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71. 发明授权

US6124416A Aqueous emulsion of (CO) polymer made from monomer containing isocyanate group and olefinic double bond 有权
标题翻译：由含有异氰酸酯基团和烯属双键的单体制备的（CO）聚合物的水乳液
公开(公告)号：US6124416A
公开(公告)日：2000-09-26
申请号：US251745
申请日：1999-02-18
申请人： Michel Desbois , Roland Reeb , Joel Richard , Fran.cedilla.oise Truchet
发明人： Michel Desbois , Roland Reeb , Joel Richard , Fran.cedilla.oise Truchet
IPC分类号： C07D521/00 , C07C275/62 , C08F2/22 , C08F12/00 , C08F16/36 , C08F20/34 , C08F20/36 , C08F20/52 , C08F20/60 , C08F26/00 , C08F212/00 , C08F214/06 , C08F214/08 , C08F218/02 , C08F218/04 , C08F220/10 , C08F220/36 , C08F220/42 , C08F220/44 , C08F220/54 , C08F222/22 , C08F226/00 , C08G18/46 , C08G18/67 , C08G18/72 , C08G18/80 , C08G18/81 , C08L31/02 , C08L31/04 , C08L33/04 , C08L33/18 , C08L33/24 , C08L39/00 , C08F26/02 , C08F26/06 , C08L39/04
CPC分类号： C08G18/4676 , C08F16/36 , C08F20/36 , C08F20/60 , C08G18/728 , C08G18/8077 , C08G18/8175
摘要： An aqueous emulsion comprising at least one (co)polymer is provided. The (co)polymer is derived from a monomer having formula (1):(R.sub.1 R.sub.2 C.dbd.CR.sub.3 --CO--L--).sub.q A(--NCOblock).sub.p(1)wherein R.sub.1, R.sub.2, and R.sub.3, which are the same or different, represent a hydrogen or a group selected from hydrocarbon chains comprising 1 to 12 carbon atoms, halogens, and electron-withdrawing functional groups; L, which is the same or different, represents a divalent hydrocarbon radical comprising 2 to 12 carbon atoms; A represents an organic backbone which has n free valencies, n is a number between 2 and 7, and is equal to p+q; NCOblock represents a protected isocyanate functional group; p is a number between 1 and 6; and q is a number between 1 and 6.
摘要翻译：提供包含至少一种（共）聚合物的水性乳液。（共）聚合物衍生自具有式（1）的单体:( R1R2C = CR3-CO-L-）qA（-NCOblock）p（1）其中R1，R2和R3相同或不同，表示氢或选自包含1至12个碳原子的烃链，卤素和吸电子官能团的基团; L相同或不同，表示包含2至12个碳原子的二价烃基; A表示具有n个自由价的有机骨架，n是2和7之间的数，并且等于p + q; NCOblock表示受保护的异氰酸酯官能团; p是1到6之间的数字; q是1到6之间的数字。

72. 发明授权

US6114402A Modified rigid, foamable urethane composition and method 失效
标题翻译：改性刚性，发泡聚氨酯组合物和方法
公开(公告)号：US6114402A
公开(公告)日：2000-09-05
申请号：US943348
申请日：1997-10-03
申请人： Stuart B. Smith
发明人： Stuart B. Smith
IPC分类号： C08J9/04 , B29C44/00 , B29K75/00 , B29K105/04 , B32B5/18 , B32B5/20 , B32B27/36 , B32B27/40 , C08G18/30 , C08G18/48 , C08G18/67 , C08G18/81 , C08G18/10 , C08J9/08
CPC分类号： B32B5/18 , B32B27/40 , C08G18/482 , C08G18/6715 , C08G18/673 , C08G18/8166 , C08G18/8175 , C08G2101/0025 , C08G2101/0083 , C08G2105/06 , Y10T428/1376 , Y10T428/24512 , Y10T428/249958 , Y10T428/249982 , Y10T428/249984 , Y10T428/249985 , Y10T428/249991 , Y10T428/31565
摘要： A polyurethane composition to provide a rigid polyurethane foam suitable for use as a core material in a composite laminate and which polyurethane composition includes an additive compound or oligomer-prepolymer having hydroxy groups for reaction with the diisocyanate of the polyurethane or which has been prereacted with a diisocyanate and which contains after the polyurethane reaction ethylenically unsaturated groups, like allyl or acrylic groups, to react with an unsaturated polyester resin. The invention includes the organic additive oligomer-prepolymer and the hybrid polyester-rigid polyurethane laminates.
摘要翻译：一种聚氨酯组合物，其提供适合用作复合层压体中的芯材的硬质聚氨酯泡沫体，并且该聚氨酯组合物包含具有羟基的添加剂化合物或低聚物预聚物，用于与聚氨酯的二异氰酸酯反应或已经与二异氰酸酯，并且其在聚氨酯反应之后含有烯键式不饱和基团（如烯丙基或丙烯酸基）与不饱和聚酯树脂反应。本发明包括有机添加剂低聚物预聚物和混合聚酯 - 硬质聚氨酯层压材料。

