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61. 发明授权

US6130181A Metathesis catalyst, and its preparation and use 有权
标题翻译：复分解催化剂及其制备与应用
公开(公告)号：US6130181A
公开(公告)日：2000-10-10
申请号：US372065
申请日：1999-08-11
申请人： Peter Schwab , Boris Breitscheidel , Ralf Schulz , Michael Schulz , Ulrich Muller
发明人： Peter Schwab , Boris Breitscheidel , Ralf Schulz , Michael Schulz , Ulrich Muller
IPC分类号： B01J23/36 , B01J35/10 , B01J37/02 , C07C6/04 , B01J23/00 , C07C6/00
CPC分类号： C07C6/04 , B01J23/36 , B01J37/0221 , B01J37/0223 , B01J21/04 , B01J35/0053 , B01J35/006 , B01J35/1042 , B01J35/1061 , C07C2521/04 , C07C2523/36
摘要： A catalyst containing Re.sub.2 O.sub.7 on an inorganic support, wherein the Re.sub.2 O.sub.7 component is on the support in the form of Re.sub.2 O.sub.7 particles having a diameter of
摘要翻译：在无机载体上含有Re 2 O 7的催化剂，其中Re 2 O 7组分以直径<1nm的Re 2 O 7颗粒的形式在载体上，由N 2 O脉冲化学吸附确定的铼表面积为至少0.4m 2 / g，并且Re 2 O 7组分以最大厚度为1.5mm的外壳的形式分布在支撑件上。

62. 发明授权

US4521618A Process for preparing acrylic or methacrylic acid 失效
标题翻译：制备丙烯酸或甲基丙烯酸的方法
公开(公告)号：US4521618A
公开(公告)日：1985-06-04
申请号：US542964
申请日：1983-10-18
申请人： Dietrich Arntz , Gunter Prescher , Werner Burkhardt , Johannes Heilos , Reinhard Manner
发明人： Dietrich Arntz , Gunter Prescher , Werner Burkhardt , Johannes Heilos , Reinhard Manner
IPC分类号： C07C57/05 , B01J23/22 , B01J23/30 , B01J23/34 , B01J23/68 , B01J23/84 , B01J23/88 , B01J23/885 , B01J23/89 , B01J27/192 , B01J27/198 , B01J27/199 , B01J33/00 , B01J37/02 , C07B31/00 , C07B33/00 , C07B61/00 , C07C27/00 , C07C27/14 , C07C45/00 , C07C45/35 , C07C47/052 , C07C47/22 , C07C51/00 , C07C51/25 , C07C57/055 , C07C67/00 , C07C253/00 , C07C253/18 , C07C255/08 , C07D213/84
CPC分类号： C07D213/84 , B01J23/885 , B01J27/192 , B01J37/0223 , C07C45/35 , C07C51/252 , B01J2523/00
摘要： A process is disclosed for preparing coated catalysts, inter alia, for gas phase oxidations in organic chemistry, comprised of an inert support and a coating of catalyst material enclosing this support, wherein a suspension of the starting material for the coating is sprayed onto an agitated bed of the support, while the suspending medium is being partially removed by a gas stream, and the raw material is then dried and heat-treated. For this purpose, the support bed is mechanically agitated and loosened by a gas stream blown in from below. The catalyst precursor containing a binder and, if appropriate, a pore-former is sprayed in an increasing amount from above onto the bed, the ratio between suspending medium sprayed on and drawn off remaining about constant. The thermal expansion coefficient of the precursor as a dry powder must not deviate by more than 15% from that of the support. The applied coating is densified by continuing the mechanical and fluidizing mixing motion, the material is then dried in a continuing gas stream and heat-treated, if appropriate after decomposition of an added pore-former.
摘要翻译：公开了一种用于制备涂覆的催化剂的方法，特别是用于有机化学中的气相氧化，包括惰性载体和包围该载体的催化剂材料的涂层，其中用于涂层的起始材料的悬浮液被喷涂到搅拌的同时通过气流部分地除去悬浮介质，然后将原料干燥和热处理。为此，支撑床被从下方吹入的气流机械搅拌和松动。含有粘合剂的催化剂前体，如果合适的话，将成孔剂从上面以增加的量喷洒到床上，喷雾和吸出的悬浮介质之间的比例保持不变。作为干粉的前体的热膨胀系数不能偏离载体的热膨胀系数的15％以上。施加的涂层通过继续机械和流化混合运动致密化，然后将材料以连续的气流干燥，并在适当的情况下在加入的成孔剂分解后进行热处理。

