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1. 发明申请

US20180065902A1 METHOD FOR CHLORINATION AND DEHYDROGENATION OF ETHANE 审中-公开
公开(公告)号：US20180065902A1
公开(公告)日：2018-03-08
申请号：US15560397
申请日：2016-05-13
申请人： ZHONGKE YIGONG (XIAMEN) CHEMICAL TECHNOLOGY CO. LTD.
发明人： Jingguang ZHONG , Xing LIU , Xuehua LIU
IPC分类号： C07C5/44 , C07C11/04 , C07C17/013 , C07C19/045
CPC分类号： C07C5/44 , B01J37/00 , C01B11/00 , C07C11/04 , C07C17/013 , C07C17/10 , C07C17/156 , C07C19/045 , C07C11/24 , C07C21/06
摘要： The present invention relates to a method for chlorination and dehydrogenation of ethane, comprising: mixing and reacting a low-melting-point metal chloride with C2H6, such that the low-melting-point metal chloride is reduced to a liquid-state low-melting-point metal, and the C2H6 is chlorinated and dehydrogenized to give a mixed gas containing HCl, C2H6, C2H4, C2H2 and C2H3Cl. In the method, the low-melting-point metal chloride is used as a raw material for chlorination and dehydrogenation, and the low-melting-point metal produced after the reaction is used as an intermediate medium. The method has the characteristics of simple process, low cost and high yield. Moreover, some acetylene and vinyl chloride can be produced as by-products at the same time when the ethylene is produced, by controlling the ratio of ethane to the chloride as desired in production.

2. 发明申请

US20170334813A1 PROCESS FOR THE PRODUCTION OF HYDROGEN CHLORIDE, ETHYLENE AND VINYL CHLORIDE FROM ETHANE 审中-公开
公开(公告)号：US20170334813A1
公开(公告)日：2017-11-23
申请号：US15525354
申请日：2015-11-10
申请人： Dow Global Technologies LLC
发明人： Barry B. Fish , Matthew T. Pretz , Max M. Tirtowidjojo
IPC分类号： C07C17/10 , C07C5/44 , C01B7/01
CPC分类号： C07C17/10 , C01B7/01 , C07C5/44 , C07C11/04 , C07C21/06
摘要： A process is provided for the chlorination of ethane using chlorine as the chlorinating agent to produce ethylene, hydrogen chloride (HCl) and vinyl chloride monomer (VCM).

3. 发明授权

US09371259B2 Method for preparing vinyl chloride from acetylene and dichlorethane 有权
标题翻译：从乙炔和二氯乙烷制备氯乙烯的方法
公开(公告)号：US09371259B2
公开(公告)日：2016-06-21
申请号：US14406931
申请日：2012-07-12
申请人： Biao Jiang , Jinguang Zhong
发明人： Biao Jiang , Jinguang Zhong
IPC分类号： C07C17/07 , C07C17/08 , C07C17/25 , C07C17/354
CPC分类号： C07C17/354 , C07C17/07 , C07C17/08 , C07C17/25 , Y02P20/582 , C07C21/06
摘要： Provided is a method for preparing vinyl chloride with acetylene and dichlorethane for large-scale industrial production. Acetylene, dichlorethane vapor and hydrogen chloride gas at a molar ratio of 1:(0.3-1.0):(0-0.20) are mixed; the raw mixed gas is preheated; the preheated raw mixed gas passes through a reactor containing a catalyst and reacts; the resultant mixed gas is cooled to 30-50° C. and pressurized to 0.4-1.0 MPa, and then cooled to ambient temperature, and further frozen to −25-15° C. for liquefaction isolation, and unliquefied gas is recycled and reused; liquefied liquid is sent to a rectifying tower for rectification, and vinyl chloride monomers meeting polymerization requirements are obtained. The present invention has the advantages of eliminating mercury contamination completely, simplifying the reactor structure, recycling hydrogen chloride and acetylene, reducing waterwash process, avoiding mass production of waste acid and improving utilization of chlorine.
摘要翻译：提供了用于大规模工业化生产乙炔和二氯乙烷的氯乙烯的方法。乙烯，二氯乙烷蒸气和摩尔比为1：（0.3-1.0）：（0-0.20）的氯化氢气体混合; 原料混合气体预热; 预热的原料混合气体通过含有催化剂的反应器并进行反应; 将所得混合气体冷却至30-50℃并加压至0.4-1.0MPa，然后冷却至环境温度，并进一步冷冻至-25-15℃以进行液化分离，并将非液化气体再循环使用 ; 将液化液送至精馏塔进行精馏，得到满足聚合要求的氯乙烯单体。本发明具有完全消除汞污染的优点，简化反应器结构，回收氯化氢和乙炔，减少洗水过程，避免大量生产废酸，提高氯的利用率。

