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    • 1. 发明授权
    • Herbicidal and growth regulator phosphorus-containing
N-phenylsulfonyl-N'-pyrimidinylureas and
N-phenylsulfonyl-N'-triazinylureas
    • 除草生长调节剂含磷的N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N'-三嗪基脲
    • US4559078A
    • 1985-12-17
    • US562659
    • 1983-12-19
    • Ludwig MaierWilly MeyerKonrad OertleAchim RoloffWerner Topfl
    • Ludwig MaierWilly MeyerKonrad OertleAchim RoloffWerner Topfl
    • A01N57/16A01N57/08A01N57/24C07D521/00C07F9/30C07F9/32C07F9/38C07F9/40C07F9/53C07F9/6512C07F9/6521C07F9/65
    • C07D521/00A01N57/08C07F9/304C07F9/3229C07F9/3808C07F9/3834C07F9/4006C07F9/4015C07F9/4021C07F9/4056C07F9/5325C07F9/65127C07F9/65217
    • Phosphorus-containing N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N'-triazinylureas of the formula ##STR1## and the salts of these compounds with amines, alkali or alkaline earth metal bases or quaternary ammonium bases have good pre-emergence and post-emergence selective herbicidal and growth-regulating properties.In this formula, X is a group ##STR2## Y is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, trifluoromethyl, C.sub.2 -C.sub.5, alkenyl, C.sub.2 -C.sub.5 -alkynyl, nitro, --COOR.sup.6 or --Q--R.sup.6, Z is nitrogen or the methine group, E is oxygen or sulfur, R.sup.1 is hydrogen or C.sub.1 -C.sub.5 -alkyl and R.sup.2 and R.sup.3 independently of one another are C.sub.1 -C.sub.3 -alkyl, C.sub.1 -C.sub.3 -alkoxy, C.sub.1 -C.sub.3 -halogenoalkyl, C.sub.1 -C.sub.3 -halogenoalkoxy, cyclopropyl, amino, methylamino or dimethylamino, and A is oxygen, sulfur, C.sub.1 -C.sub.5 -alkylene, C.sub.2 -C.sub.5 -alkenylene, C.sub.1 -C.sub.5 -halogenoalkylene or --NR.sup.7 --(CH.sub.2).sub.m --; --CH.sub.2 --NH--(CH.sub.2).sub.m --; --(CH.sub.2).sub.m --NR.sup.7 -- or --O--(CH.sub.2).sub.p --, --S--(CH.sub.2).sub.p --, --(CH.sub.2).sub.p --O-- or --(CH.sub.2).sub.p --S--, n is zero or one, G is oxygen or sulfur, R.sup.4 is C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -halogenoalkoxy, C.sub.1 -C.sub.5 -alkylthio, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -halogenoalkyl, phenyl or hydroxyl, R.sup.5 is hydrogen, C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -halogenoalkoxy, C.sub.1 -C.sub.5 -alkylthio, C.sub.1 -C.sub.5 -alkyl or hydroxyl, R.sup.6 is C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -halogenoalkyl or C.sub.2 -C.sub.6 -alkoxyalkyl, Q is oxygen, sulfur, --SO-- or --SO.sub.2 --, R.sup.7 is hydrogen, C.sub.1 -C.sub.5 -alkyl, phenyl, benzyl or phenyl which is substituted by C.sub.1 -C.sub.5 -alkyl, halogen or nitro, m is a number from zero to three, p is a number from zero to two and r is one or two.
