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    • 3. 发明授权
    • Condensation polymer containing copolymerized colorants derived from
indigo and articles produced therefrom
    • 含有衍生自靛蓝的共聚着色剂和由其制备的制品的缩合聚合物
    • US4808677A
    • 1989-02-28
    • US153635
    • 1988-02-08
    • Max A. WeaverClarence A. Coates, Jr.Wayne P. PruettSamuel D. Hilbert
    • Max A. WeaverClarence A. Coates, Jr.Wayne P. PruettSamuel D. Hilbert
    • C08G63/685C09B69/10C08G63/20
    • C09B69/109C08G63/685
    • Disclosed are colored compositions useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising condensation polymer having reacted therewith or copolymerized therein a coloring amount of the residue of a colorant compound having the formula; ##STR1## wherein R.sup.1 is ##STR2## carbonyl halide or an unsubstituted or substituted carbocyclic or hetrocyclic aryl radical;R.sup.2 is hydrogen or an unsubstituted or substituted alkyl or acyl radical;R.sup.3 is any of the substituents which R.sup.1 may represent; andA.sup.1 and A.sup.2 each is the residue of a fused benzene ring; whereinR.sup.4 is hydrogen, allyl or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; andR.sup.5 is hydrogen or an unsubstituted or substituted alkyl, cycloalkyl or aryl radical; provided the colorant compound bears at least one substituent that is reactive with one of the monomers from which the condensation polymer is derived.The colorant compound residues are present in the polymer chain and impart a red color to the polymer. The residues are nonextractable from the polymer and stable at the condition at which the polymers are prepared and processed.
    • 公开了可用于模制成诸如食品容器,饮料瓶,固化的结构塑料等制品的着色组合物,其包含与其反应或与其共聚的具有下式的着色剂化合物的着色量的缩聚物; 或者其中R 1为羰基卤或未取代或取代的碳环或杂环芳基的“IMAGE”或“IMAGE” R2是氢或未取代或取代的烷基或酰基; R3是R1可以表示的任何取代基; A1和A2各自为稠合苯环的残基; 其中R4是氢,烯丙基或未取代或取代的烷基,环烷基或芳基; 并且R 5是氢或未取代或取代的烷基,环烷基或芳基; 只要着色剂化合物具有至少一个与衍生缩合聚合物的单体之一反应的取代基。 着色剂化合物残基存在于聚合物链中并赋予聚合物红色。 残余物不可聚合,并且在制备和加工聚合物的条件下是稳定的。
    • 4. 发明授权
    • Thiophen-2-ylazopyrazole compounds as colorants for textile fibers
    • 噻吩-2-基吡唑化合物作为纺织纤维的着色剂
    • US4568738A
    • 1986-02-04
    • US590809
    • 1984-03-19
    • Max A. WeaverClarence A. Coates, Jr.
    • Max A. WeaverClarence A. Coates, Jr.
    • C09B29/00C09B29/46C09B29/033C09B29/36D06P3/26D06P3/36
    • C09B29/3652C09B29/0059
    • Thiophen-2-ylazopyrazole dyes useful for dyeing polyesters, cellulose acetate esters, and polyamides in fast yellow shades have the general formula: ##STR1## wherein: X is alkyl, allyloxy, alkoxy, aryl, aryloxy, amino, alkylamino, arylamino, cyclohexyloxy,, thienyl, cycloalkylamino, N,N-dialkylamino, or N-alkyl-N-arylamino; Y is hydrogen, alkyl, or aryl; Z is alkyl, aryl, alkylsulfonyl, 2-benzothiazolyl, cyano or COX; R and R.sub.1 are alkyl or aryl; R.sub.2 is hydrogen, alkyl, aryl, acyl, benzothiazolyl, pyridyl, sulfolanyl, quinolyl, thiocarbamyl, carbamyl, alkoxycarbonyl, aroyl, aryl-carbamyl and alkanoyl; and wherein the hydrocarbon moieties of the above radicals may be substituted with up to three of --OH, alkoxy, hydroxyalkoxy, carbamyl, and similar groups conventionally used in the azo dye art.
    • 用于染色聚酯,乙酸纤维素酯和聚酰胺的噻吩-2-基吡唑类染料具有以下通式:其中:X为烷基,烯丙氧基,烷氧基,芳基,芳氧基,氨基,烷基氨基,芳基氨基,环己氧基 ,噻吩基,环烷基氨基,N,N-二烷基氨基或N-烷基-N-芳基氨基; Y是氢,烷基或芳基; Z是烷基,芳基,烷基磺酰基,2-苯并噻唑基,氰基或COX; R和R 1是烷基或芳基; R2是氢,烷基,芳基,酰基,苯并噻唑基,吡啶基,环丁砜基,喹啉基,硫代氨基甲酰基,氨基甲酰基,烷氧基羰基,芳酰基,芳基 - 氨基甲酰基和烷酰基。 并且其中上述基团的烃部分可被至多三个-OH,烷氧基,羟基烷氧基,氨基甲酰基以及常规用于偶氮染料领域的类似基团取代。
    • 7. 发明授权
    • Azo dyes from aminophthalimides and aniline, tetrahydroquinoline, and
benzomorpholine couplers having thiosulfate groups
    • 具有硫代硫酸盐基团的氨基邻苯二甲酰亚胺和苯胺的偶氮染料,四氢喹啉和苯并吗啉成色剂
    • US4324719A
    • 1982-04-13
    • US159093
    • 1980-06-13
    • Max A. WeaverClarence A. Coates, Jr.
    • Max A. WeaverClarence A. Coates, Jr.
    • C09B29/00C09B29/08C09B29/36C09B29/44C09B29/036D06P3/26
    • C09B29/3686C09B29/0033C09B29/0803C09B29/3643
    • Disclosed are azo dyes suitable for coloring polyamide material, particularly nylon carpet and which are prepared from aminophthalimides and couplers which are ##STR1## substituted with a thiosulfate ester group. These dyes produce yellow to blue shades and also color cellulose acetate fabrics and wool. The dyes have the general formula: ##STR2## wherein R.sup.2 and R.sup.4 are each selected from hydrogen and a large variety of organic substituents, the coupler C is an aniline, 1,2,3,4-tetrahydroquinoline, or benzomorpholine derivative wherein a Q-SSO.sub.3 M group is attached to the nitrogen thereof, Q being a lower alkylene or similar linking group, and M is Na.sup.+, K.sup.+, NH.sub.4.sup.+, or H.sup.+. The present dyes are superior in such properties as fastness to light, oxides of nitrogen, wash, ozone, sublimation, perspiration and crock, and exhibit good dyeability including migration, leveling, pH stability, and build.
    • 公开了适用于着色聚酰胺材料,特别是尼龙地毯的偶氮染料,其由氨基邻苯二甲酰亚胺和由硫代硫酸酯基取代的成色剂制备。 这些染料产生黄色至蓝色的色调,并且还会着色醋酸纤维素织物和羊毛。 染料具有以下通式:其中R 2和R 4各自选自氢和大量有机取代基,成色剂C是苯胺,1,2,3,4-四氢喹啉或苯并吗啉衍生物,其中Q -SSO 3 M基团连接到其氮上,Q是低级亚烷基或类似的连接基团,M是Na +,K +,NH 4 +或H +。 本发明的染料具有如光牢度,氮氧化物,洗涤剂,臭氧,升华,排汗和烘干等特性的优异性,并且显示出良好的染色性,包括迁移,流平,pH稳定性和构建。