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    • 63. 发明申请
    • Antistatic adhesive for water-based or solvent-based dry laminate and complex plastic film
    • 用于水性或溶剂型干层压板和复合塑料薄膜的防静电粘合剂
    • US20050014892A1
    • 2005-01-20
    • US10890701
    • 2004-07-14
    • Kanji Hayashi
    • Kanji Hayashi
    • C09J9/02C08G18/08C08G18/70C08K5/098C08K5/19C08L75/04C09J11/02C09J175/00B32B7/12C08K3/00C08L75/00
    • C08K5/19C08G18/0823C08G18/706C08G2170/80C08K5/098C08L75/04C09J11/02Y10T428/28Y10T428/2896
    • An adhesive is provided with advantageous adhesive characteristics, antistatic properties, compatibility with environment, adhesion strength, and heat resistance for dry laminate. A complex plastic film using the adhesive is also provided. The environment-compatible adhesive for dry laminate is prepared by adding an antistatic agent into a water-dispersible polyurethane resin having a carboxyl group in the side chain. A water-dispersible polyisocyanate is used as a bridging/curing agent for the water-dispersible polyurethane resin, and a mixture of quarternary ammonium alt betaine and an electrolytic metallic salt is used as the antistatic agent. The quarternary ammonium salt betaine is alkyl dimethyl amino acetate. The complex plastic film is complexed with the adhesive. Further in the adhesive having high adhesion strength and heat resistance, analiphatic isocyanate-based curing agent is used as a bridging/curing agent for solvent-based polyurethane resin, and a mixture of aliphatic dimethylethyl ammonium ethosulphate salt and polyoxyethylene alkyl ether is used as the antistatic agent. By dry-laminating the plastic film with this adhesive, a product having the adhesion strength and heat resistance can be obtained.
    • 粘合剂具有有利的粘合特性,抗静电性能,与环境的相容性,粘合强度和干燥层压板的耐热性。 还提供了使用粘合剂的复合塑料膜。 通过在侧链中具有羧基的水分散性聚氨酯树脂中添加抗静电剂来制备干燥层压体的环境相容性粘合剂。 使用水分散性多异氰酸酯作为水分散性聚氨酯树脂的桥接/固化剂,并且使用季铵铵甜菜碱和电解金属盐的混合物作为抗静电剂。 季铵盐甜菜碱是烷基二甲基氨基乙酸酯。 复合塑料膜与粘合剂复合。 此外,在具有高粘合强度和耐热性的粘合剂中,使用脂族异氰酸酯基固化剂作为溶剂型聚氨酯树脂的桥联/固化剂,并且使用脂族二甲基乙基铵乙基硫酸盐和聚氧乙烯烷基醚的混合物作为 抗静电剂。 通过用该粘合剂干燥层压塑料膜,可以获得具有粘合强度和耐热性的产品。
    • 65. 发明授权
    • Colored polyester thermoplastic materials comprised of
poly(oxyalkylenated) compounds as colorants and specific surfactants as
diluents
    • 由聚(氧化烯化)化合物作为着色剂和作为稀释剂的特定表面活性剂组成的着色聚酯热塑性材料
    • US5973064A
    • 1999-10-26
    • US111218
    • 1998-07-07
    • X. Edward ZhaoTodd David DanielsonEugene Kyle StephensonElizabeth M. Irwin
    • X. Edward ZhaoTodd David DanielsonEugene Kyle StephensonElizabeth M. Irwin
    • C08J3/20B29C45/00B29C47/00C08K5/00C08K5/06C08K5/10C08K5/13C08K5/1545C08K5/19C08L67/00C08L67/02C08L71/00C08L71/02C08L101/00C09B69/00C09B69/10D06P5/13
    • C08L67/02Y10S525/935
    • This invention relates to colored polyester thermoplastics comprised of polymeric colorants having poly(oxyalkylene) moieties and/or anionic dye/quatenary ammonium substantially inorganic salt-free colorant complexes mixed with diluents selected from the group consisting essentially of sorbitan (C.sub.8 -C.sub.22) monoesters, ethoxylated sorbitan (C.sub.8 -C.sub.22) monoesters, mixtures thereof of sorbitan (C.sub.8 -C.sub.22) monoesters and ethoxylated sorbitan (C.sub.8 -C.sub.22) monoesters, ethoxylated nonyl-phenol ethers, ethoxylated dodecylphenol ethers, mixtures thereof of said ethoxylated nonyl-phenol ethers and ethoxylated dodecylphenol ethers, and mixtures of (i) sorbitan (C.sub.8 -C.sub.22) monoesters or ethoxylated sorbitan (C.sub.8 -C.sub.22) monoesters and (ii) ethoxylated nonyl-phenol ethers or ethoxylated dodecylphenol ethers. Such diluents facilitate the introduction of the preferred polymeric colorants within feedstock polyester during the extrusion or injection molding process and provide a significant improvement over traditional polyester article colorants. The inventive colored polyester thermoplastic may be molded into any shape or form; however, plastics are commonly utilized as containers for liquids, such as soft drinks. A method of coloring polyester during an extrusion or injection molding procedure utilizing the inventive colorant/diluent formulations are also provided.