63. 发明授权

US4305843A Preparation of coated catalysts 失效
标题翻译：涂层催化剂的制备
公开(公告)号：US4305843A
公开(公告)日：1981-12-15
申请号：US126384
申请日：1980-03-03
申请人： Richard Krabetz , Heinz Engelbach , Peter Palm , Heinrich Spahn , Walter Herrmann
发明人： Richard Krabetz , Heinz Engelbach , Peter Palm , Heinrich Spahn , Walter Herrmann
IPC分类号： B01J23/00 , B01J23/88 , B01J23/887 , B01J35/08 , B01J37/02 , B01J23/31 , B01J23/22 , B01J23/85
CPC分类号： B01J23/002 , B01J23/88 , B01J35/08 , B01J37/0221 , B01J37/0223 , B01J23/8876 , B01J2523/00
摘要： A coated catalyst comprising (a) an inert carrier having particles of not less than 100 .mu.m diameter and a surface area of up to 20 m.sup.2 /g and (b) a coating which contains the catalytic material and adheres firmly to the outer surface and to the edge zone, near the surface, of the carrier particles, can be prepared by applying the catalytic material as a 10-70% strength suspension in water to the agitated carrier particles, which are at below 70.degree. C., if the suspension is sprayed, at a constant rate of from 0.01 to 2.0 kg of active material/hour/liter of carrier onto the carrier particles, while at the same time uniformly passing from 0.1 to 12 m.sup.3 (S.T.P.)/hour/liter of carrier of an inert gas at from 20.degree. to 300.degree. C. over the carrier particles, under conditions such that the water only evaporates incompletely but the water content of the resulting coating is less than the maximum degree of saturation of the catalytic material.
摘要翻译：一种涂覆的催化剂，包括（a）具有不小于100μm直径的颗粒和至多20m 2 / g的表面积的惰性载体，和（b）包含催化材料并牢固地粘合到外表面的涂层，到载体颗粒表面附近的边缘区域，可以通过将催化材料作为10-70％强度的悬浮液施加到水中的搅拌的载体颗粒（其在低于70℃）下制备，如果悬浮液以0.01〜2.0kg的活性物质/小时/升的载体的恒定速率喷涂到载体颗粒上，同时将0.1〜12m 3（STP）/小时/升的载体在载体颗粒上的20至300℃的惰性气体，使得水仅不完全蒸发，但所得涂层的水含量小于催化材料的最大饱和度。

64. 发明申请

US20180169622A1 PREPARATION METHOD OF ALUMINA SUPPORTED CERIUM OXIDE POWDER MATERIAL 审中-公开
公开(公告)号：US20180169622A1
公开(公告)日：2018-06-21
申请号：US15735247
申请日：2016-05-06
申请人： HOHAI UNIVERSITY
发明人： Jianfeng Zhang , Gaiye Li , Huiyang Cao , Xin Zhang , Wenmin Guo , Yuping Wu
IPC分类号： B01J23/10 , B01J21/04 , B01J35/00 , B01J35/02 , B01J37/02
CPC分类号： B01J23/10 , B01J21/04 , B01J35/0006 , B01J35/023 , B01J35/026 , B01J37/0223 , B01J37/0238
摘要： The present invention discloses a preparation method of an alumina supported cerium oxide powder material. A cerium organometallic precursor is effectively decomposed into CeO2 nanoparticles at 500-700° C. in an oxygen atmosphere condition by using a chemical vapor deposition method, and the CeO2 nanoparticles are evenly dispersed on an Al2O3 support. The decomposition of the CeO2 precursor is accelerated by changing experimental parameters of reaction between organic materials and oxygen, so as to control the size and microstructure of powder, thereby achieving the preparation and even dispersion of cerium oxide nanoparticles, and avoiding the problem of generation of toxic waste liquor during reaction. The method of the present invention is simple, has a short preparation period, and the cerium oxide nanoparticles prepared are evenly dispersed, can be used as catalytic materials and functional materials, and have a broad application prospect in multiple fields.

