专利快速检索-快速检索全球专利，免费商用专利数据库-IPRDB

81. 发明授权

US4075231A Process for preparing phthalic anhydride 失效
公开(公告)号：US4075231A
公开(公告)日：1978-02-21
申请号：US741174
申请日：1976-11-12
申请人： Serge R. Dolhyj , Ernest C. Milberger , James F. White
发明人： Serge R. Dolhyj , Ernest C. Milberger , James F. White
IPC分类号： B01J23/22 , B01J23/24 , B01J23/34 , B01J23/68 , B01J23/84 , B01J23/847 , C07C51/265 , C07D307/89
CPC分类号： B01J23/8472 , B01J23/22 , B01J23/24 , B01J23/34 , B01J23/682 , B01J23/84 , C07C51/265
摘要： Phthalic anhydride is prepared by the oxidation of ortho-xylene with molecular oxygen at a temperature of about 200.degree. to about 600.degree. C. in the presence of an oxidation catalyst that comprises an essentially inert support having a strongly-adhering coat of a catalytic composition containing an oxide of vanadium wherein the concentration of vanadium is less than 10%.

82. 发明授权

US4072708A Process for the preparation of unsaturated acids from unsaturated aldehydes 失效
标题翻译：从不饱和醛制备不饱和酸的方法
公开(公告)号：US4072708A
公开(公告)日：1978-02-07
申请号：US764127
申请日：1977-01-31
申请人： James F. White , Wilfrid G. Shaw , Michael D. Applequist
发明人： James F. White , Wilfrid G. Shaw , Michael D. Applequist
IPC分类号： B01J23/28 , B01J23/54 , B01J23/88 , B01J23/887 , B01J23/89 , B01J27/19 , C07C51/25 , C07C57/055 , C07C51/32
CPC分类号： B01J23/8872 , B01J23/28 , B01J23/54 , B01J23/887 , B01J23/8871 , B01J23/8876 , B01J23/8933 , B01J23/8993 , B01J27/19 , C07C51/252 , B01J2523/00
摘要： Methacrylic acid or acrylic acid are produced by the oxidation of methacrolein or acrolein, respectively, with molecular oxygen in the vapor phase in the presence of a catalytic oxide of molybdenum, phosphorus, arsenic, a rare earth element or mixture thereof, oxygen, and optionally, at least one of Ag, Tl, Rh, Pd, Ru, Pt, Cd, Al, Au, Cu, alkaline earth metal, Cl, and NH.sub.4.
摘要翻译：在钼，磷，砷，稀土元素或其混合物，氧气和任选的催化氧化物的存在下，分别用气相中的分子氧氧化异丁烯醛或丙烯醛来生产甲基丙烯酸或丙烯酸，Ag，Tl，Rh，Pd，Ru，Pt，Cd，Al，Au，Cu，碱土金属，Cl和NH4中的至少一种。

83. 发明授权

US4038324A Method for reacting organic halides 失效
标题翻译：反应有机物的方法
公开(公告)号：US4038324A
公开(公告)日：1977-07-26
申请号：US569780
申请日：1975-04-21
申请人： Michael F. Farona , James F. White
发明人： Michael F. Farona , James F. White
IPC分类号： B01J31/20 , C07C37/18 , C07C45/46 , C08F4/12 , C07C68/02
CPC分类号： B01J31/2295 , B01J31/20 , C07C37/18 , C07C45/46 , C08F4/12 , B01J2231/4205 , B01J2531/60 , B01J2531/64
摘要： A method for carrying out reactions of the Friedel-Crafts type, such as alkylation, acylation, polymerization, sulfonylation and dehydrohalogenation. The reactions are catalyzed by arene-metal tricarbonyl complexes and when the reaction vessel contains aromatic substrates the catalyst may be generated in situ from a metallic hexacarbonyl. The arene-metal tricarbonyl catalyst is more selective than conventionally employed Friedel-Craft catalysts in that it yields generally para isomers with little of the ortho variety and very little if any of the meta variety when the aromatic substrate is reacted with organic halide. It is also possible to form the arene-metal tricarbonyl catalyst outside of the reaction vessel and then proceed by adding it to the vessel containing the substrate and the organic halide as is the case with dehydrohalogenation reactions wherein there are no aromatic rings available, the substrate in that instance being aliphatic.

