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81. 发明授权

US5989297A Dye mixtures processes for their preparation and their use 失效
标题翻译：染料混合物的制备及其用途
公开(公告)号：US5989297A
公开(公告)日：1999-11-23
申请号：US679784
申请日：1996-07-15
申请人： Hans Reichert , Bernhard Muller , Athanassios Tzikas
发明人： Hans Reichert , Bernhard Muller , Athanassios Tzikas
IPC分类号： C09B62/04 , C09B62/44 , C09B67/22 , C09B67/24 , D06P1/382 , D06P1/384 , D06P3/66
CPC分类号： C09B62/4403 , C09B62/043 , C09B67/004 , C09B67/0047 , Y10S8/917 , Y10S8/918
摘要： Dye mixtures comprising at least one compound of the formula ##STR1## and at least one compound of the formula ##STR2## in which the variables are as defined in the claims,which are suitable as fibre-reactive dyes for dyeing widely varying fibre materials, are described.
摘要翻译：描述了包含至少一种下式化合物和至少一种下式化合物的染料混合物，其中变量如权利要求中所定义，其适合作为用于染色广泛变化的纤维材料的纤维活性染料。

82. 发明授权

US5892006A Fibre-reactive dyes and dye mixtures and their use 失效
标题翻译：纤维活性染料和染料混合物及其用途
公开(公告)号：US5892006A
公开(公告)日：1999-04-06
申请号：US997320
申请日：1997-12-23
申请人： Athanassios Tzikas
发明人： Athanassios Tzikas
IPC分类号： C07D251/50 , C09B62/02 , C09B62/04 , C09B62/06 , C09B62/085 , C09B62/09 , C09B62/095 , C09B62/10 , C09B67/22 , D06P1/38 , D06P1/382 , D06P3/66
CPC分类号： C09B62/04 , C09B62/02 , C09B67/004 , C09B67/0041 , C09B67/0042 , C09B67/0047 , Y10S8/918
摘要： The invention relates to dye mixtures which contain dyes of the formulae ##STR1## and to dyes of the formula ##STR2## in which A.sub.1, A.sub.2, A.sub.3, B, B.sub.1, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, Z.sub.1, Z.sub.2, X.sub.1, X.sub.2 and X.sub.3 are as defined in claim 1.The dyes and dye mixtures are distinguished by generally good properties and produce dyeings and prints having good wet and light fastness properties.
摘要翻译：本发明涉及染料混合物，其含有式（1）和（IMAGE）（2）的染料和式（2a）的染料，其中A1，A2，A3，B，B1，R1 R 2，R 3，R 4，R 5，Z 1，Z 2，X 1，X 2和X 3如权利要求1中所定义。染料和染料混合物通常具有良好的性能并产生具有良好的耐湿和耐光性的染色和印花。

83. 发明授权

US5597904A Reactive dyes, process for their preparation and the use thereof 失效
标题翻译：活性染料，其制备方法及其用途
公开(公告)号：US5597904A
公开(公告)日：1997-01-28
申请号：US614119
申请日：1996-03-12
申请人： Athanassios Tzikas , Claudia Carisch
发明人： Athanassios Tzikas , Claudia Carisch
IPC分类号： C09B62/51 , C09B62/45 , D06P3/24 , D06P3/66 , C09B62/473 , D06P1/384
CPC分类号： C09B62/45
摘要： Reactive dyes of formula ##STR1## wherein Z is a group of formula --CH.dbd.CH.sub.2 or --CH.sub.2 --CH.sub.2 --Y, and Y is a leaving group, and K is a radical of formula ##STR2## wherein X is a radical of formula --(CH.sub.2).sub.n --Cl, ##STR3## or --CH.dbd.CH.sub.2 ; Hal is halogen; and n is 1, 2, 3 or 4; R is hydrogen or unsubstituted or substituted C.sub.1 -C.sub.4 alkyl; R.sub.1 is amino or hydroxyl; R.sub.2 is methyl or carboxyl; and R.sub.3 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.4 alkanoylamino, halogen or carboxyl, are particularly suitable for dyeing or printing cellulosic fibre materials or natural or synthetic polyamide fibre materials in high tinctorial yield, and give dyeings and printings with good fastness properties.
摘要翻译：式（1）的活性染料其中Z为式-CH = CH 2或-CH 2 -CH 2 -Y基团，Y为离去基团，K为式（2）或（3）其中X是式 - （CH2）n-Cl，或-CH = CH2的基团; 卤素是卤素; n为1,2,3或4; R是氢或未取代的或取代的C 1 -C 4烷基; R1是氨基或羟基; R2是甲基或羧基; 和R 3为氢，C 1 -C 4烷基，C 1 -C 4烷氧基，C 2 -C 4烷酰基氨基，卤素或羧基，特别适用于染色或印刷高亮度产率的纤维素纤维材料或天然或合成聚酰胺纤维材料，并具有良好的染色和印花坚牢性。

