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    • 72. 发明授权
    • Pearlescent hair conditioning composition
    • 珠光头发调理组成
    • US4777039A
    • 1988-10-11
    • US878870
    • 1986-06-13
    • Gunther LangPaul GrossFriedel SchroderKarin Grundmann
    • Gunther LangPaul GrossFriedel SchroderKarin Grundmann
    • A61K8/00A61K20060101A61K8/02A61K8/34A61K8/40A61K8/42A61Q5/00A61Q5/12C11D3/20A61K7/075A61K7/08
    • C11D3/0089A61K8/342A61K8/416A61K8/42A61K8/4926A61Q5/12A61K2800/596
    • Pearlescent hair conditioning composition based on a quaternary compound and a fatty alcohol, consisting of (A) 0.2 to 10 percent by weight coconut fatty acid monoethanolamide, (B) 0.4 to 10 percent by weight of a straight-chain fatty alcohol with m carbon atoms (m=14 to 18), (C) 0.1 to 4 percent by weight of a quaternary compound of the formula ##STR1## wherein R.sub.1 =C.sub.n -alkyl (n=12-22), coconut amidoethyl, coconut amidopropyl, R'--Y (R'--C.sub.n -alkyl, Y=--O--C(O)--CH.sub.2 - or --C(O)--O--CH.sub.2 CH.sub.2 --) R.sub.2 =CH.sub.3, CH.sub.2 CH.sub.2 OH or CH.sub.2 CH.sub.3, R.sub.3 =CH.sub.3, CH.sub.2 CH.sub.2 OH, benzyl or acetamidyl, X.sup..crclbar. =C1.sup.-, Br.sup.-, CH.sub.3 SO.sub.4 --, 1/2SO.sub.4 2--, lactate.sup.- or acetate.sup.-, (D) 70 to 99.3 percent by weight water and (E) 0 to 24 percent by weight conventional cosmetic added substances, wherein m+n.gtoreq.29, A/B is 0.1 to 3, C/A+B=0.05 to 0.5, and the proportion by weight of the added substances is not greater than the sum of A+B+C.
    • PCT No.PCT / EP85 / 00579 Sec。 371日期1986年6月13日第 102(e)日期1986年6月13日PCT提交1985年10月31日PCT公布。 出版物WO86 / 0282800 日期:1986年5月22日。基于季铵化合物和脂肪醇的漂白护发组合物,由(A)0.2〜10重量%的椰子脂肪酸单乙醇酰胺组成,(B)0.4〜10重量%的直链 具有m个碳原子的脂肪醇(m = 14至18),(C)0.1至4重量%的下式化合物其中R1 = Cn-烷基(n = 12-22),椰子酰氨基乙基, 椰子酰氨基丙基,R'-Y(R'-Cn - 烷基,Y = -OC(O)-CH2-或-C(O)-O-CH2CH2-)R2 = CH3,CH2CH2OH或CH2CH3,R3 = CH3,CH2CH2OH ,苄基或乙酰氨基,X( - )= C 1,Br - ,CH 3 SO 4 - ,1 / 2SO 4 2-,乳酸盐或乙酸盐 - ,(D)70-99.3重量%的水和(E)0-24重量% 常规的化妆品添加物质,其中m + n> / = 29,A / B为0.1〜3,C / A + B = 0.05〜0.5,添加物的重量比不大于A + B + C。
    • 73. 发明授权
    • Tetrahydro-1,3-thiazin-2,4-dione derivatives
    • 四氢-1,3-噻嗪-2,4-二酮衍生物
    • US4746738A
    • 1988-05-24
    • US30247
    • 1987-03-24
    • Wolfgang HanefeldRudi RothlisbergerFriedrich Noser
    • Wolfgang HanefeldRudi RothlisbergerFriedrich Noser
    • A61K8/00A61K8/49A61K31/54A61Q17/04A61Q19/00A61Q19/08C07D279/04C07D279/06C07D417/04A61K31/38
    • A61Q19/00A61K8/49C07D279/06A61Q17/00A61Q17/04A61Q19/08Y10S514/844Y10S514/846Y10S514/847Y10S514/873Y10S514/938Y10S514/939
    • Skin treating composition on the basis of compatible carrier and additional compositions with a content of a defined tetrahydro-1,3-thiazine-2,4-dion derivatives as active ingredients for thickening the epidermis. The skin treating compositions are applied 1-2 times daily onto the skin for about 3 to 4 weeks. Due to the thickening of the epidermis they cause a reinforcmenet of the skin, in particular against sun rays, cold and the contact with noxious environmental substances of all kinds. Moreover, the skin treating compositions are suitable for a proplylactic fighting of the so-called old age skin. An object of the invention are novel tetrahydro-1,3-thiazine-2,4-dion derivative which are active in the aforementioned manner having the formula ##STR1## wherein R denotes H, alkyl, aryl, arylalkyl has substituted arylalkyl or substituted aryl in the aryl portion, R.sup.a =H is aryl or substituted aryl, R.sup.b =H, denotes aryl or substituted aryl and R.sup.c -H, represents alkyl or aryl, provided that R.sup.a, R.sup.b and R.sup.c only simultaneously denote H when R denotes a substituted arylalkyl in the aryl portion and R denotes H, but only if R.sup.a =HR.sup.b =aryl and R.sup.c constitute=H.
