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81. 发明申请

US20050224365A1 One-step electrosynthesis of borohydride 审中-公开
标题翻译：一步电化学合成硼氢化物
公开(公告)号：US20050224365A1
公开(公告)日：2005-10-13
申请号：US11104120
申请日：2005-04-12
申请人： Duane Mazur , Norman Weinberg , Lawrence Guilbault , Arthur Achhing Chin , Klaus Tomantschger
发明人： Duane Mazur , Norman Weinberg , Lawrence Guilbault , Arthur Achhing Chin , Klaus Tomantschger
IPC分类号： C25B11/04 , C25B1/00 , C25B1/14 , C25B3/00
CPC分类号： C25B1/00 , C25B1/14 , C25B11/04
摘要： A method for producing borohydride by causing current to flow in an electrolytic cell between an anode and a cathode, wherein a solution of a boron-containing compound is in contact with the cathode, and wherein the cathode comprises a conductive material having activity as a high hydrogen overpotential electrode.
摘要翻译：通过使电流在阳极和阴极之间的电解池中流动而制造硼氢化物的方法，其中含硼化合物的溶液与阴极接触，并且其中阴极包括具有高活性的导电材料氢超电极。

82. 发明授权

US06638413B1 Methods and apparatus for electrolysis of water 失效
标题翻译：电解水的方法和装置
公开(公告)号：US06638413B1
公开(公告)日：2003-10-28
申请号：US08334952
申请日：1994-11-07
申请人： Norman L. Weinberg , Klaus Tomantschger , Robert S. Feldstein , J. David Genders , Joseph M. Rait
发明人： Norman L. Weinberg , Klaus Tomantschger , Robert S. Feldstein , J. David Genders , Joseph M. Rait
IPC分类号： C25B102
CPC分类号： C25B1/04 , C25B1/02 , Y02E60/366
摘要： A method and apparatus are provided for electrolyzing water for enhanced production of oxygen, hydrogen and heat by the steps of (i) providing an electrochemical cell comprising an isotopic hydrogen storage cathode, an electrically conductive anode and an ionically conducting electrolyte comprising water, and (ii) impressing a repeating sequence of voltages across the cathode and anode comprised of at least two cell voltage regimes, a first cell voltage regime consisting of a voltage sufficient to enhance cathodic absorption of hydrogen, and a second cell voltage regime consisting of at least one voltage pulse which is at least two times the voltage of the first cell voltage regime for a total duration no greater than 0.10 seconds.
摘要翻译：提供一种用于电解水以提高氧气，氢气和热量产生的方法和装置，其步骤如下：（i）提供包含同位素储氢阴极，导电阳极和包含水的离子导电电解质的电化学电池，和 ii）在包括至少两个电池电压方案的阴极和阳极之间施加电压的重复序列，由足以增强氢的阴极吸收的电压组成的第一电池电压状态，以及由至少一个电压脉冲，其持续时间不超过0.10秒是至少两倍于第一电池电压方式的电压。

83. 发明授权

US5626988A Sealed rechargeable cells containing mercury-free zinc anodes, and a method of manufacture 失效
标题翻译：含有无汞锌阳极的密封可充电电池及其制造方法
公开(公告)号：US5626988A
公开(公告)日：1997-05-06
申请号：US239059
申请日：1994-05-06
申请人： Josef Daniel-Ivad , R. James Book , Klaus Tomantschger
发明人： Josef Daniel-Ivad , R. James Book , Klaus Tomantschger
IPC分类号： H01M4/42 , H01M4/50 , H01M4/62 , H01M10/24 , H01M10/34 , H01M10/52
CPC分类号： H01M4/62 , H01M10/24 , H01M10/345 , H01M10/52 , H01M4/42 , H01M4/50
摘要： The zinc active powder for a mercury-free rechargeable electrochemical cell is coated with a surfactant, and separately with an aqueous solution of indium sulphate. Without any subsequent filtering, washing or drying, the powder is assembled into an electrochemical cell. The cell can include a hydrogen recombination catalyst in contact with the electrochemically active material of the cathode.
摘要翻译：用于无汞可充电电化学电池的锌活性粉末涂覆有表面活性剂，并分别与硫酸铟水溶液一起涂覆。没有任何后续的过滤，洗涤或干燥，将粉末组装成电化学电池。电池可以包括与阴极的电化学活性材料接触的氢复合催化剂。

