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    • 2. 发明申请
    • Slip-coat compositions and polymeric laminates
    • 滑涂组合物和聚合物层压材料
    • US20060057412A1
    • 2006-03-16
    • US10943307
    • 2004-09-15
    • Sunny JacobMarvin Hill
    • Sunny JacobMarvin Hill
    • B32B27/32C08L23/00
    • B32B27/32C08L23/0815C08L23/10C08L23/16C08L2205/02C08L2205/035C08L2205/22C08L2312/00Y10T428/31938C08L2666/02C08L2666/06
    • A polymeric laminate comprising (A) a substrate, and (B) a slip layer covering at least a portion of said substrate, where the slip layer consists essentially of (i) a polyethylene blend, where said blend includes (a) from about 3 to about 97 percent by weight, based upon the total weight of said blend, of a first polyethylene resin having a weight average molecular weight from 110,000 to about 140,000 and a polydispersity of less than about 12, (b) from about 3 to about 97 percent by weight, based upon the total weight of said blend, of a second polyethylene resin having a weight average molecular weight from 50,000 up to 109,999 and a polydispersity of less than about 12, and (c) from about 0 to about 40 percent by weight, based upon the total weight of said blend, of a third polyethylene resin having a weight average molecular weight from about 20,000 up to 49,999 and polydispersity of less than about 12, with the proviso that said blend includes at least 60 percent, based upon the total weight of said blend, of said first polyethylene and said second polyethylene combined, (ii) from about 2.5 to about 15 parts by weight, per 100 parts by weight of said polyethylene blend, of a propylene polymer or copolymer having propylene units deriving from propylene monomer, and (iii) from about 4.5 to about 20 parts by weight, per 100 parts by weight of said polyethylene blend, of a dynamically vulcanized rubber.
    • 一种聚合物层压体,其包含(A)基材和(B)覆盖所述基材的至少一部分的滑移层,其中所述滑移层基本上由(i)聚乙烯共混物组成,其中所述共混物包含(a)约3 至约97重量%,基于所述共混物的总重量,第一聚乙烯树脂的重均分子量为110,000至约140,000,多分散度小于约12,(b)约3至约97 重量百分比,基于所述共混物的总重量,重均分子量为50,000至109,999的第二聚乙烯树脂和小于约12的多分散性,和(c)约0至约40%的 基于所述共混物的总重量,重均分子量为约20,000至49,999的第三聚乙烯树脂和小于约12的多分散性,条件是所述共混物包含至少60%,基于 的 所述第一聚乙烯和所述第二聚乙烯组合的所述共混物的总重量,(ii)每100重量份所述聚乙烯共混物约2.5至约15重量份的具有丙烯单元的丙烯聚合物或共聚物,衍生自 丙烯单体,和(iii)每100重量份所述聚乙烯共混物约4.5至约20重量份的动态硫化橡胶。
    • 4. 发明授权
    • Crosslinked polyolefin polymer blends
    • 交联聚烯烃聚合物共混物
    • US08765834B2
    • 2014-07-01
    • US13273333
    • 2011-10-14
    • Sunny Jacob
    • Sunny Jacob
    • C08G18/32A61K6/083C08J3/28C08F2/46C08G61/04
    • C08L23/145C08L23/10C08L2205/02C08L2205/03C08L2312/06C08L2666/02C08L2666/06
    • Crosslinked polyolefin blends, methods for their production, and articles made of the same are provided. In at least one specific embodiment, the polyolefin blends comprise a first polymer formed in a first reactor and a second polymer formed in a second reactor. The first and second polymers, as well as the resulting blend, may comprise units derived from propylene, ethylene, and a diene. The blended composition can then be compounded with one or more coagents, antioxidants, UV sensitizers, and/or other additives and crosslinked, preferably by exposure to UV radiation and/or energetic photons. The crosslinked polymers are particularly useful for making fibers, films, and nonwovens.
    • 提供了交联聚烯烃共混物,其生产方法和由其制成的制品。 在至少一个具体实施方案中,聚烯烃共混物包含在第一反应器中形成的第一聚合物和在第二反应器中形成的第二聚合物。 第一和第二聚合物以及所得共混物可以包含衍生自丙烯,乙烯和二烯的单元。 然后可以将混合的组合物与一种或多种助剂,抗氧化剂,UV敏化剂和/或其它添加剂配混,并优选通过暴露于UV辐射和/或能量光子而交联。 交联聚合物特别适用于制造纤维,薄膜和无纺布。
    • 6. 发明申请
    • Polyolefin-Based Crosslinked Articles
    • 聚烯烃交联制品
    • US20120220682A1
    • 2012-08-30
    • US13446833
    • 2012-04-13
    • Sunny Jacob
    • Sunny Jacob
    • C08J7/18
    • C08L23/10C08K5/005C08K5/14C08K5/34924C08L23/16C08L75/00C08L2312/00C08L2666/02
    • Methods for making a crosslinked elastomeric composition and articles made of the same are provided. In at least one specific embodiment, an elastomeric composition comprising at least one propylene-based polymer is blended with at least one component selected from the group consisting of multifunctional acrylates, multifunctional methacrylates, functionalized polybutadiene resins, functionalized cyanurate, and allyl isocyanurate; and blended with at least one component selected from the group consisting of hindered phenols, phosphites, and hindered amines. The propylene-based polymer can include propylene derived units and one or more dienes, and have a triad tacticity of from 50% to 99% and a heat of fusion of less than 80 J/g. The blended composition can then be extruded and crosslinked. The extruded polymer can be crosslinked using electron beam radiation having an e-beam dose of about 100 KGy or less. The crosslinked polymers are particularly useful for making fibers and films.
    • 提供制备交联弹性体组合物的方法和由其制成的制品。 在至少一个具体实施方案中,包含至少一种基于丙烯的聚合物的弹性体组合物与至少一种选自多官能丙烯酸酯,多官能甲基丙烯酸酯,官能化聚丁二烯树脂,官能化氰尿酸酯和异氰脲酸烯丙酯的组分共混; 并与至少一种选自受阻酚,亚磷酸酯和受阻胺的组分共混。 基于丙烯的聚合物可以包括丙烯衍生的单元和一种或多种二烯,并且具有50%至99%的三单元组立构规整度和小于80J / g的熔化热。 然后可以将共混组合物挤出和交联。 挤出的聚合物可以使用约100KGy或更小的电子束剂量的电子束辐射进行交联。 交联聚合物特别适用于制造纤维和薄膜。