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    • 72. 发明授权
    • Superabsorbent crosslinked ampholytic ion pair copolymers
    • 超吸收交联两性离子对共聚物
    • US5116921A
    • 1992-05-26
    • US783735
    • 1991-10-28
    • Henry L. Hsieh
    • Henry L. Hsieh
    • A61L15/60C08F220/34C08F220/38C08F220/58C08F228/02
    • C08F228/02A61L15/60C08F220/34C08F220/38C08F220/58
    • The present invention provides crosslinked ampholytic copolymers that are highly absorbent to aqueous electrolyte solutions. The polymers of the present invention comprises polymers formed by the copolymerization of an effective amount of each of the following components to produce a polymer which is highly absorbent to aqueous electrolyte solutions:(a) an ampholytic ion pair monomer comprising(i) an ammonium cation 2-methacryloyloxyethyltrimethylammonium and(ii) a sulfonate anion selected from the group consisting of 2-acrylamido-2-methylpropane sulfonate, 2-methacryloyloxyethane sulfonate, vinyl sulfonate, styrene sulfonate and combinations of two or more thereof;(b) at least one comonomer selected from the group consisting of acrylamide, methacrylamide, acrylonitrile, acrylic acid, methacrylic acid, alkali salts of acrylic acid, alkali salts of methacrylic acid, 2-methacryloyloxyethyltrimethylamine, 2-acrylamido-2-methylpropane sulfonic acid, alkali salts of 2-acrylamido-2-methylpropane sulfonic acid, 2-methacryloyloxyethane sulfonic acid, alkali salts of 2-methacryloyloxyethane sulfonic acid, N-vinyl-2-pyrrolidone and combination of two or more thereof; and(c) at least one crosslinking agent which has at least two polymerizable olefinic functionalities wherein the olefinic functionalities are suitable for crosslinking.The invention also provides a method of using the polymers of the present invention for absorbing aqueous electrolyte solutions comprising the step of contacting the polymers of the present invention with the aqueous electrolyte solution.
    • 本发明提供了对含水电解质溶液具有高吸收性的交联的两性共聚物。 本发明的聚合物包括通过共聚有效量的以下每种组分形成的聚合物,以产生对电解质水溶液具有高吸收性的聚合物:(a)两性离子对单体,其包含(i)铵阳离子 2-甲基丙烯酰氧基乙基三甲基铵和(ii)选自2-丙烯酰胺基-2-甲基丙磺酸盐,2-甲基丙烯酰氧基乙烷磺酸盐,乙烯基磺酸盐,苯乙烯磺酸盐及其两种或更多种的组合的磺酸盐阴离子; (b)至少一种选自丙烯酰胺,甲基丙烯酰胺,丙烯腈,丙烯酸,甲基丙烯酸,丙烯酸的碱金属盐,甲基丙烯酸的碱金属盐,2-甲基丙烯酰氧基乙基三甲基胺,2-丙烯酰胺基-2-甲基丙磺酸 2-丙烯酰胺基-2-甲基丙磺酸的碱金属盐,2-甲基丙烯酰氧基乙磺酸,2-甲基丙烯酰氧基乙磺酸的碱金属盐,N-乙烯基-2-吡咯烷酮及其两种或多种的组合; 和(c)至少一种具有至少两个可聚合的烯属官能团的交联剂,其中烯属官能团适于交联。 本发明还提供了使用本发明的聚合物吸收含水电解质溶液的方法,其包括将本发明的聚合物与电解质水溶液接触的步骤。