84. 发明授权

US5340666A Rechargeable alkaline manganese cell having improved capacity and improved energy density 失效
标题翻译：可充电碱锰电池具有改进的容量和改善的能量密度
公开(公告)号：US5340666A
公开(公告)日：1994-08-23
申请号：US110203
申请日：1993-08-23
申请人： Klaus Tomantschger , Ronald J. Book , Robert D. Findlay
发明人： Klaus Tomantschger , Ronald J. Book , Robert D. Findlay
IPC分类号： H01M4/02 , H01M4/24 , H01M4/62 , H01M10/24 , H01M10/34 , H01M10/52
CPC分类号： H01M4/628 , H01M10/24 , H01M4/24 , H01M4/62 , H01M10/34 , H01M10/52 , H01M4/02 , H01M4/621
摘要： A rechargeable alkaline manganese cell provided, having improved capacity and improved energy density. The cell is anode limited, and each of the anode and cathode is physically dimensioned so that the anode has a capacity in the range of from about 55% to 100% of the theoretical one electron capacity of the cathode. The gravimetric energy density of the cell exceeds 70 Wh/kg, and the volumetric energy density of the cell exceeds 200 Wh/liter. Each of the anode and cathode may comprise additional additives. For example, the cathode may include additional hydrophobic materials and a porous additive such as carbon black so as to improve gas transport of hydrogen gas into the cathode where it is oxidized; and the anode may comprise hydrogen gassing inhibitors as well as hydrogen gas recombing agents.
摘要翻译：提供可充电碱性锰电池，具有改进的容量和改善的能量密度。电池是阳极限制的，并且阳极和阴极的每个物理尺寸使得阳极的电容在阴极的理论电子能力的约55％至100％的范围内。电池的重量能量密度超过70 Wh / kg，电池的体积能量密度超过200 Wh / l。阳极和阴极中的每一个可以包含另外的添加剂。例如，阴极可以包括另外的疏水材料和诸如炭黑的多孔添加剂，以便改善氢气进入阴极的气体输送，在那里被氧化; 并且阳极可以包括氢气放气抑制剂以及氢气推聚剂。

85. 发明授权

US5069988A Metal and metal oxide catalyzed electrodes for electrochemical cells, and methods of making same 失效
标题翻译：用于电化学电池的金属和金属氧化物催化电极及其制备方法
公开(公告)号：US5069988A
公开(公告)日：1991-12-03
申请号：US540932
申请日：1990-06-15
申请人： Klaus Tomantschger , Karl Kordesch , Robert D. Findlay
发明人： Klaus Tomantschger , Karl Kordesch , Robert D. Findlay
IPC分类号： H01M4/86 , H01M4/88 , H01M4/90 , H01M4/92 , H01M4/96
CPC分类号： H01M4/90 , H01M4/86 , H01M4/96
摘要： Porous electrodes for use in fuel cells and other electrochemical cells are disclosed. Principally, the electrodes a catalytically active layer on a porous conductive substrate, which catalytically active layer is derived from non-noble metals. The loading of the catalytically active layer is lower in terms of weight of catalyst per unit area of geometrical electrode surface than heretofore. Several alternative methods of forming the electrode are taught, including impregnating a porous conductive substrate with a metal salt solution, followed by chemical or thermal formation of the porous catalytically active layer; or mixing the catalytically active material with the material of the porous conductive substrate, followed by fabrication of the electrode; or depositing pyrolitic carbon from the gas phase onto a porous conductive substrate, at elevated temperatures in a gas atmosphere. The electrode may also have a porous metallic current collector, and also a further gas diffusion layer. If used as a fuel cell anode, a further small amount of noble metal is included in the porous catalytically active layer. Porous electrodes of this invention have particular utility in alkaline primary or secondary cells as auxiliary gas recombining electrodes, especially as oxygen consuming auxiliary transfer electrodes.
摘要翻译：公开了用于燃料电池和其它电化学电池的多孔电极。主要地，电极是多孔导电基底上的催化活性层，催化活性层衍生自非贵金属。催化活性层的负载量相对于几何电极表面的每单位面积的催化剂的重量来说比以前更低。教导了形成电极的几种替代方法，包括用金属盐溶液浸渍多孔导电衬底，然后化学或热形成多孔催化活性层; 或将催化活性材料与多孔导电衬底的材料混合，随后制造电极; 或在气体气氛中升高的温度下将来自气相的热解碳沉积到多孔导电基底上。电极也可以具有多孔金属集流体，还可以具有另外的气体扩散层。如果用作燃料电池阳极，则在多孔催化活性层中还包含另外少量的贵金属。本发明的多孔电极在碱性一次电池或二次电池中具有特别的用途，作为辅助气体复合电极，特别是作为耗氧辅助转移电极。

