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61. 发明授权

US08202467B2 Propylene-based polymer article 有权
标题翻译：丙烯基聚合物制品
公开(公告)号：US08202467B2
公开(公告)日：2012-06-19
申请号：US11880843
申请日：2007-07-24
申请人： Abdelhadi Sahnoune , Sunny Jacob
发明人： Abdelhadi Sahnoune , Sunny Jacob
IPC分类号： H01J37/30 , B29C35/08 , D01D5/24
CPC分类号： B29C47/00 , B29C47/0004 , B29C47/0023 , B29C47/0026 , B29C2035/0877 , B29C2791/001 , B29K2023/12 , B29K2301/10 , B29L2023/22 , B29L2031/753 , Y10T428/1386
摘要： A method for extruding transparent and/or translucent article is provided. In one embodiment, the method comprises providing a propylene-based polymer comprising propylene derived units and one or more dienes, the propylene-based polymer having a triad tacticity of from 50% to 99% and a heat of fusion of less than 80 J/g, extruding the propylene-based polymer in the absence of processing oil into an article; and then crosslinking the extruded article.
摘要翻译：提供了用于挤出透明和/或半透明制品的方法。在一个实施方案中，该方法包括提供包含丙烯衍生的单元和一种或多种二烯的基于丙烯的聚合物，丙烯类聚合物的三单元组立构规整度为50-99％，熔融热小于80J / g，在没有加工油的情况下将丙烯类聚合物挤出到制品中; 然后交联挤压制品。

62. 发明授权

US07994253B2 Translucent propylene-based elastomeric compositions 有权
标题翻译：半透明丙烯基弹性体组合物
公开(公告)号：US07994253B2
公开(公告)日：2011-08-09
申请号：US12103346
申请日：2008-04-15
申请人： Sunny Jacob , Gary K. Lawrence , Edward John Blok , Ralph E. Raulie
发明人： Sunny Jacob , Gary K. Lawrence , Edward John Blok , Ralph E. Raulie
IPC分类号： C08K5/00 , B32B27/32
CPC分类号： C08L23/10 , B29C47/0004 , B29C47/0021 , B29C47/0023 , B29C49/0005 , B29C51/002 , B29K2023/12 , C08L23/16 , C08L2666/06
摘要： A composition is described in one aspect as comprising one or more propylene-α-olefin terpolymers; wherein the propylene-α-olefin terpolymer(s) possess a melting temperature (Tm) within the range of from less than 105° C., and a heat of fusion (Hf) within the range of from less than 75 J/g; one or more polyolefin(s); and oil; wherein fillers are present, if at all, at a level that maintains a Haze value of 65% or less for the composition. The terpolymer in one embodiment is a polymer comprising at least 65 wt %, by weight of the terpolymer, of propylene-derived units, within the range of from 5 to 35 wt % of ethylene or other α-olefin and a diene such as ethylidiene norbornene, and in certain embodiments having a Mooney Viscosity (ML(1+4)@125° C.) within the range of from 10 to 50 (ASTM D1646). The compositions can be cured to form transparent or translucent articles such as sheets that are also flexible.
摘要翻译：组合物在一个方面描述为包含一种或多种丙烯-α-烯烃三元共聚物; 其中所述丙烯-α-烯烃三元共聚物的熔融温度（Tm）在小于105℃的范围内，熔融热（Hf）在小于75J / g的范围内; 一种或多种聚烯烃; 和油; 其中如果有的话，填料的含量维持组合物的雾度值为65％或更低。在一个实施方案中，三元共聚物是包含至少65重量％的三元共聚物的丙烯衍生的单元，在乙烯或其它α-烯烃的5-35重量％范围内和二烯如亚乙基降冰片烯，在某些具有门尼粘度（ML（1 + 4）@ 125℃）的实施方案中，在10至50的范围内（ASTM D1646）。组合物可以固化以形成也是柔性的透明或半透明制品，例如片材。

