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61. 发明授权

US6080208A Stilbene compounds and their use 失效
标题翻译：二苯乙烯化合物及其用途
公开(公告)号：US6080208A
公开(公告)日：2000-06-27
申请号：US218246
申请日：1998-12-22
申请人： Dieter Reinehr , Georges Metzger , Hanspeter Sauter
发明人： Dieter Reinehr , Georges Metzger , Hanspeter Sauter
IPC分类号： A61K8/49 , A61Q17/04 , C07D251/68 , C09B57/00 , C11D1/83 , C11D3/39 , C11D3/42 , C11D11/00 , D06L3/12 , D06M13/358 , D06P1/642 , D21H21/30 , C07D251/00 , C11D3/28 , D06P5/02
CPC分类号： C11D3/3947 , A61K8/4966 , A61Q17/04 , C07D251/68 , C11D1/83 , C11D11/0017 , C11D3/42 , D06L3/1214 , D06M13/358 , D06P1/6426 , D21H21/30 , A61K2800/434 , C11D3/3905
摘要： The present invention provides new stilbene compounds which are useful as fluorescent whitening agents (FWAs), imparting high whiteness levels to textile fibre material treated with them, and which also impart a high sun protection factor (SPF) to textile fibre material treated with them. The present invention also concerns a method of imparting a high whiteness level and a high sun protection factor to textile fibre material, especially cotton, polyamide and wool, comprising treating the textile material with the new compounds.
摘要翻译：本发明提供了可用作荧光增白剂（FWA）的新颖的二苯乙烯化合物，赋予了用它们处理的纺织纤维材料高的白度，并且还对用它们处理的纺织纤维材料赋予高的防晒因子（SPF）。本发明还涉及一种赋予纺织纤维材料，特别是棉，聚酰胺和羊毛的高白度和高防晒系数的方法，其包括用新化合物处理纺织材料。

62. 发明授权

US5800862A Textile treatment 失效
标题翻译：纺织品处理
公开(公告)号：US5800862A
公开(公告)日：1998-09-01
申请号：US438590
申请日：1995-05-10
申请人： Werner Kaufmann , Dieter Reinehr , Rolf Hilfiker
发明人： Werner Kaufmann , Dieter Reinehr , Rolf Hilfiker
IPC分类号： C09K3/00 , C11D1/62 , C11D3/42 , D06L3/12 , D06M13/02 , D06M13/03 , D06M13/224 , D06M13/322 , D06M13/35 , D06M13/352 , D06M13/355 , D06M13/358 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D06M101/10 , D06M101/12 , D06M101/16 , D06M101/18 , D06M101/28 , D06M101/30 , D06M101/32 , D06M101/34 , B05D5/00
CPC分类号： C11D3/0084 , C11D1/62 , C11D3/42 , D06L3/12 , D06L3/1207 , D06L3/1257 , D06M2200/25
摘要： The present invention relates to a improving the sun protection factor (SPF) of textile fibre material comprising treating the textile fibre material with a composition comprising at least one flourescent whitening agent which absorbs radiation in the wavelength range 280-400 nm.
摘要翻译：本发明涉及改善纺织纤维材料的防晒因子（SPF），包括用包含至少一种吸收280-400nm波长范围内的辐射的荧光增白剂的组合物处理纺织纤维材料。

