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    • 6. 发明申请
    • Weldable thermoplastic sheet compositions
    • 可焊接热塑性片组合物
    • US20070208139A1
    • 2007-09-06
    • US11366906
    • 2006-03-02
    • Ralph RauliePurushottam AgrawalNarayanaswami DharmarajanMichael WilliamsSudhin Datta
    • Ralph RauliePurushottam AgrawalNarayanaswami DharmarajanMichael WilliamsSudhin Datta
    • C08L23/04
    • C08L23/10C08J5/18C08J2323/00C08J2323/10C08L23/0815C08L2205/02E04D5/10C08L2666/06C08L2666/02
    • This disclosure in certain embodiments relates to thermoplastic sheet compositions and applications incorporating such materials. More specifically this disclosure addresses thermoplastic sheets comprising: a) from 5 to 98.5 wt % of an essentially uncross-linked, random ethylene copolymer having from 20 wt % to 90 wt % repeat units from ethylene and from 10 wt % to 80 wt % of repeat units from one or more other ethylenically unsaturated monomers based upon the weight of the random ethylene copolymer; b) from 0.3 to 83.5 wt % of a polypropylene-based thermoplastic; and c) from 0.3 to 24.5 wt % of a vulcanized rubber dispersed phase. The disclosure also relates to methods of making the sheet compositions. One method includes incorporating a thermoplastic vulcanizate to provide the c) vulcanized rubber and in come cases, to supplement the b) polypropylene thermoplastic. Another method relates to melt blending polymer blends in appropriate proportions in the presence of a curing agent to effect dynamic vulcanization of a cross-linkable rubber component. Improved welding characteristics and weld strength of the sheets and reduced blocking in the extrusion step of producing the sheets is achieved.
    • 在某些实施方案中的本公开涉及包含这些材料的热塑性片组合物和应用。 更具体地,本公开涉及热塑性片材,其包括:a)5至98.5重量%的基本上未交联的无规乙烯共聚物,其具有20重量%至90重量%的来自乙烯的重复单元和10重量%至80重量%的 基于无规乙烯共聚物的重量从一种或多种其它烯属不饱和单体重复单元; b)0.3〜83.5重量%的聚丙烯类热塑性塑料; 和c)0.3〜24.5重量%的硫化橡胶分散相。 本公开还涉及制备片组合物的方法。 一种方法包括加入热塑性硫化橡胶以提供c)硫化橡胶,并且在本例中补充b)聚丙烯热塑性塑料。 另一种方法涉及在固化剂存在下以适当比例熔融共混聚合物共混物以实现可交联橡胶组分的动态硫化。 实现了在制造片材的挤出步骤中提高了片材的焊接特性和焊接强度以及减少的阻塞。