86. 发明申请

US20150226113A1 METHOD AND SYSTEM FOR IMPROVING FUEL ECONOMY AND REDUCING EMISSIONS OF INTERNAL COMBUSTION ENGINES 审中-公开
标题翻译：改善燃油经济性和减少内燃机排放的方法和系统
公开(公告)号：US20150226113A1
公开(公告)日：2015-08-13
申请号：US14423602
申请日：2013-08-22
申请人： Robert ALEXANDER , Geoffrey SHEERIN , Klaus TOMANTSCHGER
发明人： Robert Alexander , Geoffrey Sheerin , Klaus Tomantschger
IPC分类号： F02B43/12 , F02D41/30 , F02D41/00
CPC分类号： F02B43/12 , F02B2043/106 , F02D19/08 , F02D41/0002 , F02D41/0027 , F02D41/30 , F02M21/02 , F02M25/12 , Y02T10/32 , Y02T10/36
摘要： A method and system for improving the fuel economy and lowering the emissions of internal combustion engines by injecting predetermined amounts and ratios of on-board or locally generated hydrogen and oxygen to the engine's air intake and varying the gas addition volume and hydrogen/oxygen ratio as a function of the operating conditions, e.g., in line with the instant engine load.
摘要翻译：一种用于通过将预定量的车载或局部产生的氢和氧的比例喷射到发动机的进气口并改变气体添加体积和氢气/氧气比来改善燃料经济性并降低内燃机的排放的方法和系统，操作条件的功能，例如符合即时发动机负载。

87. 发明授权

US08389150B2 Composite current collector for aqueous electrochemical cell 有权
标题翻译：用于电化学电池的复合集电器
公开(公告)号：US08389150B2
公开(公告)日：2013-03-05
申请号：US13451586
申请日：2012-04-20
申请人： Klaus Tomantschger
发明人： Klaus Tomantschger
IPC分类号： H01M2/16
CPC分类号： H01M4/667 , H01M4/14 , H01M4/244 , H01M4/661 , H01M4/662 , H01M4/72 , H01M4/74 , H01M4/742 , H01M4/765 , H01M4/78 , H01M4/808 , H01M6/06 , H01M10/06 , H01M10/24 , H01M2200/103
摘要： Composite current collectors containing coatings of metals, alloys or compounds, selected from the group of Zn, Cd, Hg, Ga, In, Tl, Sn, Pb, As, Sb, Bi and Se on non-metallic, non-conductive or poorly-conductive substrates are disclosed. The composite current collectors can be used in electrochemical cells particularly sealed cells requiring a long storage life. Selected metals, metal alloys or metal compounds are applied to polymer or ceramic substrates by vacuum deposition techniques, extrusion, conductive paints (dispersed as particles in a suitable paint), electroless deposition, cementation; or after suitable metallization by galvanic means (electrodeposition or electrophoresis). Metal compound coatings are reduced to their respective metals by chemical or galvanic means. The current collectors described are particular suitable for use in sealed primary or rechargeable galvanic cells containing mercury-fee and lead-free alkaline zinc electrodes.
摘要翻译：包含金属，合金或化合物的复合集流体，其选自Zn，Cd，Hg，Ga，In，Tl，Sn，Pb，As，Sb，Bi和Se，非金属，不导电或不良导电基底。复合集电器可用于电化学电池，特别是需要长存储寿命的密封电池。选择的金属，金属合金或金属化合物通过真空沉积技术，挤出，导电涂料（分散为合适涂料中的颗粒），无电沉积，胶结剂等应用于聚合物或陶瓷基材; 或通过电化学方法（电沉积或电泳）合适的金属化之后。金属化合物涂层通过化学或电流方法还原成各自的金属。所描述的集电器特别适用于含有汞和无铅碱性锌电极的密封初级或可充电电池。