63. 发明授权

US5760111A o-Hydroxyphenyl-s-triazines 失效
标题翻译：邻羟基苯基-s-三嗪
公开(公告)号：US5760111A
公开(公告)日：1998-06-02
申请号：US715056
申请日：1996-09-17
申请人： Jean-Luc Birbaum , Jurgen Kaschig , Dieter Reinehr , Manfred Rembold , Andre Schmitter , Helmut Luther , Bernd Herzog , Dietmar Huglin
发明人： Jean-Luc Birbaum , Jurgen Kaschig , Dieter Reinehr , Manfred Rembold , Andre Schmitter , Helmut Luther , Bernd Herzog , Dietmar Huglin
IPC分类号： C07D251/02 , A61K8/00 , A61K8/42 , A61K8/49 , A61K8/85 , A61Q17/04 , C07D251/12 , C07D251/24 , C08K5/3492 , C08L67/00 , C09K3/00 , D06P1/642 , D06P3/52 , C08K5/3495
CPC分类号： C08K5/3492 , A61K8/4966 , A61Q17/04 , C07D251/24 , D06P1/6426
摘要： o-Hydroxyphenyl-s-triazines are described which contain at least two alkoxyphenyl substituents. They have the formula (1). The compounds according to the invention are suitable as stabilizers for textile fiber materials, in particular polyester fiber materials, and for organic polymers. Furthermore, they are suitable for use as sunscreens in cosmetic preparations.
摘要翻译：描述了含有至少两个烷氧基苯基取代基的邻羟基苯基-s-三嗪。他们有公式（1）。根据本发明的化合物适用于纺织纤维材料，特别是聚酯纤维材料和有机聚合物的稳定剂。此外，它们适合用作化妆品制剂中的防晒剂。

64. 发明授权

US5545836A Process for the preparation of 1,3,5-triazines 失效
标题翻译：制备1,3,5-三嗪的方法
公开(公告)号：US5545836A
公开(公告)日：1996-08-13
申请号：US312597
申请日：1994-09-27
申请人： Dieter Reinehr , Elek Borsos
发明人： Dieter Reinehr , Elek Borsos
IPC分类号： C07D251/24 , C08K5/3492 , C09K3/00
CPC分类号： C08K5/3492 , C07D251/24
摘要： The invention relates to a simple, one-step process for the preparation of triazines of formula ##STR1## which comprises reacting the benzonitrile of formula (I) ##STR2## with the benzonitrile of formula (II) ##STR3## in the temperature range from 180.degree. to 260.degree. C., in which formulae above R.sub.1 and R.sub.2 are as defined in claim 1.The compounds prepared by this process find utility as UV absorbers or as starting materials for the preparation of UV absorbers.
摘要翻译：本发明涉及一种制备式（1）的三嗪的简单的一步法，其包括使式（I）的苄腈与图式（II）的苄腈（IMAMA）在温度范围为180℃至260℃，其中R 1和R 2上的式如权利要求1中所定义。通过该方法制备的化合物可用作UV吸收剂或作为制备UV吸收剂的起始材料。

65. 发明授权

US5488112A Dimeric benzotriazoles as UV absorbers 失效
标题翻译：二苯基三唑作为紫外线吸收剂
公开(公告)号：US5488112A
公开(公告)日：1996-01-30
申请号：US392638
申请日：1995-02-22
申请人： Dieter Reinehr , Jean-Pierre Bacher , Andre Schmitter
发明人： Dieter Reinehr , Jean-Pierre Bacher , Andre Schmitter
IPC分类号： C07D249/20 , C07D403/14 , C08K5/16 , C08K5/3472 , C08K5/3475 , C09K3/00
CPC分类号： C07D403/14 , C07D249/20 , C08K5/3475
摘要： The invention relates to dimeric 2-(2'-hydroxyphenyl)benzotriazoles of the formula I ##STR1## in which p is 0 or 1; is C.sub.1 -C.sub.12 alkylene;R.sub.1 and R'.sub.1, independently of one another, are hydrogen, halogen, C.sub.1 -C.sub.18 aklyl, C.sub.1 -C.sub.18 alkoxy or --CN;R.sub.2 and R'.sub.2, independently of one another, are hydrogen or C.sub.1 -C.sub.18 alkyl or together are C.sub.2 -C.sub.12 alkylene or C.sub.2 -C.sub.12 hydroxyalkylene; andR.sub.3 and R'.sub.3, independently of one another, are hydrogen, halogen, C.sub.1 -C.sub.18 alkyl or C.sub.1 -C.sub.18 alkoxy.The compounds of formula I are highly suitable for the stabilization of organic material against the harmful effects of heat, oxygen and light, in particular UV radiation.
摘要翻译：本发明涉及式I（I）的二聚2-（2'-羟基苯基）苯并三唑，其中p为0或1; 是C 1 -C 12亚烷基; R 1和R'1彼此独立地是氢，卤素，C 1 -C 18烷基，C 1 -C 18烷氧基或-CN; R2和R'2彼此独立地是氢或C1-C18烷基或一起是C2-C12亚烷基或C2-C12-羟基亚烷基; 和R 3和R'3彼此独立地是氢，卤素，C 1 -C 18烷基或C 1 -C 18烷氧基。式I的化合物非常适合于有机材料的稳定化，以抵抗热，氧和光，特别是UV辐射的有害影响。

