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61. 发明授权

US4785109A Certain sulfonyl carbamates or thiocarbamate intermediates 失效
标题翻译：某些磺酰氨基甲酸酯或硫代氨基甲酸酯中间体
公开(公告)号：US4785109A
公开(公告)日：1988-11-15
申请号：US008882
申请日：1987-01-30
申请人： Willy Meyer , Werner Fory , Werner Topfl
发明人： Willy Meyer , Werner Fory , Werner Topfl
IPC分类号： C07D251/16 , A01N47/36 , C07C67/00 , C07C301/00 , C07C303/36 , C07C311/53 , C07C325/00 , C07C333/12 , C07D239/42 , C07D239/47 , C07D333/38 , C07D521/00 , C07D213/70 , C07D207/36 , C07D213/69 , C07D307/64
CPC分类号： C07D521/00 , C07D333/38
摘要： These is described a process for producing sulfonylureas of the formula ##STR1## wherein G is an unsubstituted or substituted furanyl, thienyl, pyrrolyl, pyridinyl or phenyl radical,X is alkyl, haloalkyl, alkoxy, alkylthio, halogen, haloalkoxy, alkylamino or dialkylamino,Y is alkyl, alkoxy or haloalkoxy,Z is a nitrogen atom or the methyne group --CH.dbd..This novel process comprises reacting a sulfonamide of the formulaG--SO.sub.2 --NH.sub.2,in the presence of a base, with a chloroformic acid ester of the formulaCl--CO--Q--T,or a sulfonyl chloride of the formulaG--SO.sub.2 Cl,in the presence of a base, with a urethane of the formulaH.sub.2 N--CO--Q--T;and converting the formed carbamate of the formulaG--SO.sub.2 --NH--CO--Q--Tby reaction with an amine of the formula ##STR2## into the sulfonylurea of the above formula. There are also described novel sulfonylcarbamates of the above formula as intermediates.
摘要翻译：这些描述了一种制备式IMA的磺酰脲的方法，其中G是未取代或取代的呋喃基，噻吩基，吡咯基，吡啶基或苯基，X是烷基，卤代烷基，烷氧基，烷硫基，卤素，卤代烷氧基，烷基氨基或二烷基氨基， Y是烷基，烷氧基或卤代烷氧基，Z是氮原子或甲炔基-CH =。该新方法包括使式G-SO 2 -NH 2的磺酰胺在碱的存在下与式Cl-CO-QT的氯甲酸酯或式G-SO 2 Cl的磺酰氯反应，碱的存在与式H2N-CO-QT的氨基甲酸酯反应; 并且通过与下式的磺酰脲反应将式G-SO 2 -NH-CO-Q-T的所形成的氨基甲酸酯转化为式（I）所示的磺酰脲。还描述了上述式的新型磺酰基氨基甲酸酯作为中间体。

