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61. 发明授权

US5201935A Cyclohexenone derivatives 失效
标题翻译：环己烯酮衍生物
公开(公告)号：US5201935A
公开(公告)日：1993-04-13
申请号：US934304
申请日：1992-08-26
申请人： Dieter Kolassa , Juergen Kasi , Thomas Kuekenhoehner , Norbert Meyer , Karl-Otto Westphalen , Bruno Wuerzer
发明人： Dieter Kolassa , Juergen Kasi , Thomas Kuekenhoehner , Norbert Meyer , Karl-Otto Westphalen , Bruno Wuerzer
IPC分类号： A01N43/10 , A01N43/14 , A01N43/50 , A01N43/74 , A01N43/80 , A01N43/82 , C07D261/04 , C07D261/08 , C07D271/06 , C07D271/10 , C07D333/22 , C07D413/04
CPC分类号： C07D271/06 , A01N43/10 , A01N43/14 , A01N43/50 , A01N43/74 , A01N43/80 , A01N43/82 , C07D261/04 , C07D261/08 , C07D271/10 , C07D333/22 , C07D413/04
摘要： Cyclohexenone derivatives of the general formula I ##STR1## where the substituents have the following meanings: R.sup.1 substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl or C.sub.3 -C.sub.6 -alkynyl, phenyl, benzyl or thenyl;R.sup.2 substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkynyl or phenyl;R.sup.3 hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.10 -alkylcarbonyl, C.sub.1 -C.sub.6 -alkylsulfonyl, C.sub.1 -C.sub.4 -trialkylsilyl, C.sub.1 -C.sub.4 -dialkylphosphonyl, C.sub.1 -C.sub.4 -dialkylthiophosphonyl, C.sub.3 -C.sub.6 -alkenyl, C.sub.3 -C.sub.6 -alkenylcarbonyl, C.sub.3 -C.sub.6 -alkynyl orsubstituted or unsubstituted benzoyl- or phenylsulfonyl;R.sup.4 hydrogen, cyano, halogen, C.sub.1 -C.sub.6 -alkyl or C.sub.1 -C.sub.6 -alkoxycarbonyl;A a substituted or unsubstituted C.sub.1 -C.sub.4 -alkylene chain in which a methylene group may be replaced by an oxygen or sulfur atom;m 0 or 1;B a 5-membered mono- or diunsaturated heterocycle containing up to 2 nitrogen atoms and/or up to one oxygen or sulfur atom;substituted or unsubstituted C.sub.1 -C.sub.6 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkynyl;C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.3 -C.sub.6 -alkenyloxy or C.sub.3 -C.sub.6 -alkynyloxy;n 1, 2 or 3;Y not denoting hydrogen when m is 0, B is isoxazol-5-yl and X is 3-(C.sub.3 -C.sub.6 -cycloalkyl),and environmentally acceptable salts thereof, processes for their manufacture, and their use as herbicidal agents.
摘要翻译：通式I的环己烯酮衍生物，其中取代基具有以下含义：R 1取代或未取代的C 1 -C 6 - 烷基，C 3 -C 6 - 烯基或C 3 -C 6 - 炔基，苯基，苄基或异丁基; R2取代或未取代的C1-C6-烷基，C3-C6-烯基，C3-C6-炔基或苯基; R3，C1-C6-烷基，C1-C10-烷基羰基，C1-C6-烷基磺酰基，C1-C4-三烷基甲硅烷基，C1-C4-二烷基膦酰基，C1-C4-二烷基硫代膦酰基，C3-C6-烯基，C3-C6-烯基羰基，C 3 -C 6炔基或取代或未取代的苯甲酰基或苯基磺酰基; R 4氢，氰基，卤素，C 1 -C 6 - 烷基或C 1 -C 6 - 烷氧基羰基; 取代或未取代的C1-C4亚烷基链，其中亚甲基可被氧或硫原子代替; m 0或1; B是含有至多2个氮原子和/或至多一个氧原子或硫原子的5元单或二不饱和杂环; 取代或未取代的C 1 -C 6 - 烷基，C 2 -C 6 - 烯基或C 2 -C 6 - 炔基; C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 3 -C 6 - 烯氧基或C 3 -C 6 - 炔氧基; n 1，2或3; 当m为0时，Y不表示氢，B为异唑-5-基，X为3-（C 3 -C 6 - 环烷基）及其环境可接受的盐，其制备方法及其作为除草剂的用途。