88. 发明授权

US08182938B2 Composite current collector for electrochemical cell 有权
标题翻译：电化学电池用复合集电器
公开(公告)号：US08182938B2
公开(公告)日：2012-05-22
申请号：US13099390
申请日：2011-05-03
申请人： Klaus Tomantschger
发明人： Klaus Tomantschger
IPC分类号： H01M2/16
CPC分类号： H01M4/667 , H01M4/14 , H01M4/244 , H01M4/661 , H01M4/662 , H01M4/72 , H01M4/74 , H01M4/742 , H01M4/765 , H01M4/78 , H01M4/808 , H01M6/06 , H01M10/06 , H01M10/24 , H01M2200/103
摘要： Composite current collectors containing coatings of metals, alloys or compounds, selected from the group of Zn, Cd, Hg, Ga, In, Tl, Sn, Pb, As, Sb, Bi and Se on non-metallic, non-conductive or poorly-conductive substrates are disclosed. The composite current collectors can be used in electrochemical cells particularly sealed cells requiring a long storage life. Selected metals, metal alloys or metal compounds are applied to polymer or ceramic substrates by vacuum deposition techniques, extrusion, conductive paints (dispersed as particles in a suitable paint), electroless deposition, cementation; or after suitable metallization by galvanic means (electrodeposition or electrophoresis). Metal compound coatings are reduced to their respective metals by chemical or galvanic means. The current collectors described are particular suitable for use in sealed primary or rechargeable galvanic cells containing mercury-free and lead-free alkaline zinc electrodes.
摘要翻译：包含金属，合金或化合物的复合集流体，其选自Zn，Cd，Hg，Ga，In，Tl，Sn，Pb，As，Sb，Bi和Se，非金属，不导电或不良导电基底。复合集电器可用于电化学电池，特别是需要长存储寿命的密封电池。选择的金属，金属合金或金属化合物通过真空沉积技术，挤出，导电涂料（分散为合适涂料中的颗粒），无电沉积，胶结剂等应用于聚合物或陶瓷基材; 或通过电化学方法（电沉积或电泳）合适的金属化之后。金属化合物涂层通过化学或电流方法还原成各自的金属。所描述的集电器特别适用于含有无汞和无铅碱性锌电极的密封初级或可充电电池。