84. 发明授权

US5548071A Fiber-reactive triazine dyes with one AZO chromophore having a vinylsulfonyl type reactive radical and a second chromophore 失效
标题翻译：具有一个具有乙烯基磺酰基型反应性基团的AZO发色团的纤维反应性三嗪染料和第二种发色团
公开(公告)号：US5548071A
公开(公告)日：1996-08-20
申请号：US242562
申请日：1994-05-13
申请人： Rolf Deitz , Athanassios Tzikas , Paul Herzig
发明人： Rolf Deitz , Athanassios Tzikas , Paul Herzig
IPC分类号： C09B62/503 , C09B62/44 , D06P3/66 , C09B62/04 , D06P1/38
CPC分类号： C09B62/4403
摘要： The invention relates to compounds of the formula ##STR1## where the variables are each as defined in the claims. The compounds are suitable for use as dyes, in particular for dyeing and printing cellulose-containing fibre materials and produce dyeings and prints having good allround fastness properties.
摘要翻译：本发明涉及式（1）的化合物，其中变量各自如权利要求中所定义。该化合物适合用作染料，特别是用于染色和印刷含纤维素的纤维材料，并且生产具有良好全面牢固性能的染色和印花。

85. 发明授权

US5480976A Reactive dyes containing a vinylsulfonyl-substituted 2-aminonaphthalene coupling component and a haloacryloylaniline diazo component or the like 失效
标题翻译：含有乙烯基磺酰基取代的2-氨基萘偶联组分和卤代丙烯酰苯胺重氮组分等的活性染料
公开(公告)号：US5480976A
公开(公告)日：1996-01-02
申请号：US320085
申请日：1994-10-07
申请人： Athanassios Tzikas , Claudia Carisch
发明人： Athanassios Tzikas , Claudia Carisch
IPC分类号： C09B62/51 , C09B62/447 , C09B62/513 , D06P3/24 , D06P3/66 , C09B62/47 , C09B62/507 , D06P1/384
CPC分类号： C09B62/447
摘要： Reactive dyes of formula ##STR1## wherein X, Z, R.sub.1, R.sub.2, R.sub.3, R.sub.4 and m are as defined in claim 1, are particularly suitable for dyeing or printing cellulosic fiber materials or natural or synthetic polyamide fiber materials in high tinctorial yield, and give dyeings and prints with good fastness properties.
摘要翻译：式（1）的其中X，Z，R 1，R 2，R 3，R 4和m如权利要求1中所定义的式（1）的活性染料特别适用于染色或印刷纤维素纤维材料或天然或合成聚酰胺纤维材料染色和印花，色牢度好。

86. 发明授权

US5434252A Reactive dyes containing a 2,6-diaminopyridine coupling component 失效
标题翻译：含有2,6-二氨基吡啶偶联成分的活性染料
公开(公告)号：US5434252A
公开(公告)日：1995-07-18
申请号：US328599
申请日：1994-10-25
申请人： Paul Herzig , Athanassios Tzikas , Anton Andreoli , Claudia Carisch
发明人： Paul Herzig , Athanassios Tzikas , Anton Andreoli , Claudia Carisch
IPC分类号： C09B62/085 , C07D213/82 , C07D213/85 , C07D401/12 , C09B62/026 , C09B62/09 , C09B62/44 , C09B62/447 , C09B62/51 , C09B62/513 , C09B67/22 , C09B67/26 , D06P3/66 , D06P1/382
CPC分类号： C07D213/82 , C07D213/85 , C07D401/12 , C09B62/026 , C09B62/4401 , C09B62/447
摘要： Reactive dyes of the formula ##STR1## in which D, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are as defined in claim 1, are particularly suitable for dyeing or printing cellulosic fiber materials or naturally occurring or synthetic polyamide fiber materials with a high tinctorial yield, and produce dyeings and prints having good fastness properties.
摘要翻译：其中D，R1，R2，R3和R4如权利要求1中所定义的式（1）的活性染料特别适用于染色或印刷纤维素纤维材料或具有高的纤维素纤维材料或天然存在或合成的聚酰胺纤维材料并且产生具有良好坚牢性的染色和印花。