65. 发明申请

US20160152532A1 METHOD FOR OXIDATIVELY DEHYDROGENATING N-BUTENES INTO 1,3-BUTADIENE 审中-公开
公开(公告)号：US20160152532A1
公开(公告)日：2016-06-02
申请号：US14905569
申请日：2014-07-17
申请人： BASF SE
发明人： Philipp GRÜNE , Gauthier Luc Maurice AVERLANT , Ragavendra Prasad BALEGEDDE RAMACHANDRAN , Jan Pablo JOSCH
IPC分类号： C07C5/48 , C07C7/11
CPC分类号： C07C5/48 , B01J23/002 , B01J23/8878 , B01J23/8898 , B01J23/94 , B01J35/023 , B01J37/0045 , B01J37/0223 , B01J37/031 , B01J38/16 , B01J2523/00 , C07C7/11 , C07C2523/28 , C07C2523/887 , Y02P20/584 , C07C11/167 , B01J2523/13 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/845
摘要： A process for oxidative dehydrogenation of n-butenes to 1,3-butadiene in a fixed-bed reactor (R), which comprises at least two production steps (i) and at least one regeneration step (ii), and in which in a production step (i), a starting gas mixture (1) comprising the n-butenes is mixed with an oxygen-comprising gas (2) and brought into contact with a heterogeneous, particulate multimetal oxide catalyst comprising molybdenum and at least one further metal as active composition in the fixed-bed reactor (R) and in a regeneration step (ii), the heterogeneous, particulate multimetal oxide catalyst comprising molybdenum and at least one further metal as active composition is regenerated by passing an oxygen-comprising regeneration gas mixture over it and burning off the carbonaceous material deposited on the multimetal oxide catalyst, where a regeneration step (ii) is carried out between two production steps (i) and where a product gas stream (6) which comprises 1,3-butadiene and additionally unreacted n-butenes, oxygen, water and further secondary components, in particular carbon monoxide, carbon dioxide, inert gases, in particular nitrogen, high-boiling hydrocarbons, i.e. hydrocarbons having a boiling point of 95° C. or above at a pressure of one atmosphere, optionally hydrogen and optionally oxygenates is obtained in the production step (i) in the fixed-bed reactor (R) and is fed as such or after one or more intermediate steps as stream (11) to an absorption column (K) in which an absorption is carried out at a pressure in the range from 3.5 to 20 bar by means of a high-boiling absorption medium (13) which becomes loaded with the C4-hydrocarbons from the product gas stream (6) or the stream (11) and is taken off as loaded solvent stream (14) from the bottom of the absorption column (K) to give an overhead stream (12) comprising oxygen, low-boiling hydrocarbons, i.e. hydrocarbons having a boiling point of less than 95° C. at a pressure of one atmosphere, residues of C4-hydrocarbons, residues of high-boiling hydrocarbons, i.e. hydrocarbons having a boiling point of 95° C. or above at a pressure of one atmosphere, optionally inert gases, in particular nitrogen, optionally carbon oxides and optionally water vapor, and is partly or completely recycled as recycle stream to the fixed-bed reactor (R), wherein at the end of each production step (i), the introduction of the oxygen-comprising gas (2) into the reactor (R) is throttled back or shut off and the production step (i) is continued until the oxygen concentration in the overhead stream (12) has decreased to 5% by volume, based on the total volume of the overhead stream (12), whereupon the introduction of the gas stream (1) comprising the n-butenes and also the introduction of the oxygen-comprising gas (2) is shut off, if this has not already been done at the end of the production step (i), at which point the production step (i) is complete and the regeneration step (ii) is started by the overhead stream (12) from the absorption column (K) functioning as oxygen-comprising regeneration gas mixture or substream of the oxygen-comprising regeneration gas mixture, is proposed.