4. 发明授权

US09308513B2 Production of vinyl chloride from a methane conversion process 有权
标题翻译：从甲烷转化过程生产氯乙烯
公开(公告)号：US09308513B2
公开(公告)日：2016-04-12
申请号：US13915143
申请日：2013-06-11
申请人： UOP LLC
发明人： Jeffery C. Bricker , John Q. Chen , Peter K. Coughlin
IPC分类号： C07C17/156 , C07C17/08 , C07C17/07 , C07C17/354 , C07C2/82 , C07C2/80 , B01J19/10 , C07C17/25 , B01J19/26 , B01J3/08 , C07C5/09
CPC分类号： B01J19/10 , B01J3/08 , B01J19/26 , B01J2219/00006 , B01J2219/0004 , B01J2219/00123 , C07C2/78 , C07C2/82 , C07C5/09 , C07C17/156 , C07C17/25 , Y02P30/44 , C07C19/045 , C07C21/06 , C07C11/24 , C07C11/04
摘要： Methods and systems are provided for converting methane in a feed stream to acetylene. The method includes processing the acetylene to form a hydrocarbon stream having vinyl chloride. The hydrocarbon stream is introduced into a supersonic reactor and pyrolyzed to convert at least a portion of the methane to acetylene. The reactor effluent stream is be treated to convert acetylene to other hydrocarbon processes. The method according to certain aspects includes controlling the level of carbon monoxide in the hydrocarbon stream to limit downstream side reactions in the downstream processing units.
摘要翻译：提供了将进料流中的甲烷转化为乙炔的方法和系统。该方法包括加工乙炔以形成具有氯乙烯的烃流。将烃流引入超音速反应器中并热解以将至少一部分甲烷转化为乙炔。处理反应器流出物流以将乙炔转化成其它烃过程。根据某些方面的方法包括控制烃流中的一氧化碳的水平以限制下游处理单元中的下游侧反应。

5. 发明授权

US08889924B2 Process for the production of 1,3,3,3-tetrafluoropropene 有权
标题翻译：生产1,3,3,3-四氟丙烯的方法
公开(公告)号：US08889924B2
公开(公告)日：2014-11-18
申请号：US13757911
申请日：2013-02-04
申请人： Honeywell International Inc.
发明人： Haridasan K. Nair , Rajiv Ratna Singh , Andrew Joseph Poss , David Nalewajek
IPC分类号： C07C17/25 , C07C17/278 , C07C19/01 , C07C19/08 , C07C19/10 , C07C21/06 , C07C21/18 , C07C17/20
CPC分类号： C07C17/25 , C07C17/206 , C07C17/278 , C07C19/08 , C07C19/10 , C07C21/06 , C07C21/18 , C07C19/01
摘要： The present invention provides a simple three step process for the production of 1,3,3,3-tetrafluoropropene (HFO-1234ze). In the first step, carbon tetrachloride is added to vinyl fluoride to afford the compound CCl3CH2CHClF (HCFC-241fb). HCFC-241fb is then fluorinated with anhydrous HF to afford CF3CH2CHClF (HCFC-244fa) in the second step. Dehydrochlorination of HCFC-244fa, in the third step, affords the desired product, CF3CH═CHF (HFO-1234ze). Following similar chemistry, vinyl chloride may be used in place of vinyl fluoride.
摘要翻译：本发明提供了制备1,3,3,3-四氟丙烯（HFO-1234ze）的简单的三步法。在第一步中，将四氯化碳加入到氟乙烯中，得到化合物CCl 3 CH 2 CHClF（HCFC-241fb）。然后用无水HF将HCFC-241fb氟化，得到第二步中的CF 3 CH 2 CHClF（HCFC-244fa）。在第三步中HCFC-244fa的脱氯化氢提供所需产物，CF 3 CH = CHF（HFO-1234ze）。在类似的化学反应之后，可以使用氯乙烯代替氟乙烯。