66. 发明授权

US5478935A Process for the preparation of hydroxyphenyl-1,3,5-triazines 失效
标题翻译：制备羟苯基-1,3,5-三嗪的方法
公开(公告)号：US5478935A
公开(公告)日：1995-12-26
申请号：US321492
申请日：1994-10-12
申请人： Dieter Reinehr , Jean P. Bacher
发明人： Dieter Reinehr , Jean P. Bacher
IPC分类号： C07D251/10 , C07D251/24 , C08K5/3492 , C09K3/00
CPC分类号： C07D251/24 , C07D251/10 , C08K5/3492
摘要： A simple process for the preparation of a triazine of formula (1) is described, which comprises converting a dihydrotriazine of formula (2) with a reducing agent to a 1,3,5-triazine of formula (1).The triazines obtained by the novel process are suitable UV absorbers for organic materials, in particular for polyester fiber materials, or suitable starting materials for the preparation of UV absorbers.
摘要翻译：描述了制备式（1）的三嗪的简单方法，其包括用还原剂将式（2）的二氢三嗪转化为式（1）的1,3,5-三嗪。通过新方法获得的三嗪是用于有机材料的UV吸收剂，特别是用于聚酯纤维材料的UV吸收剂或用于制备UV吸收剂的合适的起始材料。

67. 发明授权

US5288867A Process for the preparation of 2-hydroxy-4,6-diaryl-1,3,5-triazines 失效
标题翻译：制备2-羟基-4,6-二芳基-1,3,5-三嗪的方法
公开(公告)号：US5288867A
公开(公告)日：1994-02-22
申请号：US11931
申请日：1993-02-01
申请人： Dieter Reinehr , Jean-Pierre Bacher
发明人： Dieter Reinehr , Jean-Pierre Bacher
IPC分类号： C07D251/22 , C07D251/52
CPC分类号： C07D251/22
摘要： There is disclosed a process for the preparation of 2-hydroxy-4,6-diaryl-1,3,5-triazines, which comprises reacting the compound of formula ##STR1## wherein R is hydrogen, C.sub.1 -C.sub.4 alkyl or halogen, with urea, using a base selected from the class of the alkali metal hydrides, alkaline earth metal hydrides, or alkali metal amides, alkaline earth metal amides, or of the alkali metal C.sub.1 -C.sub.4 alcoholates in the presence of a polar solvent, to give the final products in a one step process in which the molar ratio of urea to base is 1:2 to 1:3 and the molar ratio of compound of formula (1) to urea is 2:1 to 5:1.2-Hydroxy-4,6-diaryl-1,3,5-triazines are prepared in very good yield by the inventive process. The compounds are used as intermediates for the synthesis of UV absorbers.
摘要翻译：公开了2-羟基-4,6-二芳基-1,3,5-三嗪的制备方法，该方法包括使式（*化学结构*）（1）的化合物（其中R是氢，C1- C4烷基或卤素与尿素反应，使用选自碱金属氢化物，碱土金属氢化物或碱金属氨化物，碱土金属氨化物或碱金属C1-C4醇化物的碱在极性溶剂存在下在一步法中给出最终产物，其中脲与碱的摩尔比为1:2至1:3，式（1）化合物与脲的摩尔比为2:1至5:1。通过本发明方法以非常好的收率制备2-羟基-4,6-二芳基-1,3,5-三嗪。该化合物用作合成UV吸收剂的中间体。