66. 发明授权

US09174910B2 Method for producing acrylic acid with a fixed-bed multitubular reactor 有权
标题翻译：用固定床多管反应器生产丙烯酸的方法
公开(公告)号：US09174910B2
公开(公告)日：2015-11-03
申请号：US14383705
申请日：2013-03-28
申请人： Nippon Shokubai Co., Ltd.
发明人： Toshiya Nishiguchi
IPC分类号： C07C51/16 , C07C45/00 , C07C45/35 , B01J27/192 , C07C51/235 , B01J23/889 , B01J23/00 , B01J23/28 , B01J23/888 , B01J27/199 , C07C51/25
CPC分类号： C07C51/235 , B01J23/002 , B01J23/28 , B01J23/8885 , B01J23/8892 , B01J27/199 , B01J35/0006 , B01J35/10 , B01J35/1038 , B01J35/1066 , B01J35/1071 , B01J35/1076 , B01J35/108 , B01J37/0036 , B01J37/0045 , B01J37/0223 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/53 , B01J2523/55 , B01J2523/68 , B01J2523/69 , B01J2523/845
摘要： This invention provides a method for producing acrylic acid by catalytic gas-phase oxidation, which method makes it possible to carry out a continuous operation steadily for a long period of time while a high yield is maintained.This method is characterized by comprising filling each of reaction tubes of a fixed-bed multitubular reactor with at least two species of catalysts each of which essentially comprises, as catalytically active components, oxide of molybdenum and oxide of vanadium and/or composite oxide of the same, said at least two species of catalysts being different in the ratio of D1/D2, D1 denoting the proportion of the total pore volume of pores whose pore diameter falls within the range of at least 0.03 μm and less than 0.4 μm to the total pore volume of the whole pores, and D2 denoting the proportion of the total pore volume of pores whose pore diameter fails within the range of at least 0.4 μm and at most 5 μm to the total pore volume of the whole pores, in such a manner that at least two reaction zones are formed axially in each of the reaction tubes.
摘要翻译：本发明提供了一种通过催化气相氧化制备丙烯酸的方法，该方法使得可以在保持高产率的情况下长时间稳定地进行连续操作。该方法的特征在于包括用至少两种催化剂填充固定床多管反应器的每个反应管，每种催化剂基本上包含钼的氧化物和钒的氧化物和/或复合氧化物的催化活性组分相同的是，至少两种催化剂的比例不同，D1 / D2，D1表示其孔径落入至少0.03μm且小于0.4μm的范围内的孔的总孔体积的比例相对于总量整个孔的孔体积，D2表示孔径在孔的总体积体积不小于0.4μm至最多5μm的孔的总孔体积的比例，以全孔的总孔体积在每个反应管中至少形成两个反应区域。

