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    • 72. 发明授权
    • Heat developable light-sensitive material containing an amidine based
precursor
    • 含有脒基前体的热显影感光材料
    • US5093229A
    • 1992-03-03
    • US236491
    • 1988-08-25
    • Yoshiharu YabukiHiroyuki Hirai
    • Yoshiharu YabukiHiroyuki Hirai
    • G03C8/40G03C1/498G03C1/61
    • G03C1/49845G03C1/615Y10S430/156
    • A heat developable light-sensitive material comprising a support having thereon at least one layer containing a base precursor, a lgiht-sensitive silver halide, a binder, and a dye-providing substance which produces or releases a diffusible dye in correspondence or countercorrespondence to the reduction of the light-sensitive silver halide to silver at an elevated temperature, the base precursor comprising a salt of a carboxylic acid and a diacidic, triacidic or tetraacidic organic base comprising a hydrocarbon group or a heterocyclic group substituted with 2 to 4 amidine groups represents by formula (I-2): ##STR1## wherein R.sup.15, R.sup.16 and R.sup.17 are as defined in the specification. The heat developable light-sensitive material has excellent age preservability and provides a high sensitivity and low-fog image.
    • 一种可热显影的感光材料,其包括其上具有至少一层的载体,所述至少一层含有碱性前体,敏感的卤化银,粘合剂和提供染料的物质,其产生或释放对应于或对应于 包含羧基酸的碱前体和包含被2〜4个脒基取代的烃基或杂环基的二酸,三元酸或四元酸有机碱的碱前体代表的基础前体代表 (I-2):其中R 15,R 16和R 17如说明书中所定义。 可热显影的感光材料具有优异的保存时间,并提供高灵敏度和低雾图像。
    • 74. 发明授权
    • Heat developable photographic materials
    • 热显影照相材料
    • US4705737A
    • 1987-11-10
    • US767405
    • 1985-08-20
    • Hiroyuki HiraiKozo SatoYoshiharu YabukiKen Kawata
    • Hiroyuki HiraiKozo SatoYoshiharu YabukiKen Kawata
    • G03C1/43G03C1/498G03C8/40G03C5/54G03C1/40
    • G03C8/4086C07C317/00C07C321/00G03C1/43G03C8/4033Y10S430/156
    • A heat developable photographic material comprising a support having thereon at least a photosensitive silver halide, a binder, and at least on of base precursors represented by following formula (I) or (II): ##STR1## wherein R represents an alkyl group, an alkylene group, an aryl group, an arylene group, a monovalent or divalent heterocyclic group, each of which may be unsubstituted or substituted; B represents a mono- or di-acidic, nitrogen-containing, sulfur-free base having a pKa of not lower than about 7 and containing 12 carbon atoms or less; x is an integer of 1 when R represents a monovalent group or an integer of 2 when R represents a divalent group, y is the same as x when B represents the mono-acidic base or an integer of 1 when B represents the di-acidic base; and z is an integer of 2 when R represents a monovalent group and B represents the di-acidic base or otherwise an integer of 1; R' represents an alkyl group, a cycloalkyl group, an alkenyl group, an alkynyl group, an aralkyl group, an aryl group or a heterocyclic group, each of which may be substituted or unsubstituted; X represents a substituent; p represents an integer of 0 to 4; and m' represents the valence number of M whereby stability with the passge of time prior to heat development is improved.
    • 一种可显影照相材料,其包含至少一种光敏卤化银,粘合剂和至少一种由下式(I)或(II)表示的基础前体的载体:[R(SO 2 CH 2 COOH)x] z.By( I)其中R表示烷基,亚烷基,芳基,亚芳基,一价或二价杂环基,其各自可以是未取代的或取代的; B表示pKa不低于约7并且含有12个碳原子或更少的单 - 或二 - 酸,含氮,无硫的碱; 当R表示二价基团,当R表示一价基团或整数2时,x为1,当B表示单酸性碱时,y与x相同,当B表示二酸时,x表示1以上的整数 基础; 当R表示一价基团时,z表示2的整数,B表示二酸基,否则为1的整数。 R'表示可以被取代或未取代的烷基,环烷基,烯基,炔基,芳烷基,芳基或杂环基, X表示取代基; p表示0〜4的整数, 并且m'表示M的化合价数,从而提高了在显影之前经过时间的稳定性。