73. 发明授权

US06107361A Solvent-free, radiation-curable, optical glass fiber coating composition and solvent-free method for making a solvent-free, radiation-curable, optical glass fiber coating composition 失效
标题翻译：无溶剂，可辐射固化，光学玻璃纤维涂料组合物和无溶剂方法制备无溶剂，可辐射固化的光学玻璃纤维涂料组合物
公开(公告)号：US06107361A
公开(公告)日：2000-08-22
申请号：US168290
申请日：1998-10-08
申请人： Anthony J. Tortorello , Edward J. Murphy
发明人： Anthony J. Tortorello , Edward J. Murphy
IPC分类号： C03C25/24 , C03C25/10 , C08F2/06 , C08F2/50 , C08F8/30 , C08F290/12 , C08G18/62 , C08G18/81 , C09D4/06 , G03F7/027 , G03F7/038 , C08G18/10 , C08G18/12
CPC分类号： G03F7/0388 , C03C25/1055 , C03C25/106 , C03C25/1065 , C08G18/6229 , C08G18/8158 , G03F7/027 , Y10T428/2938
摘要： The invention relates to a solvent-free radiation curable, optical glass fiber coating composition containing:a) a urethane oligomer having a functional group capable of polymerization in the presence of actinic radiation, with an average functionality of at least about 1.2, having a vinyl addition polymer as backbone.b) a urethane compound having a functional group capable of polymerization in the presence of actinic radiation, with an average functionality of at least about 1, containing an organic moiety having about 5 or more carbon atoms as backbone.c) a reactive diluent.Furthermore, the invention relates to a solvent-free method for producing a solvent-free, radiation curable urethane oligomer composition.
摘要翻译：本发明涉及无溶剂的可辐射固化的光学玻璃纤维涂料组合物，其含有：a）具有能在光化辐射存在下能够聚合的官能团的氨基甲酸酯低聚物，平均官能度至少为约1.2，具有乙烯基加成聚合物作为骨架。 b）具有能够在光化辐射存在下能够聚合的官能团的氨基甲酸酯化合物，其平均官能度为至少约1，其含有具有约5个或更多个碳原子的有机部分作为主链。 c）反应性稀释剂。此外，本发明涉及一种无溶剂的无辐射固化型氨基甲酸酯低聚物组合物的制造方法。

74. 发明授权

US6080812A Water-dispersible blocked isocyanate composition, and water-base paint composition and water-base adhesive composition using the same 失效
标题翻译：水分散性封端异氰酸酯组合物和水基涂料组合物和使用其的水基粘合剂组合物
公开(公告)号：US6080812A
公开(公告)日：2000-06-27
申请号：US373543
申请日：1999-08-13
申请人： Takeshi Morishima , Shogo Itoh , Shin Konishi
发明人： Takeshi Morishima , Shogo Itoh , Shin Konishi
IPC分类号： C08G18/70 , C08G18/80 , C08J3/00 , C08G18/81 , C08K3/20 , C08L75/00
CPC分类号： C08G18/706 , C08G18/8016 , C08G18/8051 , C08G18/807 , C08G2105/02 , C08G2170/80
摘要： A water-dispersible blocked isocyanate composition, including an isocyanate group-terminated precursor and a blocking agent for blocking a free isocyanate group of the precursor, wherein the precursor includes at least an organic diisocyanate, a low-molecular glycol, and a hydrophilic surfactant having at least one active hydrogen group. The precursor also has an isocyanurate ring structure; an average functional group number (f) satisfying 2.0.ltoreq.f.ltoreq.4.2; a low-molecular glycol content (X) satisfying 0.5 wt. %.ltoreq..times..ltoreq.15 wt. %; and a hydrophilic surfactant content(Y) satisfying 0.1 wt. %.ltoreq.Y.ltoreq.50 wt. %.
摘要翻译：一种水分散性封端异氰酸酯组合物，其包括异氰酸酯基封端的前体和用于封闭前体的游离异氰酸酯基的封闭剂，其中前体包括至少一种有机二异氰酸酯，低分子量二醇和亲水性表面活性剂，其具有至少一个活性氢基团。前体还具有异氰脲酸酯环结构; 平均官能团数（f）满足2.0