    • 基于相容​​载体和含有定义的四氢-1,3-噻嗪-2,4-二酮衍生物的额外组合物的皮肤处理组合物作为增稠表皮的活性成分。 将皮肤处理组合物每天1-2次施用至皮肤上约3至4周。 由于表皮增厚,它们会导致皮肤的增强,特别是对抗阳光,感冒和与各种有害环境物质的接触。 此外,皮肤处理组合物适合于所谓的老年皮肤的预防性作用。 本发明的目的是以上述方式活化的具有下式的新的四氢-1,3-噻嗪-2,4-二酮衍生物:其中R表示H,烷基,芳基,芳基烷基具有取代的芳基烷基或取代的芳基 在芳基部分中,Ra = H是芳基或取代的芳基,Rb = H,表示芳基或取代的芳基,Rc-H表示烷基或芳基,条件是当R表示取代的芳基烷基时,Ra,Rb和Rconly同时表示H 芳基部分和R表示H,但只有当Ra = HRb =芳基且Rc构成= H时。
    • 76. 发明授权
    • Agent for oxidative dyeing of hair
    • 头发氧化染色剂
    • US4479803A
    • 1984-10-30
    • US253510
    • 1981-04-08
    • Heinrich BachmannPlato Portmann
    • Heinrich BachmannPlato Portmann
    • A61K8/00A61K8/33A61K8/35A61K8/40A61K8/41A61K8/42A61K8/44A61K8/49A61Q5/10A61K7/13
    • A61K8/40A61K8/37A61K8/42A61Q5/10
    • Use is made in the oxidative dyeing of hair of a preliminary coloring stage of the general formula ##STR1## wherein R signifies COOR', CONH.sub.2, CONHR', CONR'.sub.2, CONH--NH.sub.2, CONH--OH, CN, CH.sub.2 OH, CHO, CH(OH)(OR'), CH(OR').sub.2 and R' represents an alkyl group with 1 to 5 carbon atoms. The preliminary coloring stages as per formula (I) may be contained in the hair dyeing agents singly or in a mixture with known preliminary coloring stages and/or direct-acting hair dyeing agents. The hair dyeing agents may, in particular, additionally contain amino acids present in nature, their esters and/or their amides. The hair dyeing agents as described, are well compatible physiologically and it will particularly be brown to reddish-brown colorings having a natural effect, that may be obtained by their use.
    • PCT No.PCT / EP80 / 00103 Sec。 371日期:1981年4月8日 102(e)日期1981年4月8日PCT申请日1980年9月25日PCT公布。 出版物WO81 / 00810 日本1981年4月2日。使用通式(I)的预着色阶段的毛发氧化染色,其中R表示COOR',CONH 2,CONHR',CONR 2,CONH-NH 2, CONH-OH,CN,CH2OH,CHO,CH(OH)(OR'),CH(OR')2,R'表示碳原子数1〜5的烷基。 根据式(I)的初步着色阶段可以单独地或与已知的预着色阶段和/或直接作用的染发剂的混合物包含在染发剂中。 染发剂特别可以另外包含天然存在的氨基酸,它们的酯和/或它们的酰胺。 如上所述的染发剂在生理学上是良好相容的,并且特别是具有天然效果的棕色至红褐色的着色剂,可以通过其使用获得。
    • 77. 发明授权
    • Composition and method for the coloring of hair
    • 头发着色的组成和方法
    • US4473375A
    • 1984-09-25
    • US405339
    • 1982-08-05
    • Thomas Clausen
    • Thomas Clausen
    • C09B53/00A61K20060101A61K8/00A61K8/22A61K8/23A61K8/31A61K8/33A61K8/34A61K8/36A61K8/37A61K8/40A61K8/41A61K8/42A61K8/46A61K8/49A61K8/73A61K8/92A61Q5/10A61K7/13
    • A61Q5/10A61K8/4926
    • A composition and method for the oxidative coloring of hair are disclosed, on the basis of a developer substance-coupler substance combination, whereby as coupler substance at least one 3,5-diaminopyridine derivative of the general Formula ##STR1## in which R.sup.1 and R.sup.2 independent of each other are CH.sub.3, C.sub.2 H.sub.5 or C.sub.2 H.sub.4 OH and R.sup.3 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -hydroxyalkyl, also in the form of the physiologically compatible salt, is used. The coupler substance, 3,5-diamino-2,6-dimethoxypyridine being preferred, should be present in the hair coloring composition in a concentration from 0.01 to 3.0% by weight, preferably 0.1 to 2.0% by weight. The coupler substances according to Formual I are storage-stable, well soluble in water, and have toxicologically as well as dermatologically favorable characteristics. The coupler substances according to Formula I produce in combination with 1,4-diaminobenzene or its derivatives very intensive blue-black tones without red portions, and in combination with 4-aminophenol, strongly lustrous gold-orange tones.
