翻译： N-（四氢苯并噻唑基氨基甲酰基）恶唑酸的衍生物的盐和含有活性成分的除草组合物的盐
公开(公告)号：US4549902A
公开(公告)日：1985-10-29
申请号：US597269
申请日：1984-04-06
申请人： Katsumichi Aoki , Takafumi Shida , Hideo Arabori , Satoru Kumazawa , Susumu Shimizu , Takeo Watanabe , Yohichi Kanda , Keigo Satake , Shiro Yamazaki , Hiroyasu Shinkawa , Tsuneaki Chida
发明人： Katsumichi Aoki , Takafumi Shida , Hideo Arabori , Satoru Kumazawa , Susumu Shimizu , Takeo Watanabe , Yohichi Kanda , Keigo Satake , Shiro Yamazaki , Hiroyasu Shinkawa , Tsuneaki Chida
IPC分类号： A01N47/36 , C07D277/82
CPC分类号： A01N47/36 , C07D277/82
摘要： Disclosed herein are a salt of a derivative of N-(tetrahydrobenzothiazolylcarbamoyl)oxamic acid, represented by the formula: ##STR1## wherein R.sup.1 represents a straight-chain alkyl group having one to six carbon atoms, branched-chain alkyl group having up to and including six carbon atoms, cyclic alkyl group having up to and including six carbon atoms or a phenyl group; R.sup.2 represents a hydrogen atom or a methyl group; M represents an alkali metal atom or an alkaline earth metal atom; n is 1 when M is an alkali metal atom and n is 1/2 when M is an alkaline earth metal atom and M' is a hydrogen atom or the same as M, and a herbicidal composition containing the same as an active ingredient.
摘要翻译：本文公开了由下式表示的N-（四氢苯并噻唑基氨基甲酰基）氧杂恶唑酸的衍生物的盐：其中R 1表示具有1至6个碳原子的直链烷基，支链烷基具有直到并包括6个碳原子，具有至多且包括6个碳原子的环状烷基或苯基; R2表示氢原子或甲基; M表示碱金属原子或碱土金属原子; 当M为碱金属原子时，n为1，当M为碱土金属原子且M为氢原子或与M相同时，n为1/2，和含有该活性成分的除草组合物。

4. 发明授权

US4551168A Herbicidal 2-(1,3,5-1H-triazin-2-one)-tetrahydrobenzothiazole derivatives, and compositions therefor 失效
标题翻译：除草剂2-（1,3,5-1H-三嗪-2-酮） - 四氢苯并噻唑衍生物及其组合物
公开(公告)号：US4551168A
公开(公告)日：1985-11-05
申请号：US596928
申请日：1984-04-05
申请人： Katsumichi Aoki , Takafumi Shida , Satoru Kumazawa , Susumu Shimizu , Yohichi Kanda , Keigo Satake , Shiro Yamazaki , Hiroyasu Shinkawa , Tsuneaki Chida , Hideo Arabori , Takeo Watanabe
发明人： Katsumichi Aoki , Takafumi Shida , Satoru Kumazawa , Susumu Shimizu , Yohichi Kanda , Keigo Satake , Shiro Yamazaki , Hiroyasu Shinkawa , Tsuneaki Chida , Hideo Arabori , Takeo Watanabe
IPC分类号： A01N43/78 , C07D417/04 , A01N43/64
CPC分类号： C07D417/04 , A01N43/78
摘要： Disclosed herein are a derivative of tetrahydrobenzothiazole represented by the formula (I): ##STR1## wherein R.sup.1 and R.sup.2 represent respectively a straight chain alkyl group having 1 to 6 carbon atoms or a branched chain alkyl group having 1 to 6 carbon atoms, and a herbicidal composition containing the same as an active ingredient.
摘要翻译：本文公开了由式（I）表示的四氢苯并噻唑的衍生物：其中R 1和R 2分别代表具有1至6个碳原子的直链烷基或具有1至6个碳原子的支链烷基，以及含有该活性成分的除草组合物。