75. 发明授权

US5990345A Process for preparation of ethylenically unsaturated isocyanates 失效
标题翻译：制备烯属不饱和异氰酸酯的方法
公开(公告)号：US5990345A
公开(公告)日：1999-11-23
申请号：US982654
申请日：1997-12-02
申请人： Dieter Lohmann , Rudolf Duthaler
发明人： Dieter Lohmann , Rudolf Duthaler
IPC分类号： C07C263/00 , C07C263/04 , C07C265/04 , C07C265/06 , C08F12/22 , C08F12/26 , C08F20/10 , C08F20/36 , C08G18/81
CPC分类号： C07C263/04
摘要： A process for the preparation of ethylenically unsaturated isocyanates is described, which process comprises silylating an appropriate ethylenically unsaturated urethane precursor at the urethane nitrogen and converting the resulting unsaturated N-silyl-urethane by means of thermolysis at elevated temperature into the desired isocyanate. The unsaturated isocyanates obtainable according to the process are suitable, for example, as monomers or comonomers in the preparation of polymerisates or copolymerisates.
摘要翻译：描述了制备烯属不饱和异氰酸酯的方法，该方法包括在氨基甲酸乙酯氮上甲酰化适当的烯属不饱和氨基甲酸酯前体，并通过在升高的温度下热解将所得的不饱和N-甲硅烷基 - 氨基甲酸酯转化成所需的异氰酸酯。根据该方法可获得的不饱和异氰酸酯在制备聚合物或共聚物时适用于例如单体或共聚单体。

76. 发明授权

US5981684A Highly functionalized polyurethanes 失效
标题翻译：高功能化聚氨酯
公开(公告)号：US5981684A
公开(公告)日：1999-11-09
申请号：US973729
申请日：1997-12-15
申请人： Bernd Bruchmann , Frank Wingerter , Hermann Graf , Stefan Wolff
发明人： Bernd Bruchmann , Frank Wingerter , Hermann Graf , Stefan Wolff
IPC分类号： C08G18/06 , C08F283/00 , C08G18/10 , C08G18/28 , C08G18/32 , C08G18/80 , C08G18/83 , C08G83/00 , C09D201/00 , C08G18/81 , C08G18/00
CPC分类号： C08G83/003 , C08G18/2825 , C08G18/3203 , C08G18/3275 , C08G18/8064 , C08G18/8077 , C08G18/832 , C09D201/005
摘要： The invention relates to highly functionalized polyurethanes which are synthesized from molecules containing the functional groups A(B).sub.n, where A is an NCO group or a group reactive with an NCO group, B is an NCO group or a group reactive with an NCO group, A is reactive with B and n is a positive number and is at least equal to 2.
摘要翻译： PCT No.PCT / EP96 / 02705 Sec。 371 1997年12月15日第 102（e）日期1997年12月15日PCT提交1996年6月21日PCT公布。公开号WO97 / 02304 日期1997年1月23日本发明涉及由含有官能团A（B）n的分子合成的高官能化聚氨酯，其中A为NCO基团或与NCO基团反应的基团，B为NCO基团或基团与NCO基团反应，A与B反应，n是正数，并且至少等于2。