62. 发明授权

US4677217A Phosphorous-containing phenylsulfonamides 失效
标题翻译：含磷苯基磺酰胺
公开(公告)号：US4677217A
公开(公告)日：1987-06-30
申请号：US784274
申请日：1985-10-04
申请人： Ludwig Maier , Willy Meyer , Konrad Oertle , Achim Roloff , Werner Topfl
发明人： Ludwig Maier , Willy Meyer , Konrad Oertle , Achim Roloff , Werner Topfl
IPC分类号： A01N57/16 , A01N57/08 , A01N57/24 , C07D521/00 , C07F9/30 , C07F9/32 , C07F9/38 , C07F9/40 , C07F9/53 , C07F9/6512 , C07F9/6521
CPC分类号： C07D521/00 , A01N57/08 , C07F9/304 , C07F9/3229 , C07F9/3808 , C07F9/3834 , C07F9/4006 , C07F9/4015 , C07F9/4021 , C07F9/4056 , C07F9/5325 , C07F9/65127 , C07F9/65217
摘要： Phenylsulfonamides of the formula ##STR1## in which X is a group ##STR2## Y is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, trifluoromethyl, C.sub.2 -C.sub.5 -alkenyl, C.sub.2 -C.sub.5 -alkynyl, nitro, --COOR.sup.6 or --Q--R.sup.6, A is oxygen, sulfur, a direct bond, C.sub.1 -C.sub.5 -alkylene, C.sub.2 -C.sub.5 -alkenylene, C.sub.1 -C.sub.5 -halogenoalkylene or --NR.sup.7 --(CH.sub.2).sub.m --; --CH.sub.2 --NH--(CH.sub.2).sub.m ; --(CH.sub.2).sub.m --NR.sup.7 -- or --O--(CH.sub.2).sub.p --, --S--(CH.sub.2).sub.p --, --(CH.sub.2).sub.p --O-- or --(CH.sub.2).sub.p --S--, n is zero or one, G is oxygen or sulfur, R.sup.4 is C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -halogenoalkoxy, C.sub.1 -C.sub.5 -alkylthio, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -halogenoalkyl, phenyl or hydroxyl, R.sup.5 is hydrogen, C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -halogenoalkoxy, C.sub.1 -C.sub.5 -alkylthio, C.sub.1 -C.sub. 5 -alkyl or hydroxyl, R.sup.6 is hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -halogenoalkyl or C.sub.2 -C.sub.6 -alkoxyalkyl, Q is oxygen, sulfur, --SO-- or --SO.sub.2 --, R.sup.7 is hydrogen, C.sub.1 -C.sub.5 -alkyl, phenyl, benzyl or phenyl which is substituted by C.sub.1 -C.sub.5 -alkyl, halogen, or nitro, m is a number from zero to three, p is a number from zero to two and r is one or two are useful as intermediates for phosphorous-containing N-phenylsulfonyl-N'-pyrimdinylurea and N-phenylsulfonyl-N'-triazinylurea herbicides.
摘要翻译：其中X是基团Y的式“IMAGE”的苯磺酰胺是氢，卤素，C 1 -C 5 - 烷基，三氟甲基，C 2 -C 5 - 烯基，C 2 -C 5炔基，硝基，-COOR 6或-Q- R6，A是氧，硫，直接键，C1-C5-亚烷基，C2-C5-亚烯基，C1-C5-卤代亚烷基或-NR7-（CH2）m-; -CH 2 -NH-（CH 2）m; - （CH 2）m -NR 7 - 或-O-（CH 2）p - ， - S-（CH 2）p - ， - （CH 2）p O-或 - （CH 2）p -S-，n为0或1，G为氧或硫，R4是C1-C5-烷氧基，C1-C5-卤代烷氧基，C1-C5-烷硫基，C1-C5-烷基，C1-C5-卤代烷基，苯基或羟基，R5是氢，C1-C5-烷氧基，C1 -C5-卤代烷氧基，C1-C5-烷硫基，C1-C5-烷基或羟基，R6是氢，C1-C5-烷基，C1-C5-卤代烷基或C2-C6-烷氧基烷基，Q是氧，硫，-SO - 或-SO 2 - ，R 7是氢，C 1 -C 5 - 烷基，苯基，苄基或被C 1 -C 5 - 烷基，卤素或硝基取代的苯基，m是0至3的数，p是 0至2，r是1或2个可用作含磷的N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N'-三嗪基脲除草剂的中间体。