67. 发明申请

US20150217287A1 METHOD FOR MANUFACTURING CATALYST FOR CARBON NANOTUBE SYNTHESIS 有权
标题翻译：制备碳纳米管合成催化剂的方法
公开(公告)号：US20150217287A1
公开(公告)日：2015-08-06
申请号：US14424229
申请日：2013-08-08
申请人： Hitachi Chemical Company, Ltd.
发明人： Shunsuke Ueda , Eisuke Haba
IPC分类号： B01J37/34 , B01J35/02 , C01B31/02
CPC分类号： C23C14/223 , B01J23/745 , B01J37/0223 , B01J37/347 , B82Y30/00 , B82Y40/00 , C01B32/16 , C01B32/162 , C23C14/0036 , C23C14/14 , C23C14/34
摘要： Single walled carbon nanotubes can be synthesized and production efficiency of carbon nanotubes can be enhanced by a method including a supplying step (S11) in which particulate carriers are supplied into a drum, a sputtering step (S12) for supporting a catalyst, in which sputtering is performed while this drum 10 is rotated around the axis and is swung so that one end portion and the other end portion in the axial direction of the drum 10 are relatively vertically switched, and a recovering step (S13) in which the particulate carriers are recovered by inclining the drum to discharge the particulate carriers from the drum.
摘要翻译：可以合成单壁碳纳米管，并且可以通过以下方法提高碳纳米管的生产效率：包括将载体提供到滚筒中的供给步骤（S11），用于负载催化剂的溅射步骤（S12），其中溅射在滚筒10绕轴旋转的同时进行摆动，使滚筒10的轴向的一端部和另一端部相对垂直地切换，并且在该步骤（S13）中，颗粒载体为通过使滚筒倾斜以从滚筒排出颗粒载体来回收。

68. 发明申请

US20150080605A1 CATALYST FOR PREPARATION OF AN UNSATURATED CARBOXYLIC ACID BY GAS PHASE OXIDATION OF AN UNSATURATED ALDEHYDE 有权
标题翻译：用于通过气相氧化不饱和二醛制备不饱和羧酸的催化剂
公开(公告)号：US20150080605A1
公开(公告)日：2015-03-19
申请号：US14487383
申请日：2014-09-16
申请人： BASF SE
发明人： Cathrin Alexandra WELKER-NIEUWOUDT , Cornelia Katharina Dobner , Holger Borchert , Ulrich Hammon , Josef Macht , Andrey Karpov , Christian Walsdorff
IPC分类号： B01J23/888 , B01J37/04 , C07C51/25 , B01J35/04
CPC分类号： B01J23/8885 , B01J23/002 , B01J23/8877 , B01J23/94 , B01J35/0006 , B01J35/002 , B01J35/008 , B01J35/023 , B01J35/04 , B01J35/1004 , B01J35/1033 , B01J35/1038 , B01J35/1066 , B01J35/1071 , B01J35/1076 , B01J35/108 , B01J37/0009 , B01J37/0018 , B01J37/0036 , B01J37/0045 , B01J37/0223 , B01J37/0232 , B01J37/04 , B01J37/08 , B01J2523/00 , C07C51/235 , C07C51/25 , C07C51/252 , Y02P20/584 , Y10T428/13 , Y10T428/249953 , Y10T428/273 , B01J2523/17 , B01J2523/55 , B01J2523/68 , B01J2523/69 , C07C57/04
摘要： What is described is a catalyst for preparation of an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde, comprising a shaped support body with an active composition applied thereto, wherein the active composition coverage q q = Q ( 100 - Q )  S m is at most 0.3 mg/mm2, where Q is the active composition content of the catalyst in % by weight and Sm is the specific geometric surface area of the shaped support body in mm2/mg. Also described are a process for preparing the catalyst and a process for preparing an α,β-unsaturated carboxylic acid by gas phase oxidation of an α,β-unsaturated aldehyde over a fixed catalyst bed comprising a bed of the catalyst. The catalyst, with constantly high conversion of acrolein, reduces overoxidation to COx and increases the selectivity of acrylic acid formation.
摘要翻译：所描述的是通过α，bgr-不饱和醛的气相氧化制备α，β-不饱和羧酸的催化剂，其包括施加有活性组合物的成型载体，其中活性组合物覆盖率qq = Q（100-Q）S m为至多0.3mg / mm 2，其中Q为催化剂的活性组成含量，重量％，Sm为成形载体的特定几何表面积，单位为mm2 / mg。还描述了制备催化剂的方法和通过在包含催化剂床的固定催化剂床上气相氧化α，β-不饱和醛来制备α，β-不饱和羧酸的方法。具有不断高的丙烯醛转化率的催化剂减少了对COx的过氧化，并增加了丙烯酸形成的选择性。

