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61. 发明授权

US08097753B2 Mixtures composed or monocarboxy-functionalized dialkylphosphinic acids, their use and a process for their preparation 有权
标题翻译：混合物或单羧基官能化二烷基次膦酸，其用途及其制备方法
公开(公告)号：US08097753B2
公开(公告)日：2012-01-17
申请号：US11714482
申请日：2007-03-06
申请人： Wiebke Maas , Werner Krause , Harald Bauer
发明人： Wiebke Maas , Werner Krause , Harald Bauer
IPC分类号： C07F9/22
CPC分类号： C08K5/5313 , C07F9/301 , C07F9/306 , C08K2201/014
摘要： The invention relates to mixtures composed of monocarboxy-functionalized dialkylphosphinic acids and of further components, which comprise A) from 98 to 100% by weight of monocarboxy-functionalized dialkylphosphinic acids of the formula (I) in which R1, R2, R3, R4, R5, R6, and R7 are identical or different and, independently of one another, are H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, and/or phenyl, X and Y are identical or different and, independently of one another, are H, Li, Na, K, or NH4, and B) from 0 to 2% by weight of halogens, where the entirety of the components always amounts to 100% by weight.
摘要翻译：本发明涉及由单羧基官能化的二烷基次膦酸和其它组分组成的混合物，其包含A）98至100重量％的式（I）的单羧基官能化二烷基次膦酸，其中R 1，R 2，R 3，R 4， R 5，R 6和R 7是相同或不同的，彼此独立地是H，甲基，乙基，正丙基，异丙基，正丁基，异丁基，叔丁基和/或苯基，X和Y是相同的或者不同，并且彼此独立地是H，Li，Na，K或NH 4，和B）0-2重量％的卤素，其中整个组分总计为100重量％。

62. 发明申请

US20110213078A1 Method for Producing Mono-Aminofunctionalized Dialkylphosphinic Acids and Esters and Salts Thereof by Means of Acrylnitriles and Use Thereof 有权
标题翻译：通过丙烯腈生产单氨基官能化二烷基膦酸及其酯及其盐的方法及用途
公开(公告)号：US20110213078A1
公开(公告)日：2011-09-01
申请号：US13127072
申请日：2009-10-06
申请人： Michael Hill , Werner Krause , Martin Sicken
发明人： Michael Hill , Werner Krause , Martin Sicken
IPC分类号： C08L67/02 , C07F9/30 , C07F9/32 , C07F5/06 , C07F7/28 , C08G63/183 , C08L77/06 , C08G69/26
CPC分类号： C07F9/3211 , C07F9/301 , C07F9/3264 , C07F9/4816 , C07F9/4866 , C08K5/5313 , C09K21/12
摘要： The invention relates to a method for producing mono-aminofunctionalized dialkylphosphinic acids and esters and salts thereof by means of acrylnitriles, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the thus obtained alkylphosphonic acid, salt or ester (II) thereof is reacted with an acrylnitrile of formula (V) to yield a mono-functionalized dialkylphosphinic acid derivative (VI) in the presence of a catalyst B, and c) the thus obtained mono-functionalized dialkylphosphinic acid derivative (VI) is reacted to yield a mono-aminofunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst C or a reduction agent, wherein R1, R2, R3, R4, R5, R6, R7 are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl and X stands for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and Y stands for a mineral acid, a carboxylic acid, a Lewis acid or an organic acid, n=an integer or fractional number of 0 to 4 and the catalysts A and C are formed by transition metals, transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand, and catalyst B is formed by compounds forming peroxides, peroxo compounds, azo compounds, alkali metals, alkaline earth metals, alkali hydrides, alkaline earth hydrides and/or alkali alcoholates and alkaline earth alcoholates.
摘要翻译：本发明涉及一种通过丙烯腈生产单氨基官能化二烷基次膦酸及其酯及其盐的方法，其特征在于a）将次膦酸源（I）与烯烃（Ⅳ）反应，得到烷基膦酸盐或盐酯（II），b）将由此得到的烷基膦酸，其盐或酯（II）与式（V）的丙烯腈反应，得到单官能化二烷基次膦酸衍生物（Ⅵ）在催化剂B存在下，和c）将由此得到的单官能化二烷基次膦酸衍生物（Ⅵ）反应，得到单氨基官能化二烷基次膦酸衍生物（Ⅲ），其中催化剂C或还原剂存在下，其中对于H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基，R 1，R 2，R 3，R 4，R 5，R 6，R 7相同或不同，彼此独立烷基芳基，X代表H，C1-C18烷基，C6-C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K 和/或质子化的氮碱，Y表示无机酸，羧酸，路易斯酸或有机酸，n = 0至4的整数或分数，催化剂A和C由过渡金属形成由过渡金属和/或过渡金属化合物和至少一种配体组成的过渡金属化合物和/或催化剂体系和催化剂B通过形成过氧化物，过氧化合物，偶氮化合物，碱金属，碱土金属，碱金属氢化物，碱土金属氢化物和/或碱金属醇盐和碱土金属盐。