84. 发明授权

US3933752A Method for reacting organic halides 失效
标题翻译：使有机卤化物反应的方法
公开(公告)号：US3933752A
公开(公告)日：1976-01-20
申请号：US459482
申请日：1974-04-10
申请人： Michael F. Farona , James F. White
发明人： Michael F. Farona , James F. White
IPC分类号： B01J31/20 , C07C2/86 , C07C37/18 , C07C45/46 , C07C315/00 , C07C317/14 , C07C317/22 , C07F11/00 , C08F4/12 , C08G61/00 , C08G61/02 , C08G16/02 , C08G75/20
CPC分类号： B01J31/2295 , B01J31/20 , C07C2/861 , C07C315/00 , C07C37/18 , C07C45/46 , C07F11/00 , C08F4/12 , C08G61/00 , C08G61/02 , B01J2231/14 , B01J2231/4205 , B01J2531/60 , B01J2531/64 , C07C2531/20 , Y10S585/906 , Y10S585/942
摘要： A method for carrying out reactions of the Friedel-Crafts types, such as alkylation, acylation, polymerization, sulfonylation and dehydrohalogenation. The reactions are catalyzed by arene-metal tricarbonyl complexes and when the reaction vessel contains aromatic substrates the catalyst may be generated in situ from a metallic hexacarbonyl. The arene-metal tricarbonyl catalyst is more selective than conventionally employed Friedel-Craft catalysts in that it yields generally para isomers with little of the ortho variety and very little if any of the meta variety when the aromatic substrate is reacted with organic halide. It is also possible to form the arene-metal tricarbonyl catalyst outside of the reaction vessel and then proceed by adding it to the vessel containing the substrate and the organic halide as is the case with dehydrohalogenation reactions wherein there are no aromatic rings available, the substrate in that instance being aliphatic.
摘要翻译：用于进行Friedel-Crafts类型的反应的方法，例如烷基化，酰化，聚合，磺酰化和脱卤化氢。反应由芳族金属三羰基络合物催化，并且当反应容器含有芳族基底时，可以从金属六羰基原位产生催化剂。芳族金属三羰基催化剂比常规使用的Friedel-Craft催化剂更具选择性，因为当芳族底物与有机卤化物反应时，它产生通常具有少量邻位变化的非对位异构体，并且如果有任何间位异构体则极少。也可以在反应容器的外部形成芳族金属三羰基催化剂，然后通过将其加入到含有底物和有机卤化物的容器中进行，如脱卤化氢反应的情况，其中不存在芳环，基材在这种情况下是脂肪族的。

85. 发明申请

US20140295508A1 METHODS FOR PREPARING 2,5-FURANDICARBOXYLIC ACID 有权
标题翻译：制备2,5-FURANDICARBOXYLIC酸的方法
公开(公告)号：US20140295508A1
公开(公告)日：2014-10-02
申请号：US14229388
申请日：2014-03-28
申请人： Yasuo Yoshikuni , Susan R. Cooper , Adam J. Wargacki , Leo E. Manzer , James F. White , Lou Kapicak , Dennis J. Miller , Lars Peereboom
发明人： Yasuo Yoshikuni , Susan R. Cooper , Adam J. Wargacki , Leo E. Manzer , James F. White , Lou Kapicak , Dennis J. Miller , Lars Peereboom
IPC分类号： C07D307/68
CPC分类号： C07D307/68
摘要： Provided are methods of producing 2,5-furandicarboxylic acid (FDCA) from renewable sources such as seaweed, alginate, oligoalginate, pectin, oligopectin, polygalacturonate, galacturonate, and/or oligogalacturonate. The sugars in the renewable sources can be converted into one or more intermediates such as 4-deoxy-L-erythro-5-hexoseulose uronate (DEHU), 4-deoxy-L-threo-5-hexosulose uronate (DTHU), 5-hydroxymethyl furfural (HMF), 2,5-dihydroxymethyl furan (DHMF), and 5-formyl-2-furancarboxylic acid (FFA), which can be converted into FDCA by dehydration and cyclization to produce 5-formyl-2-furancarboxylic acid (FFA), followed by oxidation to produce FDCA. DEHU or DTHU may also be converted into FDCA by oxidation to produce 2,3-dihydroxy-5-oxohexanedioic acid (DOHA), which then undergoes dehydration and cyclization to produce FDCA.
摘要翻译：提供从可再生来源例如海藻，藻酸盐，低聚海藻酸盐，果胶，寡聚糖蛋白，聚半乳糖醛酸盐，半乳糖醛酸盐和/或寡聚半乳糖醛酸盐生产2,5-呋喃二羧酸（FDCA）的方法。可再生资源中的糖可以转化为一种或多种中间体，例如4-脱氧-L-赤式5-己糖糖酸糖（DEHU），4-脱氧-L-苏糖-5-己糖糖酸糖（DTHU），5- 羟基甲基糠醛（HMF），2,5-二羟甲基呋喃（DHMF）和5-甲酰基-2-呋喃甲酸（FFA），其可以通过脱水和环化转化成FDCA以产生5-甲酰基-2-呋喃甲酸（ FFA），然后氧化生成FDCA。 DEHU或DTHU也可以通过氧化转化成FDCA，生成2,3-二羟基-5-氧代己二酸（DOHA），然后进行脱水和环化以产生FDCA。