    • 具有式“IMAGE”的含磷N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N'-三嗪基脲和这些化合物与胺,碱金属或碱土金属碱或季铵碱的盐具有良好的出苗前 和出苗后选择性除草和生长调节性质。 在该式中,X是基团Y是氢,卤素,C 1 -C 5 - 烷基,三氟甲基,C 2 -C 5,烯基,C 2 -C 5炔基,硝基,-COOR 6或-Q-R 6,Z是氮 或次甲基,E是氧或硫,R1是氢或C1-C5-烷基,R2和R3彼此独立地是C1-C3-烷基,C1-C3-烷氧基,C1-C3-卤代烷基,C1-C3 - 卤代烷氧基,环丙基,氨基,甲基氨基或二甲基氨基,A是氧,硫,C1-C5-亚烷基,C2-C5-亚烯基,C1-C5-卤代亚烷基或-NR7-(CH2)m- -CH 2 -NH-(CH 2)m - ; - (CH 2)m -NR 7 - 或-O-(CH 2)p - , - S-(CH 2)p - , - (CH 2)p O-或 - (CH 2)p -S-,n为0或1,G为氧 或硫,R4是C1-C5-烷氧基,C1-C5-卤代烷氧基,C1-C5-烷硫基,C1-C5-烷基,C1-C5-卤代烷基,苯基或羟基,R5是氢,C1-C5-烷氧基,C1 -C 5 - 卤代烷氧基,C 1 -C 5 - 烷硫基,C 1 -C 5 - 烷基或羟基,R 6是C 1 -C 5 - 烷基,C 1 -C 5 - 卤代烷基或C 2 -C 6 - 烷氧基烷基,Q是氧,硫,-SO-或 - SO 2 - ,R 7为氢,C 1 -C 5 - 烷基,苯基,苄基或被C 1 -C 5 - 烷基,卤素或硝基取代的苯基,m为0至3的数,p为0至2的数, r是一两个。
    • 2. 发明授权
    • Phosphorous-containing phenylsulfonamides
    • 含磷苯基磺酰胺
    • US4677217A
    • 1987-06-30
    • US784274
    • 1985-10-04
    • Ludwig MaierWilly MeyerKonrad OertleAchim RoloffWerner Topfl
    • Ludwig MaierWilly MeyerKonrad OertleAchim RoloffWerner Topfl
    • A01N57/16A01N57/08A01N57/24C07D521/00C07F9/30C07F9/32C07F9/38C07F9/40C07F9/53C07F9/6512C07F9/6521
    • C07D521/00A01N57/08C07F9/304C07F9/3229C07F9/3808C07F9/3834C07F9/4006C07F9/4015C07F9/4021C07F9/4056C07F9/5325C07F9/65127C07F9/65217
    • Phenylsulfonamides of the formula ##STR1## in which X is a group ##STR2## Y is hydrogen, halogen, C.sub.1 -C.sub.5 -alkyl, trifluoromethyl, C.sub.2 -C.sub.5 -alkenyl, C.sub.2 -C.sub.5 -alkynyl, nitro, --COOR.sup.6 or --Q--R.sup.6, A is oxygen, sulfur, a direct bond, C.sub.1 -C.sub.5 -alkylene, C.sub.2 -C.sub.5 -alkenylene, C.sub.1 -C.sub.5 -halogenoalkylene or --NR.sup.7 --(CH.sub.2).sub.m --; --CH.sub.2 --NH--(CH.sub.2).sub.m ; --(CH.sub.2).sub.m --NR.sup.7 -- or --O--(CH.sub.2).sub.p --, --S--(CH.sub.2).sub.p --, --(CH.sub.2).sub.p --O-- or --(CH.sub.2).sub.p --S--, n is zero or one, G is oxygen or sulfur, R.sup.4 is C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -halogenoalkoxy, C.sub.1 -C.sub.5 -alkylthio, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -halogenoalkyl, phenyl or hydroxyl, R.sup.5 is hydrogen, C.sub.1 -C.sub.5 -alkoxy, C.sub.1 -C.sub.5 -halogenoalkoxy, C.sub.1 -C.sub.5 -alkylthio, C.sub.1 -C.sub. 5 -alkyl or hydroxyl, R.sup.6 is hydrogen, C.sub.1 -C.sub.5 -alkyl, C.sub.1 -C.sub.5 -halogenoalkyl or C.sub.2 -C.sub.6 -alkoxyalkyl, Q is oxygen, sulfur, --SO-- or --SO.sub.2 --, R.sup.7 is hydrogen, C.sub.1 -C.sub.5 -alkyl, phenyl, benzyl or phenyl which is substituted by C.sub.1 -C.sub.5 -alkyl, halogen, or nitro, m is a number from zero to three, p is a number from zero to two and r is one or two are useful as intermediates for phosphorous-containing N-phenylsulfonyl-N'-pyrimdinylurea and N-phenylsulfonyl-N'-triazinylurea herbicides.