    • 本发明涉及由具有聚(氧化烯)部分的聚合物着色剂和/或阴离子染料/季铵盐基本上无机无盐的着色剂配合物混合的着色聚酯热塑性塑料,所述着色剂与选自以下的稀释剂混合:脱水山梨糖醇(C8-C22)单酯, 乙氧基化脱水山梨醇(C8-C22)单酯,其脱水山梨糖醇(C8-C22)单酯和乙氧基化脱水山梨糖醇(C8-C22)单酯的混合物,乙氧基化壬基酚醚,乙氧基化十二烷基酚醚,所述乙氧基化壬基酚醚和乙氧基化壬基苯酚醚的混合物 十二烷基苯酚醚和(i)脱水山梨糖醇(C8-C22)单酯或乙氧基化脱水山梨糖醇(C8-C22)单酯和(ii)乙氧基化壬基酚醚或乙氧基化十二烷基苯酚醚的混合物。 这种稀释剂有助于在挤出或注射成型过程中在原料聚酯中引入优选的聚合物着色剂,并提供相对于传统聚酯制品着色剂的显着改进。 本发明的着色聚酯热塑性塑料可以模制成任何形状或形式; 然而,塑料通常用作液体的容器,例如软饮料。 还提供了在使用本发明的着色剂/稀释剂制剂的挤出或注射成型过程中着色聚酯的方法。
    • 66. 发明授权
    • Acrylic copolymer elastomer, its blend rubber and blend rubber
composition
    • 丙烯酸共聚物弹性体,其混合橡胶和混合橡胶组合物
    • US5959037A
    • 1999-09-28
    • US692686
    • 1996-08-06
    • Kuniyoshi SaitoIwao MoriyamaJun Okabe
    • Kuniyoshi SaitoIwao MoriyamaJun Okabe
    • C08K5/19C08F220/10C08F220/12C08F220/28C08K5/42C08K5/49C08L27/12C08L33/00C08L33/04C08L33/06C08L33/14C08L15/02
    • C08F220/12C08L27/12C08L33/06
    • A novel acrylic copolymer elastomer comprising �I! an alkyl acrylate; �II! (a) CH.sub.a .dbd.CRCOOR.sub.2 OCOR.sub.1, (b) CH.sub.2 .dbd.CRCO�O(CH.sub.2) pCO!qOR.sub.1 or (c) CH.sub.2 .dbd.CRCOOR.sub.2 �CO(CH.sub.2)pO!qCOR.sub.1 ; and �III! (1) CH.sub.2 .dbd.CRCOO(CH.sub.2)nPhOR', (2) CH.sub.2 .dbd.CRCOO(CH.sub.2)nOCO(CH.sub.2)mPhOR', (3) CH.sub.2 .dbd.CHOCO(CH.sub.2)mPhOR', (4) CH.sub.2 .dbd.CHOCO(CH.sub.2)nOCO(CH.sub.2)mPhOR', (5) CH.sub.2 .dbd.CHO(CH.sub.2)nOCO(CH.sub.2)mPhOR' or (6) CH.sub.2 .dbd.CHPh(CH.sub.2)nOCO(CH.sub.2)mPhOR' where R is a hydrogen atom or a methyl group, R.sub.1 is an alkyl group, R.sub.2 is an alkylene group, R' is a hydrogen atom, an acyl group or a trialkylsilyl group and Ph is a phenylene group, provides a blend rubber having an improved cold resistance and an intermediate heat resistance between the heat resistance of acrylic copolymer elastomer and that of fluorine-containing elastomer, when blended with the fluorine-containing elastomer.
    • 包含[I]丙烯酸烷基酯的新型丙烯酸共聚物弹性体; [II](a)CHa = CRCOOR2OCOR1,(b)CH2 = CRCO [O(CH2)pCO] qOR1或(c)CH2 = CRCOOR2 [CO(CH2)pO] qCOR1; 和(III)(1)CH2 = CRCOO(CH2)nPhOR',(2)CH2 = CRCOO(CH2)nOCO(CH2)mPhOR',(3)CH2 = CHOCO(CH2)mPhOR',(4)CH2 = CHOCO (CH2)nOCO(CH2)mPhOR',(5)CH2 = CHO(CH2)nOCO(CH2)mPhOR'或(6)CH2 = CHPh(CH2)nOCO(CH2)mPhOR'其中R是氢原子或甲基 基团,R 1是烷基,R 2是亚烷基,R'是氢原子,酰基或三烷基甲硅烷基,Ph是亚苯基,提供了具有改善的耐寒性和中间耐热性的共混橡胶, 当与含氟弹性体共混时,丙烯酸共聚物弹性体和含氟弹性体的耐热性。