5. 发明授权

US4561877A Derivatives of tetrahydrobenzothiazole and herbicidal compositions containing the same as active ingredient 失效
标题翻译：四氢苯并噻唑的衍生物和含有与活性成分相同的除草组合物
公开(公告)号：US4561877A
公开(公告)日：1985-12-31
申请号：US596927
申请日：1984-04-05
申请人： Katsumichi Aoki , Takafumi Shida , Hideo Arabori , Satoru Kumazawa , Susumu Shimizu , Takeo Watanabe , Yohichi Kanda , Keigo Satake , Shiro Yamazaki , Hiroyasu Shinkawa , Tsuneaki Chida
发明人： Katsumichi Aoki , Takafumi Shida , Hideo Arabori , Satoru Kumazawa , Susumu Shimizu , Takeo Watanabe , Yohichi Kanda , Keigo Satake , Shiro Yamazaki , Hiroyasu Shinkawa , Tsuneaki Chida
IPC分类号： A01N43/78 , A01N43/88 , C07D417/04 , A01N43/54 , A01N43/66
CPC分类号： C07D417/04 , A01N43/78 , A01N43/88
摘要： Disclosed herein are a derivative of tetrahydrobenzothiazole represented by the formula (I): ##STR1## wherein R represents a hydrogen atom, a hydroxyl group or a lower acyloxy group such as acetoxy group and propionyloxy group and X represents a methylene group, C.sub.1 to C.sub.4 -alkylamino group, benzylamino group or --O--, and a herbicidal composition containing the same as an active ingredient.
摘要翻译：本文公开的是由式（I）表示的四氢苯并噻唑的衍生物：其中R表示氢原子，羟基或低级酰氧基如乙酰氧基和丙酰氧基，X表示亚甲基， C1〜C4烷基氨基，苄基氨基或-O-，以及含有该活性成分的除草组合物。

6. 发明授权

US4902805A Derivatives of dihydrotriazole, and herbicidal compositions containing the same as an active ingredient 失效
标题翻译：二氢三唑衍生物和含有其作为活性成分的除草组合物
公开(公告)号：US4902805A
公开(公告)日：1990-02-20
申请号：US820948
申请日：1986-01-21
申请人： Takafumi Shida , Takeo Watanabe , Shiro Yamazaki , Hiroyasu Shinkawa , Keigo Satake
发明人： Takafumi Shida , Takeo Watanabe , Shiro Yamazaki , Hiroyasu Shinkawa , Keigo Satake
IPC分类号： A01N43/653 , C07D249/10 , C07D405/04
CPC分类号： C07D405/04 , A01N43/653 , C07D249/10
摘要： Disclosed herein are a derivative of dihydrotriazole represented by the general formula (I): ##STR1## wherein R.sup.1 represents an amino group, lower alkoxy group, or lower alkyl amino group, R.sup.2 represents a hydrogen atom, halogen atom, or lower alkyl group and R.sup.3 represents a hydrogen atom, lower alkyl group, benzyl group, furyl group, phenyl group or phenyl group substituted with a halogen atom, hydroxyl group, carboxyl group, methoxycarbonyl group, lower alkyl group or lower alkoxy group, and a herbicidal composition containing as an active ingredient at least one of the derivatives of dihydrotriazole.
摘要翻译：本文公开了由通式（I）表示的二氢三唑衍生物：其中R 1表示氨基，低级烷氧基或低级烷基氨基，R 2表示氢原子，卤原子或低级烷基，R 3表示氢原子，低级烷基，苄基，呋喃基，苯基或被卤素原子，羟基，羧基，甲氧基羰基，低级烷基或低级烷氧基取代的苯基，除草组合物，其含有作为活性成分的二氢三唑衍生物中的至少一种。

7. 发明授权

US4973353A 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide derivatives and herbicidal composition containing the same 失效
标题翻译： 1,5-二苯基-1H-1,2,4-三唑-3-甲酰胺衍生物和含有它们的除草组合物
公开(公告)号：US4973353A
公开(公告)日：1990-11-27
申请号：US162699
申请日：1988-03-01
申请人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Yoshikazu Kubota , Isao Ichinose , Yoichi Kanda , Shiro Yamazaki , Hiroyasu Shinkawa
发明人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Yoshikazu Kubota , Isao Ichinose , Yoichi Kanda , Shiro Yamazaki , Hiroyasu Shinkawa
IPC分类号： A01N43/653 , C07C205/34 , C07C205/35 , C07C217/76 , C07D249/10
CPC分类号： C07C205/34 , A01N43/653 , C07C205/35 , C07C217/76 , C07D249/10
摘要： Disclosed herein is a derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the formula (I): ##STR1## wherein R is a straight-chain alkyl group having 1 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a branched alkyl group having 3 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a cyclic alkyl group having 3 to 10 carbon atoms, an alkyl group having 1 to 3 carbon atoms which is substituted with an alicyclic structure having 3 to 7 carbon atoms, a phenyl group or an aralkyl group having 7 to 9 carbon atoms; X.sup.1 is a halogen or an alkyl group having 1 to 3 carbon atoms; X.sup.2 is a hydrogen, a halogen or an alkyl group having 1 to 3 carbon atoms; Y.sup.1 is a hydrogen or a fluorine; and Y.sup.2 is a hydrogen or a fluorine, and the herbicidal compositions containing said derivatives as active ingredient therefor.The derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the formula (I) of the present invention is the compound having high herbicidal activity and also showing excellent selectivity for killing weeds alone without doing any serious harm to the crops such as rice, wheat and corn.

