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    • 1. 发明授权
    • Polysiloxane coating
    • 聚硅氧烷涂层
    • US5275645A
    • 1994-01-04
    • US980908
    • 1992-11-24
    • Leonard R. TernoirRaymond E. FoscanteRoland L. Gasmena
    • Leonard R. TernoirRaymond E. FoscanteRoland L. Gasmena
    • C08L83/04C09D183/04C09D183/14C09J183/00C09J183/04C09K3/18
    • C09K3/18C09D183/04C09D183/14
    • A protective coating is made by polymerizing at ambient temperatures a silicon-oxygen bond compound selected from a group consisting of oxysilanes having side groups selected from the group consisting hydrogen and alkyl, aryl, hydroxyalkyl, alkoxyalkyl and hydroxyalkoxyalkyl groups containing up to six carbon atoms, where there are at least two hydrolyzable side groups for polymerization, and where the number of repeating units of the oxysilane is in the range of from 1 to 5, and/or silicone intermediates with side groups selected from the group consisting of hydrogen, the hydroxy group and alkyl, aryl and alkoxy groups having up to twelve carbon atoms and having an average molecular weight of up to 5000. The polymerization is catalyzed by a basic compound selected from a group consisting of mercaptans, silane substituted amines, polyamides, polyimides, amidoamines, and aliphatic amine compounds and aromatic amine compounds; and an organotin compound. Carbinols with at least two carbon bonded hydroxy groups per carbinol may also be included in the coating composition.
    • 通过在环境温度下聚合选择硅氧键化合物制备保护涂层,所述硅 - 氧键化合物选自具有选自氢和具有至多6个碳原子的烷基,芳基,羟基烷基,烷氧基烷基和羟基烷氧基烷基的侧基的氧基硅烷, 其中存在用于聚合的至少两个可水解侧基,并且其中氧基硅烷的重复单元的数量为1至5的范围,和/或具有选自氢,羟基的侧基的硅氧烷中间体 基团和烷基,芳基和烷氧基,其具有至多12个碳原子并且具有高达5000的平均分子量。聚合由选自硫醇,硅烷取代胺,聚酰胺,聚酰亚胺,酰胺基胺的碱性化合物催化 ,和脂族胺化合物和芳族胺化合物; 和有机锡化合物。 每个甲醇具有至少两个碳键羟基的甲醇也可以包括在涂料组合物中。