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61. 发明授权

US5644014A Coating compositions based on fluorine-containing inorganic polycondensates, their production and their use 失效
标题翻译：基于含氟无机缩聚物的涂料组合物及其制备及其用途
公开(公告)号：US5644014A
公开(公告)日：1997-07-01
申请号：US150003
申请日：1994-04-29
申请人： Helmut Schmidt , Reiner Kasemann , Stefan Bruck
发明人： Helmut Schmidt , Reiner Kasemann , Stefan Bruck
IPC分类号： C09D183/04 , C09D183/08 , C09D183/14 , C09D185/00 , C09D201/00 , C08G77/24
CPC分类号： C09D183/08 , C09D183/14 , C09D185/00
摘要： A coating composition is disclosed based on polycondensates of hydrolyzable compounds in particular of Si, Al, Ti and/or Zr, whereas at least part of the non-hydrolyzable groups linked to these elements contain in average 2 to 30 fluorine atoms linked to aliphatic carbon atoms. A process for producing such coating compositions is also disclosed. The corresponding cured (transparent) coatings are characterized in particular by a very good adherence to various types of substrates, in particular glass, besides an antiadhesive effect with respect to many different materials.
摘要翻译： PCT No.PCT / EP92 / 01233 371日期1994年04月29日 102（e）日期1994年4月29日PCT提交1992年6月3日PCT公布。第WO92 / 21729号公报日期1993年12月10日公开了基于可水解化合物，特别是Si，Al，Ti和/或Zr的缩聚物的涂料组合物，而与这些元素连接的至少部分不可水解基团含有平均2至30个氟与脂族碳原子连接的原子。还公开了制备这种涂料组合物的方法。相应的固化（透明）涂层特别地特征在于除了对许多不同材料的抗粘附效应之外，对各种类型的基材，特别是玻璃具有非常好的粘合性。

62. 发明授权

US5545682A Silicone compositions for the formation of cured release coatings 失效
标题翻译：用于形成固化剥离涂层的硅氧烷组合物
公开(公告)号：US5545682A
公开(公告)日：1996-08-13
申请号：US447663
申请日：1995-05-23
申请人： Nobuo Kaiya , Hideki Kobayashi
发明人： Nobuo Kaiya , Hideki Kobayashi
IPC分类号： C08L83/05 , C08L83/04 , C08L83/07 , C08L83/14 , C09D183/00 , C09D183/04 , C09D183/05 , C09D183/07 , C09D183/14 , C09J7/02 , D21H19/00 , C08K5/54
CPC分类号： C09D183/04 , C09D183/14
摘要： The introduction of release coating-forming silicone compositions that yield cured release coatings that exhibit excellent release properties against tacky substances and do not impair the residual adhesion of tacky substances.Silicone composition for the formation of cured release coatings, that characteristically comprises(A) 100 weight parts of a cured coating-forming silicone composition into which there is admixed(B) 0.5 to 500 weight parts organosilicon polymer with the following average unit formula ##STR1## wherein R represents C.sub.1 to C.sub.10 monovalent hydrocarbon groups that are free of aliphatic unsaturation; R.sup.1 represents organic groups selected from the group consisting essentially of C.sub.2 to C.sub.20 alkylene groups and organic groups with the formulas --R.sup.3 (OR.sup.3).sub.y -- and --R.sup.3 --(R.sub.2 SiO).sub.z R.sub.2 Si--R.sup.3 -- (R is defined as above, R.sup.3 denotes C.sub.2 to C.sub.20 alkylene groups, which may be the same or different, y is an integer with a value of 1 or more, and z is zero or an integer with a value of 1 or more); R.sup.2 represents groups selected from the group consisting essentially of C.sub.1 to C.sub.10 monovalent hydrocarbon groups, the hydrogen atom, C.sub.1 to C.sub.10 alkoxy groups, and the hydroxyl group; n=3 to 20; x=1 to 13; and n.gtoreq.x.
摘要翻译：引入形成脱胶涂层的脱模涂层硅氧烷组合物，其产生对粘性物质具有优异的剥离性能并且不损害粘性物质的残留粘附性的固化脱模涂层。用于形成固化剥离涂层的硅氧烷组合物，其特征在于包含（A）100重量份固化的涂覆形成硅氧烷组合物，其中混合（B）0.5至500重量份的具有以下平均单元式的有机硅聚合物其中R表示不含脂族不饱和度的C1至C10单价烃基; R1表示选自基本上由C2〜C20亚烷基组成的组的有机基团和具有式-R3（OR3）y-和-R3-（R2SiO）zR2Si-R3-的有机基团（R定义如上，R3表示C2 至20个亚烷基，其可以相同或不同，y为1以上的整数，z为0或为1以上的整数）。 R2表示选自基本上由C1至C10单价烃基，氢原子，C1至C10烷氧基和羟基组成的组的基团; n = 3〜20; x = 1〜13; 和n> / = x。