63. 发明授权

US07867433B2 Polyolefin-based crosslinked articles 有权
标题翻译：聚烯烃基交联物品
公开(公告)号：US07867433B2
公开(公告)日：2011-01-11
申请号：US12130745
申请日：2008-05-30
申请人： Sunny Jacob , Alistair D. Westwood , Tonson Abraham
发明人： Sunny Jacob , Alistair D. Westwood , Tonson Abraham
IPC分类号： C08L23/10 , B29C47/00
CPC分类号： C08L23/10 , C08K5/005 , C08K5/14 , C08K5/34924 , C08L23/16 , C08L75/00 , C08L2312/00 , C08L2666/02
摘要： Methods for making a crosslinked elastomeric composition and articles made of the same are provided. In at least one specific embodiment, an elastomeric composition comprising at least one propylene-based polymer is blended with at least one component selected from the group consisting of multifunctional acrylates, multifunctional methacrylates, functionalized polybutadiene resins, functionalized cyanurate, and allyl isocyanurate; and blended with at least one component selected from the group consisting of hindered phenols, phosphites, and hindered amines. The propylene-based polymer can include propylene derived units and one or more dienes, and have a triad tacticity of from 50% to 99% and a heat of fusion of less than 80 J/g. The blended composition can then be extruded and crosslinked. The extruded polymer can be crosslinked using electron beam radiation having an e-beam dose of about 100 KGy or less. The crosslinked polymers are particularly useful for making fibers and films.
摘要翻译：提供制备交联弹性体组合物的方法和由其制成的制品。在至少一个具体实施方案中，包含至少一种基于丙烯的聚合物的弹性体组合物与至少一种选自多官能丙烯酸酯，多官能甲基丙烯酸酯，官能化聚丁二烯树脂，官能化氰尿酸酯和异氰脲酸烯丙酯的组分共混; 并与至少一种选自受阻酚，亚磷酸酯和受阻胺的组分共混。基于丙烯的聚合物可以包括丙烯衍生的单元和一种或多种二烯，并且具有50％至99％的三单元组立构规整度和小于80J / g的熔融热。然后可以将共混组合物挤出和交联。挤出的聚合物可以使用约100KGy或更小的电子束剂量的电子束辐射进行交联。交联聚合物特别适用于制造纤维和薄膜。

64. 发明授权

US07803875B2 Curing of rubbers and thermoplastic vulcanizates in the absence of halogen donors 失效
标题翻译：在没有卤素供体的情况下固化橡胶和热塑性硫化橡胶
公开(公告)号：US07803875B2
公开(公告)日：2010-09-28
申请号：US11823250
申请日：2007-06-27
申请人： Sunny Jacob , Rodney May
发明人： Sunny Jacob , Rodney May
IPC分类号： C08L61/10 , C08L9/00
CPC分类号： C08L23/16 , C08K3/011 , C08K3/22 , C08K5/0025 , C08K5/098 , C08L21/00 , C08L23/12 , C08L61/04 , C08L2666/06 , C08L2666/16
摘要： Aspects of the invention include a method of curing a rubber composition comprising providing a rubber; intimately contacting a curative agent with the rubber; wherein the curative agent consists essentially of a phenol formaldehyde resin, a metal oxide and a carboxylic acid metal salt. Another aspect of the present invention is to a method of curing a rubber composition comprising providing a rubber; intimately contacting a curative agent with the rubber; wherein the curative agent comprises a phenol formaldehyde resin and carboxylic acid metal salt; and wherein halogen-donating species are absent from the rubber and curative agent.
摘要翻译：本发明的方面包括固化橡胶组合物的方法，包括提供橡胶; 使治疗剂与橡胶紧密接触; 其中所述固化剂基本上由酚甲醛树脂，金属氧化物和羧酸金属盐组成。本发明的另一方面是一种固化橡胶组合物的方法，包括提供橡胶; 使治疗剂与橡胶紧密接触; 其中所述固化剂包含苯酚甲醛树脂和羧酸金属盐; 并且其中卤素供体物质不存在于橡胶和固化剂中。

