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1. 发明授权

US08501963B2 Process for producing cyclic compounds 有权
标题翻译：环状化合物的制备方法
公开(公告)号：US08501963B2
公开(公告)日：2013-08-06
申请号：US13175601
申请日：2011-07-01
申请人： Todd A. Werpy , John G. Frye, Jr. , James F. White , Johnathan E. Holladay , Alan H. Zacher
发明人： Todd A. Werpy , John G. Frye, Jr. , James F. White , Johnathan E. Holladay , Alan H. Zacher
IPC分类号： C07D207/267
CPC分类号： C07D207/404
摘要： The invention includes methods of processing an initial di-carbonyl compound by conversion to a cyclic compound. The cyclic compound is reacted with an alkylating agent to form a derivative having an alkylated ring nitrogen. The invention encompasses a method of producing an N-alkyl product. Ammonia content of a solution is adjusted to produce a ratio of ammonia to di-carboxylate compound of from about 1:1 to about 1.5:1. An alkylating agent is added and the initial compound is alkylated and cyclized. The invention includes methods of making N-methyl pyrrolidinone (NMP). Aqueous ammonia and succinate is introduced into a vessel and ammonia is adjusted to provide a ratio of ammonia to succinate of less than 2:1. A methylating agent is reacted with succinate at a temperature of from greater than 100° C. to about 400° C. to produce N-methyl succinimide which is purified and hydrogenated to form NMP.
摘要翻译：本发明包括通过转化为环状化合物来处理初始二羰基化合物的方法。环状化合物与烷基化剂反应形成具有烷基化环氮的衍生物。本发明包括生产N-烷基产物的方法。调节溶液的氨含量以产生约1：1至约1.5：1的氨与二羧酸酯化合物的比例。加入烷基化剂并将该初始化合物烷基化并环化。本发明包括制备N-甲基吡咯烷酮（NMP）的方法。将氨水和琥珀酸钠引入容器中，并调节氨以提供小于2:1的氨与琥珀酸的比例。甲基化剂与琥珀酸酯在大于100℃至约400℃的温度下反应，生成N-甲基琥珀酰亚胺，将其纯化并氢化形成NMP。

2. 发明申请

US20130018213A1 DEOXYGENATION OF FATTY ACIDS FOR PREPARATION OF HYDROCARBONS 有权
公开(公告)号：US20130018213A1
公开(公告)日：2013-01-17
申请号：US13620197
申请日：2012-09-14
申请人： Richard T. Hallen , Karl O. Albrecht , Heather M. Brown , James F. White
发明人： Richard T. Hallen , Karl O. Albrecht , Heather M. Brown , James F. White
IPC分类号： C07C1/22
CPC分类号： B01J23/6525 , B01J21/066 , B01J21/18 , B01J23/624 , B01J23/626 , B01J23/6527 , B01J37/0203 , B01J37/0205 , C10G3/44 , C10G3/47 , C10G3/48 , C10G2300/1014 , C10G2300/1018 , C10G2300/205 , C10G2300/4012 , C10G2300/4018 , C10G2300/4081 , C10G2300/44 , C10G2400/04 , C10G2400/08 , C10G2400/30 , C10L1/08 , C10L1/1208 , C10L2200/0469 , C10L2270/02 , C10L2270/04 , C11C3/00 , Y02E50/13 , Y02P30/20 , Y02T50/678
摘要： Embodiments of methods for making renewable diesel by deoxygenating (decarboxylating/decarbonylating/dehydrating) fatty acids to produce hydrocarbons are disclosed. Fatty acids are exposed to a catalyst selected from a) Pt and MO3 on ZrO2 (M is W, Mo, or a combination thereof), or b) Pt/Ge or Pt/Sn on carbon, and the catalyst decarboxylates at least 10% of the fatty acids. In particular embodiments, the catalyst consists essentially of 0.7 wt % Pt and 12 wt % WO3, relative to a mass of catalyst, or the catalyst consists essentially of a) 5 wt % Pt and b) 0.5 wt % Ge or 0.5 wt % Sn, relative to a mass of catalyst. Deoxygenation is performed without added hydrogen and at less than 100 psi. Disclosed embodiments of the catalysts deoxygenate at least 10% of fatty acids in a fatty acid feed, and remain capable of deoxygenating fatty acids for at least 200 minutes to more than 350 hours.

