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71. 发明授权

US08518351B2 Apparatus for producing diesel 有权
标题翻译：柴油生产设备
公开(公告)号：US08518351B2
公开(公告)日：2013-08-27
申请号：US13076631
申请日：2011-03-31
申请人： Andrew P. Wieber , Paul R. Zimmerman
发明人： Andrew P. Wieber , Paul R. Zimmerman
IPC分类号： B01J8/04 , B01J8/00 , B01J19/00 , C07C1/00 , C07C2/00 , C07C4/00 , C07C5/00 , C07C6/00 , C10G69/00 , C10G47/00
CPC分类号： B01D3/009 , B01J8/00 , C10G7/08 , C10G45/02 , C10G45/32 , C10G45/44 , C10G47/00 , C10G47/04 , C10G47/14 , C10G47/16 , C10G65/12 , C10G69/02 , C10G2400/04 , C10G2400/30
摘要： An apparatus is disclosed for hydrocracking hydrocarbon feed in a hydrocracking unit and hydrotreating a diesel product from the hydrocracking unit in a hydrotreating unit. The hydrocracking unit and the hydrotreating unit shares the same recycle gas compressor. A warm separator separates recycle gas and hydrocarbons from diesel in the hydrotreating effluent, so fraction of the diesel is relatively simple. The warm separator also keeps the diesel product separate from the more sulfurous diesel in the hydrocracking effluent, and still retains heat needed for fractionation of lighter components from the low sulfur diesel product.
摘要翻译：公开了一种用于在加氢裂化装置中加氢裂化烃进料并在加氢处理装置中从加氢裂化装置加氢处理柴油产品的装置。加氢裂化装置和加氢处理装置共享相同的循环气体压缩机。热分离器在加氢处理流出物中将循环气体和碳氢化合物与柴油分离，因此柴油馏分比较简单。暖型分离器还使柴油机与加氢裂化废液中的更多的亚硫酸柴油分离，并且仍然保留了从低硫柴油产品中分馏较轻组分所需的热量。

72. 发明授权

US08487147B2 Nano-catalyst for fast track bio-diesel production from non-edible oils 失效
标题翻译：用于非食用油快速生物柴油生产的纳米催化剂
公开(公告)号：US08487147B2
公开(公告)日：2013-07-16
申请号：US12714730
申请日：2010-03-01
申请人： Syed Tajammul Hussain , M. Bilal Khan
发明人： Syed Tajammul Hussain , M. Bilal Khan
IPC分类号： C07C1/00
CPC分类号： C10L1/026 , B01J21/063 , B01J27/04 , B01J35/1047 , B01J37/031 , Y02E50/13
摘要： Doped nanomaterials are used for the conversion of non-edible oils into biodiesels.
摘要翻译：掺杂的纳米材料用于将非食用油转化为生物柴油。

73. 发明授权

US08450233B2 Process for obtaining catalyst composites comprising MeAPO and their use in conversion of organics to olefins 失效
标题翻译：用于获得包含MeAPO的催化剂复合物的方法及其在将有机物转化为烯烃中的用途
公开(公告)号：US08450233B2
公开(公告)日：2013-05-28
申请号：US12811218
申请日：2009-01-23
申请人： Nikolai Nesterenko , Walter Vermeiren , Sander Van Donk
发明人： Nikolai Nesterenko , Walter Vermeiren , Sander Van Donk
IPC分类号： B01J29/06 , C08F2/00 , C07C1/00
CPC分类号： C07C1/32 , B01J29/005 , B01J29/40 , B01J29/85 , B01J2229/186 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C1/26 , Y02P30/42 , C07C11/02
摘要： The present invention relates to a mixture comprising 0.01 to 30% by weight of at least one medium or large pore crystalline silicoaluminate, silicoaluminophosphate materials or silicoaluminate mesoporous molecular sieves (co-catalyst) (A) and respectively 99.99 to 70% by weight of at least a MeAPO molecular sieve. The present invention also relates to catalysts consisting of the above mixture or comprising the above mixture. The present invention also relates to a process (hereunder referred as “XTO process”) for making an olefin product from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock, wherein said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock is contacted with the above catalyst (in the XTO reactor) under conditions effective to convert the oxygen-containing, halogenide-containing or sulphur-containing organic feedstock to olefin products (the XTO reactor effluent). The present invention also relates to a process (hereunder referred as “combined XTO and OCP process”) to make light olefins from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in the XTO reactor with the above catalyst at conditions effective to convert at least a portion of the feedstock to form an XTO reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; and contacting said heavy hydrocarbon fraction in the OCP reactor at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins.
摘要翻译：本发明涉及包含0.01至30重量％的至少一种中等或大孔结晶硅铝酸盐，硅铝磷酸盐材料或硅铝酸盐介孔分子筛（助催化剂）（A）和分别为99.99至70重量％至少一种MeAPO分子筛。本发明还涉及由上述混合物组成或包含上述混合物的催化剂。本发明还涉及从含氧卤化物或含硫有机原料制备烯烃产物的方法（以下称为“XTO法”），其中所述含氧卤化物或含硫化合物的含硫或含硫有机原料，含有有机原料的有机原料在有效将含氧卤化物或含硫有机原料转化为烯烃产物（XTO反应器流出物）的条件下与上述催化剂（在XTO反应器中）接触。本发明还涉及从含氧的含卤化物或含硫有机原料制备轻质烯烃的方法（以下称为“组合的XTO和OCP方法”），包括：使含有氧的含卤素的或含硫有机原料在具有上述催化剂的XTO反应器中，在有效地转化至少一部分原料以形成包含轻质烯烃和重质烃馏分的XTO反应器流出物的条件下; 将所述轻质烯烃与所述重质烃馏分分离; 并在有效将至少一部分所述重质烃馏分转化成轻质烯烃的条件下使OCP反应器中的所述重质烃馏分接触。