63. 发明授权

US4634465A Fused N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'triazinylureas 失效
标题翻译：熔融的N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N'-三嗪基脲
公开(公告)号：US4634465A
公开(公告)日：1987-01-06
申请号：US512091
申请日：1983-07-08
申请人： Josef Ehrenfreund , Werner Fory , Willy Meyer , Werner Topfl
发明人： Josef Ehrenfreund , Werner Fory , Willy Meyer , Werner Topfl
IPC分类号： A01N47/36 , C07D209/08 , C07D215/00 , C07D215/36 , C07D239/00 , C07D251/00 , C07D307/00 , C07D307/79 , C07D307/82 , C07D307/83 , C07D307/88 , C07D311/00 , C07D311/18 , C07D311/20 , C07D311/22 , C07D311/58 , C07D311/70 , C07D311/76 , C07D317/00 , C07D317/46 , C07D317/62 , C07D319/00 , C07D319/18 , C07D327/00 , C07D327/04 , C07D327/06 , C07D333/00 , C07D333/54 , C07D333/62 , C07D335/00 , C07D335/06 , C07D401/12 , C07D403/12 , C07D405/12 , C07D409/12 , C07D411/12 , C07D417/12 , C07D521/00
CPC分类号： C07D307/79 , A01N47/36 , C07D209/08 , C07D215/36 , C07D307/83 , C07D307/88 , C07D311/18 , C07D311/22 , C07D311/58 , C07D311/70 , C07D311/76 , C07D317/46 , C07D317/62 , C07D319/18 , C07D327/06 , C07D333/54 , C07D335/06 , C07D521/00
摘要： The invention relates to N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N-triazinylureas of the general formula ##STR1## wherein Z is oxygen or sulfur,E is nitrogen or .dbd.CH--,R.sub.1 is hydrogen, halogen, nitro, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 alkoxycarbonyl, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 alkylsulfonyl or C.sub.2 -C.sub.5 alkoxyalkoxy,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl or C.sub.1 -C.sub.3 alkoxy,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.1 -C.sub.4 alkylthio, halogen, C.sub.2 -C.sub.5 alkoxyalkyl, C.sub.2 -C.sub.5 alkoxyalkoxy or --NR.sub.5 R.sub.6, wherein R.sub.5 and R.sub.6 are hydrogen or C.sub.1 -C.sub.4 alkyl, andA is an unsubstituted or substituted bridge of 3 or 4 atoms which contains 1 or 2 oxygen, sulfur or nitrogen atoms and, together with the linking carbon atom, forms a non-aromatic 5- or 6-membered heterocyclic ring system, with the proviso that two oxygen atoms are separated by at least one carbon atom and that oxygen and sulfur atoms are only linked to each other if the sulfur atom takes the form of the --SO-- or --SO.sub.2 -- group;and to the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases. These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.
摘要翻译：本发明涉及通式为（I）的N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N-三嗪基脲，其中Z是氧或硫，E是氮或= CH-，R 1是氢，卤素，硝基，C1-C4烷基，C1-C4卤代烷基，C1-C4烷氧基，C1-C4卤代烷氧基，C1-C4烷氧基羰基，C1-C4烷硫基，C1-C4烷基亚磺酰基，C1-C4烷基磺酰基或C2-C5烷氧基烷氧基，R2是氢，C 1 -C 4烷基或C 1 -C 3烷氧基，R 3和R 4各自独立地是氢，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4卤代烷氧基，C 1 -C 4卤代烷硫基，C 1 -C 4烷硫基，卤素，C 2 -C 5烷氧基烷基，C 2 -C 5烷氧基烷氧基或-NR 5 R 6，其中R 5和R 6是氢或C 1 -C 4烷基，A是3或4个原子的未取代或取代的桥，其含有1或2个氧，硫或氮原子，并与连接碳原子一起形成非芳族的5或6元杂环系，条件是两个氧原子被至少一个碳原子隔开，而氧如果硫原子是-SO-或-SO 2 - 基团的形式，则硫原子彼此相连; 以及这些化合物与胺，碱金属碱或碱土金属碱或季铵碱的盐。这些化合物具有良好的芽前和芽后选择性除草和生长调节性质。