63. 发明申请

US20110213061A1 Method for Producing Mono-Aminofunctionalized Dialkylphosphinic Acids and Esters and Salts Thereof and Use Thereof 审中-公开
标题翻译：单氨基官能化二烷基膦酸及其酯及其盐的制备方法及用途
公开(公告)号：US20110213061A1
公开(公告)日：2011-09-01
申请号：US13125359
申请日：2009-10-06
申请人： Michael Hill , Werner Krause , Martin Sicken
发明人： Michael Hill , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313 , C07F9/30 , C08L67/02 , C08L77/06
CPC分类号： C09K21/12 , C07F9/301 , C07F9/3211 , C08K5/5313
摘要： The invention relates to a method for producing mono-aminofunctionalized dialkylphosphinic acids and esters and salts thereof, characterized in that a) a phosphinic acid source (I) is reacted with olefins (IV) to yield an alkylphosphonic acid, salt or ester (II) thereof in the presence of a catalyst A, b) the thus obtained alkylphosphonic acid, salt or ester (II) thereof is reacted with acetylenic compounds of formula (V) to yield a mono-functionalized dialkylphosphinic acid derivative (VI) in the presence of a catalyst B, and c) the thus obtained mono-functionalized dialkylphosphinic acid derivative (VI) is reacted with a hydrogen cyanide source to yield a mono-functionalized dialkylphosphinic acid derivative (VII) in the presence of a catalyst C, and d) the thus obtained mono-functionalized dialkylphosphinic acid derivative (VII); is reacted to yield a mono-aminofunctionalized dialkylphosphinic acid derivative (III) in the presence of a catalyst D or a reduction agent, wherein R1, R2, R3, R4, R5, R6 are the same or different and stand independently of each other, among other things, for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, and X stands for H, C1-C18 alkyl, C6-C18 aryl, C6-C18 aralkyl, C6-C18 alkylaryl, Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K and/or a protonized nitrogen base, and Y stands for a mineral acid, a carboxylic acid, a Lewis acid or an organic acid, n=0 to 4 and the catalysts A, B, C and D are formed by transition metals, transition metal compounds and/or catalyst systems composed of a transition metal and/or a transition metal compound and at least one ligand.
摘要翻译：本发明涉及一种用于制备单氨基官能化二烷基次膦酸及其酯和盐的方法，其特征在于a）将次膦酸源（I）与烯烃（Ⅳ）反应，得到烷基膦酸盐或酯（Ⅱ）在催化剂A存在下，将由此得到的烷基膦酸，其盐或酯（II）与式（Ⅴ）的炔属化合物反应，得到单官能化二烷基次膦酸衍生物（Ⅵ）催化剂B和c）由此获得的单官能化二烷基次膦酸衍生物（VI）与氰化氢源反应，在催化剂C存在下得到单官能化二烷基次膦酸衍生物（Ⅶ），和d）得到单官能化二烷基次膦酸衍生物（VII）; 在催化剂D或还原剂的存在下反应得到单氨基官能化二烷基次膦酸衍生物（III），其中R1，R2，R3，R4，R5，R6相同或不同并且彼此独立，对于H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基，C 6 -C 18烷基芳基，X代表H，C 1 -C 18烷基，C 6 -C 18芳基，C 6 -C 18芳烷基， C18烷基芳基，Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K和/或质子化氮碱，Y 代表无机酸，羧酸，路易斯酸或有机酸，n = 0〜4，催化剂A，B，C和D由过渡金属，过渡金属化合物和/或催化剂体系过渡金属和/或过渡金属化合物和至少一种配体。