69. 发明申请

US20140163291A1 Process for the Oxidative Dehydrogenation of N-Butenes to Butadiene 审中-公开
标题翻译：丁烯丁二烯氧化脱氢工艺
公开(公告)号：US20140163291A1
公开(公告)日：2014-06-12
申请号：US14097452
申请日：2013-12-05
申请人： BASF SE
发明人： Philipp Grüne , Wolfgang Rüttinger , Oliver Hammen , Christian Walsdorff
IPC分类号： B01J23/887 , C07C5/48
CPC分类号： B01J23/8878 , B01J35/023 , B01J35/026 , B01J37/0036 , B01J37/0045 , B01J37/0221 , B01J37/0223 , B01J37/038 , B01J37/08 , B01J37/088 , B01J2523/00 , C07C5/48 , C07C2523/18 , C07C2523/28 , C07C2523/745 , C07C2523/75 , C07C2523/887 , Y02P20/52 , B01J2523/54 , B01J2523/67 , B01J2523/68 , B01J2523/842 , B01J2523/845 , B01J2523/847 , C07C11/167
摘要： The invention relates to a catalyst, in particular a coated catalyst, for the oxidative dehydrogenation of n-butenes to butadiene, its use and also a process for the oxidative dehydrogenation of n-butenes to butadiene.
摘要翻译：本发明涉及用于将丁烯氧化脱氢成丁二烯的催化剂，特别是涂覆的催化剂，其用途以及正丁烯氧化脱氢为丁二烯的方法。

70. 发明申请

US20130204052A1 CATALYST FOR PREPARING VINYL CHLORIDE, METHODS OF PREPARATION AND APPLICATION THEREOF 有权
标题翻译：制备氯乙烯的催化剂，其制备方法及其应用
公开(公告)号：US20130204052A1
公开(公告)日：2013-08-08
申请号：US13806726
申请日：2011-10-26
申请人： Biao Jiang , Jinguang Zhong
发明人： Biao Jiang , Jinguang Zhong
IPC分类号： B01J27/18 , C07C17/25
CPC分类号： B01J27/1806 , B01J21/18 , B01J23/02 , B01J27/138 , B01J37/0018 , B01J37/0201 , B01J37/0203 , B01J37/0223 , B01J37/084 , C07C17/08 , C07C17/25 , C07C21/06
摘要： The present invention discloses a catalyst used in preparing vinyl chloride, its method of preparation, and its applications. Said catalyst used in making vinyl chloride comprises activated carbon as a support, a barium compound and a phosphorus compound supported thereon. The barium compound accounts for 0.2% to 20% of the total mass of the catalyst and the phosphorus compound accounts for 0% to 10% of the total mass of the catalyst based on the mass percentage. A water-soluble barium compound, a water-soluble phosphorus compound, an aqueous polymer monomer, and water are mixed to form a solution or emulsion A. The activated carbon is added into the solution or emulsion A. The activated carbon is removed from water after impregnation, spin-dried, and then the monomers are polymerized. The activated carbon, after polymerization step, is heated to remove water and to decompose and carbonize the polymer. The catalyst after carbonization was activated to obtain a catalyst used in making vinyl chloride.
摘要翻译：本发明公开了用于制备氯乙烯的催化剂及其制备方法及其应用。用于制备氯乙烯的所述催化剂包括作为载体的活性炭，负载在其上的钡化合物和磷化合物。钡化合物占催化剂总质量的0.2％至20％，磷化合物占催化剂总质量的0％至10％，基于质量百分比。将水溶性钡化合物，水溶性磷化合物，水性聚合物单体和水混合以形成溶液或乳液A.将活性炭加入到溶液或乳液A中。将活性炭从水中除去浸渍后，旋转干燥，然后使单体聚合。在聚合步骤之后，将活性炭加热以除去水并分解和碳化聚合物。碳化后的催化剂被活化，得到用于制备氯乙烯的催化剂。

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