6. 发明申请

US20130204052A1 CATALYST FOR PREPARING VINYL CHLORIDE, METHODS OF PREPARATION AND APPLICATION THEREOF 有权
标题翻译：制备氯乙烯的催化剂，其制备方法及其应用
公开(公告)号：US20130204052A1
公开(公告)日：2013-08-08
申请号：US13806726
申请日：2011-10-26
申请人： Biao Jiang , Jinguang Zhong
发明人： Biao Jiang , Jinguang Zhong
IPC分类号： B01J27/18 , C07C17/25
CPC分类号： B01J27/1806 , B01J21/18 , B01J23/02 , B01J27/138 , B01J37/0018 , B01J37/0201 , B01J37/0203 , B01J37/0223 , B01J37/084 , C07C17/08 , C07C17/25 , C07C21/06
摘要： The present invention discloses a catalyst used in preparing vinyl chloride, its method of preparation, and its applications. Said catalyst used in making vinyl chloride comprises activated carbon as a support, a barium compound and a phosphorus compound supported thereon. The barium compound accounts for 0.2% to 20% of the total mass of the catalyst and the phosphorus compound accounts for 0% to 10% of the total mass of the catalyst based on the mass percentage. A water-soluble barium compound, a water-soluble phosphorus compound, an aqueous polymer monomer, and water are mixed to form a solution or emulsion A. The activated carbon is added into the solution or emulsion A. The activated carbon is removed from water after impregnation, spin-dried, and then the monomers are polymerized. The activated carbon, after polymerization step, is heated to remove water and to decompose and carbonize the polymer. The catalyst after carbonization was activated to obtain a catalyst used in making vinyl chloride.
摘要翻译：本发明公开了用于制备氯乙烯的催化剂及其制备方法及其应用。用于制备氯乙烯的所述催化剂包括作为载体的活性炭，负载在其上的钡化合物和磷化合物。钡化合物占催化剂总质量的0.2％至20％，磷化合物占催化剂总质量的0％至10％，基于质量百分比。将水溶性钡化合物，水溶性磷化合物，水性聚合物单体和水混合以形成溶液或乳液A.将活性炭加入到溶液或乳液A中。将活性炭从水中除去浸渍后，旋转干燥，然后使单体聚合。在聚合步骤之后，将活性炭加热以除去水并分解和碳化聚合物。碳化后的催化剂被活化，得到用于制备氯乙烯的催化剂。

7. 发明授权

US08058490B2 Process for the manufacture of 1,2-dichloroethane 有权
标题翻译：制备1,2-二氯乙烷的方法
公开(公告)号：US08058490B2
公开(公告)日：2011-11-15
申请号：US12304329
申请日：2007-06-22
申请人： Michel Strebelle , Dominique Balthasart
发明人： Michel Strebelle , Dominique Balthasart
IPC分类号： C07C17/15 , C07C17/10
CPC分类号： C07C17/25 , C07C17/02 , C07C17/156 , C07C17/389 , C07C19/045 , C07C21/06 , C08F14/06 , Y02P20/582 , C08F2/02
摘要： Process for the manufacture of 1,2-dichloroethane (DCE) starting from a stream of ethane which is subjected to a catalytic oxydehydrogenation (ODH) thus producing a gas mixture containing ethylene which is then dried and conveyed to a chlorination reactor supplied with a flow of chlorine so that at least 10% of the ethylene is converted to DCE. The stream of products derived from the chlorination reactor is then conveyed to an oxychlorination reactor in which the majority of the balance of ethylene is converted to DCE.
摘要翻译：从经过催化氧化脱氢（ODH）的乙烷流开始制造1,2-二氯乙烷（DCE）的方法，由此产生含有乙烯的气体混合物，然后将其干燥并输送到提供有流动的氯化反应器的氯，使得至少10％的乙烯转化为DCE。然后将来自氯化反应器的产物流输送到氧氯化反应器，其中大部分余量的乙烯转化成DCE。

