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    • 3. 发明授权
    • Process for the preparation of organopolysiloxane resins
    • 制备有机聚硅氧烷树脂的方法
    • US5359022A
    • 1994-10-25
    • US148102
    • 1993-11-03
    • Konrad MautnerRichard WeidnerHelmut Oswaldbauer
    • Konrad MautnerRichard WeidnerHelmut Oswaldbauer
    • C08G77/06C08G77/20C08G77/08
    • C08G77/20C08G77/06
    • A process for preparing an organopolysiloxane resin, which comprises reacting in a first stage at least one silane of the formulaR.sub.a Si(OR.sup.1).sub.4-a (I)in which a is 0, 1, 2 or 3, R is a monovalent organic radical, and/or a partial hydrolyzate thereof, with the proviso that at least one silane of formula (I) in which a is equal to 0 or 1, and/or a partial hydrolyzate thereof, is employed, and, if appropriate, an organo(poly) siloxane with water in the presence of acid and, if appropriate, other substances, in a second stage reacting the reaction mixture obtained from the first stage in the presence of base and, if appropriate, other substances, and in a third stage adding with stirring, the reaction mixture obtained in the second stage into water, and if appropriate mixed with additives.
    • 一种制备有机聚硅氧烷树脂的方法,其包括在第一阶段使至少一种式R a Si(OR 1)4-a(I)的硅烷,其中a是0,1,2或3,R是一价有机基团 ,和/或其部分水解产物,条件是使用至少一种其中a等于0或1的式(I)的硅烷和/或其部分水解产物,并且如果合适,使用有机物 (多)硅氧烷在酸的存在下,如果合适的话,在适当的情况下,在其它物质的存在下,在第二阶段中,在碱的存在下,如果合适的话,在第三阶段使第一阶段获得的反应混合物反应,并在第三阶段 搅拌下加入第二阶段得到的反应混合物,并加入添加剂。
    • 6. 发明授权
    • Copolymers containing nanoparticles
    • 含纳米颗粒的共聚物
    • US07674868B2
    • 2010-03-09
    • US11722567
    • 2005-12-22
    • Oliver MingeRichard WeidnerFrank SandmeyerHans-Peter Weitzel
    • Oliver MingeRichard WeidnerFrank SandmeyerHans-Peter Weitzel
    • C08F230/08
    • C09C1/3081C01P2004/64C08F2/22C08F4/40C08F218/08C08F220/14C08F220/18C08F230/08C08F283/12C08F292/00C08L51/085C09D133/06Y10T428/2995Y10T428/2998C08L2666/02
    • The invention provides copolymers of ethylenically unsaturated monomers and of ethylenically functionalized nanoparticles in the form of their aqueous polymer dispersions or water-redispersible polymer powders, obtainable by means of free-radically initiated polymerization in an aqueous medium and, if desired, subsequent drying of the resultant polymer dispersion, ofA) one or more monomers from the group consisting of vinyl esters, (meth)acrylic esters, vinylaromatics, olef ins, 1,3-dienes, vinyl ethers and vinyl halides and, if desired, further monomers copolymerizable therewith, in the presence ofB) at least one particle P having an average diameter of ≦1000 nm, which is functionalized with ethylenically unsaturated, free-radically polymerizable groups, characterized in thatB2) particles P used are one or more from the group of metal oxides and semimetal oxides, and/orB2) particles P used are silicone resins composed of repeating units of the general formula [R4(p+Z)SiO(4−p−Z)/2] (II), where for at least 20 mol % of the respective silicone resin p+z=0, 1 or 3,and where B1) and B2) are each functionalized with one or more α-organosilanes of the general formula (R1O)3−(R2)nSi—(CR32)—X (I), where X is a radical having 2 to 20 hydrocarbon atoms and containing an ethylenically unsaturated group.
