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    • 62. 发明授权
    • Azo dyes from aminophthalimides and aniline, tetrahydroquinoline, and
benzomorpholine couplers having thiosulfate groups
    • 具有硫代硫酸盐基团的氨基邻苯二甲酰亚胺和苯胺的偶氮染料,四氢喹啉和苯并吗啉成色剂
    • US4324719A
    • 1982-04-13
    • US159093
    • 1980-06-13
    • Max A. WeaverClarence A. Coates, Jr.
    • Max A. WeaverClarence A. Coates, Jr.
    • C09B29/00C09B29/08C09B29/36C09B29/44C09B29/036D06P3/26
    • C09B29/3686C09B29/0033C09B29/0803C09B29/3643
    • Disclosed are azo dyes suitable for coloring polyamide material, particularly nylon carpet and which are prepared from aminophthalimides and couplers which are ##STR1## substituted with a thiosulfate ester group. These dyes produce yellow to blue shades and also color cellulose acetate fabrics and wool. The dyes have the general formula: ##STR2## wherein R.sup.2 and R.sup.4 are each selected from hydrogen and a large variety of organic substituents, the coupler C is an aniline, 1,2,3,4-tetrahydroquinoline, or benzomorpholine derivative wherein a Q-SSO.sub.3 M group is attached to the nitrogen thereof, Q being a lower alkylene or similar linking group, and M is Na.sup.+, K.sup.+, NH.sub.4.sup.+, or H.sup.+. The present dyes are superior in such properties as fastness to light, oxides of nitrogen, wash, ozone, sublimation, perspiration and crock, and exhibit good dyeability including migration, leveling, pH stability, and build.
    • 公开了适用于着色聚酰胺材料,特别是尼龙地毯的偶氮染料,其由氨基邻苯二甲酰亚胺和由硫代硫酸酯基取代的成色剂制备。 这些染料产生黄色至蓝色的色调,并且还会着色醋酸纤维素织物和羊毛。 染料具有以下通式:其中R 2和R 4各自选自氢和大量有机取代基,成色剂C是苯胺,1,2,3,4-四氢喹啉或苯并吗啉衍生物,其中Q -SSO 3 M基团连接到其氮上,Q是低级亚烷基或类似的连接基团,M是Na +,K +,NH 4 +或H +。 本发明的染料具有如光牢度,氮氧化物,洗涤剂,臭氧,升华,排汗和烘干等特性的优异性,并且显示出良好的染色性,包括迁移,流平,pH稳定性和构建。
    • 66. 发明授权
    • Azo dyes from substituted 2-aminothiophenes and acyclic active methylene
couplers
    • 取代的2-氨基噻吩和无环活性亚甲基偶联剂的偶氮染料
    • US4579939A
    • 1986-04-01
    • US590088
    • 1984-03-16
    • Max A. WeaverClarence A. Coates, Jr.
    • Max A. WeaverClarence A. Coates, Jr.
    • C09B29/00C09B29/32C09B29/033C09B29/33C09B67/20D06P3/54
    • C09B29/0059C09B29/325
    • Yellow dyes from substituted 2-aminothiophene and acyclic active methylene coupling components are of particular interest for dyeing polyester fibers. The dyes have the formula: ##STR1## wherein: X is a group such as alkyl, allyloxy, alkoxy, aryl or the like; Y is hydrogen, alkyl, or aryl; Z is alkyl, aryl, alkylsulfonyl, cyano or COX where X is defined above; R is cyano, carbamyl, alkanoyl, aroyl, or the like; R.sub.1 is selected from the R groups and ##STR2## wherein R.sub.2 represents the atoms necessary to complete an azole radial selected from benzothiazole, benzimidazole, benzoxazole, 1,3,4-oxadiazole, 1,3,4-thiadiazole, and pyrazole; and wherein the hydrocarbon moieties of each of the above radicals or groups may be substituted with up to three of --OH, alkoxy, hydroxyalkoxy, alkylcarbamyl, or the like.
    • 来自取代的2-氨基噻吩和无环活性亚甲基偶联组分的黄色染料对于染色聚酯纤维是特别有意义的。 染料具有下式:其中:X为烷基,烯丙氧基,烷氧基,芳基等基团; Y是氢,烷基或芳基; Z是烷基,芳基,烷基磺酰基,氰基或COX,其中X定义如上; R是氰基,氨基甲酰基,烷酰基,芳酰基等; R1选自R基团和,其中R2表示完成选自苯并噻唑,苯并咪唑,苯并恶唑,1,3,4-恶二唑,1,3,4-噻二唑和吡唑的放射唑所需的原子。 并且其中每个上述基团或基团的烃部分可以被至多三个-OH,烷氧基,羟基烷氧基,烷基氨基甲酰基等取代。
    • 68. 发明授权
    • Substituted 5-acyl-3-carbamoyl-2-thienyl azo dyes with aniline,
tetrahydroquinoline, and benzomorpholine couplers, process of
manufacture, and polyamide testile materials dyed therewith
    • 用苯胺,四氢喹啉和苯并吗啉成色剂取代的5-酰基-3-氨基甲酰基-2-噻吩基偶氮染料,其制造方法和用其染色的聚酰胺纤维素材料
    • US4400318A
    • 1983-08-23
    • US318189
    • 1981-11-04
    • Max A. WeaverClarence A. Coates, Jr.
    • Max A. WeaverClarence A. Coates, Jr.