    • 其中X是基团Y的式“IMAGE”的苯磺酰胺是氢,卤素,C 1 -C 5 - 烷基,三氟甲基,C 2 -C 5 - 烯基,C 2 -C 5炔基,硝基,-COOR 6或-Q- R6,A是氧,硫,直接键,C1-C5-亚烷基,C2-C5-亚烯基,C1-C5-卤代亚烷基或-NR7-(CH2)m-; -CH 2 -NH-(CH 2)m; - (CH 2)m -NR 7 - 或-O-(CH 2)p - , - S-(CH 2)p - , - (CH 2)p O-或 - (CH 2)p -S-,n为0或1,G为氧 或硫,R4是C1-C5-烷氧基,C1-C5-卤代烷氧基,C1-C5-烷硫基,C1-C5-烷基,C1-C5-卤代烷基,苯基或羟基,R5是氢,C1-C5-烷氧基,C1 -C5-卤代烷氧基,C1-C5-烷硫基,C1-C5-烷基或羟基,R6是氢,C1-C5-烷基,C1-C5-卤代烷基或C2-C6-烷氧基烷基,Q是氧,硫,-SO - 或-SO 2 - ,R 7是氢,C 1 -C 5 - 烷基,苯基,苄基或被C 1 -C 5 - 烷基,卤素或硝基取代的苯基,m是0至3的数,p是 0至2,r是1或2个可用作含磷的N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N'-三嗪基脲除草剂的中间体。
    • 5. 发明授权
    • N-phenylsulfonyl-N'-triazinylureas
    • N-苯基磺酰基-N'-三嗪基脲
    • US4671819A
    • 1987-06-09
    • US810010
    • 1985-12-17
    • Willy MeyerKonrad Oertle
    • Willy MeyerKonrad Oertle
    • C07D249/16A01N43/70A01N47/36C07C20060101C07C67/00C07C301/00C07C309/86C07C311/15C07C311/16C07C311/17C07C311/29C07C311/39C07C311/53C07C311/65C07C325/00C07C331/16C07C331/32C07D239/42C07D239/46C07D239/47C07D239/48C07D239/52C07D239/56C07D239/69C07D251/16C07D251/18C07D251/22C07D251/46C07D251/52C07D521/00
    • C07C309/86A01N47/36C07C311/65C07D521/00
    • N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## wherein A is 3,3,3-trifluoropropyl or 3,3-difluorobutyl,R.sup.1 is hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, --CO--R.sup.6, --NR.sup.7 R.sup.8, --CO--NR.sup.9 R.sup.10 or --SO.sub.2 --NR.sup.11 R.sup.12,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl or C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.3 and R.sup.4 independently of one another are each hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.1 -C.sub.4 -alkoxy or --NR.sup.12 R.sup.13,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sup.6 is C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.2 -C.sub.6 -alkoxyalkoxy, hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -haloalkyl,R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl,E is nitrogen, andZ is oxygen or sulfur;and also the salts of these compounds.