87. 发明授权

US5232462A Fibre-reactive dyes and dye mixtures and their use for dyeing or printing cotton 失效
标题翻译：纤维反应性染料和染料混合物及其用于染色或印花棉花的用途
公开(公告)号：US5232462A
公开(公告)日：1993-08-03
申请号：US764555
申请日：1991-09-20
申请人： Athanassios Tzikas
发明人： Athanassios Tzikas
IPC分类号： C07D251/50 , C09B62/02 , C09B62/04 , C09B62/06 , C09B62/085 , C09B62/09 , C09B62/095 , C09B62/10 , C09B67/22 , D06P1/38 , D06P1/382 , D06P3/66
CPC分类号： C09B62/04 , C09B62/02 , C09B67/004 , C09B67/0041 , C09B67/0042 , C09B67/0047 , Y10S8/918
摘要： The invention relates to dye mixtures which contain dyes of the formulae ##STR1## and to dyes of the formula ##STR2## in which A.sub.1, A.sub.2, A.sub.3, B, B.sub.1, R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5, Z.sub.1, Z.sub.2, X.sub.1, X.sub.2 and X.sub.3 are as defined in claim 1. The dyes and dye mixtures are distinguished by generally good properties and produce dyeings and prints having good wet and light fastness properties.
摘要翻译：本发明涉及染料混合物，其含有式（1）＆lt; IMAGE＆gt;（2）所述的染料和式（2a）的染料，其中A1，A2，A3，B，B1，R1， R2，R3，R4，R5，Z1，Z2，X1，X2和X3如权利要求1中所定义。染料和染料混合物通常具有良好的性能并产生具有良好的耐湿和耐光性的染色和印花。

88. 发明授权

US5212312A Vattable and non-vattable quinoid dyes 失效
标题翻译：增值税和非增值税金属染色体
公开(公告)号：US5212312A
公开(公告)日：1993-05-18
申请号：US912174
申请日：1986-09-22
申请人： Jean-Marie Adam , Athanassios Tzikas
发明人： Jean-Marie Adam , Athanassios Tzikas
IPC分类号： C09B69/00
CPC分类号： C09B69/001
摘要： Dyes of the formula ##STR1## in which F is the radical of an indigoid dye, of a benzothioxanthene or of an aromatic dye which contains at least 4 alicyclic and/or heterocyclic, fused six-membered rings and at least two ring keto groups and is not water-soluble, R.sub.1 is a substituted or unsubstituted C.sub.1-4 -alkyl radical, a substituted or unsubstituted cycloalkyl radical, a substituted or unsubstituted aryl radical or a radical of the formula--A--Qwhere A is a substituted or unsubstituted C.sub.1-4 -alkylene radical and Q is a basic radical, which may be quaternised, and R.sub.2 is hydrogen or a substituted or unsubstituted C.sub.1-4 -alkyl radical, or in which R.sub.1 and R.sub.2 together with the ##STR2## group are a phthalimide radical, and R.sub.3 is hydrogen, a substituted or unsubstituted C.sub.1-4 -alkyl radical, a substituted or unsubstituted aryl radical, a C.sub.1-4 -alkoxycarbonyl radical or a N,N-di-C.sub.1-4 -alkylcarboxamide radical and n is 1, 2, 3 or 4.The novel dyes are suitable as vat dyes for dyeing natural or regenerated cellulose and as cationic dyes for dyeing paper.
摘要翻译：式“IMAGE”的染料，其中F是靛类染料，苯并噻吩或芳族染料的基团，其含有至少4个脂环族和/或杂环稠合的六元环和至少两个环酮基团，不是水溶性的，R1是取代或未取代的C1-4 - 烷基，取代或未取代的环烷基，取代或未取代的芳基或式-AQ的基团，其中A是取代或未取代的C1-4 - 亚烷基，Q是碱性基团，其可以是季铵化的，并且R 2是氢或取代或未取代的C 1-4 - 烷基，或者其中R 1和R 2与基团一起是邻苯二甲酰亚胺基，和 R 3是氢，取代或未取代的C 1-4 - 烷基，取代或未取代的芳基，C 1-4 - 烷氧基羰基或N，N-二-C 1-4烷基羧酰胺基，n是1,2， 3或4.新染料适合用作染色天然或再生的瓮染料纤维素和用作染色纸的阳离子染料。