64. 发明申请

US20110021676A1 Method for the Production of a Flame-retardant, Non-corrosive, and Easily flowable Polyamide and Polyester Molding Compounds 审中-公开
标题翻译：阻燃，无腐蚀，易流动的聚酰胺和聚酯成型化合物的制备方法
公开(公告)号：US20110021676A1
公开(公告)日：2011-01-27
申请号：US12919792
申请日：2009-02-25
申请人： Sebastian Hoerold , Ottmar Schacker , Harald Bauer , Werner Krause , Daniela Eisenhauer
发明人： Sebastian Hoerold , Ottmar Schacker , Harald Bauer , Werner Krause , Daniela Eisenhauer
IPC分类号： C08K5/3492 , C08K5/5313 , C09K21/12
CPC分类号： C09K21/12 , C08K5/0066 , C08K5/5313 , C08L77/00 , C08L67/02
摘要： The invention relates to a process for producing flame-retardant, non-corrosive, highly flawable polyamides and polyesters, which comprises using a flame retardant mixture made of a phosphinic salt of the formula (I), where M═Al, Mg, Ca, Ti, or Na (component A) in which R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; n is from 1 to 3, and, as component B, a metal salt of an organic acid, and/or an inorganic zinc, calcium, magnesium, potassium, sodium, aluminum, titanium, tin, antimony, bismuth, or barium compound, where the amount of component A present in the flame retardant mixture is from 70 to 99.5% by weight and the amount of component B present in the flame retardant mixture is from 0.5 to 30% by weight.
摘要翻译：本发明涉及一种制造阻燃，非腐蚀性，高度可破坏的聚酰胺和聚酯的方法，其包括使用由式（I）的次膦酸盐制成的阻燃混合物，其中M = Al，Mg，Ca， Ti或Na（组分A），其中R 1和R 2相同或不同，为直链或支链的C 1 -C 6 - 烷基和/或芳基; n为1〜3，作为成分B的有机酸金属盐和/或无机锌，钙，镁，钾，钠，铝，钛，锡，锑，铋或钡化合物，其中存在于阻燃剂混合物中的组分A的量为70至99.5重量％，并且阻燃混合物中存在的组分B的量为0.5至30重量％。

65. 发明授权

US07635785B2 Process for preparation of dialkylphosphinic salts 有权
标题翻译：制备二烷基次膦酸盐的方法
公开(公告)号：US07635785B2
公开(公告)日：2009-12-22
申请号：US11016663
申请日：2004-12-17
申请人： Harald Bauer , Werner Krause , Martin Sicken , Norbert Weferling
发明人： Harald Bauer , Werner Krause , Martin Sicken , Norbert Weferling
IPC分类号： C07F9/30
CPC分类号： C07F9/30 , C08K5/5313
摘要： The invention relates to a process for preparation of salts of dialkylphosphinic acids, which comprises a) reacting hypophosphorous acid and/or its salts with olefins in the presence of a free-radical initiator to give dialkylphosphinic acids and/or their alkali metal salts, in a solvent system, and b) reacting the dialkylphosphinic acids and/or alkali metal dialkylphosphinates obtained in a) with compounds of the metals Mg, Ca, Al, Zn, Ti, Sn, Zr, and/or Fe to give the dialkylphosphinic salts of these metals. The invention also relates to the use of the metal dialkylphosphinic salts obtained by the inventive process, in particular for preparation of flame retardants.
摘要翻译：本发明涉及二烷基次膦酸的盐的制备方法，该方法包括：a）在自由基引发剂存在下使次亚磷酸和/或其盐与烯烃反应，得到二烷基次膦酸和/或其碱金属盐，溶剂体系，b）使a）中得到的二烷基次膦酸和/或碱金属二烷基次膦酸盐与金属Mg，Ca，Al，Zn，Ti，Sn，Zr和/或Fe的化合物反应，得到这些金属。本发明还涉及通过本发明方法获得的二烷基次膦酸金属盐的用途，特别是制备阻燃剂。