64. 发明授权

US4594097A N-phenylsulfonyl-N'-triazinylureas 失效
标题翻译： N-苯基磺酰基-N'-三嗪基脲
公开(公告)号：US4594097A
公开(公告)日：1986-06-10
申请号：US745749
申请日：1985-06-17
申请人： Rolf Schurter , Werner Fory , Willy Meyer
发明人： Rolf Schurter , Werner Fory , Willy Meyer
IPC分类号： C07D251/16 , A01N47/36 , C07C67/00 , C07C301/00 , C07D239/42 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D251/42 , C07D401/12 , C07D409/12 , C07D521/00 , C07D251/50 , A01N43/70 , C07D251/52
CPC分类号： C07D521/00 , A01N47/36
摘要： N-Phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'-triazinylureas of the general formula I ##STR1## wherein A is a radical of the formula --C.tbd.C--R,m is 1 or 2,Z is oxygen or sulfur,R is hydrogen; unsubstituted or substituted, branched or unbranched C.sub.1 -C.sub.9 alkyl; unsubstituted or substituted C.sub.3 -C.sub.9 cycloalkyl; unsubstituted or substituted phenyl; or an unsubstituted or substituted 5- or 6-membered aromatic heterocyclic ring,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or a radical --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, halogen, C.sub.2 -C.sub.5 alkoxyalkyl, --NR.sub.9 R.sub.10 or --O--CH.sub.2 --CH.sub.2 --NR.sub.9 R.sub.10,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl, C.sub.1 -C.sub.5 haloalkyl, C.sub.2 -C.sub.5 haloalkenyl or C.sub.2 -C.sub.6 alkoxyalkyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl,R.sub.9 is hydrogen, methyl or ethyl,R.sub.10 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, methoxymethyl, cyanomethyl, cyanoethyl, C.sub.3 -C.sub.5 alkenyl or C.sub.3 -C.sub.6 alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridgeand the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases or with quaternary ammonium bases, have good preemergence and postemergence selective herbicidal and growth regulating properties.
摘要翻译： N-苯基磺酰基-N'-嘧啶基脲和通式I的N-苯基磺酰基-N'-三嗪基脲其中A是式-CB 3 CR的基团，m是1或2，Z是氧或硫，R是氢; 未取代或取代的支链或非支链C 1 -C 9烷基; 未取代或取代的C 3 -C 9环烷基; 未取代或取代的苯基; 或未取代或取代的5元或6元芳族杂环，R 1为氢，卤素，C 1 -C 5烷基，C 2 -C 5烯基或自由基-Y-R 5，R 2为氢，卤素，C 1 -C 5烷基，C 2 -C 5链烯基， C1-C4卤代烷基或自由基-Y-R5，-COOR6，-NO2或-CO-NR7-R8，R3和R4各自独立地为氢，C1-C4烷基，C1-C4烷氧基，C1-C4烷硫基， C1-C4卤代烷基，C1-C4卤代烷氧基，C1-C4卤代烷硫基，卤素，C2-C5烷氧基烷基，-NR9R10或-O-CH2-CH2-NR9R10，R5和R6各自独立地为C1-C5烷基，C2-C5链烯基或C2 C 1-6炔基，C 1 -C 5卤代烷基，C 2 -C 5卤代烯基或C 2 -C 6烷氧基烷基，R 7和R 8各自独立地为氢，C 1 -C 5烷基，C 2 -C 5烯基或C 2 -C 6炔基，R 9为氢，甲基或乙基，R 10为氢，C1-C4烷基，C1-C4烷氧基，甲氧基甲基，氰基甲基，氰乙基，C3-C5链烯基或C3-C6炔基，Y是氧，硫，亚磺酰基或磺酰基桥，这些化合物与胺，碱金属碱或碱地球金属碱基或季铵碱基，具有良好的出芽前和出芽后选择性除草和生长调节性质。