86. 发明授权

US08742144B2 Hydroxymethylfurfural reduction methods and methods of producing furandimethanol 有权
标题翻译：羟甲基糠醛还原方法和生产呋喃二甲醇的方法
公开(公告)号：US08742144B2
公开(公告)日：2014-06-03
申请号：US13174181
申请日：2011-06-30
申请人： Michael A. Lilga , Richard T. Hallen , James F. White , Michel J. Gray
发明人： Michael A. Lilga , Richard T. Hallen , James F. White , Michel J. Gray
IPC分类号： C07D307/02
CPC分类号： C07D307/42 , C07D307/46
摘要： A method of reducing hydroxymethylfurfural (HMF) where a starting material containing HMF in a solvent comprising water is provided. H2 is provided into the reactor and the starting material is contacted with a catalyst containing at least one metal selected from Ni, Co, Cu, Pd, Pt, Ru, Ir, Re and Rh, at a temperature of less than or equal to 250° C. A method of hydrogenating HMF includes providing an aqueous solution containing HMF and fructose. H2 and a hydrogenation catalyst are provided. The HMF is selectively hydrogenated relative to the fructose at a temperature at or above 30° C. A method of producing tetrahydrofuran dimethanol (THFDM) includes providing a continuous flow reactor having first and second catalysts and providing a feed comprising HMF into the reactor. The feed is contacted with the first catalyst to produce furan dimethanol (FDM) which is contacted with the second catalyst to produce THFDM.
摘要翻译：提供一种还原羟甲基糠醛（HMF）的方法，其中含有HMF的原料在包含水的溶剂中。将H2置于反应器中，并使原料与含有至少一种选自Ni，Co，Cu，Pd，Pt，Ru，Ir，Re和Rh的金属的催化剂在小于或等于250的温度下接触氢化HMF的方法包括提供含有HMF和果糖的水溶液。 H2和氢化催化剂。在30℃或更高的温度下，HMF相对于果糖选择性地氢化。制备四氢呋喃二甲醇（THFDM）的方法包括提供具有第一和第二催化剂的连续流动反应器，并向反应器提供包含HMF的进料。进料与第一催化剂接触以产生与第二催化剂接触以产生THFDM的呋喃二甲醇（FDM）。

87. 发明授权

US08388829B2 Deoxygenation of fatty acids for preparation of hydrocarbons 有权
标题翻译：用于制备碳氢化合物的脂肪酸脱氧
公开(公告)号：US08388829B2
公开(公告)日：2013-03-05
申请号：US13620268
申请日：2012-09-14
申请人： Richard T. Hallen , Karl O. Albrecht , Heather M. Brown , James F. White
发明人： Richard T. Hallen , Karl O. Albrecht , Heather M. Brown , James F. White
IPC分类号： C10M101/00 , C10M177/00 , C10G71/00
CPC分类号： B01J23/6525 , B01J21/066 , B01J21/18 , B01J23/624 , B01J23/626 , B01J23/6527 , B01J37/0203 , B01J37/0205 , C10G3/44 , C10G3/47 , C10G3/48 , C10G2300/1014 , C10G2300/1018 , C10G2300/205 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2300/44 , C10G2400/04 , C10G2400/08 , C10G2400/30 , C10L1/08 , C10L1/1208 , C10L2200/0469 , C10L2270/02 , C10L2270/04 , C11C3/00 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.
摘要翻译：公开了通过脱氧（脱羧/脱羰/脱水）脂肪酸制备可再生柴油以生产烃的方法的实施方案。将脂肪酸暴露于选自a）Pt和MO3的ZrO 2上的催化剂（M为W，Mo或其组合），或b）Pt / Ge或Pt / Sn在碳上，催化剂脱羧至少10％的脂肪酸。在具体实施方案中，催化剂相对于催化剂质量基本上由0.7重量％的Pt和12重量％的WO 3组成，或者催化剂基本上由a）5重量％的Pt和b）0.5重量％的Ge或0.5重量％的Sn ，相对于催化剂的质量。在不加入氢气的情况下进行脱氧，并且小于100psi。在脂肪酸进料中脱氧至少10％脂肪酸的催化剂的公开实施方案，并且能够使脂肪酸脱氧至少200分钟至超过350小时。