89. 发明授权

US07976976B2 Composite current collector 有权
标题翻译：复合集电器
公开(公告)号：US07976976B2
公开(公告)日：2011-07-12
申请号：US12024139
申请日：2008-02-01
申请人： Klaus Tomantschger
发明人： Klaus Tomantschger
IPC分类号： H01M2/16
CPC分类号： H01M4/667 , H01M4/14 , H01M4/244 , H01M4/661 , H01M4/662 , H01M4/72 , H01M4/74 , H01M4/742 , H01M4/765 , H01M4/78 , H01M4/808 , H01M6/06 , H01M10/06 , H01M10/24 , H01M2200/103
摘要： Composite current collectors containing coatings of metals, alloys or compounds, selected from the group of Zn, Cd, Hg, Ga, In, Tl, Sn, Pb, As, Sb, Bi and Se on non-metallic, non-conductive or poorly-conductive substrates are disclosed. The composite current collectors can be used in electrochemical cells particularly sealed cells requiring a long storage life. Selected metals, metal alloys or metal compounds are applied to polymer or ceramic substrates by vacuum deposition techniques, extrusion, conductive paints (dispersed as particles in a suitable paint), electroless deposition, cementation; or after suitable metallization by galvanic means (electrodeposition or electrophoresis). Metal compound coatings are reduced to their respective metals by chemical or galvanic means. The current collectors described are particular suitable for use in sealed primary or rechargeable galvanic cells containing mercury-fee and lead-free alkaline zinc electrodes.
摘要翻译：包含金属，合金或化合物的复合集流体，其选自Zn，Cd，Hg，Ga，In，Tl，Sn，Pb，As，Sb，Bi和Se，非金属，不导电或不良导电基底。复合集电器可用于电化学电池，特别是需要长存储寿命的密封电池。选择的金属，金属合金或金属化合物通过真空沉积技术，挤出，导电涂料（分散为合适涂料中的颗粒），无电沉积，胶结剂等应用于聚合物或陶瓷基材; 或通过电化学方法（电沉积或电泳）合适的金属化之后。金属化合物涂层通过化学或电流方法还原成各自的金属。所描述的集电器特别适用于含有汞和无铅碱性锌电极的密封初级或可充电电池。

90. 发明授权

US5424145A High capacity rechargeable cell having manganese dioxide electrode 失效
标题翻译：具有二氧化锰电极的大容量可再充电电池
公开(公告)号：US5424145A
公开(公告)日：1995-06-13
申请号：US207629
申请日：1994-03-09
申请人： Klaus Tomantschger , R. James Book , Josef Daniel-Ivad
发明人： Klaus Tomantschger , R. James Book , Josef Daniel-Ivad
IPC分类号： H01M2/16 , H01M4/42 , H01M4/50 , H01M4/62 , H01M10/05 , H01M10/24 , H01M10/26 , H01M10/36 , H01M10/52
CPC分类号： H01M2/1686 , H01M10/05 , H01M10/24 , H01M10/26 , H01M10/36 , H01M4/62 , H01M4/622 , H01M4/623 , H01M4/628 , H01M10/523 , H01M2/1653 , H01M4/42 , H01M4/50 , H01M4/621 , H01M4/625
摘要： A rechargeable manganese dioxide/zinc cell is provided, where the cell has high capacity, high volumetric and gravimetric energy densities, high cycle life, and is capable of continued charge-discharge cycles following an overdischarge. The cell has an aqueous electrolyte, with the usual solute of potassium hydroxide, but the solute may also be a mixture of zinc chloride and ammonium chloride. The electrode balance as determined by the ration of the theoretical discharge capacity of the zinc and the theoretical one electron discharge capacity of the manganese dioxide ranges from greater than 65% up to 110%. On the 15th discharge, a cell of the present invention will deliver a discharge capacity of at least 20% of the discharge capacity delivered on the first discharge. A cell according to the present invention is capable of continued charge-discharge cycles after overdischarge or voltage reversal.
摘要翻译：提供了可充电的二氧化锰/锌电池，其中电池具有高容量，高体积和重量能量密度，高循环寿命，并且能够在过放电之后继续充电 - 放电循环。电池具有通常的氢氧化钾溶质的电解质，但是溶质也可以是氯化锌和氯化铵的混合物。通过锌的理论放电容量和二氧化锰的理论电子放电容量的比例确定的电极平衡范围从大于65％到高达110％。在第15次放电时，本发明的电池将提供至少在第一次放电时输送的放电容量的20％的放电容量。根据本发明的电池能够在过放电或电压反转之后继续充电 - 放电循环。

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