65. 发明授权

US4562210A Bactericides 失效
标题翻译：杀菌剂
公开(公告)号：US4562210A
公开(公告)日：1985-12-31
申请号：US563841
申请日：1983-12-21
申请人： Willy Meyer , Werner Topfl , Haukur Kristinsson , Wolfgang Eckhardt
发明人： Willy Meyer , Werner Topfl , Haukur Kristinsson , Wolfgang Eckhardt
IPC分类号： A01N47/34 , A01N47/36 , C07C311/54 , C07C127/19 , C07C157/09
CPC分类号： C07C309/89 , A01N47/36 , C07C311/65
摘要： Novel N-[2-(1,2-dichlorovinyloxy)phenylsulfonyl]-(thio)ureas of the general formula I ##STR1## in which X is oxygen or sulfur, R.sub.1 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.6 -alkenyl or C.sub.2 -C.sub.6 -alkinyl; and R.sub.2 is hydrogen, C.sub.1 -C.sub.12 -alkyl, C.sub.2 -C.sub.6 -alkenyl, C.sub.2 -C.sub.6 -alkinyl or C.sub.1 -C.sub.6 -alkoxy; and the salts of these compounds are described.These compounds have pronounced bactericidal properties and can be used without problems against bacteria which damage plants, especially in the agricultural sector.
摘要翻译：通式I的新型N- [2-（1,2-二氯乙烯氧基）苯基磺酰基] - （硫代）脲其中X是氧或硫，R 1是氢，C 1 -C 12烷基，C 2 -C 1-6 - 烯基或C 2 -C 6 - 炔基; 并且R 2是氢，C 1 -C 12 - 烷基，C 2 -C 6 - 烯基，C 2 -C 6 - 炔基或C 1 -C 6 - 烷氧基; 并描述了这些化合物的盐。这些化合物具有显着的杀菌性质，并且可以在不损害特别是农业部门的植物细菌的情况下使用。

66. 发明授权

US4510325A Phenyl sulfonamides 失效
标题翻译：苯磺酰胺
公开(公告)号：US4510325A
公开(公告)日：1985-04-09
申请号：US417743
申请日：1982-09-13
申请人： Willy Meyer , Werner Fury
发明人： Willy Meyer , Werner Fury
IPC分类号： C07D239/42 , A01N41/06 , A01N43/66 , A01N47/36 , A01P13/00 , C07C20060101 , C07C67/00 , C07C301/00 , C07C311/00 , C07C311/29 , C07C313/00 , C07C317/14 , C07C317/18 , C07C317/22 , C07C317/44 , C07C323/12 , C07C323/67 , C07D239/46 , C07D239/47 , C07D239/52 , C07D239/56 , C07D251/14 , C07D251/16 , C07D251/22 , C07D251/42 , C07D251/44 , C07D251/46 , C07D521/00 , C07C143/78
CPC分类号： C07D521/00 , A01N47/36
摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts thereof with amines, alkali metal or alkaline earth metal bases or with quaternary ammonium bases, have good pre- and postemergence selective herbicidal and growth regulating properties. In the above formulaA is a C.sub.1 -C.sub.6 alkyl radical which is substituted by C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, C.sub.1 -C.sub.4 haloalkoxy, C.sub.1 -C.sub.4 haloalkylthio, C.sub.1 -C.sub.4 haloalkylsulfinyl or C.sub.1 -C.sub.4 haloalkylsulfonyl, or a C.sub.2 -C.sub.6 -alkenyl radical which is unsubstituted or substituted by the above substituents, or is a C.sub.2 -C.sub.6 haloalkenyl radical,E is the methine group or nitrogen,X is oxygen, sulfur, a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is 1 or 2,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or a radical --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 -haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, halogen or alkoxyalkyl of at most 4 carbon atoms,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridge.
摘要翻译：具有通式“IMAGE”的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲及其与胺，碱金属或碱土金属碱或季铵碱的盐具有良好的芽前和芽后选择性除草和生长调节属性。在上式中，A是被C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基亚磺酰基，C 1 -C 4烷基磺酰基，C 1 -C 4卤代烷氧基，C 1 -C 4卤代烷硫基，C 1 -C 4卤代烷基亚磺酰基或C 1 -C 4卤代烷基磺酰基取代的C 1 -C 6烷基，或未被取代或被上述取代基取代的C2-C6-烯基，或是C2-C6卤代烯基，E是次甲基或氮，X是氧，硫，亚磺酰基或磺酰基桥，Z是氧或硫，m为1或2，R 1为氢，卤素，C 1 -C 5烷基，C 2 -C 5烯基或自由基-Y-R 5，R 2为氢，卤素，C 1 -C 5烷基，C 2 -C 5烯基，C 1 -C 4卤代烷基或自由基-Y-R5，-COOR6，-NO2或-CO-NR7-R8，R3和R4分别独立地为氢，C1-C4烷基，C1-C4烷氧基，C1-C4烷氧基，C1-C4烷硫基，C1- 最多4个碳原子的C 4卤代烷基，卤素或烷氧基烷基，R 5和R 6各自独立地为C 1 -C 5烷基，C 2 -C 5烯基或C 2 -C 6炔基，R 7和R 8各自独立地为氢，C1- C5烷基，C 2 -C 5烯基或C 2 -C 6炔基，Y是氧，硫，亚磺酰基或磺酰基桥。