    • 公开了一种用于头发氧化着色的组合物和方法,其基于显影剂物质 - 成色剂物质组合,由此作为成色剂物质,至少一种通式为其中的3,5-二氨基吡啶衍生物(I),其中 R 1和R 2彼此独立的是CH 3,C 2 H 5或C 2 H 4 OH,R 3是氢,也可以是生理上相容的盐形式的C 1 -C 4 - 烷基或C 1 -C 4 - 羟基烷基。 配偶体物质,优选的3,5-二氨基-2,6-二甲氧基吡啶应以0.01至3.0重量%,优选0.1至2.0重量%的浓度存在于染发组合物中。 根据本发明的成色剂物质是储存稳定的,易溶于水,并具有毒理学以及皮肤病学上的有利特征。 根据式I的成色剂物质与1,4-二氨基苯或其衍生物组合产生非常强烈的蓝黑色色调而没有红色部分,并与4-氨基苯酚组合,具有强光泽的金橙色调。
    • 78. 发明授权
    • Process for permanently shaping hair
    • 永久塑造头发的方法
    • US4470423A
    • 1984-09-11
    • US453883
    • 1982-12-13
    • Theodor Wajaroff
    • Theodor Wajaroff
    • A61K8/00A45D20060101A45D7/04A61K20060101A61K8/46A61Q5/04A61Q5/10
    • A61Q5/04A61K8/46
    • Multistage process for permanent shaping of hair, whereby the hair is at first treated with a liquid hair keratine reducing permanent shaping agent before and/or after rolling the hair onto rollers. This liquid, weak shaping effective permanent shaping medium is able to shape the hair in the area of the hair tips without damaging the hair tips during the reaction time. Subsequently, a consistent keratine reducing permanent shaping medium is applied to the rolled up hair which has a viscosity of 50 to 5000 m Pa.multidot.s, preferably 100 to 500 m Pa.multidot.s at a temperature of 30.degree. C. and which has a stronger shaping effectiveness with respect to the liquid permanent shaping medium. The consistent permanent shaping medium screens the hair to the outside and prevents the access of atmospheric oxygen, on the one hand, and the escaping of a volatile alkalization agent like, for example, ammonia, on the other hand. Furthermore, due to the higher shaping effectiveness of the consistent permanent shaping medium a good shaping of the beginning of the hair is obtained without the danger of an excess curling of the tips of the hair. After a sufficient reaction time, the hair is rinsed and is then treated with an oxidating effective solution.
    • PCT No.PCT / EP82 / 00092 Sec。 371日期1982年12月13日 102(e)1982年12月13日日期PCT提交1982年5月4日PCT公布。 出版物WO82 / 03985 日期:1982年11月25日。头发永久成型的成型方法,其中毛发首先在将头发卷入辊子之前和/或之后用液体毛发角质素还原永久性成形剂进行处理。 这种液体,弱成形的有效的永久成形介质能够在发梢的区域中成形头发,而不会在反应时间期间损伤头发尖端。 随后,将一致的减少角质素的永久性成形培养基施加到在30℃的温度下具有50至5000μmPax,优选100至500μmPax的粘度的卷起的毛发,并且其具有更强的成形效果 到液体永久性成形介质。 一致的永久成形介质将头发屏蔽到外部,另一方面防止大气氧气的进入,另一方面防止挥发性碱化剂逸出,例如氨。 此外,由于一致的永久性成形介质的较高的成形效果,可以获得头发开始的良好成形,而不会发生头发过度卷曲的危险。 在足够的反应时间后,将头发冲洗,然后用氧化有效溶液处理。