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1. 发明申请

US20110021676A1 Method for the Production of a Flame-retardant, Non-corrosive, and Easily flowable Polyamide and Polyester Molding Compounds 审中-公开
标题翻译：阻燃，无腐蚀，易流动的聚酰胺和聚酯成型化合物的制备方法
公开(公告)号：US20110021676A1
公开(公告)日：2011-01-27
申请号：US12919792
申请日：2009-02-25
申请人： Sebastian Hoerold , Ottmar Schacker , Harald Bauer , Werner Krause , Daniela Eisenhauer
发明人： Sebastian Hoerold , Ottmar Schacker , Harald Bauer , Werner Krause , Daniela Eisenhauer
IPC分类号： C08K5/3492 , C08K5/5313 , C09K21/12
CPC分类号： C09K21/12 , C08K5/0066 , C08K5/5313 , C08L77/00 , C08L67/02
摘要： The invention relates to a process for producing flame-retardant, non-corrosive, highly flawable polyamides and polyesters, which comprises using a flame retardant mixture made of a phosphinic salt of the formula (I), where M═Al, Mg, Ca, Ti, or Na (component A) in which R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; n is from 1 to 3, and, as component B, a metal salt of an organic acid, and/or an inorganic zinc, calcium, magnesium, potassium, sodium, aluminum, titanium, tin, antimony, bismuth, or barium compound, where the amount of component A present in the flame retardant mixture is from 70 to 99.5% by weight and the amount of component B present in the flame retardant mixture is from 0.5 to 30% by weight.
摘要翻译：本发明涉及一种制造阻燃，非腐蚀性，高度可破坏的聚酰胺和聚酯的方法，其包括使用由式（I）的次膦酸盐制成的阻燃混合物，其中M = Al，Mg，Ca， Ti或Na（组分A），其中R 1和R 2相同或不同，为直链或支链的C 1 -C 6 - 烷基和/或芳基; n为1〜3，作为成分B的有机酸金属盐和/或无机锌，钙，镁，钾，钠，铝，钛，锡，锑，铋或钡化合物，其中存在于阻燃剂混合物中的组分A的量为70至99.5重量％，并且阻燃混合物中存在的组分B的量为0.5至30重量％。

2. 发明授权

US07259200B2 Phosphorus-containing flame retardant agglomerates 有权
标题翻译：含磷阻燃剂
公开(公告)号：US07259200B2
公开(公告)日：2007-08-21
申请号：US10959515
申请日：2004-10-06
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
IPC分类号： C08K5/5313
CPC分类号： C08K5/0066 , C08J3/223 , C08J2367/02 , C08J2377/02 , C08J2377/06 , C08K5/5313
摘要： The invention relates to phosphorus-containing flame retardant agglomerates comprising a) from 99.99 to 80% by weight of aggregates and/or primary particles composed of a phosphinic salt of the formula (I) and/or composed of a diphosphinic salt of the formula (II), and/or composed of polymers of these, where R1,R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4 and b) from 0.01 to 20% by weight of auxiliaries. The invention likewise relates to a process for the production of these phosphorus-containing flame retardant agglomerates, and also to polymeric compositions and moldings which comprise these phosphorus-containing flame retardant agglomerates.
摘要翻译：本发明涉及含磷阻燃附聚物，其包含a）99.99至80重量％的由式（I）的次膦酸盐组成的和/或由式（I）的次膦酸盐和/或由式（I）的二膦酸盐组成的聚集体和/ II）和/或由它们的聚合物组成，其中R 1，R 2，R 2相同或不同，为C 1 -C 3烷基，直链或支链的亚烷基，和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4，和b）0.01至20重量％的助剂。本发明同样涉及一种生产这些含磷阻燃附聚物的方法，以及包含这些含磷阻燃剂附聚物的聚合物组合物和模制品。