67. 发明授权

US4487951A N-Phenylsulfonylcarbamates 失效
标题翻译： N-苯基磺酰基氨基甲酸酯
公开(公告)号：US4487951A
公开(公告)日：1984-12-11
申请号：US571976
申请日：1984-01-19
申请人： Werner F/o/ ry , Karl Gass , Willy Meyer , Rolf Schurter
发明人： Werner F/o/ ry , Karl Gass , Willy Meyer , Rolf Schurter
IPC分类号： A01N47/24 , A01N47/08 , A01N47/22 , A01N47/36 , C07C303/36 , C07C311/16 , C07C311/53 , C07C323/67 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D251/16 , C07D251/22 , C07D251/40 , C07D251/46 , C07D251/52 , C07D521/00 , C07C143/83
CPC分类号： C07C311/65 , A01N47/36 , C07D239/47 , C07D239/48 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.
摘要翻译：具有通式（I）的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后芽后选择性，除草和生长调节性质。该式中的符号如下：A是C 3 -C 6炔基，E是次甲基或氮，X是氧，硫或亚磺酰基或磺酰基桥，Z是氧或硫，m是第一个或两个，R 1是氢，卤素，C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5，R 2是氢，卤素，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5，-COOR 6，-NO 2或-CO-NR 7 -R 8，R 3和R 4彼此独立地为氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，卤素或至多4个碳原子的烷氧基烷基，R 5和R 6各自为C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6炔基，R 7和R 8独立地为各自为氢，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6 - 炔基，Y为氧，硫或亚磺酰基或磺酰基桥。

