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    • 71. 发明申请
    • METHOD FOR PRODUCING MODIFIED POLYMER AND HYDROGENATED PRODUCT THEREOF
    • 生产改性聚合物及其氢化产物的方法
    • US20140275422A1
    • 2014-09-18
    • US14292386
    • 2014-05-30
    • JSR CORPORATION
    • Kentarou UEBASadataka OOTAYoshirou SAKURA
    • C08F236/10
    • C08F236/10B01D11/0426C08C1/12C08C19/25C08F2/06C08F6/04C08F6/06C08F6/10C08F8/42C08J11/02C08F8/04C08F297/04C08L53/02
    • A method for producing a modified polymer or a hydrogenated product thereof, includes polymerizing a monomer in a polymerization solvent which includes a hydrocarbon-based solvent, using a polymerization initiator to obtain a reaction solution. A functional group is introduced into the modified polymer or the hydrogenated product thereof, using a compound having the functional group protected with a silyl group. The reaction solution is separated into a solvent fraction including the hydrocarbon-based solvent, and a solid fraction including the modified polymer or the hydrogenated product thereof. The solvent fraction separated from the reaction solution is distilled to obtain a low-boiling fraction including the hydrocarbon-based solvent and a silanol compound. At least part of the silanol compound is removed from the low-boiling fraction by liquid-liquid extraction. At least part of a raffinate of the low-boiling fraction is recycled as a polymerization solvent.
    • 一种改性聚合物或其氢化物的制造方法,包括使用聚合引发剂使单体聚合在包含烃系溶剂的聚合溶剂中,得到反应溶液。 使用具有被甲硅烷基保护的官能团的化合物将官能团引入改性聚合物或其加氢产物中。 将反应溶液分离成包含烃基溶剂的溶剂馏分和包含改性聚合物的固体部分或其氢化物。 将从反应溶液中分离的溶剂馏分蒸馏,得到包含烃基溶剂和硅烷醇化合物的低沸点馏分。 通过液 - 液萃取从低沸点馏分中除去至少部分硅烷醇化合物。 低沸点馏分的残液的至少一部分作为聚合溶剂再循环。
    • 72. 发明授权
    • Solvent transfer process for organic polymers
    • 有机聚合物的溶剂转移过程
    • US08481613B2
    • 2013-07-09
    • US13055796
    • 2009-08-03
    • Douglas C. Greminger
    • Douglas C. Greminger
    • C08J3/00
    • C08F6/06C08C19/12
    • An organic polymer is transferred from one solvent to another. In a first step, a solution of the polymer in a first solvent is divided into droplets, dispersed into a liquid phase such as water bath, and the first solvent is removed from the droplets to produce a slurry in the liquid phase. Then, the second solvent is contacted with the slurry to dissolve the organic polymer and produce a second solution. The second solution is removed from the liquid phase. The process is especially suitable for transferring a butadiene polymer from a hydrocarbon solvent into a halogenated solvent for bromination.
    • 有机聚合物从一种溶剂转移到另一种溶剂。 在第一步骤中,将聚合物在第一溶剂中的溶液分成液滴,分散在液相如水浴中,并从液滴中除去第一溶剂以产生液相中的浆液。 然后,将第二溶剂与浆料接触以溶解有机聚合物并产生第二溶液。 从液相中除去第二种溶液。 该方法特别适用于将丁二烯聚合物从烃溶剂转移到用于溴化的卤化溶剂中。
    • 80. 发明授权
    • Method for producing poly(p-t-butoxystyrene)
    • 聚(对叔丁氧基苯乙烯)的制备方法
    • US06423821B1
    • 2002-07-23
    • US09935046
    • 2001-08-23
    • Takanori OkahashiHiroharu TakeshimaSeigo Ito
    • Takanori OkahashiHiroharu TakeshimaSeigo Ito
    • C08F606
    • C08F6/06C08L25/00
    • A method for producing poly(p-t-butoxystyrene), which comprises polymerizing p-t-butoxystyrene in a hydrocarbon type reaction solvent in the presence of a polymerization initiator, and, after termination of the polymerization reaction, conducting a separation of the hydrocarbon type reaction solvent layer containing poly(p-t-butoxystyrene) and the water layer in the presence of 1-50 parts by weight of a polar solvent per 100 parts by weight of the hydrocarbon type reaction solvent layer, wherein the separation efficiency, after termination of the polymerization reaction, of the hydrocarbon type reaction solvent layer containing poly(p-t-butoxystyrene) and the water or acidic water layer conspicuously improves.
    • 一种聚(对丁氧基苯乙烯)的制造方法,其特征在于,在聚合引发剂的存在下,在烃类反应溶剂中聚合叔丁氧基苯乙烯,在聚合反应结束后,进行烃类反应溶剂层 在每100重量份烃类反应溶剂层中,在1-50重量份极性溶剂存在下,含有聚(对丁氧基苯乙烯)和水层,其中分离效率在聚合反应结束后, 含有聚(对丁氧基苯乙烯)和水或酸性水层的烃类反应溶剂层明显改善。