    • C09B29/00C09B29/08C09B29/36C09B29/44C09B29/033C09B29/09C09B29/34
    • C09B29/0821C09B29/0059C09B29/0805C09B29/0832C09B29/3643C09B29/3686
    • Disclosed are azo compounds having the formula ##STR1## in which R.sup.4 is straight or branched lower alkylene, Z is 1-3 groups selected from such heteroatom groups as --OH, lower alkanoyloxy, lower alkoxy, lower alkoxycarbonyl, lower alkoxyalkoxy, mono- or dialkylamino, --CN, carbamoyl, formamide, lower alkyl substituted carbamoyl, lower alkoxycarbonylamino, lower alkanoylamino, hydroxy substituted lower alkoxy, halogen, lower alkylthio, lower alkylsulfonyl, and various heterocyclic groups such as furyl and pyrrolidono, R is selected from straight or branched lower alkyl, phenyl and phenyl substituted with straight or branched lower alkyl, halogen, or straight or branched lower alkoxy, R.sup.2 is hydrogen or lower alkyl, and A is an aniline, tetrahydroquinoline, or benzomorpholine coupler component which may be substituted with a wide variety of groups. These azo compounds produce red to blue shades on polyamide, polyester and cellulose acetate fibers and exhibit markedly improved properties such as fastness and dyeability, particularly on synthetic polyamide fibers.
    • 公开了具有式“IMAGE”的偶氮化合物,其中R 4是直链或支链低级亚烷基,Z是1-3个选自-OH,低级烷酰氧基,低级烷氧基,低级烷氧基羰基,低级烷氧基烷氧基, 二烷基氨基,-CN,氨基甲酰基,甲酰胺,低级烷基取代的氨基甲酰基,低级烷氧基羰基氨基,低级烷酰基氨基,羟基取代的低级烷氧基,卤素,低级烷硫基,低级烷基磺酰基和各种杂环基如呋喃基和吡咯烷酮,R选自直链或支链 低级烷基,苯基和被直链或支链的低级烷基,卤素或直链或支链的低级烷氧基取代的苯基,R2是氢或低级烷基,A是苯并四氢喹啉或苯并吗啉偶联剂组分,其可被多种 的群体。 这些偶氮化合物在聚酰胺,聚酯和醋酸纤维素纤维上产生红色至蓝色,并且显示出显着改善的性能,如牢度和染色性,特别是合成聚酰胺纤维。
    • 70. 发明授权
    • Azo dyes from five membered ring heterocyclic amines and aniline,
tetrahydroquinoline and benzomorpholine couplers containing thiosulfate
alkyl groups
    • 来自五元环杂环胺的偶氮染料和含有硫代硫酸盐烷基的苯胺,四氢喹啉和苯并吗啉成色剂
    • US4301069A
    • 1981-11-17
    • US159092
    • 1980-06-13
    • Max A. WeaverClarence A. Coates, Jr.
    • Max A. WeaverClarence A. Coates, Jr.
    • C09B29/033C09B29/08C09B29/36C09B29/44C09B29/036C09B29/039C09B29/042C09B29/048
    • C09B29/3643C09B29/0025C09B29/0803C09B29/3686
    • Disclosed are mono azo dyes derived from diazotized 5-membered heterocyclic amines and certain aniline, 1,2,3,4-tetrahydroquinoline, and benzomorpholine couplers containing thiosulfate alkyl groups. These dyes are useful for dyeing synthetic fibers, cellulose acetate and wool, and particularly impart fast violet to blue shades on polyamide fibers, and in general, exhibit improved properties such as fastness to light, sublimation, ozone, oxides of nitrogen, perspiration, crock, and wash, and exhibit excellent build, pH stability, bloom resistance, depth of shade, leveling, migration, and the like. The dyes have the general formula:D--N.dbd.N--Couplerwherein D is a thiadiazol, isothiazol, pyrazol or thiophene type radical, and the Coupler is an aniline, tetrahydroquinoline, or benzomorpholine derivative wherein a --ZSSO.sub.3 M group is attached to the nitrogen thereof, the coupler ring may contain substituents such as alkyl, alkoxy, halogen, acylamido, alkylthio or aryloxy, the remaining hydrogen of the aniline coupler may be replaced by a substituent such as alkyl, substituted alkyl, alkenyl, aryl, or cycloalkyl, M is Na.sup.+, K.sup.+, NH.sub.4.sup.+ or H.sup.+, and Z is a linking group such as ethylene.
    • 公开了衍生自重氮化的5元杂环胺和某些苯胺,1,2,3,4-四氢喹啉和含有硫代硫酸盐烷基的苯并吗啉成色剂的单偶氮染料。 这些染料可用于染色合成纤维,醋酸纤维素和羊毛,特别是在聚酰胺纤维上赋予蓝紫色的快紫色,通常表现出改善的性能,例如耐光牢度,升华性,臭氧,氮氧化物,汗液, 并进行洗涤,表现出优异的构造,pH稳定性,耐开花性,深度,均匀性,迁移性等。 染料具有以下通式:DN = N-偶联剂,其中D为噻二唑,异噻唑,吡唑或噻吩型自由基,所述成色剂为苯并四氢喹啉或苯并吗啉衍生物,其中-ZSSO 3 M基团连接至其氮, 成色剂环可以含有取代基如烷基,烷氧基,卤素,酰氨基,烷硫基或芳氧基,苯胺成色剂的剩余氢可以被诸如烷基,取代的烷基,烯基,芳基或环烷基的取代基取代,M是Na + ,K +,NH 4 +或H +,Z是连接基团,例如乙烯。