8. 发明授权

US5130475A Derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide, herbicidal compositions containing the derivative and process for producing the derivative 失效
标题翻译： 1,5-二苯基-1H-1,2,4-三唑-3-羧酰胺的衍生物，含有衍生物的除草剂组合物和用于生产衍生物的方法
公开(公告)号：US5130475A
公开(公告)日：1992-07-14
申请号：US798007
申请日：1991-11-26
申请人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Shiro Yamazaki , Hiroyasu Shinkawa
发明人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Shiro Yamazaki , Hiroyasu Shinkawa
IPC分类号： A01N43/653 , C07C65/21 , C07C67/14 , C07C69/734 , C07C235/42 , C07D249/10 , C07D263/42 , C07D263/48
CPC分类号： C07C65/21 , A01N43/653 , C07D249/10 , C07D263/48
摘要： Disclosed herein is a derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the following formula (I): ##STR1## wherein R represents an alkyl group of 2 to 10 carbon atoms, which is substituted by fluorine atom(s), and X represents a hydrogen atom or a fluorine atom, a process for producing the derivative and a herbicidal compositions containing the derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide as an active ingredient.

9. 发明授权

US5094684A Derivative of 1,5-diphenyl-1H-1,2-triazole-3-carboxamide, herbicidal compositions containing the derivative and process for producing the derivative 失效
标题翻译： 1,5-二苯基-1H-1,2-三唑-3-羧酰胺的衍生物，含有衍生物的除草剂组合物和用于生产衍生物的方法
公开(公告)号：US5094684A
公开(公告)日：1992-03-10
申请号：US554986
申请日：1990-07-17
申请人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Shiro Yamazaki , Hiroyasu Shinkawa
发明人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Shiro Yamazaki , Hiroyasu Shinkawa
IPC分类号： A01N43/653 , C07C65/21 , C07C67/14 , C07C69/734 , C07C235/42 , C07D249/10 , C07D263/42 , C07D263/48
CPC分类号： C07C65/21 , A01N43/653 , C07D249/10 , C07D263/48
摘要： Disclosed herein is a derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide represented by the following formula (I): ##STR1## wherein R represents an alkyl group of 2 to 10 carbon atoms, which is substituted by fluorine atom(s), and X represents a hydrogen atom or a fluorine atom, a process for producing the derivative and herbicidal compositions containing the derivative of 1,5-diphenyl-1H-1,2,4-triazole-3-carboxamide as an active ingredient.

10. 发明授权

US5162583A Benzylether derivatives 失效
标题翻译：苄醚衍生物
公开(公告)号：US5162583A
公开(公告)日：1992-11-10
申请号：US588996
申请日：1990-09-27
申请人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Yoshikazu Kubota , Isao Ichinose , Yoichi Kanda , Shiro Yamazaki , Hiroyasu Shinkawa
发明人： Takafumi Shida , Hideo Arabori , Takeo Watanabe , Yoshikazu Kubota , Isao Ichinose , Yoichi Kanda , Shiro Yamazaki , Hiroyasu Shinkawa
IPC分类号： A01N43/653 , C07C201/12 , C07C205/33 , C07C205/34 , C07C205/35 , C07C217/76 , C07D249/10
CPC分类号： A01N43/653 , C07C205/33 , C07C205/34 , C07C205/35 , C07C217/76 , C07D249/10
摘要： Disclosed herein are the derivative of benzyl ether represented by the formula (I) ##STR1## which is useful as an intermediate compound of the derivatives of 1,5-diphenyl-1H-1,2,4- triazole-3-carboxamide represented by the formula (II), ##STR2## wherein R is a straight-chain alkyl group having 1 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a branched alkyl group having 3 to 10 carbon atoms which is non-substituted or substituted with 1 to 19 fluorine atoms, a cyclic alkyl group having 3 to 10 carbon atoms, an alkyl group having 1 to 3 carbon atoms which is substituted with an alicyclic structure having 3 to 7 carbon atoms, a phenyl group or an aralkyl group having 7 to 9 carbon atoms; X.sup.1 is a halogen or an alkyl group having 1 to 3 carbon atoms; X.sup.2 is a hydrogen, a halogen or an alkyl group having 1 to 3 carbon atoms; Y.sup.1 is a hydrogen or a fluorine; Y.sup.2 is a hydrogen or a fluorine; and Z is a nitro group or an amino group.
摘要翻译：本文公开了由式（I）表示的苄基醚衍生物，其可用作1,5-二苯基-1H-1,2,4-三唑-3-基的衍生物的中间体化合物，由式（II）表示的羧酰胺，其中R是未取代或被1〜19个氟原子取代的碳原子数为1〜10的直链烷基，具有3个未取代或被1〜19个氟原子取代的10个碳原子，碳原子数3〜10的环状烷基，碳原子数1〜3的被碳数3〜7的脂环结构取代的烷基原子，苯基或碳原子数为7〜9的芳烷基; X1是卤素或具有1至3个碳原子的烷基; X 2是氢，卤素或具有1至3个碳原子的烷基; Y1是氢或氟; Y2是氢或氟; Z为硝基或氨基。

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