66. 发明申请

US20090137707A1 Mixed salts of diorganylphosphinic acids and carboxylic acids 有权
标题翻译：二有机基次膦酸和羧酸的混合盐
公开(公告)号：US20090137707A1
公开(公告)日：2009-05-28
申请号：US12313523
申请日：2008-11-21
申请人： Harald Bauer , Werner Krause , Wolfgang Wanzke
发明人： Harald Bauer , Werner Krause , Wolfgang Wanzke
IPC分类号： C09K21/12 , C07F19/00
CPC分类号： C07F9/301 , C07C63/28 , C08K5/0066 , C08K5/5313 , C08L21/00
摘要： The invention relates to mixtures of diorganylphosphinic acids and carboxylic acids of the formula [cationn+(phosphinate−)x(carboxylic acid anionz−1/z)y] where n=from 1 to 4 x=from 0.01 to n−0.01 y=n−x z=from 1 to 4, where “cation” means an element of the second main and/or transition group, an element of the third main and/or transition group, an element of the fourth main and/or transition group, an element of the fifth main and/or transition group, an element of the sixth transition group, an element of the seventh transition group, and/or an element of the eighth transition group, “phosphinate” means the anion of diorganylphosphinic acids of the formula where R1 and R2 are identical or different and, independently of one another, are H, C1-C6-alkyl, linear or branched, and/or aryl, and/or hydroxyalkyl, and “carboxylic acid anion” means C1-C18 carboxylic acid anions. The invention also relates to processes for their production, and to their use.
摘要翻译：本发明涉及二有机基次膦酸和羧酸的混合物，其结构式为：α-in-line-formula description =“In-line Formulas”end =“lead”→[cationn +（phosphinate-）x（carboxylic acid anionz-1 / z）y] <？in-line-formula description =“In-line Formulas”end =“tail”？>其中n = 1至4 x =从0.01到n-0.01 y = nx z =从1到4 其中“阳离子”是指第二主和/或转移基团的元素，第三主和/或过渡基团的元素，第四主和/或过渡基团的元素，第五主元素和/或过渡基团的元素和/ 或过渡组，第六过渡组的元素，第七过渡组的元素和/或第八过渡组的元素，“次膦酸酯”是指下式的二有机基次膦酸的阴离子，其中R 1和R 2相同或不同且彼此独立地为H，C 1 -C 6 - 烷基，直链或支链和/或芳基和/或羟烷基，“羧酸阴离子”是指C 1 -C 18羧酸a 国王本发明还涉及其生产方法及其用途。

67. 发明授权

US07482398B2 Elastic covering material having improved flame retardant properties and production thereof 失效
标题翻译：弹性覆盖材料具有改进的阻燃性能及其制备
公开(公告)号：US07482398B2
公开(公告)日：2009-01-27
申请号：US10890068
申请日：2004-07-13
申请人： Harald Bauer , Hans-Matthias Deger , Werner Krause
发明人： Harald Bauer , Hans-Matthias Deger , Werner Krause
IPC分类号： C08K5/5313
CPC分类号： C08K5/5313 , C04B26/045 , C04B26/08 , C04B26/16 , C04B2111/00482 , C04B2111/503 , C04B2111/60 , C09K21/12 , D06N1/00 , D06N3/0056 , D06N3/0059 , D06N7/0073 , D06N2209/067 , Y10S524/914 , Y10T428/25 , Y10T428/31674 , C04B14/062 , C04B14/106 , C04B14/28 , C04B14/30 , C04B24/003 , C04B24/243 , C04B2103/54 , C04B2103/63 , C04B14/06 , C04B14/36 , C04B24/04 , C04B24/08
摘要： The invention relates to an elastic covering material, which comprises, as a flame retardant, a phosphinate salt of the formula (I) and/or a diphosphinate salt of the formula (II) and/or polymers thereof where R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4. The invention relates to processes for producing such elastic covering materials.
摘要翻译：本发明涉及一种弹性覆盖材料，其包含作为阻燃剂的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物，其中R 1，R 2相同或不同且各自为C 1 -C 6 - 烷基，直链或支链和/或芳基; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1〜4。本发明涉及生产这种弹性覆盖材料的方法。

68. 发明申请

US20080241529A1 Flameproofed adhesive and sealing materials 审中-公开
标题翻译：防火胶粘剂和密封材料
公开(公告)号：US20080241529A1
公开(公告)日：2008-10-02
申请号：US12079211
申请日：2008-03-25
申请人： Harald Bauer , Mathias Dietz , Werner Krause
发明人： Harald Bauer , Mathias Dietz , Werner Krause
IPC分类号： C09J101/00 , C08K5/5313 , C09J103/00 , C09J123/00 , C09J175/04 , C09J167/00 , C09J163/00 , B32B27/06 , C09J153/00 , C09J109/00 , C09J133/04 , C09J105/00 , C08K5/3492
CPC分类号： C09J9/00 , C08K5/5313 , C08L9/06 , C08L21/00 , C09J11/06 , Y10T428/2852
摘要： The invention relates to flameproofed adhesive and sealing materials containing 0.1-99.9% by weight of adhesive or thermoplastic polymer and 0.1-99.9% by weight of flameproofing agent, wherein the flameproofing agent contains at least one phosphinic acid salt of the formula (I) and/or one diphosphinic acid salt of the formula (II) in which R1, R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, C6-C10-alkylarylene or C6-C10-arylalkylene; M is Mg, Ca, Al, Zn, Sb, Sn, Ge, Zn, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4 and x is 1 to 4, the adhesive polymers being acrylate resins, polyurethane resins, saturated and unsaturated polyester resins, styrene-butadiene copolymers, vinyl acetate copolymers, silicones, synthetic rubber and/or polyolefin resins.
摘要翻译：本发明涉及含有0.1-99.9重量％的粘合剂或热塑性聚合物和0.1-99.9重量％的防火剂的防火粘合剂和密封材料，其中该防火剂含有至少一种式（I）的次膦酸盐和 /或其中R 1，R 2，R 2相同或不同的式（II）的一种二膦酸盐是C 1 -C 直链或支链的烷基，和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - 10亚芳基，C 6 -C 10 - 亚烷基亚芳基或C 6 -C 10 - 芳基亚烷基; M是Mg，Ca，Al，Zn，Sb，Sn，Ge，Zn，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1〜4，x为1〜4，粘合性聚合物为丙烯酸酯树脂，聚氨酯树脂，饱和和不饱和聚酯树脂，苯乙烯 - 丁二烯共聚物，乙酸乙烯酯共聚物，硅酮，合成橡胶和/或聚烯烃树脂。