65. 发明申请

US20090298964A1 Polyolefin-Based Crosslinked Articles 有权
标题翻译：聚烯烃交联制品
公开(公告)号：US20090298964A1
公开(公告)日：2009-12-03
申请号：US12130745
申请日：2008-05-30
申请人： Sunny Jacob , Alistair D. Westwood , Tonson Abraham
发明人： Sunny Jacob , Alistair D. Westwood , Tonson Abraham
IPC分类号： B29C71/04
CPC分类号： C08L23/10 , C08K5/005 , C08K5/14 , C08K5/34924 , C08L23/16 , C08L75/00 , C08L2312/00 , C08L2666/02
摘要： Methods for making a crosslinked elastomeric composition and articles made of the same are provided. In at least one specific embodiment, an elastomeric composition comprising at least one propylene-based polymer is blended with at least one component selected from the group consisting of multifunctional acrylates, multifunctional methacrylates, functionalized polybutadiene resins, functionalized cyanurate, and allyl isocyanurate; and blended with at least one component selected from the group consisting of hindered phenols, phosphites, and hindered amines. The propylene-based polymer can include propylene derived units and one or more dienes, and have a triad tacticity of from 50% to 99% and a heat of fusion of less than 80 J/g. The blended composition can then be extruded and crosslinked. The extruded polymer can be crosslinked using electron beam radiation having an e-beam dose of about 100 KGy or less. The crosslinked polymers are particularly useful for making fibers and films.
摘要翻译：提供制备交联弹性体组合物的方法和由其制成的制品。在至少一个具体实施方案中，包含至少一种基于丙烯的聚合物的弹性体组合物与至少一种选自多官能丙烯酸酯，多官能甲基丙烯酸酯，官能化聚丁二烯树脂，官能化氰尿酸酯和异氰脲酸烯丙酯的组分共混; 并与至少一种选自受阻酚，亚磷酸酯和受阻胺的组分共混。基于丙烯的聚合物可以包括丙烯衍生的单元和一种或多种二烯，并且具有50％至99％的三单元组立构规整度和小于80J / g的熔化热。然后可以将共混组合物挤出和交联。挤出的聚合物可以使用约100KGy或更小的电子束剂量的电子束辐射进行交联。交联聚合物特别适用于制造纤维和薄膜。

66. 发明申请

US20090258209A1 Translucent Propylene-Based Elastomeric Compositions 有权
标题翻译：半透明丙烯弹性组合物
公开(公告)号：US20090258209A1
公开(公告)日：2009-10-15
申请号：US12103346
申请日：2008-04-15
申请人： Sunny Jacob , Gary K. Lawrence , Edward John Blok , Ralph E. Raulie
发明人： Sunny Jacob , Gary K. Lawrence , Edward John Blok , Ralph E. Raulie
IPC分类号： B32B27/32 , C08L23/10 , C08L23/06 , B29C45/00 , B29C47/00 , B29C49/00
CPC分类号： C08L23/10 , B29C47/0004 , B29C47/0021 , B29C47/0023 , B29C49/0005 , B29C51/002 , B29K2023/12 , C08L23/16 , C08L2666/06
摘要： A composition is described in one aspect as comprising one or more propylene-α-olefin terpolymers; wherein the propylene-α-olefin terpolymer(s) possess a melting temperature (Tm) within the range of from less than 105° C., and a heat of fusion (Hf) within the range of from less than 75 J/g; one or more polyolefin(s); and oil; wherein fillers are present, if at all, at a level that maintains a Haze value of 65% or less for the composition. The terpolymer in one embodiment is a polymer comprising at least 65 wt %, by weight of the terpolymer, of propylene-derived units, within the range of from 5 to 35 wt % of ethylene or other α-olefin and a diene such as ethylidiene norbornene, and in certain embodiments having a Mooney Viscosity (ML(1+4)@125° C.) within the range of from 10 to 50 (ASTM D1646). The compositions can be cured to form transparent or translucent articles such as sheets that are also flexible.
摘要翻译：组合物在一个方面描述为包含一种或多种丙烯-α-烯烃三元共聚物; 其中所述丙烯-α-烯烃三元共聚物的熔融温度（Tm）在小于105℃的范围内，熔融热（Hf）在小于75J / g的范围内; 一种或多种聚烯烃; 和油; 其中如果有的话，填料的含量维持组合物的雾度值为65％或更低。在一个实施方案中，三元共聚物是包含至少65重量％的三元共聚物，丙烯衍生的单元，在乙烯或其它α-烯烃的5-35重量％范围内和二烯如亚乙基降冰片烯，在某些具有门尼粘度（ML（1 + 4）@ 125℃）的实施方案中，在10至50的范围内（ASTM D1646）。组合物可以固化以形成也是柔性的透明或半透明制品，例如片材。