3. 发明申请

US20060214144A1 Phosphorus-containing thermally stabilized flame retardant agglomerates 审中-公开
标题翻译：含磷热稳定阻燃剂团聚体
公开(公告)号：US20060214144A1
公开(公告)日：2006-09-28
申请号：US11388916
申请日：2006-03-24
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause
IPC分类号： C09K21/00
CPC分类号： C08K5/5313 , C08K5/3492
摘要： The invention relates to phosphorus-containing thermally stabilized flame retardant agglomerates, comprising as component A from 6 to 99.99% by weight of aggregates and/or primary particles composed of a phosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II), and/or of their polymers, where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Zn, Ti, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; and x is from 1 to 4; as component B from 0 to 90% by weight of a synergist which comprises a nitrogen compound or which comprises a phosphorus compound, or which comprises a phosphorus-nitrogen compound; as component C from 0 to 20% by weight of compounds of the elements of the second main and transition group; and as component D from 0.01 to 20% by weight of auxiliary. The invention also relates to a process for their production, and to their use.
摘要翻译：本发明涉及含磷热稳定的阻燃附聚物，其包含作为组分A的6至99.99重量％的由式（I）的次膦酸盐和/或由式（I）的次膦酸盐组成的聚集体和/或一次颗粒和/ 式（II）和/或它们的聚合物，其中R 1和R 2相同或不同，为直链或支链的C 1 -C 6 - 烷基，和 /或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Zn，Ti，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1〜4; 作为组分B的0至90重量％的增效剂，其包含氮化合物或包含磷化合物，或包含磷 - 氮化合物; 作为组分C的0至20重量％的第二主要和过渡基团的元素的化合物; 并且作为组分D为辅助剂的0.01至20重量％。本发明还涉及其生产方法及其用途。

4. 发明申请

US20060226404A1 Stabilized flame retardant 审中-公开
标题翻译：稳定阻燃剂
公开(公告)号：US20060226404A1
公开(公告)日：2006-10-12
申请号：US11399982
申请日：2006-04-07
申请人： Harald Bauer , Frank Eisentraeger , Sebastian Hoerold , Werner Krause
发明人： Harald Bauer , Frank Eisentraeger , Sebastian Hoerold , Werner Krause
IPC分类号： C09K21/00
CPC分类号： C09K21/12 , C08K5/34928
摘要： The invention relates to a stabilized flame retardant comprising a) from 99 to 1% by weight of melamine polyphosphate b) from 1 to 99% by weight of additive with latent alkalinity.
摘要翻译：本发明涉及稳定的阻燃剂，其包含a）99至1重量％的三聚氰胺多磷酸盐b）1至99重量％的具有潜在碱度的添加剂。

5. 发明申请

US20060020064A1 Flame-retardant polymer molding compositions 审中-公开
标题翻译：阻燃聚合物模塑组合物
公开(公告)号：US20060020064A1
公开(公告)日：2006-01-26
申请号：US11182693
申请日：2005-07-15
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
IPC分类号： C08K5/49
CPC分类号： B82Y30/00 , C08K5/5313 , C08K2201/011 , C08L21/00
摘要： The invention relates to a flame-retardant polymer molding composition which comprises a nanoparticulate phosphorus-containing flame retardant system which comprises at least one phosphinic salt of the formula (I) and/or diphosphinic salt of the formula (II) and/or their polymers, where R1 and R2 are identical or different and are C1-C6-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene, or -arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Fe, Zr, Zn, Ce, Bi, Sr, Mn, Li, Na, K, and/or a protonated nitrogen base; m is from 1 to 4; n is from 1 to 4; x is from 1 to 4.
摘要翻译：本发明涉及一种阻燃聚合物模塑组合物，其包含纳米颗粒含磷阻燃体系，其包含至少一种式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物其中R 1和R 2相同或不同，为C 1 -C 6 - 烷基，线性或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 6 -C 13 - - 亚芳基， - 亚烷基亚芳基或 - 芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Fe，Zr，Zn，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1至4; x为1至4。

6. 发明申请

US20050101707A1 Compacted flame-retardant composition 审中-公开
标题翻译：压实阻燃组合物
公开(公告)号：US20050101707A1
公开(公告)日：2005-05-12
申请号：US10656406
申请日：2003-09-05
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
IPC分类号： C09K21/12 , C08K5/49 , C08K5/5313 , C08L101/00 , C09K21/02 , C09K21/04 , C09K21/10 , C09K21/14 , C09K21/00
CPC分类号： C08K5/5313
摘要： The invention related to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where F1 and R2 are identical or different and are C1-C8-alcyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C8-10-arylene, -alkylarylene or -arylakylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with malamine, melam and/or melem.
摘要翻译：本发明涉及一种阻燃剂组合物，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或其中F 1和/ R 2相同或不同，为C 1 -C 8 - 烷硫基，直链或支链和/或芳基; R 3是C 1 -C 10 - 亚烷基，直链或支链C 8 - 10 亚芳基， - 烷基亚芳基或 - 芳基亚芳基; M是钙离子，镁离子，铝离子和/或锌离子，m是2或3; n为1或3; x为1或2; 并且包含组分B1，B2和/或B3，其中B1是1,3,5-三嗪化合物与多磷酸的盐，其中B2是三聚氰胺聚偏磷酸盐，并且其中B3是多磷酸与malamine的复合盐，蜜胺和/或马力。