3. 发明申请

US20110306780A1 Hydroxymethylfurfural Reduction Methods and Methods of Producing Furandimethanol 有权
公开(公告)号：US20110306780A1
公开(公告)日：2011-12-15
申请号：US13173942
申请日：2011-06-30
申请人： Michael A. Lilga , Richard T. Hallen , Todd A. Werpy , James F. White , Johnathan E. Holladay , John G. Frye, JR. , Alan H. Zacher
发明人： Michael A. Lilga , Richard T. Hallen , Todd A. Werpy , James F. White , Johnathan E. Holladay , John G. Frye, JR. , Alan H. Zacher
IPC分类号： C07D307/42 , C07D307/12
CPC分类号： C07D307/42 , C07D307/46
摘要： A method of reducing hydroxymethylfurfural (HMF) where a starting material containing HMF in a solvent comprising water is provided. H2 is provided into the reactor and the starting material is contacted with a catalyst containing at least one metal selected from Ni, Co, Cu, Pd, Pt, Ru, Ir, Re and Rh, at a temperature of less than or equal to 250° C. A method of hydrogenating HMF includes providing an aqueous solution containing HMF and fructose. H2 and a hydrogenation catalyst are provided. The HMF is selectively hydrogenated relative to the fructose at a temperature at or above 30° C. A method of producing tetrahydrofuran dimethanol (THFDM) includes providing a continuous flow reactor having first and second catalysts and providing a feed comprising HMF into the reactor. The feed is contacted with the first catalyst to produce furan dimethanol (FDM) which is contacted with the second catalyst to produce THFDM.

4. 发明申请

US20110257419A1 Hydroxymethylfurfural Reduction Methods and Methods of Producing Furandimethanol 有权
标题翻译：羟甲基糠醛还原方法和生产呋喃二甲醇的方法
公开(公告)号：US20110257419A1
公开(公告)日：2011-10-20
申请号：US13174181
申请日：2011-06-30
申请人： Michael A. Lilga , Richard T. Hallen , Todd A. Werpy , James F. White , Johnathan E. Holladay , John G. Frye, JR. , Alan H. Zacher
发明人： Michael A. Lilga , Richard T. Hallen , Todd A. Werpy , James F. White , Johnathan E. Holladay , John G. Frye, JR. , Alan H. Zacher
IPC分类号： C07D307/44
CPC分类号： C07D307/42 , C07D307/46
摘要： A method of reducing hydroxymethylfurfural (HMF) where a starting material containing HMF in a solvent comprising water is provided. H2 is provided into the reactor and the starting material is contacted with a catalyst containing at least one metal selected from Ni, Co, Cu, Pd, Pt, Ru, Ir, Re and Rh, at a temperature of less than or equal to 250° C. A method of hydrogenating HMF includes providing an aqueous solution containing HMF and fructose. H2 and a hydrogenation catalyst are provided. The HMF is selectively hydrogenated relative to the fructose at a temperature at or above 30° C. A method of producing tetrahydrofuran dimethanol (THFDM) includes providing a continuous flow reactor having first and second catalysts and providing a feed comprising HMF into the reactor. The feed is contacted with the first catalyst to produce furan dimethanol (FDM) which is contacted with the second catalyst to produce THFDM.
摘要翻译：提供一种还原羟甲基糠醛（HMF）的方法，其中含有HMF的原料在包含水的溶剂中。将H2置于反应器中，并使原料与含有至少一种选自Ni，Co，Cu，Pd，Pt，Ru，Ir，Re和Rh的金属的催化剂在小于或等于250的温度下接触氢化HMF的方法包括提供含有HMF和果糖的水溶液。 H2和氢化催化剂。在30℃或更高的温度下，HMF相对于果糖选择性地氢化。制备四氢呋喃二甲醇（THFDM）的方法包括提供具有第一和第二催化剂的连续流动反应器，并向反应器中提供包含HMF的进料。进料与第一催化剂接触以产生与第二催化剂接触以产生THFDM的呋喃二甲醇（FDM）。

5. 发明申请

US20110251175A1 Stigmine Conjugates for Substance Use Disorders 审中-公开
标题翻译：用于物质使用障碍的丝氨酸缀合物
公开(公告)号：US20110251175A1
公开(公告)日：2011-10-13
申请号：US13003721
申请日：2009-07-16
申请人： Nadia Rupniak , James F. White
发明人： Nadia Rupniak , James F. White
IPC分类号： A61K31/27 , A61K31/4525 , A61K31/445 , A61P9/00 , A61K31/553 , A61P25/30 , A61P25/36 , A61P25/00 , A61K31/55 , A61K31/381
CPC分类号： A61K31/137 , A61K9/0019 , A61K31/138 , A61K31/407
摘要： The invention relates to methods for the treatment or prevention of substance use disorders.
摘要翻译：本发明涉及用于治疗或预防物质使用障碍的方法。