68. 发明授权

US4479821A N-Phenylsulfonyl-N'-triazinylureas 失效
标题翻译： N-苯基磺酰基-N'-三嗪基脲
公开(公告)号：US4479821A
公开(公告)日：1984-10-30
申请号：US458695
申请日：1983-01-17
申请人： Willy Meyer , Werner F/o/ ry
发明人： Willy Meyer , Werner F/o/ ry
IPC分类号： C07D239/42 , A01N41/06 , A01N43/66 , A01N47/36 , A01P13/00 , C07C20060101 , C07C67/00 , C07C301/00 , C07C311/00 , C07C311/29 , C07C313/00 , C07C317/14 , C07C317/18 , C07C317/22 , C07C317/44 , C07C323/12 , C07C323/67 , C07D239/46 , C07D239/47 , C07D239/52 , C07D239/56 , C07D251/14 , C07D251/16 , C07D251/22 , C07D251/42 , C07D251/44 , C07D251/46 , C07D521/00
CPC分类号： C07D521/00 , A01N47/36
摘要： N-Phenylsulfonyl-N'-triazinylureas of the general formula ##STR1## and the salts thereof with amines, alkali metal or alkaline earth metal bases or with quaternary ammonium bases, have good pre- and postemergence selective herbicidal and growth regulating properties. In the above formulaA is a C.sub.1 -C.sub.6 alkyl radical which is substituted by C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 alkylsulfinyl or C.sub.1 -C.sub.4 alkylsulfonyl,X is oxygen, sulfur, a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is 1 or 2,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl, C.sub.1 -C.sub.4 haloalkyl, or a radical --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4, each independently of the other, are hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, halogen or alkoxyalkyl or at most 4 carbon atoms,R.sub.5 and R.sub.6, each independently of the other, are C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl,R.sub.7 and R.sub.8, each independently of the other, are hydrogen, C.sub.1 -C.sub.5 alkyl, C.sub.2 -C.sub.5 alkenyl or C.sub.2 -C.sub.6 alkynyl, andY is oxygen, sulfur, a sulfinyl or sulfonyl bridge.
摘要翻译：具有通式“IMAGE”的N-苯基磺酰基-N'-三嗪基脲及其与胺，碱金属或碱土金属碱基或季铵碱的盐具有良好的芽前和芽后选择性除草和生长调节性质。在上式中，A是被C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基取代的C 1 -C 6烷基，X是氧，硫，亚磺酰基或磺酰基桥，Z是氧或硫，m 是1或2，R2是氢，卤素，C1-C5烷基，C2-C5链烯基，C1-C4卤代烷基或基团-Y-R5，-COOR6，-NO2或-CO-NR7-R8，R3和R4各自独立地的另一个是氢，C 1 -C 4烷基，C 1 -C 4烷氧基，C 1 -C 4烷硫基，C 1 -C 4卤代烷基，卤素或烷氧基烷基或至多4个碳原子，R 5和R 6各自独立地是C 1 -C 5烷基， C 5链烯基或C 2 -C 6炔基，R 7和R 8各自独立地为氢，C 1 -C 5烷基，C 2 -C 5烯基或C 2 -C 6炔基，Y为氧，硫，亚磺酰基或磺酰基桥。

69. 发明授权

US4478635A N-Arylsulfonyl-N'-pyrimidinylureas 失效
标题翻译： N-芳基磺酰基-N'-嘧啶基脲
公开(公告)号：US4478635A
公开(公告)日：1984-10-23
申请号：US455175
申请日：1983-01-03
申请人： Willy Meyer , Karl Gass , Werner Topfl , Rolf Schurter , Georg Pissiotas
发明人： Willy Meyer , Karl Gass , Werner Topfl , Rolf Schurter , Georg Pissiotas
IPC分类号： A01N47/36 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D251/46 , C07D239/69 , A01N43/54
CPC分类号： C07D239/47 , A01N47/36 , C07D239/48 , C07D239/52 , C07D239/56 , C07D251/46
摘要： The invention relates to N-arylsulfonyl-N'-pyrimidinyl ureas of the general formula ##STR1## and to the salts thereof with amines, alkali metal hydroxides or alkaline earth metal hydroxides or with quaternary ammonium bases. These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.In the formula, R.sub.18 is hydrogen, alkyl or alkoxy, X is an unsubstituted or substituted phenyl radical or an unsubstituted or substituted naphthyl radical, Y is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy, C.sub.1 -C.sub.3 haloalkoxy, C.sub.1 -C.sub.3 alkylthio, C.sub.2 -C.sub.3 alkoxyalkyl, halogen or an unsubstituted amino group and Z is oxygen or sulfur.
摘要翻译：本发明涉及通式为（I）的N-芳基磺酰基-N'-嘧啶基脲，以及其与胺，碱金属氢氧化物或碱土金属氢氧化物或季铵碱的盐。这些化合物具有良好的芽前和芽后选择性除草和生长调节性质。式中，R 18为氢，烷基或烷氧基，X为未取代或取代的苯基或未取代或取代的萘基，Y为C1-C3烷基，C1-C3卤代烷基，C1-C3烷氧基，C1-C3卤代烷氧基，C1-C3烷硫基， C 2 -C 3烷氧基烷基，卤素或未取代的氨基，Z是氧或硫。