74. 发明申请

US20130055632A1 METHODS AND PROCEDURES FOR PRODUCING USEFUL PRODUCTS FROM WASTE MATERIALS 有权
标题翻译：从废物中生产有用的产品的方法和程序
公开(公告)号：US20130055632A1
公开(公告)日：2013-03-07
申请号：US13579526
申请日：2011-02-21
申请人： Dieter Peter Petry , Aldo Mario Higinio Acosta Ayala , Andres Anastacio Barrios Maciel , Leon Isaac Vera Vera
发明人： Dieter Peter Petry , Aldo Mario Higinio Acosta Ayala , Andres Anastacio Barrios Maciel , Leon Isaac Vera Vera
IPC分类号： C01B3/02 , C07C4/00 , C07C51/00 , C07C63/06 , C07C1/00 , C07C57/145 , C07C53/00 , C07C53/08 , C07C53/02 , C10G1/04 , C10L5/44 , C07C55/22
CPC分类号： C10L5/46 , C10B19/00 , C10B53/00 , C10B53/02 , C10L5/42 , C10L5/44 , Y02E50/10 , Y02E50/14 , Y02E50/30
摘要： The invention relates to a method for producing coal, asphalt, liquid hydrocarbon, organic acids, methane gas and/or hydrogen from a waste material comprising: a) providing a waste material; b) subjecting the waste material to irradiation with low frequency macro waves, with a wavelength of between 700 nm and 1 mm, whereby the temperature is between 2050 C and 9000 C and the pressure is between 1.0 bar and 19.0 bar, thereby producing coal; c) optionally subjecting the residual materials in gaseous state from step b) to a physicochemical reaction in the presence of a solid metal identified as DPP B102, whereby the temperature is between 1800 C and 5000 C and the pressure is between 0.98 bar and 5.5 bar, thereby producing asphalt; d) optionally subjecting the residual materials in gaseous state from step b) or c) to a physicochemical reaction and/or condensation, whereby the temperature is between 1500 C and 7500 C and the pressure is between 0.96 bar and 200 bar, thereby producing liquid hydrocarbon; e) optionally subjecting the residual materials in gaseous state from step b), c) or d) to a physicochemical reaction in the presence of a solid metal identified as DPP D102, whereby the temperature is between 500 C and 1500 C and the pressure is between 0.95 bar and 1.5 bar, thereby producing organic acids; f) optionally subjecting the residual materials in gaseous state from step b), c) d) or e) to an absorbent wash and cooling at room temperature, thereby producing methane gas and hydrogen, whereinsaid waste material has a composition with a carbon content of 9-85%, a hydrogen content of 1-15% and an oxygen content of 0-65% based on dry weight of the material. The invention further relates to products obtainable by such methods and an apparatus for performing such methods.
摘要翻译：本发明涉及一种从废料生产煤，沥青，液态烃，有机酸，甲烷气和/或氢的方法，包括：a）提供废料; b）使废料以波长在700nm和1mm之间的低频宏波照射，由此温度在2050℃和9000℃之间，压力在1.0巴和19.0巴之间，从而产生煤; c）任选地在被鉴定为DPP B102的固体金属的存在下将来自步骤b）的气态残留物质进行物理化学反应，由此温度在1800℃和5000℃之间，压力在0.98bar和5.5bar之间，从而生产沥青; d）任选地将来自步骤b）或c）的气态残留物质经历物理化学反应和/或冷凝，由此温度在1500℃和7500℃之间，压力在0.96巴和200巴之间，从而产生液体烃; e）在被鉴定为DPP D102的固体金属的存在下，任选地使来自步骤b），c）或d）的气态残留物质经历物理化学反应，由此温度在500℃和1500℃之间，压力为在0.95巴和1.5巴之间，从而产生有机酸; f）任选地使来自步骤b），c）d）或e）的气态残留物质在室温下进行吸收性洗涤和冷却，由此产生甲烷气体和氢气，其中所述废物具有碳含量的组成的9-85％，氢含量为1-15％，氧含量为0-65％，基于材料的干重。本发明还涉及通过这些方法可获得的产品和用于执行这些方法的装置。