7. 发明申请

US20050032958A1 Pulverulent flame-retardant composition with low dust level, its use, and process for its preparation, and flame-retardant polymeric molding compositions 审中-公开
标题翻译：低粉尘等级的粉煤灰阻燃组合物，其用途及其制备方法，以及阻燃聚合物成型组合物
公开(公告)号：US20050032958A1
公开(公告)日：2005-02-10
申请号：US10656313
申请日：2003-09-05
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
IPC分类号： C08L101/00 , C08K5/5313 , C08K9/04 , C08L1/00
CPC分类号： C08K5/5313
摘要： The invention relates to a flame retardant combination comprising, as component A, a phosphinate of the formula (I) and/or a diphosphinate of the formula (II) and/or polymers of these where R1 and R2 are identical or different and are C1-C5-alkyl, linear or branched, and/or aryl; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, -alkylarylene or -arylalkylene; M is calcium ions, magnesium ions, aluminum ions and/or zinc ions, m is 2 or 3; n is 1 or 3; x is 1 or 2; and comprising a component B1, B2 and/or B3 wherein B1 is a salt of 1,3,5-triazine compound with polyphosphoric acid, and wherein B2 is a melamine polymetaphosphate, and wherein B3 is a composite salt of polyphosphoric acid with melamine, melam and/or melem.
摘要翻译：本发明涉及一种阻燃剂组合物，其包含作为组分A的式（I）的次膦酸盐和/或式（II）的二膦酸盐和/或其中R 1和R 2的聚合物为是C 1 -C 5烷基，直链或支链和/或芳基; R 3是C 1 -C 10亚烷基，直链或支链的C 6 -C 10亚芳基， - 烷基亚芳基或 - 芳基亚烷基; M是钙离子，镁离子，铝离子和/或锌离子，m是2或3; n为1或3; x为1或2; 并且包含B1，B2和/或B3组分，其中B1是1,3,5-三嗪化合物与多磷酸的盐，其中B2是三聚氰胺聚偏磷酸盐，并且其中B3是多磷酸与三聚氰胺的复合盐，黑夜和/或混战。