89. 发明授权

US5128456A Reactive dyes 失效
标题翻译：反应性染料
公开(公告)号：US5128456A
公开(公告)日：1992-07-07
申请号：US604551
申请日：1990-10-26
申请人： Athanassios Tzikas , Paul Herzig
发明人： Athanassios Tzikas , Paul Herzig
IPC分类号： C09B62/085 , D06P3/66
CPC分类号： C09B62/085
摘要： Novel reactive dyes of the formula ##STR1## in which (R).sub.0-3 is 0-3 substituents R, independent of one another, from the group comprising halogen, nitro, cyano, trifluoromethyl, sulfamoyl, carbamoyl, C.sub.1-4 alkyl, C.sub.1-4 alkoxy, amino, acetylamino, ureido, hydroxyl, carboxyl, sulfomethyl and sulfo, R.sub.1 is hydrogen, C.sub.1-8 alky or C.sub.5-7 cycloalkyl and R.sub.2 is C.sub.1-8 alkyl or C.sub.5-7 cycloalkyl, it being possible for the alkyl and cycloalkyl radicals R.sub.1 and R.sub.2 to be substituted independently of one another by hydroxyl, C.sub.1-4 alkoxy, hydroxy-C.sub.1-4 alkoxy, HO--(CH.sub.2 CH.sub.2 --O).sub.2-4 --, sulfato-C.sub.1-4 alkoxy, C.sub.2-4 alkanoyl, C.sub.1-4 alkoxy-carbonyl, C.sub.2-4 alkanoyloxy, carboxyl, cyano, halogen, C.sub.1-4 alkylamino, or N,N-Di-C.sub.1-4 alkylamino, or sulfato, or in which R.sub.1 is C.sub.1-8 alkyl or C.sub.5-7 cycloalkyl, and the alkyl or cycloalkyl radical can be substituted as defined, and R.sub.2 is a C.sub.1-8 alkyl or C.sub.5-7 cycloalkyl radical which is substituted by sulfo, give deep yellow to orange dyeings and prints with good fastness properties on cellulose fibres.
摘要翻译：式（1）的新型活性染料其中（R）0-3为0-3取代基R彼此独立地为卤素，硝基，氰基，三氟甲基，氨磺酰基，氨基甲酰基，C 1-4烷基，C 1-4烷氧基，氨基，乙酰氨基，脲基，羟基，羧基，磺基甲基和磺基，R 1是氢，C 1-8烷基或C 5-7环烷基，R 2是C 1-8烷基或C 5-7环烷基，烷基和环烷基 R 1和R 2彼此独立地被羟基，C 1-4烷氧基，羟基-C 1-4烷氧基，HO-（CH 2 CH 2 -O）2-4 - ，硫酸基-C 1-4烷氧基，C 2-4烷酰基，C 1-4烷氧基羰基 C 2-4烷酰氧基，羧基，氰基，卤素，C 1-4烷基氨基或N，N-二-C 1-4烷基氨基或硫酸酯，或其中R 1为C 1-8烷基或C 5-7环烷基，并且烷基或环烷基可为被定义为取代基，R2是被磺基取代的C 1-8烷基或C 5-7环烷基，在纤维素纤维上产生深黄色至橙色染色和具有良好牢度性质的印花。

90. 发明授权

US5081296A Bis(.beta.-hydroxyethylthio)-C.sub.1 -C.sub.4 -alkylamines 失效
标题翻译： BIS（（BETA）-HYOXOXYETHYLTHIO）-C1-C4-烷基胺
公开(公告)号：US5081296A
公开(公告)日：1992-01-14
申请号：US510384
申请日：1990-04-17
申请人： Athanassios Tzikas , Paul Herzig
发明人： Athanassios Tzikas , Paul Herzig
IPC分类号： C07C323/25 , C07C67/00 , C07C313/00 , C07C317/28 , C07C323/42 , C07D213/69 , C07D231/22 , C07D251/50 , C07D251/52 , C07D498/04 , C09B62/44 , C09B62/503
CPC分类号： C09B62/4401 , C09B62/503
摘要： This application relates to intermediates useful for the preparation of fiber-reactive dyes, said intermediates having the formulae ##STR1## in which B is a --(CH.sub.2).sub.n -- or --O--(CH.sub.2).sub.n -- radical, where n is 1 to 6; Q is selected from the group consisting of hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, halogen, carboxyl and sulfo; and A is an amino substituent of the formula ##STR2## and Z and Z', independently of one another, are .beta.-sulfatoethyl, .beta.-thiosulfatoethyl, .beta.-phosphatoethyl, .beta.-acyloxyethyl, .beta.-haloethyl or vinyl.
摘要翻译：本申请涉及可用于制备纤维活性染料的中间体，所述中间体具有式（IMAGE）＆lt; IMAGE＆gt;和＆lt; IMAGE＆gt;（31）或其中B是 - （CH 2）n - 或-O-（CH 2）n - 基，其中n为1至6; Q选自氢，C 1 -C 4烷基，C 1 -C 4烷氧基，卤素，羧基和磺基; 并且A是式（1a）的氨基取代基，Z和Z'彼此独立地是β-磺基乙基，β-硫代硫代乙基，β-磷酸乙基，β-酰氧基乙基，β-卤代乙基或乙烯基。

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