63. 发明授权

US5445894A Ceramic coatings 失效
标题翻译：陶瓷涂料
公开(公告)号：US5445894A
公开(公告)日：1995-08-29
申请号：US688233
申请日：1991-04-22
申请人： Loren A. Haluska , Keith W. Michael
发明人： Loren A. Haluska , Keith W. Michael
IPC分类号： B05D3/06 , B05D7/24 , C04B41/87 , C08G77/12 , C08G77/48 , C09D183/04 , C09D183/05 , C09D183/14 , H01B3/30 , H01L21/312 , H01L21/316 , B22F7/08 , C08K5/07
CPC分类号： C08G77/48 , C08G77/12 , C09D183/14 , Y10T428/1209
摘要： The present invention relates to the application of ceramic coatings on substrates. The method comprises applying a preceramic coating comprising hydrogen silsesquioxane resin, a material containing Si--Si bonds which forms volatile SiH compounds, and a catalyst followed by pyrolyzing the preceramic coating in an inert atmosphere. The novel ceramic coatings formed by the process of this invention are especially valuable on electronic devices.
摘要翻译：本发明涉及陶瓷涂层在基片上的应用。该方法包括施加包含氢倍半硅氧烷树脂的预陶瓷涂层，含有形成挥发性SiH化合物的Si-Si键的材料和催化剂，然后在惰性气氛中热解该陶瓷涂层。通过本发明的方法形成的新型陶瓷涂层在电子设备上是特别有价值的。

64. 发明授权

US5414093A Hydrolyzable and polymerizable silanes 失效
标题翻译：可水解和可聚合的硅烷
公开(公告)号：US5414093A
公开(公告)日：1995-05-09
申请号：US916584
申请日：1992-07-20
申请人： Herbert Wolter
发明人： Herbert Wolter
IPC分类号： C07F7/08 , C07F7/10 , C07F7/12 , C07F7/18 , C08F30/08 , C08G65/04 , C08G65/10 , C08G77/04 , C08G77/14 , C08G77/22 , C08G77/58 , C08J3/24 , C08L43/00 , C08L43/04 , C08L83/04 , C09D4/02 , C09D183/06 , C09D183/07 , C09D183/14 , C09J4/00 , C09J4/02 , C07D323/02
CPC分类号： C09D183/06 , C07F7/182 , C07F7/1836 , C08G77/14 , C09D183/14
摘要： Hydrolyzable and polymerizable silanes for producing poly (hetero) condensation products and (hetero) polymers, the silanes having the general formula (I)Y.sub.n Si X.sub.m R.sub.4-(n+m) (I),wherein the residues X, Y and R may be the same or different and are defined as follows:R=alkyl, alkenyl, aryl, alkylaryl or arylalkyl,X=hydrogen, halogen, hydroxyl, alkoxy, acyloxy, alkylcarbonyl, alkoxycarbonyl or NR'.sub.2, with R'=hydrogen, alkyl or aryl,Y=a substituent containing a substituted or unsubstituted 1,4,6 -trioxaspiro-[4,4]-nonane residue,n=1, 2 or 3, m=1, 2 or 3, with n+m.ltoreq.4.The silanes of the present invention are processed to form scratch-resistant coatings, filling, adhesive or sealing compounds, molded articles or embedding media.
摘要翻译：用于制备聚（杂）缩合产物和（杂）聚合物的可水解和可聚合硅烷，具有通式（I）Y n Si X m R 4 - （n + m）（I）的硅烷，其中残基X，Y和R可以 R =烷基，烯基，芳基，烷基芳基或芳基烷基，X =氢，卤素，羟基，烷氧基，酰氧基，烷基羰基，烷氧基羰基或NR'2，其中R'=氢，烷基或芳基，Y =含有取代或未取代的1,4,6-三氧杂螺[4,4] - 壬烷残基的取代基，n = 1,2或3，m = 1,2或3，其中n + / = 4。加工本发明的硅烷以形成耐刮擦涂料，填充剂，粘合剂或密封剂，模塑制品或嵌入介质。