70. 发明授权

US4443243A N-Phenylsulfonyl-N-triazinylureas 失效
标题翻译： N-苯基磺酰基-N-三嗪基脲
公开(公告)号：US4443243A
公开(公告)日：1984-04-17
申请号：US396959
申请日：1982-07-09
申请人： Werner Fory , Karl Gass , Willy Meyer , Rolf Schurter
发明人： Werner Fory , Karl Gass , Willy Meyer , Rolf Schurter
IPC分类号： A01N47/24 , A01N47/08 , A01N47/22 , A01N47/36 , C07C303/36 , C07C311/16 , C07C311/53 , C07C323/67 , C07D239/42 , C07D239/46 , C07D239/47 , C07D239/48 , C07D239/52 , C07D239/56 , C07D251/16 , C07D251/22 , C07D251/40 , C07D251/46 , C07D251/52 , C07D521/00 , C07D251/44 , A01N43/66 , C07D251/42
CPC分类号： C07C311/65 , A01N47/36 , C07D239/47 , C07D239/48 , C07D521/00
摘要： N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the general formula ##STR1## and the salts of these compounds with amines, with alkali or alkaline-earth metal bases or with quaternary ammonium bases, have good pre- and post-emergence selective, herbicidal and growth-regulating properties.The symbols in this formula are as follows:A is a C.sub.3 -C.sub.6 -alkynyl group,E is the methine group or nitrogen,X is oxygen, sulfur or a sulfinyl or sulfonyl bridge,Z is oxygen or sulfur,m is the number one or two,R.sub.1 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl or C.sub.2 -C.sub.5 -alkenyl or a group --Y--R.sub.5,R.sub.2 is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.1 -C.sub.4 -haloalkyl, or a group --Y--R.sub.5, --COOR.sub.6, --NO.sub.2 or --CO--NR.sub.7 --R.sub.8,R.sub.3 and R.sub.4 independently of one another are each hydrogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -haloalkoxy, halogen or alkoxyalkyl having at most 4 carbon atoms,R.sub.5 and R.sub.6 are each C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl,R.sub.7 and R.sub.8 independently of one another are each hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.2 -C.sub.5 -alkenyl or C.sub.2 -C.sub.6 -alkynyl, andY is oxygen, sulfur or a sulfinyl or sulfonyl bridge.
摘要翻译：具有通式（I）的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲和这些化合物与胺与碱金属或碱土金属碱或季铵碱的盐具有良好的前和后芽后选择性，除草和生长调节性质。该式中的符号如下：A是C 3 -C 6炔基，E是次甲基或氮，X是氧，硫或亚磺酰基或磺酰基桥，Z是氧或硫，m是第一个或两个，R 1是氢，卤素，C 1 -C 5 - 烷基或C 2 -C 5 - 烯基或基团-Y-R 5，R 2是氢，卤素，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 1 -C 4 - 卤代烷基或基团-Y-R 5，-COOR 6，-NO 2或-CO-NR 7 -R 8，R 3和R 4彼此独立地为氢，C 1 -C 4 - 烷基，C 1 -C 4 - 烷氧基，C 1 -C 4 - 烷硫基，C 1 -C 4卤代烷基，C 1 -C 4卤代烷氧基，卤素或至多4个碳原子的烷氧基烷基，R 5和R 6各自为C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6炔基，R 7和R 8 各自独立地为氢，C 1 -C 5 - 烷基，C 2 -C 5 - 烯基或C 2 -C 6 - 炔基，Y为氧，硫或亚磺酰基或磺酰基桥。

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