62. 发明授权

US5120880A Preparation of muscone, intermediates for this preparation and preparation of said intermediates 失效
标题翻译：麦芽糖的制备，本制剂的中间体和制备中间体
公开(公告)号：US5120880A
公开(公告)日：1992-06-09
申请号：US757305
申请日：1991-09-10
申请人： Michael Huellmann , Thomas Kuekenhoehner , Karl Brenner , Rainer Becker , Matthias Irgang , Charles Schommer
发明人： Michael Huellmann , Thomas Kuekenhoehner , Karl Brenner , Rainer Becker , Matthias Irgang , Charles Schommer
IPC分类号： B01J21/06 , B01J23/04 , B01J23/10 , B01J23/12 , C07B61/00 , C07C45/30 , C07C45/61 , C07C45/62 , C07C45/66 , C07C45/68 , C07C45/72 , C07C49/203 , C07C49/385
CPC分类号： C07C45/68 , C07C45/30 , C07C45/62 , C07C45/66 , C07C45/72
摘要： Muscone of the formula I ##STR1## is prepared by a process in which an open-chain 2,15-diketone of the general formula IICH.sub.3 --CO--X--CO--CH.sub.3 (II)whereX is one of the radicals--(--CH.sub.2 --).sub.12 -- (a)--CH.dbd.CH--(--CH.sub.2 --).sub.8 --CH.dbd.CH-- (b)--CH.sub.2 --CH.dbd.CH--(--CH.sub.2 --).sub.6 --CH.dbd.CH--CH.sub.2 --(c)--CH.sub.2 --CH.sub.2 --CH.dbd.CH--(--CH.sub.2 --).sub.4 --CH.dbd.CH--CH.sub.2 --CH.sub.2 -- (d)or--CH.sub.2 --CH.sub.2 --CH.sub.2 --CH.dbd.CH--(--CH.sub.2 --).sub.2 --CH.dbd.CH--CH.sub.2 --CH.sub.2 --CH.sub.2 -- (e)is brought into contact, at from 300.degree. to 400.degree. C. in the presence of from 5 to 15% by weight, based on the amount of catalyst, of water, in the gas phase, with a fixed-bed catalyst containing TiO.sub.2, CeO.sub.2 or ThO.sub.2 as the catalytically active compound and the unsaturated cyclic ketone formed by intramolecular aldol condensation is subjected to catalytic hydrogenation. Furthermore, the open-chain unsaturated ketones of the formulae IIb, IIc and IId and advantageous processes for their preparation and their use as intermediates for a simple industrial synthesis of muscone are claimed.

63. 发明授权

US5081311A Preparation of muscone, intermediates for this preparation and preparation of said intermediates 失效
标题翻译：麦芽糖的制备，本制剂的中间体和制备中间体
公开(公告)号：US5081311A
公开(公告)日：1992-01-14
申请号：US524929
申请日：1990-05-18
申请人： Michael Huellmann , Thomas Kuekenhoehner , Karl Brenner , Rainer Becker , Matthias Irgang , Charles Schommer
发明人： Michael Huellmann , Thomas Kuekenhoehner , Karl Brenner , Rainer Becker , Matthias Irgang , Charles Schommer
IPC分类号： B01J21/06 , B01J23/04 , B01J23/10 , B01J23/12 , C07B61/00 , C07C45/30 , C07C45/61 , C07C45/62 , C07C45/66 , C07C45/68 , C07C45/72 , C07C49/203 , C07C49/385
CPC分类号： C07C45/68 , C07C45/30 , C07C45/62 , C07C45/66 , C07C45/72
摘要： Muscone of the formula I ##STR1## is prepared by a process in which an open-chain 2,15-diketone of the general formula IICH.sub.3 --CO--X--CO--CH.sub.3 (II)where X is one of the radicals--(--CH.sub.2 --).sub.12 -- (a)--CH.dbd.CH--(--CH.sub.2 --).sub.8 --CH.dbd.CH-- (b)--CH.sub.2 --CH.dbd.CH--(--CH.sub.2 --).sub.6 --CH.dbd.CH--CH.sub.2 --(c)--CH.sub.2 --CH.sub.2 --CH.dbd.CH--(--CH.sub.2 --).sub.4 --CH.dbd.CH--CH.sub.2 --CH.sub.2 -- (d) or--CH.sub.2 --CH.sub.2 CH.sub.2 --CH.dbd.CH--(--CH.sub.2 --).sub.2 --CH.dbd.CH--CH.sub.2 --CH.sub.2 --CH.sub.2 -- (e)is brought into contact, at from 300.degree. to 400.degree. C. in the presence of from 5 to 15% by weight, based on the amount of catalyst, of water, in the gas phase, with a fixed-bed catalyst containing TiO.sub.2, CeO.sub.2 or the ThO.sub.2 as the catalytically active compound and the unsaturated cyclic ketone formed by intramolecular aldol condensation is subjected to catalytic hydrogenation. Furthermore, the open-chain unsaturated ketones of the formulae IIb, IIc and IId and advantageous processes for their preparation and their use as intermediates for a simple industrial synthesis of muscone are claimed.
摘要翻译：通式Ⅰ（I）的肌醇通过以下方法制备，其中通式II CH3-CO-X-CO-CH3（Ⅱ）的开链2,15-二酮其中X是基团 - （ - CH2-）12-（a）-CH = CH - （ - CH2-）8-CH = CH-（b）-CH2-CH = CH-（ - CH2-）6-CH = CH-CH2 - （c）-CH 2 -CH 2 -CH = CH - （ - CH 2 - ）4 -CH = CH-CH 2 -CH 2 - （d）或-CH 2 -CH 2 CH 2 -CH = CH - （ - CH 2 - ）2 -CH = CH-CH 2 -CH 2 -CH 2 - （e）在300-400℃下，以5-15重量％的量存在下，基于催化剂的量，在气体中使用含有TiO 2，CeO 2或ThO 2作为催化活性化合物的固定床催化剂和通过分子内醛醇缩合形成的不饱和环酮进行催化氢化。此外，要求具有式IIb，IIc和IId的开链不饱和酮及其制备的有利方法及其作为简单的工业合成肌肉的中间体的用途。

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