67. 发明授权

US07445846B2 Thermoplastic vulcanizates and laminates made therewith 失效
标题翻译：热塑性硫化胶和由其制成的层压板
公开(公告)号：US07445846B2
公开(公告)日：2008-11-04
申请号：US11097434
申请日：2005-04-01
申请人： Sunny Jacob , William Gary Stevenson
发明人： Sunny Jacob , William Gary Stevenson
IPC分类号： B32B25/08 , B32B25/14 , B32B25/16
CPC分类号： C08L23/10 , B32B25/04 , B32B25/08 , B32B25/16 , B32B25/18 , B32B27/08 , B32B27/18 , B32B27/32 , B32B2250/02 , B32B2250/24 , B32B2270/00 , B32B2274/00 , B32B2307/546 , B32B2307/554 , B32B2307/558 , B32B2307/56 , B32B2307/746 , B32B2419/00 , B32B2479/00 , B32B2605/08 , C08L23/16 , C08L23/22 , Y10T428/3154 , Y10T428/31544 , Y10T428/31913 , Y10T428/31917 , Y10T428/31924 , Y10T428/31931 , Y10T428/31938 , C08L2666/06
摘要： A thermoplastic vulcanizate comprising a) a dynamically vulcanized rubber, b) a thermoplastic resin, and c) optionally a synthetic oil, where the thermoplastic vulcanizate is substantially devoid of mineral oils.
摘要翻译：一种热塑性硫化橡胶，其包含a）动态硫化橡胶，b）热塑性树脂，和c）任选的合成油，其中热塑性硫化橡胶基本上不含矿物油。

68. 发明申请

US20070083007A1 Microcellular foams of thermoplastic vulcanizates 有权
标题翻译：热塑性硫化胶的微孔泡沫
公开(公告)号：US20070083007A1
公开(公告)日：2007-04-12
申请号：US11246772
申请日：2005-10-07
申请人： Sunny Jacob
发明人： Sunny Jacob
IPC分类号： C08L53/00 , B29C44/34
CPC分类号： C08L23/16 , C08J9/0061 , C08J2323/10 , C08J2421/00 , C08J2451/00 , C08L23/10 , C08L23/12 , C08L23/14 , C08L23/142 , C08L23/283 , C08L51/06 , C08L51/08 , C08L53/02 , C08L53/025 , C08L91/00 , C08L2205/02 , C08L2205/035 , C08L2205/22 , C08L2207/07 , C08L2312/00 , C08L2666/02 , C08L2666/24 , C08L2666/08 , C08L2666/06 , C08L2666/14
摘要： The invention described relates to formed profiles comprising microcellular TPE foam compositions, and articles therefrom, wherein the TPE are thermoplastic vulcanizates. The foamed thermoplastic elastomer profile comprises a foamable thermoplastic elastomer composition having a) a cross-linkable hydrocarbon rubber in the presence of b) a thermoplastic polyolefin resin having a Tm greater than 120° C. wherein said composition further comprising: a) 25 to 30 wt % of a partially or fully vulcanized reaction product of said cross-linkable hydrocarbon rubber with a cross-linking agent, said reaction product being present as a dispersed phase; b) 7 to 12 wt % of said thermoplastic resin as a continuous phase; c) 8-22 wt % of an elastomeric thermoplastic modifier comprising 1) 3-7 wt. % copolymers of propylene with one or more of ethylene and C4-C10 alpha-olefins, said copolymers having a Tm greater than 20° C. and less than 120° C., and, 2) 5-15 wt. % hydrogenated, triblock styrenic copolymers from styrene and isoprene; and, optionally, d) 3-12 wt. % solid filler; and/or e) 35-45 wt. % of non-aromatic hydrocarbon oil; wherein said wt. % amounts are based upon the total weight of the composition, and where the composition has been prepared by a process comprising dynamically vulcanizing said composition. The foamed thermoplastic elastomer profiles having smooth surfaces, improved low water absorption, improved compression set and compression load deflection.
摘要翻译：所描述的本发明涉及包含微孔TPE泡沫组合物的成型型材及其制品，其中TPE是热塑性硫化橡胶。发泡热塑性弹性体轮廓包括可发泡的热塑性弹性体组合物，其具有a）可交联烃橡胶，其存在b）具有Tm大于120℃的热塑性聚烯烃树脂。其中所述组合物还包含：a）25至30 所述可交联烃橡胶与交联剂的部分或完全硫化的反应产物的wt％，所述反应产物以分散相存在; b）作为连续相的7〜12重量％的所述热塑性树脂; c）8-22重量％的弹性体热塑性改性剂，其包含1）3-7重量％丙烯与乙烯和C 4 -C 10α-烯烃中的一种或多种的共聚物，所述共聚物的Tm大于20℃且小于120℃ C.，和2）5-15wt。％苯乙烯和异戊二烯的氢化三嵌段苯乙烯共聚物; 和任选地，d）3-12重量％％固体填料; 和/或e）35-45wt。％的非芳香烃油; 其中所述wt。％的量基于组合物的总重量，并且其中组合物通过包括动态硫化所述组合物的方法制备。发泡热塑性弹性体轮廓具有光滑的表面，改善的低吸水率，改进的压缩永久变形和压缩载荷偏转。