75. 发明申请

US20130030234A1 Single Module Apparatus for Production of Hydro-Carbons and Method of Synthesis 审中-公开
标题翻译：用于生产碳氢化合物的单一模块装置及其合成方法
公开(公告)号：US20130030234A1
公开(公告)日：2013-01-31
申请号：US13306209
申请日：2011-11-29
申请人： Viktor V. Astafiev , Sergii G. Iakovliev , Alexander Kozlov , Sergii A. Lytvynenko
发明人： Viktor V. Astafiev , Sergii G. Iakovliev , Alexander Kozlov , Sergii A. Lytvynenko
IPC分类号： C07C1/00 , B01J19/00
CPC分类号： C10G2/35 , C10G2300/805
摘要： Disclosed herein is a method to synthesize hydrocarbons directly from water and atmospheric air in the presence of small amount of hydrocarbons. A module apparatus for gaseous and liquid hydrocarbons production and a technological process of hydrocarbons synthesis is provided. The peculiarity of the developed technological process is that atmospheric air and water are consumed in the process of synthesis, while a hydrocarbon matrix is maintained unconsumed.The apparatus consists of a hydrocarbon synthesis chamber, a sump tank to collect hydro carbonic condensation derived in the process of synthesis, and a bubbling chamber. All of the chambers as well as sump tank are interconnected by means of pipes. The synthesis chamber is equipped with devices to supply water. Furthermore, the bumbling chamber is equipped with device to supply atmospheric air inside the chamber.
摘要翻译：本文公开了一种在少量烃存在下直接从水和大气中合成碳氢化合物的方法。提供了一种用于气态和液态碳氢化合物生产的模块装置以及烃类合成技术过程。发达的技术过程的特点是在合成过程中大气和水被消耗，而烃基质保持未被消耗。该装置由烃合成室，用于收集合成过程中得到的碳氢化合物缩合物的沉淀池和鼓泡室组成。所有的室以及贮槽通过管道相互连接。合成室装有供水的装置。此外，笨重的房间配备有在室内供应大气的装置。

76. 发明申请

US20130023707A1 METHOD AND SYSTEM FOR BIOMASS HYDROGASIFICATION 有权
标题翻译：生物量加氢法的方法与系统
公开(公告)号：US20130023707A1
公开(公告)日：2013-01-24
申请号：US13474453
申请日：2012-05-17
申请人： Bowie G. Keefer , Matthew L. Babicki , Brian G. Sellars , Edson Ng
发明人： Bowie G. Keefer , Matthew L. Babicki , Brian G. Sellars , Edson Ng
IPC分类号： C07C1/00 , B01J8/04
CPC分类号： C10L3/08 , B01J38/12 , B01J38/22 , C01B3/38 , C01B3/503 , C01B3/56 , C01B2203/0233 , C01B2203/0405 , C01B2203/042 , C01B2203/0475 , C01B2203/048 , C01B2203/062 , C01B2203/148 , C10B49/22 , C10B53/02 , C10G2/32 , C10G2300/708 , C10K1/026 , C10K1/32 , C10K3/04 , C10L3/104 , C10L3/106 , C10L2290/02 , C10L2290/08 , C10L2290/12 , C10L2290/38 , C25B1/04 , Y02E20/16 , Y02E50/14 , Y02E50/32 , Y02E60/366 , Y02P20/133 , Y02P20/134 , Y02P20/145 , Y02P20/584
摘要： The present invention provides a system and method for producing hydrocarbons from biomass. The method is particularly useful for producing substitute natural gas from forestry residues. Certain disclosed embodiments convert a biomass feedstock into a product hydrocarbon by fast pyrolysis. The resulting pyrolysis gas is converted to the product hydrocarbon and carbon dioxide in the presence of hydrogen and steam while simultaneously generating the required hydrogen by reaction with steam under prescribed conditions for self-sufficiency of hydrogen. Methane is a preferred hydrocarbon product. A system also is disclosed for cycling the catalyst between steam reforming, methanation and regeneration zones.
摘要翻译：本发明提供一种从生物质中生产碳氢化合物的系统和方法。该方法对于生产来自林业残留物的替代天然气特别有用。某些公开的实施方案通过快速热解将生物质原料转化成产物烃。将得到的热分解气体被转化为产物烃和二氧化碳在氢气和蒸汽存在下，同时为氢的自给自足规定的条件下同时产生通过与蒸汽反应所需的氢。甲烷是优选的烃产物。公开了一种用于在蒸汽重整，甲烷化和再生区之间循环催化剂的系统。