65. 发明授权

US5386007A Siloxane copolymers containing alkenyl groups, their preparation and their use 失效
标题翻译：含有烯基的硅氧烷共聚物，其制备及其应用
公开(公告)号：US5386007A
公开(公告)日：1995-01-31
申请号：US179408
申请日：1994-01-10
申请人： Christian Herzig , Michael Geck , Alfred Rengstl , Friedrich Hockemeyer , Helmut Oswaldbauer
发明人： Christian Herzig , Michael Geck , Alfred Rengstl , Friedrich Hockemeyer , Helmut Oswaldbauer
IPC分类号： C08L83/05 , C08G77/20 , C08G77/22 , C08G77/50 , C08L83/02 , C08L83/04 , C08L83/07 , C08L83/14 , C09D183/07 , C09D183/14 , D21H19/32 , C08G77/06
CPC分类号： D21H19/32 , C08G77/50 , C08L83/14 , C09D183/14
摘要： The present invention relates to siloxane copolymers containing alkenyl groups and a process for their preparation. The siloxane copolymers of the present invention can be used in cross-linkable compositions for the production of coatings which repel tacky substances, an example of which would include coatings for release papers or films.
摘要翻译：本发明涉及含烯基的硅氧烷共聚物及其制备方法。本发明的硅氧烷共聚物可用于生产排斥粘性物质的涂料的可交联组合物，其实例包括用于剥离纸或薄膜的涂料。

66. 发明授权

US5357024A Method for preparing a polysiloxane and titanate composition for high refractive index coatings 失效
$Method for preparing a polysiloxane and titanate composition for high refractive index coatings$
标题翻译：制备用于高折射率涂层的聚硅氧烷和钛酸酯组合物的方法
公开(公告)号：US5357024A
公开(公告)日：1994-10-18
申请号：US92922
申请日：1993-07-19
申请人： Yves Leclaire
发明人： Yves Leclaire
IPC分类号： C08K5/09 , C08G77/58 , C08G79/00 , C08L83/04 , C09D183/04 , C09D183/14 , C08G77/06
CPC分类号： C08G77/58 , C08G79/00 , C09D183/14 , Y10T428/31663
摘要： A method of preparation of a polysiloxane resin composition for an antiabrasion coating having a high refractive index involves hydrolysis of a first constituent of the organosiloxane type to an alkoxysilane hydrolyzate containing condensable silanol groups, and reaction of the hydrolyzate obtained with a second constituent formed of an organic compound of titanium having at least one titanium ester function of carboxylic acid, with addition of a quantity of water such as to cause hydrolysis of the hydrolyzable groups which remain in the mixture obtained and formation of a siloxane prepolymer which integrates the titanium.
摘要翻译：制备具有高折射率的抗磨损涂层的聚硅氧烷树脂组合物的方法包括将有机硅氧烷型的第一组分水解成含有可缩合硅烷醇基团的烷氧基硅烷水解产物，以及由第二组分形成的水解产物的反应具有至少一种羧酸钛酯官能团的钛的有机化合物，加入一定量的水以引起残留在所得混合物中的可水解基团的水解，以及形成与钛结合的硅氧烷预聚物。

67. 发明授权

US5328975A Ultraviolet radiation absorbing coating 失效
标题翻译：紫外线吸收涂层
公开(公告)号：US5328975A
公开(公告)日：1994-07-12
申请号：US42184
申请日：1993-04-02
申请人： Michael E. Hanson , Robert M. Hunia , Chia-Cheng Lin
发明人： Michael E. Hanson , Robert M. Hunia , Chia-Cheng Lin
IPC分类号： C09D5/32 , C09D5/00 , C09D183/04 , C09D183/14 , C09D185/00 , C08G77/04
CPC分类号： C09D183/14
摘要： An organoalkoxysilane/metal oxide sol-gel composition and method for its production are disclosed whereby an organoalkoxysilane of the general formulaR.sub.x Si(OR').sub.4-xwherein R is an organic radical, R' is a low molecular weight alkyl radical, and x is less than 4 and may be zero, is partially hydrolyzed in organic solution and reacted with a titanium alkoxide of the general formula Ti(OR'').sub.4 wherein R'' is a lower alkyl radical. The composition is hydrolyzed, dried and heat treated to form a silicon oxide/titanium oxide abrasion-resistant coating on a substrate with high ultraviolet radiation absorbance.
摘要翻译：公开了一种有机烷氧基硅烷/金属氧化物溶胶凝胶组合物及其制备方法，其中通式为RxSi（OR'）4-x的有机烷氧基硅烷，其中R为有机基团，R'为低分子量烷基，x为小于4，可以为零，在有机溶液中部分水解，并与通式Ti（OR“）4的钛醇盐反应，其中R”为低级烷基。将组合物水解，干燥和热处理，以在具有高紫外线吸光度的基底上形成氧化硅/氧化钛耐磨涂层。