69. 发明申请

US20070000926A1 Thermoplastic vulcanizates and sealing devices made therewith 有权
标题翻译：热塑性硫化胶和密封装置
公开(公告)号：US20070000926A1
公开(公告)日：2007-01-04
申请号：US11173033
申请日：2005-07-01
申请人： Sunny Jacob , Marvin Hill , Purushottam Agrawal
发明人： Sunny Jacob , Marvin Hill , Purushottam Agrawal
IPC分类号： B65D53/00 , C08L75/00 , B65D55/00
CPC分类号： C08L75/04 , C08G2190/00 , C08L23/22 , C08L51/06 , C08L75/06 , C08L75/08 , C08L2666/02 , C08L2666/20 , C08L2666/04 , C08L2666/06
摘要： An article for sealing the contents of a container, the article comprising a member adapted for sealing the container, where the member includes a thermoplastic vulcanizate including a dynamically cured butyl rubber, a thermoplastic polyurethane having a glass transition temperature of less than about 60° C., and a synthetic oil.
摘要翻译：一种用于密封容器内容物的制品，该制品包括适于密封容器的构件，其中该构件包括热塑性硫化橡胶，其包含动态固化的丁基橡胶，玻璃化转变温度低于约60℃的热塑性聚氨酯和合成油。

70. 发明授权

US06787607B2 Thermoplastic elastomers having enhanced foaming and physical properties 失效
标题翻译：具有增强发泡和物理性能的热塑性弹性体
公开(公告)号：US06787607B2
公开(公告)日：2004-09-07
申请号：US10203323
申请日：2002-10-28
申请人： Abdelhadi Sahnoune , Terry M. Finerman , Sunny Jacob , Sydney Ham
发明人： Abdelhadi Sahnoune , Terry M. Finerman , Sunny Jacob , Sydney Ham
IPC分类号： C08F800
CPC分类号： C08J9/0061 , C08J2323/16 , C08J2427/00 , C08L23/02 , C08L23/04 , C08L23/10 , C08L23/16 , C08L27/18 , C08L33/06 , C08L2203/14 , C08L2205/22 , C08L2666/04 , C08L2666/06
摘要： An olefinic thermoplastic elastomer composition which includes an acrylic-modified polytetrafluoroethylene. When foamed, such compositions produce a very soft foam with improved processing properties and physical characteristics. A process of foaming and foamed articles are also disclosed.
摘要翻译：一种包含丙烯酸改性聚四氟乙烯的烯烃类热塑性弹性体组合物。当发泡时，这种组合物产生非常柔软的泡沫，具有改进的加工性能和物理特性。还公开了发泡和发泡制品的方法。

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