77. 发明授权

US08344194B2 Process for the conversion of solid particulated biomass materials 有权
标题翻译：固体颗粒生物质材料转化工艺
公开(公告)号：US08344194B2
公开(公告)日：2013-01-01
申请号：US12917980
申请日：2010-11-02
申请人： Robert Bartek , Steve Yanik
发明人： Robert Bartek , Steve Yanik
IPC分类号： C07C1/00 , C10L1/00
CPC分类号： C10G11/18 , C10G1/002 , C10G1/06 , C10G1/08 , C10G3/42 , C10G3/50 , C10G3/56 , C10G3/57 , C10G3/62 , C10G45/02 , C10G47/00 , C10G47/02 , C10G47/30 , C10G47/34 , C10G49/007 , C10G2300/1011 , C10G2300/1014 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , Y02P30/20
摘要： A process for producing bio-fuel from biomass is disclosed herein. The process includes processing the mean particle diameter of the biomass by mechanical processing to a size ranging from 1 μm to 1000 μm to form particulated biomass. The particulated biomass is mixed with a liquid hydrocarbon to form a suspension, wherein the suspension includes between 1 weight percent to 40 weight percent particulated biomass. The suspension is heated to a temperature between 50° C. and 550° C. The heated suspension is fed into a unit selected from the group consisting of a pyrolysis reactor, a fluid catalytic cracking unit, a delayed coker, a fluid coker, a hydroprocessing unit, and a hydrocracking unit; and then at least a portion of the particulated biomass of the heated suspension is converted into fuel.
摘要翻译：本文公开了一种从生物质生产生物燃料的方法。该方法包括通过机械加工将生物质的平均粒径加工至1μm至1000μm的尺寸以形成颗粒状生物质。将颗粒生物质与液体烃混合以形成悬浮液，其中悬浮液包含1重量％至40重量％的颗粒生物质。将悬浮液加热至50℃至550℃之间的温度。将加热的悬浮液加入到选自热解反应器，流化催化裂化装置，延迟焦化器，流体焦化器，加氢处理装置和加氢裂化装置; 然后加热的悬浮液的至少一部分微粒生物质被转化为燃料。

78. 发明申请

US20120297665A1 HYBRID FUEL AND METHOD OF MAKING THE SAME 有权
标题翻译：混合燃料及其制备方法
公开(公告)号：US20120297665A1
公开(公告)日：2012-11-29
申请号：US13434587
申请日：2012-03-29
申请人： David J. GOERZ, JR.
发明人： David J. GOERZ, JR.
IPC分类号： C10L1/02 , C10L1/14 , B01J19/08 , C10G1/00 , C07C1/00 , C10G35/00 , C10L1/32 , C01B3/02
CPC分类号： C10L1/328 , B01J19/088 , B01J2219/0809 , B01J2219/0869 , B01J2219/0875 , B01J2219/0894 , C07C1/00 , C10G15/08 , C10G15/12 , C10G32/00 , C10G2300/1011 , C10G2300/1025 , C10G2300/304 , C10L1/02 , C10L2200/0469 , C10L2290/06 , C10L2290/38 , F02D19/0652 , F02D19/081 , F02M27/042 , Y02P30/10 , Y02P30/20 , Y02T10/36
摘要： A hybrid fuel and methods of making the same are disclosed. A process for making a hybrid fuel includes the steps of combining a biofuel emulsion blend and a liquid fuel product to form a hybrid fuel. Optionally, the hybrid fuel can be combined with water in a water-in-oil process and include oxygenate additives and additive packages. A hybrid fuel includes blends of biofuel emulsions and liquid fuel products, including light gas diesel. Optionally, the hybrid fuel can include water, oxygenate additives, and other additive packages.
摘要翻译：公开了一种混合燃料及其制备方法。制备混合燃料的方法包括将生物燃料乳液混合物和液体燃料产物组合以形成混合燃料的步骤。任选地，混合燃料可以在水包油工艺中与水组合，并且包括含氧化合物添加剂和添加剂包装。混合燃料包括生物燃料乳液和液体燃料产品的混合物，包括轻质柴油。任选地，混合燃料可以包括水，含氧化合物添加剂和其它添加剂包。