77. 发明授权

US5951911A Low viscosity ethylenically unsaturated polyurethanes containing allophanate groups 失效
标题翻译：含有脲基甲酸酯基团的低粘度烯属不饱和聚氨酯
公开(公告)号：US5951911A
公开(公告)日：1999-09-14
申请号：US5272
申请日：1998-01-09
申请人： Lanny D. Venham , Arthur W. Mason , Michael K. Jeffries , Michael J. Dvorchak
发明人： Lanny D. Venham , Arthur W. Mason , Michael K. Jeffries , Michael J. Dvorchak
IPC分类号： C08F290/06 , C08G18/67 , C08G18/68 , C08G18/78 , C08G18/81 , C08G18/83 , C09D175/14
CPC分类号： C08G18/68 , C08G18/672 , C08G18/7837 , C08G18/8166 , C09D175/14
摘要： The present invention relates to ethylenically unsaturated polyurethanes which are substantially free from isocyanate groups and havea) a content of .beta.,.gamma.-ethylenically unsaturated ether groups (calculated as C.dbd.C, MW 24) incorporated through allophanate groups of 0.5 to 10% by weight,b) an allophanate group content (calculated as N.sub.2 C.sub.2 HO.sub.3, MW 101) of 1 to 20% by weight andc) a total content of ethylenically unsaturated groups of (calculated as C.dbd.C, MW 24) of 1 to 15% by weight.The present invention also relates to ethylenically unsaturated polyisocyanates which contain allophanate groups and havei) an NCO content of 5 to 25% by weight,ii) a content of .beta.,.gamma.-ethylenically unsaturated ether groups (calculated as C.dbd.C, MW 24) incorporated through allophanate groups of 0.5 to 15% by weight andiii) an allophanate group content (calculated as N.sub.2 C.sub.2 HO.sub.3, MW 101) of 1 to 30%.Finally, the present invention relates to one-component coating compositions containing the ethylenically unsaturated polyurethanes according to the invention.
摘要翻译：本发明涉及烯属不饱和聚氨酯，其基本上不含异氰酸酯基团，并且具有a）通过脲基甲酸酯基团通过0.5至10％的通过以下方式引入的β，γ-烯属不饱和醚基团的含量（以C = C，MW 24计算）重量，b）脲基甲酸酯基含量（以N2C2HO3，MW101计算）为1〜20重量％，c）（计算为C = C，MW 24）的烯属不饱和基团的总含量为1〜15％重量。本发明还涉及含有脲基甲酸酯基并且i）NCO含量为5至25重量％的烯属不饱和多异氰酸酯，ii）β，γ-烯属不饱和醚基团的含量（按C = C计算，MW 24 ）通过0.5至15重量％的脲基甲酸酯基组合，和iii）脲基甲酸酯基含量（以N 2 C 2 HO 3，MW 101计算）为1至30％。最后，本发明涉及含有根据本发明的烯属不饱和聚氨酯的单组分涂料组合物。

78. 发明授权

US5945498A Polysiloxane-comprising perfluoroalkyl ethers and the preparation and use thereof 失效
标题翻译：含全氟烷基醚的聚硅氧烷及其制备及应用
公开(公告)号：US5945498A
公开(公告)日：1999-08-31
申请号：US776985
申请日：1997-12-22
申请人： Jens Hopken , Dieter Lohmann , Angelika Domschke
发明人： Jens Hopken , Dieter Lohmann , Angelika Domschke
IPC分类号： G02C7/04 , A61F20060101 , A61F2/14 , A61L27/00 , A61L27/26 , A61L27/34 , B05D7/24 , B29C39/42 , B29C71/00 , B29D11/00 , C08F220/22 , C08F290/06 , C08F290/14 , C08F299/02 , C08F299/08 , C08G20060101 , C08G18/10 , C08G18/48 , C08G18/50 , C08G18/61 , C08G18/67 , C08G18/81 , C08G18/83 , C08G77/00 , C08G77/04 , C08G77/46 , C08J5/00 , C08K3/00 , C08L20060101 , C08L33/08 , C08L33/10 , C08L83/04 , G02B1/04 , G02C20060101 , C08G77/24
CPC分类号： B29D11/00076 , A61L27/26 , A61L27/34 , B05D1/62 , B29C39/42 , C08G18/10 , C08G18/4833 , C08G18/5015 , C08G18/61 , C08G18/672 , C08G18/8116 , C08G18/8175 , G02B1/043 , B29C71/00 , B29L2011/0041 , Y10S525/903 , Y10S525/936 , Y10S525/937 , Y10T428/3154 , Y10T428/31544 , Y10T428/31663
摘要： The present invention describes a free radical polymerizable segmented macromonomer based on perfluoroelkyl ether, polysiloxane and divalent organic segments. This macromoner can be polymerized and used to form moldings, contact lenses, corneal implants and other biomedical articles.
摘要翻译： PCT No.PCT / EP96 / 01255 Sec。 371 1997年12月22日第 102（e）日期1997年12月22日PCT提交1996年3月22日PCT公布。公开号WO96 / 31791 日期：1996年10月10日本发明描述了基于全氟烷基醚，聚硅氧烷和二价有机链段的自由基可聚合分段大分子单体。这种大分子单体可以被聚合并用于形成模制品，隐形眼镜，角膜植入物和其它生物医学制品。

