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    • 76. 发明申请
    • Silane-crosslinkable coating formulations
    • 硅烷交联涂料配方
    • US20050271885A1
    • 2005-12-08
    • US10523873
    • 2003-08-07
    • Volker StanjekSilva Jung-RossetiFelicitas Shauer
    • Volker StanjekSilva Jung-RossetiFelicitas Shauer
    • C08G18/71C08G18/80C08G65/336B32B27/00C08L83/00
    • C08G65/336C08G18/718C08G18/8025Y10T428/31663
    • The invention relates to coating formulations (B) which can be hardened to form coatings having a pencil hardness according to ISO 15184 of at least HB. Said formulations contain prepolymers (A) having alkoxysilane functions of general formula (6)-X—CH2—Si (OR) 3-xR′x, wherein R represents hydrogen, an alkyl, cycloalkyl or aryl radical respectively having between 1 and 6 atoms, and the carbon chain can be broken by non-adjacent oxygen, sulphur or NR″ groups; R′ represents an alkyl, cycloalkyl, aryl or arylalkyl radical respectively having between 1 and 12 C atoms, and the carbon chain can be broken by non-adjacent oxygen, sulphur or NR″ groups; R″ represents hydrogen, an alkyl, cycloalkyl, aryl, aminoalkyl, or aspartate acid ester radical; X represents oxygen, sulphur or a group of general formula (20)-O—CO—NR″—; and x represents 0 or 1.
    • 本发明涉及可以硬化以形成具有至少HB的符合ISO 15184的铅笔硬度的涂层的涂料配方(B)。 所述制剂含有具有通式(6)的烷氧基​​硅烷官能团的预聚物(A)-X-CH 2 -Si(OR)3-X R' / SUB,其中R表示氢,分别具有1至6个原子的烷基,环烷基或芳基,并且碳链可被不相邻的氧,硫或NR“基团断裂; R'表示分别具有1至12个C原子的烷基,环烷基,芳基或芳基烷基,碳链可被非相邻的氧,硫或NR“基团断裂; R“表示氢,烷基,环烷基,芳基,氨基烷基或天冬氨酸酯基; X表示氧,硫或通式(20)-O-CO-NR“ - 的基团。 x表示0或1。
    • 78. 发明授权
    • Blocked polyisocyanate and uses thereof
    • 封端多异氰酸酯及其用途
    • US6111048A
    • 2000-08-29
    • US77700
    • 1998-05-27
    • Yoshiyuki AsahinaTaketoshi Usui
    • Yoshiyuki AsahinaTaketoshi Usui
    • C08G18/10C08G18/80C09J175/04
    • C08G18/10C08G18/8025C08G18/8077C09J175/04
    • Disclosed is a novel blocked polyisocyanate obtained by blocking the terminal isocyanate groups of a non-blocked polyisocyanate with a thermally dissociative blocking agent, wherein the non-blocked polyisocyanate is obtained by reacting at least one diisocyanate selected from the group consisting of an aliphatic diisocyanate and an alicyclic diisocyanate with a polyhydroxy compound having an average number of hydroxyl groups as many as 4.5 to 10, and removing substantially all unreacted diisocyanate monomers. A coating composition comprising the blocked polyisocyanate of the present invention as a curing agent and a polyol as a main agent not only has excellent curability even under low temperature conditions, but is also capable of forming a coating which has excellent impact resistance. The blocked polyisocyanate of the present invention has excellent miscibility with a plasticizer for the blocked polyisocyanate, so that, an adhesive property-imparting composition comprising the blocked polyisocyanate and a plasticizer and/or a solvent can be combined with a plastisol to prepare a plastisol composition having excellent adhesive properties even under low temperature conditions.
    • PCT No.PCT / JP96 / 03539 Sec。 371日期:1998年5月27日 102(e)日期1998年5月27日PCT提交1996年12月4日PCT公布。 公开号WO97 / 31961 日期1997年9月4日公开是通过用热解离封闭剂封端未封端多异氰酸酯的末端异氰酸酯基得到的新型封端多异氰酸酯,其中非封闭多异氰酸酯是通过使至少一种二异氰酸酯与 的脂肪族二异氰酸酯和脂环族二异氰酸酯与平均羟基数多4.5〜10的多羟基化合物反应,除去基本上全部未反应的二异氰酸酯单体。 包含作为固化剂的本发明的封端多异氰酸酯和作为主剂的多元醇的涂料组合物即使在低温条件下也不仅具有优异的固化性,而且还能形成耐冲击性优异的涂料。 本发明的封端多异氰酸酯与封端多异氰酸酯的增塑剂的混合性优异,可以将包含封端多异氰酸酯和增塑剂和/或溶剂的赋予粘合剂的组合物与增塑溶胶组合以制备增塑溶胶组合物 即使在低温条件下也具有优异的粘合性能。