79. 发明授权

US08288599B2 Co-processing solid biomass in a conventional petroleum refining process unit 有权
标题翻译：在常规石油炼制过程单元中共同处理固体生物质
公开(公告)号：US08288599B2
公开(公告)日：2012-10-16
申请号：US12867214
申请日：2009-06-29
申请人： Steve Yanik , Paul O'Connor , Robert Bartek
发明人： Steve Yanik , Paul O'Connor , Robert Bartek
IPC分类号： C07C1/00
CPC分类号： C09K3/00 , C10G1/002 , C10G1/08 , C10G11/00 , C10G11/18 , C10G2300/1014 , C10G2300/1037 , C10G2300/4056 , C10G2400/02 , C10G2400/04 , C10G2400/08 , C10G2400/20 , C10G2400/28 , Y02P30/20
摘要： Preparing solid biomass particles for catalytic conversion includes agitating solid biomass particles and providing a biomass-catalyst mixture to a conventional petroleum refinery process unit. The biomass-catalyst mixture includes the solid biomass particles and a catalyst. Agitating solid biomass particles includes flowing a gas to provide a velocity to at least a portion of the solid biomass particles sufficient to reduce their sizes. Co-processing a biomass feedstock and a conventional petroleum feedstock includes liquefying at least a portion of a biomass-catalyst mixture and co-processing at least a portion of the liquefied biomass feedstock and a conventional petroleum feedstock in a conventional petroleum refinery process unit. The biomass feedstock includes a plurality of solid biomass particles and a catalyst, which is liquefied to produce a liquefied biomass feedstock.
摘要翻译：制备用于催化转化的固体生物质颗粒包括搅拌固体生物质颗粒并向传统的炼油工艺单元提供生物质 - 催化剂混合物。生物质 - 催化剂混合物包括固体生物质颗粒和催化剂。搅拌固体生物质颗粒包括使气体流动以提供足以减小其尺寸的至少一部分固体生物质颗粒的速度。共同处理生物质原料和常规石油原料包括液化生物质 - 催化剂混合物的至少一部分，并在常规的炼油工艺单元中共同处理至少一部分液化生物质原料和常规石油原料。生物质原料包括多个固体生物质颗粒和催化剂，其被液化以产生液化生物质原料。

80. 发明申请

US20120251424A1 METHOD FOR THE REMOVAL OF PHOSPHORUS 有权
标题翻译：去除磷的方法
公开(公告)号：US20120251424A1
公开(公告)日：2012-10-04
申请号：US13243353
申请日：2011-09-23
申请人： Peter Havlik , Ramin Abhari , Gary Roth , H. Lynn Tomlinson
发明人： Peter Havlik , Ramin Abhari , Gary Roth , H. Lynn Tomlinson
IPC分类号： C07C1/00 , C01B25/04
CPC分类号： C10G3/50 , C10G1/065 , C10G3/42 , C10G3/45 , C10G3/46 , C10G45/58 , C10G2300/1014 , C10G2300/1018 , C10G2300/202 , C10G2300/44 , C10G2400/04 , C10G2400/18 , C10L1/08 , Y02E50/13 , Y02P20/145 , Y02P30/20
摘要： A process for producing a hydrocarbon from biomass. A feed stream containing biomass having fatty acids, mono-, di-, and/or triglycerides, and a phosphorus content of between about 1 wppm and about 1,000 wppm is provided. A heated hydrocarbon solvent and a hydrogen-rich gas are provided. The feed stream, the heated hydrocarbon solvent, and the hydrogen-rich gas are combined in the presence of a low activity hydrogenation catalyst. A spent low activity hydrogenation catalyst is recovered at the end of a run wherein the spent low activity hydrogenation catalyst contains at least 3% by weight phosphorus.
摘要翻译：从生物质生产烃的方法。提供了含有具有脂肪酸，甘油单酯，甘油三酯和/或甘油三酯的生物质，含磷量在约1wppm至约1,000wppm之间的进料流。提供加热的烃溶剂和富氢气体。进料流，加热的烃溶剂和富氢气体在低活性氢化催化剂的存在下合并。在运行结束时回收废低活性氢化催化剂，其中废低活性氢化催化剂含有至少3重量％的磷。

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