6. 发明授权

US07858667B2 Alcohol synthesis from CO or CO2 有权
标题翻译：来自CO或CO 2的酒精合成
公开(公告)号：US07858667B2
公开(公告)日：2010-12-28
申请号：US11611160
申请日：2006-12-15
申请人： Jianli Hu , Robert A. Dagle , Jamelyn D. Holladay , Chunshe Cao , Yong Wang , James F. White , Douglas C. Elliott , Don J. Stevens
发明人： Jianli Hu , Robert A. Dagle , Jamelyn D. Holladay , Chunshe Cao , Yong Wang , James F. White , Douglas C. Elliott , Don J. Stevens
IPC分类号： C07C27/00
CPC分类号： C07C29/152 , B01J19/0093 , B01J2219/00835 , B01J2219/00873 , B01J2219/00961 , B01J2219/00984 , C07C29/157 , Y02P20/52 , C07C31/04 , C07C31/08 , C07C31/02
摘要： Methods for producing alcohols from CO or CO2 and H2 utilizing a palladium-zinc on alumina catalyst are described. Methods of synthesizing alcohols over various catalysts in microchannels are also described. Ethanol, higher alcohols, and other C2+ oxygenates can produced utilizing Rh—Mn or a Fisher-Tropsch catalyst.
摘要翻译：描述了使用氧化铝催化剂上的钯 - 锌从CO或CO 2和H 2生产醇的方法。还描述了在微通道中在各种催化剂上合成醇的方法。可以使用Rh-Mn或Fisher-Tropsch催化剂生产乙醇，高级醇和其他C2 +含氧化合物。

7. 发明申请

US20100145072A1 Process for Producing Cyclic Compounds 有权
标题翻译：生产环状化合物的方法
公开(公告)号：US20100145072A1
公开(公告)日：2010-06-10
申请号：US12702818
申请日：2010-02-09
申请人： Todd A. Werpy , John G. Frye, JR. , James F. White , Johnathan E. Holladay , Alan H. Zacher
发明人： Todd A. Werpy , John G. Frye, JR. , James F. White , Johnathan E. Holladay , Alan H. Zacher
IPC分类号： C07D207/408 , C07D207/267
CPC分类号： C07D207/404
摘要： The invention includes methods of processing an initial di-carbonyl compound by conversion to a cyclic compound. The cyclic compound is reacted with an alkylating agent to form a derivative having an alkylated ring nitrogen. The invention encompasses a method of producing an N-alkyl product. Ammonia content of a solution is adjusted to produce a ratio of ammonia to di-carboxylate compound of from about 1:1 to about 1.5:1. An alkylating agent is added and the initial compound is alkylated and cyclized. The invention includes methods of making N-methylpyrrolidinone (NMP). Aqueous ammonia and succinate is introduced into a vessel and ammonia is adjusted to provide a ratio of ammonia to succinate of less than 2:1. A methylating agent is reacted with succinate at a temperature of from greater than 100° C. to about 400° C. to produce N-methyl succinimide which is purified and hydrogenated to form NMP.
摘要翻译：本发明包括通过转化为环状化合物来处理初始二羰基化合物的方法。环状化合物与烷基化剂反应形成具有烷基化环氮的衍生物。本发明包括生产N-烷基产物的方法。调节溶液的氨含量以产生约1：1至约1.5：1的氨与二羧酸酯化合物的比例。加入烷基化剂并将该初始化合物烷基化并环化。本发明包括制备N-甲基吡咯烷酮（NMP）的方法。将氨水和琥珀酸钠引入容器中，并调节氨以提供小于2:1的氨与琥珀酸的比例。甲基化剂与琥珀酸酯在大于100℃至约400℃的温度下反应，生成N-甲基琥珀酰亚胺，将其纯化并氢化形成NMP。