8. 发明申请

US20110230683A1 Process and apparatus for producing ethylenically unsaturated halogenated hydrocarbons 审中-公开
标题翻译：烯键式不饱和卤代烃的制备方法和装置
公开(公告)号：US20110230683A1
公开(公告)日：2011-09-22
申请号：US12998172
申请日：2009-09-03
申请人： Michael Benje , Peter Kammerhofer , Klaus Krejci , Rainer Kampschulte , Helmut Grumann
发明人： Michael Benje , Peter Kammerhofer , Klaus Krejci , Rainer Kampschulte , Helmut Grumann
IPC分类号： C07C17/25 , G05D7/00 , B01J19/00 , B01J19/08
CPC分类号： B01J19/088 , B01J19/12 , B01J19/24 , B01J2219/00157 , B01J2219/0024 , B01J2219/0896 , C07C17/25 , C07C21/06
摘要： Process and apparatus for producing ethylenically unsaturated halogenated hydrocarbonsThe invention relates to a process and an apparatus for preparing ethylenically unsaturated halogenated hydrocarbons, preferably vinyl chloride by thermal dissociation of 1,2-dichloroethane, using physical or chemical measures which initiate the dissociation reaction.The process/apparatus described makes it possible to increase the amount produced using dissociation reactors of a given size considerably. Use is made here of initiating measures to increase the heat flux through the wall of the reaction tube and at the same time the feed stream and the heating power of the reaction furnace are increased so that the conversion of the reaction is not significantly increased compared to processes without use of initiating measures.To be able to continue to operate the process economically despite the reduction in the reaction temperature, the process parameters have to be set so that at least 50% of the amount of feed used are vaporized by means of the sensible heat content of the reaction mixture leaving the reaction zone.
摘要翻译：用于生产烯属不饱和卤代烃的方法和装置本发明涉及使用引发解离反应的物理或化学措施制备烯属不饱和卤代烃，优选氯乙烯通过1,2-二氯乙烷的热解作用的方法和装置。所描述的方法/装置使得可以显着增加使用给定尺寸的解离反应器产生的量。在这里使用的措施是增加通过反应管的壁的热通量，同时反应炉的进料流和加热功率增加，使得反应的转化率不会显着增加过程不使用启动措施。尽管反应温度降低，为了能够经济地继续操作该方法，必须设定工艺参数，使得所用进料量的至少50％通过反应混合物的显热含量蒸发离开反应区。

9. 发明授权

US07968756B2 Process and apparatus for production of vinyl chloride monomer 有权
标题翻译：用于生产氯乙烯单体的方法和设备
公开(公告)号：US07968756B2
公开(公告)日：2011-06-28
申请号：US12190227
申请日：2008-08-12
申请人： John W. Olver , Jason Andrew Simmons
发明人： John W. Olver , Jason Andrew Simmons
IPC分类号： C07C17/25
CPC分类号： C07C21/06 , B01J19/02 , B01J19/2425 , B01J2219/00157 , B01J2219/0263 , B01J2219/0286 , C07C17/02 , C07C17/156 , C07C17/25 , C07C19/045
摘要： Process and apparatus to form vinyl chloride monomer from ethylene dichloride in a cracking furnace, including a firebox chamber having a thermal protective layer disposed on refractory walls and/or process tubes disposed within the chamber, a quencher to form vinyl chloride monomer, and fractionator separate products. The thermal protective layer which contains an inorganic adhesive for metal/alloy tubes or colloidal silica and/or colloidal alumina for refractory walls or ceramic tubes, a filler, and one or more emissivity agents.
摘要翻译：在裂解炉中由二氯乙烯形成氯乙烯单体的方法和装置，包括具有设置在室内的耐热壁和/或处理管上的热保护层的火炉室，形成氯乙烯单体的猝灭剂和分离器产品。包含用于金属/合金管的无机粘合剂或用于耐火壁或陶瓷管的胶体二氧化硅和/或胶体氧化铝的热保护层，填料和一种或多种发射剂。

10. 发明授权

US07435983B2 Device for injecting electromagnetic radiation into a reactor 有权
标题翻译：将电磁辐射注入反应器的装置
公开(公告)号：US07435983B2
公开(公告)日：2008-10-14
申请号：US10554555
申请日：2004-03-01
申请人： Michael Benje
发明人： Michael Benje
IPC分类号： H01J49/00 , B01D59/44 , H01S3/09 , C23C16/00
CPC分类号： B01J19/243 , B01J19/121 , B01J19/123 , B01J2219/00094 , B01J2219/00247 , B01J2219/0875 , C07C17/25 , C07C21/06
摘要： Device for injecting electromagnetic radiation into a reactor and a reactor comprising this deviceA device for injecting electromagnetic radiation into a reactor for carrying out free-radical gas-phase reactions and a reactor comprising such a device are described.This comprises the elements: a) a compartment which is separated from the reaction space of the reactor and is b) connected to the reaction space of the reactor via at least one opening, c) at least one feed line for introducing a flushing gas into the compartment, and also d) at least one source of electromagnetic radiation which is arranged so that e) the electromagnetic radiation passes through the compartment and the reaction space of the reactor adjoining the compartment. The device and reactor make an increase in the yield of free-radical chain reactions possible.
摘要翻译：用于将电磁辐射注入反应器的装置和包括该装置的反应器描述了用于将电磁辐射注入用于进行自由基气相反应的反应器的装置和包括这种装置的反应器。这包括以下要素：a）与反应器的反应空间分离的隔室，b）通过至少一个开口连接到反应器的反应空间，c）至少一条用于将冲洗气体引入的进料管线隔室，以及d）至少一个电磁辐射源，其被布置成使得e）电磁辐射通过隔室和邻接隔室的反应器的反应空间。装置和反应器使得自由基链反应的产率增加。

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