79. 发明授权

US5905121A Active ester urethane crosslinking agents and their use in film-forming compositions 失效
标题翻译：活性酯聚氨酯交联剂及其在成膜组合物中的应用
公开(公告)号：US5905121A
公开(公告)日：1999-05-18
申请号：US994610
申请日：1997-12-19
申请人： Padmanabhan Sundararaman
发明人： Padmanabhan Sundararaman
IPC分类号： C08G18/80 , C08F20/00 , C08G18/81
CPC分类号： C08G18/8064
摘要： An active ester compound having an alkoxy group is provided having the structure: wherein:R.sup.1 is derived from a polyisocyanate R.sup.1 (NCO).sub.m reacted with an active hydrogen-containing material to form the urethane group in the compound;m is an integer of at least 2; andR.sup.2 and R.sup.3 are independently alkyl groups having from 1 to 4 carbon atoms.The compound is useful as a crosslinking agent when combined with active hydrogen-containing resinous binders in curable film-forming compositions.
摘要翻译：提供了具有烷氧基的活性酯化合物，其具有以下结构：其中：R1衍生自与含活性氢的材料反应形成化合物中的氨基甲酸酯基团的多异氰酸酯R 1（NCO）m; m为至少2的整数; R2和R3独立地为具有1-4个碳原子的烷基。当与可固化成膜组合物中的含活性氢的树脂粘合剂组合时，该化合物可用作交联剂。

80. 发明授权

US5637745A Organometallic compounds and polymers made therefrom 失效
标题翻译：有机金属化合物和由其制成的聚合物
公开(公告)号：US5637745A
公开(公告)日：1997-06-10
申请号：US380095
申请日：1995-01-30
申请人： Gary S. Silverman , Haewon L. Uhm , Kenneth K. S. Tseng
发明人： Gary S. Silverman , Haewon L. Uhm , Kenneth K. S. Tseng
IPC分类号： A01N61/00 , A01N25/10 , C07F9/00 , C07F9/141 , C07F9/68 , C07F9/90 , C07F9/94 , C07F19/00 , C08F20/18 , C08F20/26 , C08F30/04 , C08F220/06 , C08F220/10 , C08F220/18 , C08F230/04 , C08G18/81 , C08G61/10 , C08G61/12 , C08G63/00 , C08G73/00 , C08L33/10 , C09D5/14 , C09D5/16 , C09D133/04 , C09D133/06 , C09D143/00 , C09K3/00 , C07F1/08 , C07F3/00 , C07F15/00
CPC分类号： C07F9/1417 , A01N25/10 , C08F30/04 , C09D5/1625 , C09D5/1637
摘要： Compounds of formula (I) are disclosed: ##STR1## wherein L.sup.1 is a main group atom, L.sup.2 is a neutral ligand, M is a transition element or a metal element of Group 13, 14, 15, or 16 of the Periodic Table, x is the number of coordination sites of M, R.sup.1 is a polymerizable group, R.sup.2, R.sup.3, and R.sup.4 are ligands, and R.sup.5 is an anionic ligand. The compounds or monomers of formula (I) are capable of conversion to polymers by combination with one or more other known monomers, such as methyl methacrylate. Such polymers can then be added as a binder in a paint formulation to make marine antifouling coating compositions. Also described is a method to prevent fouling on surfaces wherein a composition containing a metal complex compound of formula (II): ##STR2## wherein M, x, L.sup.2, n, and R.sup.4 have the same meaning as in formula (I), is applied to the surface susceptible to fouling.
摘要翻译：公开了式（I）的化合物：其中L 1是主要原子，L 2是中性配体，M是周期表第13,14,15或16族的过渡元素或金属元素， x是M的配位点数，R1是可聚合基团，R2，R3和R4是配体，R5是阴离子配体。式（I）的化合物或单体可以通过与一种或多种其它已知的单体如甲基丙烯酸甲酯的组合转化成聚合物。然后可以将这样的聚合物作为粘合剂加入到油漆配方中以制备海洋防污涂料组合物。还描述了防止在其上含有式（II）的金属络合物：其中M，x，L2，n和R4具有与式（I）中相同含义的式（II）的金属络合物的组合物的表面上的结垢的方法：应用于容易污染的表面。

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