    • 本发明提供烯键式不饱和单体和烯属官能化纳米颗粒的共聚物,其形式为它们的水性聚合物分散体或水分可再分散聚合物粉末,其通过在水性介质中自由引发聚合获得,并且如果需要,随后干燥 得到的聚合物分散体A)一种或多种由乙烯基酯,(甲基)丙烯酸酯,乙烯基芳烃,烯烃,1,3-二烯,乙烯基醚和乙烯基卤化物组成的组中的单体,如果需要,可与其共聚的其它单体 在B存在的情况下,至少一个具有平均直径为≦̸ 1000nm的颗粒P,其被烯键式不饱和的可自由基聚合的基团官能化,其特征在于所用的B2)颗粒P是一个或多个基团 的金属氧化物和半金属氧化物,和/或B2)颗粒P是由通式[R4(p + Z)SiO(4-p)的重复单元构成的硅氧烷树脂 -Z)/ 2](II),其中对于至少20mol%的各有机硅树脂p + z = 0,1或3,并且其中B1)和B2)各自被一个或多个α-有机硅烷官能化 通式(R1O)3-(R2)nSi-(CR32)-X(I),其中X是具有2至20个烃原子且含有烯属不饱和基团的基团。
    • 8. 发明授权
    • Organopolysiloxanes having aliphatically unsaturated radicals, the
preparation thereof and the use thereof in crosslinkable materials
    • 具有脂肪族不饱和基团的有机聚硅氧烷,其制备方法及其在可交联材料中的应用
    • US6034225A
    • 2000-03-07
    • US91529
    • 1998-06-19
    • Richard WeidnerFriedrich Hockemeyer
    • Richard WeidnerFriedrich Hockemeyer
    • C08L83/05C08G77/20C08G77/50C08L83/07C08L83/14C09D183/14D21H19/32C08K5/54
    • D21H19/32C08G77/50C08L83/14C09D183/14
    • The invention relates to organopolysiloxanes which have aliphatically unsaturated radicals, are soluble to at least 80 wt % in organic solvents selected from xylene and toluol at a temperature of 25.degree. C. and a pressure of from 900 to 1100 hPa and contain at least one unit of the following formula (I) R.sup.1.sub.a R.sub.2-a SiO.sub.2/2, at least one unit of the following formula (II) R.sup.1.sub.b R.sub.3-b SiO.sub.1/2, at least one unit of the following formula (III) O.sub.1/2 R.sub.2 SiO.sub.x YRSiO.sub.2/2, and optionally at least one unit of the following formula (IV) O.sub.1/2 R.sub.2 SiO.sub.x YR.sub.2 SiO.sub.1/2, in which:R can be identical or different and is a monovalent, substituted or unsubstituted, SiC-bonded, aliphatically saturated hydrocarbon radical.R.sup.1 can be identical or different and is a monovalent, SiC-bonded, substituted or unsubstituted, aliphatically unsaturated hydrocarbon radical,a is 0, 1 or 2,b is 0, 1, 2 or 3,x is 0 or 1 andy is a radical --(CR.sup.3.sub.2).sub.n CHR.sup.3 -- with at least two carbon atoms, where n is 0 or an integer from 1 to 3 and R.sup.3 is a hydrogen atom or is as defined for R,with the proviso that the organopolysiloxane includes at least one unit of the formula (II) where b is not 0. It also relates to the preparation of the organopolysiloxanes and the use thereof in crosslinkable materials.
    • PCT No.PCT / EP96 / 05721 Sec。 371日期:1998年6月19日 102(e)1998年6月19日PCT 1996年12月19日PCT PCT。 公开号WO97 / 23548 日期1997年7月3日本发明涉及具有脂肪族不饱和基团的有机聚硅氧烷,在25℃的温度和900〜1100hPa的压力下,在选自二甲苯和甲苯的有机溶剂中可溶于至少80重量% 含有下式(I)R1aR2-aSiO2 / 2的至少一个单元,下式(II)中的至少一个单元R1bR3-bSiO1 / 2,下式(III)的至少一个单元:O1 / 2R2SiOxYRSiO2 / 2和任选的至少一个下式(Ⅳ)单元O1 / 2R2SiOxYR2SiO1 / 2,其中:R可以相同或不同,并且是一价,取代或未取代的与SiC键合的脂族饱和烃基。 R1可以相同或不同,为单价,SiC键合的取代或未取代的脂族不饱和烃基,a为0,1或2,b为0,1,2或3,x为0或1,y为 具有至少两个碳原子的基团 - (CR 32)n CHR 3 - ,其中n为0或1至3的整数,并且R 3为氢原子或如对R所定义,条件是有机聚硅氧烷包括至少一个单元 其中b不为0的式(II)的化合物。它还涉及有机聚硅氧烷的制备及其在可交联材料中的用途。