    • 式I的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲其中A是3,3,3-三氟丙基或3,3-二氟丁基,R 1是氢,卤素,硝基,氰基,C 1 C 1-4烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4 - 烷基亚磺酰基,C 1 -C 4烷基磺酰基,-CO-R 6,-NR 7 R 8,-CO-NR 9 R 10或-SO 2 -NR 11 R 12,R 2是氢,卤素,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基,R 3和R 4彼此独立地各自为氢, 卤素,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 2 -C 4卤代烷氧基,C 1 -C 4烷硫基,C 1 -C 4卤代烷硫基,C 2 -C 4烷氧基烷基,C 1 -C 4烷氧基或-NR 12 R 13, ,C 1 -C 4烷基或C 1 -C 4 - 烷氧基,R 6是C 1 -C 4 - 烷氧基,C 1 -C 4卤代烷氧基,C 1 -C 4烷硫基,C 2 -C 6烷氧基烷氧基,氢,C 1 -C 4烷基或C 1 -C 4 卤代烷基,R7,R8,R9,R10,R11,R12和R13各自独立地为氢或C1-C4烷基,E为氮,Z为氧或硫; 以及这些化合物的盐。
    • 6. 发明授权
    • Phenylsulfonyl isocyanates and thioisocyanates
    • 苯磺酰基异氰酸酯和硫代异氰酸酯
    • US4952726A
    • 1990-08-28
    • US440004
    • 1989-11-21
    • Willy MeyerKonrad Oertle
    • Willy MeyerKonrad Oertle
    • C07D249/16A01N43/70A01N47/36C07C20060101C07C67/00C07C301/00C07C309/86C07C311/15C07C311/16C07C311/17C07C311/29C07C311/39C07C311/53C07C311/65C07C325/00C07C331/16C07C331/32C07D239/42C07D239/46C07D239/47C07D239/48C07D239/52C07D239/56C07D239/69C07D251/16C07D251/18C07D251/22C07D251/46C07D251/52C07D521/00
    • C07C309/86A01N47/36C07C311/65C07D521/00
    • N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## wherein A is 3,3,3-trifluoropropyl or 3,3-difluorobutyl,R.sup.1 is hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfonyl, C.sub.1 -C.sub.4 -alkylsulfonyl, --CO--R.sup.6, --NR.sup.7 R.sup.8, --CO--NR.sup.9 R.sup.10 or --SO.sub.2 --NR.sup.11 R.sup.12,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkysulfonyl or C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.3 and R.sup.4 independently of one another are each hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.1 -C.sub.4 -alkoxy or --NR.sup.13 R.sup.13,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sup.6 is C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.2 -C.sub.6 -alkoxyalkoxy, hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -haloalkyl,R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl,E is nitrogen or the methine bridge, andZ is oxygen or sulfur;and also the salts of these compounds.
    • 式I的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲其中A是3,3,3-三氟丙基或3,3-二氟丁基,R 1是氢,卤素,硝基,氰基,C 1 C 1-4烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4 - 烷基亚磺酰基,C 1 -C 4烷基磺酰基,-CO-R 6,-NR 7 R 8,-CO-NR 9 R 10或-SO 2 -NR 11 R 12,R 2是氢,卤素,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基,R 3和R 4彼此独立地各自为氢, 卤素,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 2 -C 4卤代烷氧基,C 1 -C 4烷硫基,C 1 -C 4卤代烷硫基,C 2 -C 4烷氧基烷基,C 1 -C 4烷氧基或-NR 12 R 13, ,C 1 -C 4烷基或C 1 -C 4 - 烷氧基,R 6是C 1 -C 4 - 烷氧基,C 1 -C 4卤代烷氧基,C 1 -C 4烷硫基,C 2 -C 6烷氧基烷氧基,氢,C 1 -C 4烷基或C 1 -C 4 卤代烷基,R 7,R 8,R 9,R 10,R 11,R 12和R 13各自独立地为氢或C 1 -C 4烷基,E为氮或次甲基桥,Z为氧或硫; 以及这些化合物的盐。
    • 7. 发明授权
    • Certain fluoroalkylphenylsulfonamides
    • 某些氟代烷基苯基磺酰胺
    • US4908467A
    • 1990-03-13
    • US179339
    • 1988-04-08
    • Willy MeyerKonrad Oertle
    • Willy MeyerKonrad Oertle
    • C07D249/16A01N43/70A01N47/36C07C20060101C07C67/00C07C301/00C07C309/86C07C311/15C07C311/16C07C311/17C07C311/29C07C311/39C07C311/53C07C311/65C07C325/00C07C331/16C07C331/32C07D239/42C07D239/46C07D239/47C07D239/48C07D239/52C07D239/56C07D239/69C07D251/16C07D251/18C07D251/22C07D251/46C07D251/52C07D521/00
    • C07C309/86A01N47/36C07C311/65C07D521/00
    • N-Phenylsulfonyl-B'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## wherein A is 3,3,3-trifluoropropyl or 3,3-difluorobutyl,R.sup.1 is hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, --CO--R.sup.6, --NR.sup.7 R.sup.8, --CO--NR.sup.9 R.sup.10 or --SO.sub.2 --NR.sup.11 R.sup.12,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl or C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.3 and R.sup.4 independently of one another are each hydrogen, halogen C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.1 -C.sub.4 -alkoxy or --NR.sup.12 R.sup.13,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sup.6 is C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.2 -C.sub.6 -alkoxyalkoxy, hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -haloalkyl,R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl,E is nitrogen or the methine bridge, andZ is oxygen or sulfur;and also the salts of these compounds.