8. 发明授权

US07708955B2 Staged alkylation in microchannels 有权
标题翻译：微通道分阶段烷基化
公开(公告)号：US07708955B2
公开(公告)日：2010-05-04
申请号：US11973447
申请日：2007-10-09
申请人： Yong Wang , James F. White
发明人： Yong Wang , James F. White
IPC分类号： B01J8/04 , B01J10/00
CPC分类号： C10G29/205 , B01J19/0093 , B01J2219/00835 , B01J2219/00844 , B01J2219/00873 , B01J2219/00894 , C10G2300/1081 , C10G2300/1088 , C10G2300/1096 , C10G2300/4081 , C10G2400/02
摘要： The invention provides methods and systems for alkylating a paraffinic feed stream in a microchannel utilizing the staged addition of olefin.
摘要翻译：本发明提供了利用分阶段加入烯烃在微通道中烷基化进入石蜡原料流的方法和系统。

9. 发明申请

US20090054695A1 Chemical production processes, systems, and catalyst compositions 有权
标题翻译：化学生产过程，系统和催化剂组合物
公开(公告)号：US20090054695A1
公开(公告)日：2009-02-26
申请号：US11895414
申请日：2007-08-24
申请人： Thomas H. Peterson , Alan H. Zacher , Michel J. Gray , James F. White , Todd A. Werpy
发明人： Thomas H. Peterson , Alan H. Zacher , Michel J. Gray , James F. White , Todd A. Werpy
IPC分类号： C07C45/29 , B01J21/00 , B01J27/053 , B01J8/00
CPC分类号： B01J27/186 , B01J8/025 , B01J23/96 , B01J27/1856 , B01J27/285 , B01J37/03 , B01J38/12 , B01J2208/00212 , B01J2208/00256 , B01J2219/00247 , C07C45/52 , Y02P20/584 , C07C47/22 , C07C49/17
摘要： Chemical production processes are provided that can include exposing a reactant composition to a catalyst composition to form a product composition. The reactant composition can include a multihydric alcohol compound and the product composition can include a carbonyl compound. The catalyst composition can include a metal effective to facilitate catalyst activation. Processes disclosed also include supplementing a dehydration catalyst with a promoter, and activating the supplemented catalyst in the presence of oxygen. Processes also include providing a supplemented dehydration catalyst to within a reactor, and exposing a multihydric alcohol compound to the dehydration catalyst, with the exposing forming coke within the reactor. Oxygen can be provided to the reactor to remove at least a portion of the coke.
摘要翻译：提供化学生产方法，其可以包括将反应物组合物暴露于催化剂组合物以形成产物组合物。反应物组合物可以包括多元醇化合物，并且产物组合物可以包括羰基化合物。催化剂组合物可以包括有效促进催化剂活化的金属。所公开的方法还包括用助催化剂补充脱水催化剂，并在氧的存在下活化补充的催化剂。方法还包括在反应器内提供补充的脱水催化剂，并将多元醇化合物暴露于脱水催化剂中，同时在反应器内形成曝光的焦炭。可以将氧气提供给反应器以除去至少一部分焦炭。

10. 发明申请

US20090054538A1 Chemical production processes, systems, and catalyst compositions 审中-公开
标题翻译：化学生产过程，系统和催化剂组合物
公开(公告)号：US20090054538A1
公开(公告)日：2009-02-26
申请号：US11895592
申请日：2007-08-24
申请人： Thomas H. Peterson , Alan H. Zacher , Michel J. Gray , James F. White , Johnathon E. Holladay , Todd A. Werpy
发明人： Thomas H. Peterson , Alan H. Zacher , Michel J. Gray , James F. White , Johnathon E. Holladay , Todd A. Werpy
IPC分类号： C07C27/22
CPC分类号： B01J27/188 , B01J8/025 , B01J23/20 , B01J23/24 , B01J23/34 , B01J23/8474 , B01J27/195 , B01J37/0236 , B01J2208/00212 , B01J2208/00256 , C07C45/52 , C07C47/22
摘要： Chemical production processes are provided than can include exposing a reactant composition to a catalyst composition to form a product composition, with the reactant composition including a multihydric alcohol compound and product composition including a carbonyl compound. The catalyst composition can include one or more elements of groups 5 and 6 of the periodic table of elements. Catalyst compositions are provided that can include one or more of niobia, hydrated niobia, tungstic acid, phosphotungstic acid, and phosphomolybdic acid.
摘要翻译：提供化学生产方法可以包括将反应物组合物暴露于催化剂组合物以形成产物组合物，反应物组合物包含多元醇化合物和包含羰基化合物的产物组合物。催化剂组合物可以包括元素周期表第5和6族的一个或多个元素。提供的催化剂组合物可以包括铌，氧化铌，钨酸，磷钨酸和磷钼酸中的一种或多种。

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