68. 发明授权

US5097076A Phenylalkyl glycidyl ether addition products 失效
标题翻译：苯乙醇甘油醚添加剂
公开(公告)号：US5097076A
公开(公告)日：1992-03-17
申请号：US543941
申请日：1990-06-26
申请人： Dieter Reinehr , Rosemarie Topfl
发明人： Dieter Reinehr , Rosemarie Topfl
IPC分类号： B01F17/42 , C08G65/04 , C08G65/26 , C08G65/32 , C08G65/331 , C08G65/338 , C09B67/46 , C11D1/06 , C11D1/12 , C11D1/29 , C11D1/34 , C11D1/72 , C11D3/37 , D06L1/14 , D06M13/02 , D06M13/224 , D06M13/322 , D06M13/402 , D06M13/405 , D06M13/51 , D06M13/513 , D06M15/53 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D06M101/16 , D06M101/30 , D06M101/32 , D06M101/34 , D06P1/613
CPC分类号： C08G65/04 , C08G65/2609 , C08G65/331 , C08G65/338 , C09B67/0085 , C11D1/06 , C11D1/123 , C11D1/29 , C11D1/345 , C11D1/72 , C11D3/3707 , D06L1/14 , D06P1/6133 , D06P1/6135
摘要： Addition products of phenylalkyl glycidyl ethers to polyalkylene glycol ethers of the formulaR-O Alkylene--O.sub.m H (1)their acid esters and salts thereof, wherein R is an aliphatic radical having at least 4 carbon atoms, "Alkylene" is an alkylene radical of 2 or 3 carbon atoms, and m is a number from 2 to 100.These products represent a novel class of non-ionic or anionic surfactants that are used as textile finishing agents, especially as emulsifiers, wetting agents, foaminhibitors or dyeing auxiliaries.
摘要翻译：苯基烷基缩水甘油醚与式RO亚烷基-OmH的聚亚烷基二醇醚的加成产物（1）它们的酸酯及其盐，其中R是具有至少4个碳原子的脂族基团，“亚烷基”是2或 3个碳原子，m为2至100.这些产品代表一类新型非离子或阴离子表面活性剂，用作纺织品整理剂，特别是作为乳化剂，润湿剂，阻燃剂或染色助剂。

69. 发明授权

US4918215A 4-halogenostilbene derivatives and processes for their preparation 失效
标题翻译： 4-卤代茋衍生物及其制备方法
公开(公告)号：US4918215A
公开(公告)日：1990-04-17
申请号：US657451
申请日：1984-10-03
申请人： Dieter Reinehr , Alwyn Spencer
发明人： Dieter Reinehr , Alwyn Spencer
IPC分类号： C07C69/65 , C07C17/00 , C07C17/26 , C07C25/24 , C07C63/66 , C07C63/74 , C07C67/00 , C07C69/618 , C07C253/00 , C07C255/34 , C07C255/35 , C07C255/51 , C07D295/16 , C07D295/185
CPC分类号： C07D295/185 , C07C17/2637 , C07C25/24 , C07C255/00 , C07C63/66 , C07C63/74
摘要： Novel compounds of the formula ##STR1## and processes for their preparation are described. X represents bromine or iodine and R.sub.1, R.sub.2 and R.sub.3 have the meaning indicated in the patent claim. The compounds (I) are valuable intermediates for the preparation of fluorescent brighteners of the divinylstilbene type.
摘要翻译：描述了新颖的式（Ⅰ）化合物及其制备方法。 X表示溴或碘，R1，R2和R3具有专利权利要求中所示的含义。化合物（I）是制备二乙烯基芪类荧光增白剂的有价值的中间体。

70. 发明授权

US4782187A Process for the preparation of 4,4'-stilbenedialdehydes 失效
标题翻译：制备4,4'-二苯乙醛的方法
公开(公告)号：US4782187A
公开(公告)日：1988-11-01
申请号：US940312
申请日：1986-12-10
申请人： Dieter Reinehr , Heinz Steiner
发明人： Dieter Reinehr , Heinz Steiner
IPC分类号： C07C47/546 , B01J23/00 , C07B61/00 , C07C45/00 , C07C45/41 , C07C65/30 , C07C67/00
CPC分类号： C07C45/41 , C07C65/30
摘要： The preparation of 4,4'-stilbenedialdehydes from the corresponding acid chlorides in the presence of a noble metal catalyst.
摘要翻译：在贵金属催化剂存在下，从相应的酰氯制备4,4'-二苯乙醛。

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