68. 发明授权

US5322557A Primer compositions 失效
标题翻译：底漆组合物
公开(公告)号：US5322557A
公开(公告)日：1994-06-21
申请号：US994990
申请日：1992-12-22
申请人： Hiroshi Inomata , Yasuo Tarumi , Kazuhiko Tomaru
发明人： Hiroshi Inomata , Yasuo Tarumi , Kazuhiko Tomaru
IPC分类号： C08J7/04 , C07F7/18 , C08J5/12 , C09D4/00 , C09D183/14 , C09J5/02 , C09J183/00 , C09J185/00 , C09K3/00
CPC分类号： C08J5/125 , C07F7/182 , C07F7/1836 , C09D183/14 , C09D4/00 , C08J2383/08
摘要： A primer composition comprising (A) a fluorinated alkoxysilane containing an epoxy group, (B) an organic titanium or aluminum compound, and (C) a solvent is effective in bonding fluorinated organic polymers to metal and glass members.
摘要翻译：包含（A）含有环氧基的氟化烷氧基硅烷，（B）有机钛或铝化合物和（C）溶剂）的底漆组合物有效地将氟化有机聚合物粘合到金属和玻璃构件。

69. 发明授权

US5318618A Primer compositions 失效
标题翻译：底漆组合物
公开(公告)号：US5318618A
公开(公告)日：1994-06-07
申请号：US979075
申请日：1992-11-19
申请人： Yoshifumi Inoue , Kin Saito , Keisuke Imai , Masatoshi Arai
发明人： Yoshifumi Inoue , Kin Saito , Keisuke Imai , Masatoshi Arai
IPC分类号： C08G77/02 , C08G77/398 , C08G79/00 , C08L83/00 , C08L83/02 , C09D4/00 , C09D5/00 , C09D183/00 , C09D183/02 , C09D183/04 , C09D183/06 , C09D183/14 , C09K3/00
CPC分类号： C09D183/14 , C09D4/00
摘要： A primer composition comprises (A) an organosilicon compound having different alkoxy groups in its molecule, (B) a tetraalkoxytitanium, (C) an acid and water, and (D) an organic solvent. The composition shows excellent adhesion properties to fluororesin coating materials, acrylic resin coating materials, etc. When applied to the surface of a metal coated with such a coating material, the primer composition is capable of providing a remarkably enhanced adhesion, for example, between a silicone elastomer and the coated metal.
摘要翻译：底漆组合物包含（A）分子中具有不同烷氧基的有机硅化合物，（B）四烷氧基钛，（C）酸和水，和（D）有机溶剂。该组合物对氟树脂涂料，丙烯酸树脂涂料等的粘附性优异。当涂布在涂覆有这种涂料的金属的表面上时，底漆组合物能够提供显着增强的粘附性，例如在硅橡胶和涂层金属。

70. 发明授权

US5316799A Method for applying paint with a water repellant composition 失效
标题翻译：用防水剂组合物涂抹油漆的方法
公开(公告)号：US5316799A
公开(公告)日：1994-05-31
申请号：US969658
申请日：1992-10-30
申请人： Dean E. Brunken , Arnulf P. Hagen
发明人： Dean E. Brunken , Arnulf P. Hagen
IPC分类号： C04B41/49 , C04B41/84 , C09D5/00 , C09D183/04 , C09D183/14 , B05D1/02
CPC分类号： C04B41/009 , C04B41/4922 , C04B41/4961 , C04B41/84 , C09D183/04 , C09D183/14 , C09D5/00 , Y10T428/4935
摘要： Methods for treating siliceous and carbon central structures with a water repellant composition and a paint are provided. An effective amount of water repellant composition is dispersed in paint or in paint and water, and the mixture then is applied in a continuous process after mixing to the object to be treated.
摘要翻译：提供了用防水组合物和涂料处理硅质和碳中心结构的方法。将有效量的防水组合物分散在油漆或油漆和水中，然后在混合到待处理物体之后以连续方式施加混合物。

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