88. 发明授权

US08193382B2 Hydroxymethyl furfural oxidation methods 有权
公开(公告)号：US08193382B2
公开(公告)日：2012-06-05
申请号：US12712100
申请日：2010-02-24
申请人： Michael A. Lilga , Richard T. Hallen , Jianli Hu , James F. White , Michel J. Gray
发明人： Michael A. Lilga , Richard T. Hallen , Jianli Hu , James F. White , Michel J. Gray
IPC分类号： C07D307/48
CPC分类号： C07D307/48 , C07D307/44
摘要： A method of oxidizing hydroxymethylfurfural (HMF) includes providing a starting material which includes HMF in a solvent comprising water into a reactor. At least one of air and O2 is provided into the reactor. The starting material is contacted with the catalyst comprising Pt on a support material where the contacting is conducted at a reactor temperature of from about 50° C. to about 200° C. A method of producing an oxidation catalyst where ZrO2 is provided and is calcined. The ZrO2 is mixed with platinum (II) acetylacetonate to form a mixture. The mixture is subjected to rotary evaporation to form a product. The product is calcined and reduced under hydrogen to form an activated product. The activated product is passivated under a flow of 2% O2.

89. 发明授权

US08193381B2 Hydroxymethyl furfural oxidation methods 有权
标题翻译：羟甲基糠醛氧化法
公开(公告)号：US08193381B2
公开(公告)日：2012-06-05
申请号：US12712095
申请日：2010-02-24
申请人： Michael A. Lilga , Richard T. Hallen , Jianli Hu , James F. White , Michel J. Gray
发明人： Michael A. Lilga , Richard T. Hallen , Jianli Hu , James F. White , Michel J. Gray
IPC分类号： C07D307/02 , C07D307/48
CPC分类号： C07D307/48 , C07D307/44
摘要： A method of oxidizing hydroxymethylfurfural (HMF) includes providing a starting material which includes HMF in a solvent comprising water into a reactor. At least one of air and O2 is provided into the reactor. The starting material is contacted with the catalyst comprising Pt on a support material where the contacting is conducted at a reactor temperature of from about 50° C. to about 200° C. A method of producing an oxidation catalyst where ZrO2 is provided and is calcined. The ZrO2 is mixed with platinum (II) acetylacetonate to form a mixture. The mixture is subjected to rotary evaporation to form a product. The product is calcined and reduced under hydrogen to form an activated product. The activated product is passivated under a flow of 2% O2.
摘要翻译：氧化羟甲基糠醛（HMF）的方法包括在包含水的溶剂中提供包含HMF的原料进入反应器。将空气和O2中的至少一个提供到反应器中。起始材料与包含Pt的催化剂在载体材料上接触，其中接触在约50℃至约200℃的反应器温度下进行。制备其中提供ZrO 2并被煅烧的氧化催化剂的方法。将ZrO 2与乙酰丙酮化铂（II）混合以形成混合物。将混合物进行旋转蒸发以形成产物。将产物在氢气下煅烧和还原以形成活化产物。活化产物在2％O 2的流量下钝化。

90. 发明授权

US08129410B2 Benzisoxazole piperidine compounds and methods of use thereof 有权
标题翻译：苯并异恶唑哌啶化合物及其使用方法
公开(公告)号：US08129410B2
公开(公告)日：2012-03-06
申请号：US11912741
申请日：2006-04-26
申请人： Daniel Coughlin , James F. White , Kazumi Shiosaki , David G. Hangauer , Michael Solomon , Dale M. Edgar
发明人： Daniel Coughlin , James F. White , Kazumi Shiosaki , David G. Hangauer , Michael Solomon , Dale M. Edgar
IPC分类号： A61K31/445 , C07D413/04
CPC分类号： C07D413/04 , C07D261/20
摘要： The invention includes benzisoxazole piperidine compositions and methods of using them for modulating sleep.
摘要翻译：本发明包括苯并异恶唑哌啶组合物及其用于调节睡眠的方法。

你已经成功收藏专利！

检索式保存成功!

IPRDB

热门服务

关于我们

友情链接

联系方式