69. 发明申请

US20080233128A1 Treatment of Viral Infections 审中-公开
标题翻译：病毒感染的治疗
公开(公告)号：US20080233128A1
公开(公告)日：2008-09-25
申请号：US11933691
申请日：2007-11-01
申请人： Werner Krause
发明人： Werner Krause
IPC分类号： A61K39/42 , A61P31/12
CPC分类号： A61K39/39541 , Y02A50/394 , A61K2300/00
摘要： A method of treating viral infections comprises administering to a patient a regimen that is able to temporarily reduce the number or functionality of the host cells which the virus uses for its reproduction in a controlled manner. Preferably, host cells are part of the immune system.
摘要翻译：治疗病毒感染的方法包括向患者施用能够以受控方式暂时降低病毒用于其繁殖的宿主细胞的数量或功能性的方案。优选地，宿主细胞是免疫系统的一部分。

70. 发明申请

US20070213563A1 Mixtures composed of monocarboxy-functionalized dialkylphosphinic acid salts, their use und a process for their preparation 审中-公开
标题翻译：由单羧基官能化的二烷基次膦酸盐组成的混合物，其用途及其制备方法
公开(公告)号：US20070213563A1
公开(公告)日：2007-09-13
申请号：US11714331
申请日：2007-03-06
申请人： Wiebke Maas , Werner Krause , Harald Bauer
发明人： Wiebke Maas , Werner Krause , Harald Bauer
IPC分类号： C07F9/02
CPC分类号： C08K5/5313 , C07F9/301
摘要： The invention relates to mixtures composed of monocarboxy-functionalized dialkylphosphinic salts and of further components, which comprise A) from 98 to 100% by weight of monocarboxy-functionalized dialkylphosphinic salts of the formula (I) in which X and Y are different, where X is Ca, Al, or Zn, and Y is methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, phenyl, 2-hydroxyethyl, 2,3-dihydroxypropyl, 2-hydroxypropyl, 3-hydroxypropyl, 4-hydroxybutyl, 3-hydroxybutyl, 2-hydroxybutyl, and/or 6-hydroxyhexyl, allyl and/or glycerol; or X and Y are different and are Mg, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Cu, Ni, Li, Na, K, H, and/or a protonated nitrogen base; or X and Y are identical or different and each is then Ca, Al, or Zn; R1, R2, R3, R4, R5, R6, and R7 are identical or different and, independently of one another, are H, methyl, ethyl, n-propyl, isopropyl, n-butyl, isobutyl, tert-butyl, and/or phenyl, and B) from 0 to 2% by weight of halogens, where the entirety of the components always amounts to 100% by weight; and to a process for their preparation and to their use.
摘要翻译：本发明涉及由单羧基官能化的二烷基次膦酸盐和其它组分组成的混合物，其包含A）98至100重量％的式（I）的单羧基官能化二烷基次膦酸盐，其中X和Y不同，其中X 是Ca，Al或Zn，Y是甲基，乙基，正丙基，异丙基，正丁基，异丁基，叔丁基，苯基，2-羟乙基，2,3-二羟丙基，2-羟丙基，，4-羟基丁基，3-羟基丁基，2-羟基丁基和/或6-羟基己基，烯丙基和/或甘油; 或X和Y不同，分别为Mg，Sb，Sn，Ge，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Cu，Ni，Li，Na，K，H和/或质子化氮碱; 或X和Y相同或不同，然后分别为Ca，Al或Zn; R 1，R 2，R 3，R 4，R 5， R 6和R 7相同或不同，彼此独立地为H，甲基，乙基，正丙基，异丙基，正丁基，异丁基，叔丁基和/或苯基，和B）0至2重量％的卤素，其中全部组分总计为100重量％以及其准备和使用过程。

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