8. 发明申请

US20130190432A1 Flame Retardant-Stabilizer Combination For Thermoplastic Polymers 审中-公开
标题翻译：阻燃稳定剂组合热塑性聚合物
公开(公告)号：US20130190432A1
公开(公告)日：2013-07-25
申请号：US13878145
申请日：2011-09-30
申请人： Werner Krause , Harald Bauer , Martin Sicken , Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
发明人： Werner Krause , Harald Bauer , Martin Sicken , Sebastian Hoerold , Wolfgang Wanzke , Elke Schlosser
IPC分类号： C08K5/5313 , C08K5/3492 , C08K5/10 , C08K3/22 , C08K5/5317 , C08K5/56 , C08K5/52 , C08K3/38
CPC分类号： C08K5/5313 , C08K3/22 , C08K3/38 , C08K5/0008 , C08K5/10 , C08K5/34922 , C08K5/34924 , C08K5/52 , C08K5/5317 , C08K5/56
摘要： A novel flame retardant-stabilizer combination for thermoplastic polymers, comprising as component A 20 to 99% by weight of a dialkylphosphinic salt of the formula (I) and/or of a diphosphinic salt of the formula (II) and/or polymers thereof in which R1, R2 are the same or different and are each C1-C6-alkyl, linear or branched; R3 is C1-C10-alkylene, linear or branched, C6-C10-arylene, C7-C20-alkylarylene or C7-C20-arylalkylene; M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na, K and/or a protonated nitrogen base; m is 1 to 4; n is 1 to 4; x is 1 to 4, as component B 1 to 80% by weight of a salt of the phosphorous acid with the general formula (III) [HP(═O)O2]2−Mm+ (III) in which M is Mg, Ca, Al, Sb, Sn, Ge, Ti, Zn, Fe, Zr, Ce, Bi, Sr, Mn, Li, Na and/or K and m is 1 to 4, as component C 0 to 30% by weight of a nitrogen-containing synergist and/or of a phosphorus/nitrogen flame retardant, as component D 0 to 10% by weight of a zinc salt and/or of a basic or amphoteric oxide, hydroxide, carbonate, silicate, borate, stannate, mixed oxide hydroxide, oxide hydroxide carbonate, hydroxide silicate and/or hydroxide borate and/or mixtures of these substances, as component E 0 to 3% by weight of a phosphonite and/or of a mixture of a phosphonite and a phosphite, and as component F 0 to 3% by weight of an ester and/or salt of long-chain aliphatic carboxylic acids (fatty acids) which typically have chain lengths of C14 to C40, where the sum of the components is always 100% by weight.
摘要翻译：一种热塑性聚合物的新型阻燃稳定剂组合物，其包含作为组分A 20至99重量％的式（I）的二烷基次膦酸盐和/或式（II）的二膦酸盐和/或其聚合物其中R 1，R 2相同或不同，并且各自为直链或支链的C 1 -C 6烷基; R3是C1-C10-亚烷基，直链或支链的C6-C10亚芳基，C7-C20-烷基亚芳基或C7-C20-芳基亚烷基; M是Mg，Ca，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na，K和/或质子化氮碱; m为1〜4; n为1〜4; x为1〜4，作为成分B，通式（III）的亚磷酸盐为1〜80重量％[HP（= O）O 2] 2 -Mm +（III），其中M为Mg，Ca ，Al，Sb，Sn，Ge，Ti，Zn，Fe，Zr，Ce，Bi，Sr，Mn，Li，Na和/或K和m为1〜4，作为组分C 0〜30重量％含氮增效剂和/或磷/氮阻燃剂，作为组分D 0至10重量％的锌盐和/或碱性或两性氧化物，氢氧化物，碳酸盐，硅酸盐，硼酸盐，锡酸盐，混合氧化物氢氧化物，氢氧化物碳酸盐，氢氧化硅酸盐和/或氢氧化物硼酸盐和/或这些物质的混合物，作为组分E 0至3重量％的亚膦酸盐和/或亚磷酸盐和亚磷酸盐的混合物，并且作为组分F 0至3重量％的通常具有C14至C40链长度的长链脂族羧酸（脂肪酸）的酯和/或盐，其中组分的总量总是为100重量％。

9. 发明申请

US20060217469A1 Use of stabilizers in phosphorus-containing thermally stabilized flame retardant agglomerates 审中-公开
标题翻译：在含磷热稳定的阻燃聚集体中使用稳定剂
公开(公告)号：US20060217469A1
公开(公告)日：2006-09-28
申请号：US11388329
申请日：2006-03-24
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause
IPC分类号： C08K5/49
CPC分类号： C08K5/5313 , C08K3/22 , C08K5/0066
摘要： The invention relates to the use of stabilizers in phosphorus-containing thermally stabilized flame retardant agglomerates.
摘要翻译：本发明涉及在含磷热稳定化阻燃剂附聚物中使用稳定剂。

10. 发明申请

US20060208239A1 Compacted flame-retardant composition 审中-公开
标题翻译：压实阻燃组合物
公开(公告)号：US20060208239A1
公开(公告)日：2006-09-21
申请号：US11438594
申请日：2006-05-22
申请人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
发明人： Harald Bauer , Sebastian Hoerold , Werner Krause , Martin Sicken
IPC分类号： C09K21/00
CPC分类号： C08K5/5313
摘要： The invention relates to a compacted flame-retardant composition comprising an organophosphorus flame-retardant component, prepared by compacting an organophosphorus flame-retardant component with or without a compacting auxiliary, and to a process for preparing these flame-retardant compositions, and to polymer molding compositions which comprise these flame-retardant compositions.
摘要翻译：本发明涉及一种压实的阻燃组合物，其包含通过压实有或无压实助剂的有机磷阻燃组分制备的有机磷阻燃组分，以及制备这些阻燃组合物的方法和聚合物成型包含这些阻燃组合物的组合物。

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