    • 式I的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲其中A是3,3,3-三氟丙基或3,3-二氟丁基,R 1是氢,卤素,硝基,氰基,C 1 C 1-4烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4 - 烷基亚磺酰基,C 1 -C 4烷基磺酰基,-CO-R 6,-NR 7 R 8,-CO-NR 9 R 10或-SO 2 -NR 11 R 12,R 2是氢,卤素,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基,R 3和R 4彼此独立地各自为氢, 卤素,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 2 -C 4卤代烷氧基,C 1 -C 4烷硫基,C 1 -C 4卤代烷硫基,C 2 -C 4烷氧基烷基,C 1 -C 4烷氧基或-NR 12 R 13, ,C 1 -C 4烷基或C 1 -C 4 - 烷氧基,R 6是C 1 -C 4 - 烷氧基,C 1 -C 4卤代烷氧基,C 1 -C 4 - 烷硫基,C 2 -C 6 - 烷氧基烷氧基,氢,C 1 -C 4烷基或C 1 -C 4 卤代烷基,R 7,R 8,R 9,R 10,R 11,R 12和R 13各自独立地为氢或C 1 -C 4烷基,E为氮或次甲基桥,Z为氧或硫; 以及这些化合物的盐。
    • 8. 发明授权
    • N-phenylsulfonyl-N'-triazinylureas
    • N-苯基磺酰基-N'-三嗪基脲
    • US4780125A
    • 1988-10-25
    • US525366
    • 1983-08-22
    • Willy MeyerDieter ReinehrKonrad OertleRolf Schurter
    • Willy MeyerDieter ReinehrKonrad OertleRolf Schurter
    • B01J31/24A01N47/36A01P13/00C07B61/00C07C303/22C07C309/29C07C309/30C07C309/44C07C309/86C07C309/87C07C311/15C07C311/16C07C311/29C07C311/53C07C311/54C07C311/58C07C311/65C07C317/10C07D239/42C07D239/46C07D239/47C07D239/52C07D239/69C07D251/16C07D251/42C07D251/46C07D251/52C07D521/00A01N43/66
    • C07C311/65A01N47/36C07C309/00C07D239/47C07D521/00
    • The invention relates to N-phenylsulfonyl-N'-pyrimidinylureas and N-phenylsulfonyl-N-triazinylureas of the general formula ##STR1## wherein R.sub.1 is hydrogen, halogen, nitro, amino, C.sub.1 -C.sub.5 alkyl, C.sub.1 -C.sub.4 haloalkyl or a --Q--R.sub.7, --CO--OR.sub.8 or --(CO).sub.n --NR.sub.9 R.sub.10 radical,R.sub.2 is hydrogen, C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.1 -C.sub.4 alkylthio, C.sub.1 -C.sub.4 haloalkyl, C.sub.1 -C.sub.4 haloalkoxy, halogen or alkoxyalkyl containing not more than 4 carbon atoms,R.sub.3 is C.sub.2 -C.sub.10 alkenyl which is substituted by one or more fluorine or bromine atoms or by one or more hydroxyl, cyano, nitro, --(Y).sub.m --CO--(Z).sub.n --R.sub.8, --SO.sub.2 --NR.sub.11 R.sub.12, --S(O).sub.p --C.sub.1 --C.sub.3 haloalkyl or --S(O).sub.n --C.sub.1 -C.sub.3 alkyl groups and which may additionally be substituted by one or more chlorine atoms,R.sub.4 is C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.3 haloalkoxy, R.sub.5 is hydrogen, halogen, --NR.sub.13 R.sub.14, C.sub.1 -C.sub.3 alkyl, C.sub.1 -C.sub.3 haloalkyl, C.sub.1 -C.sub.3 alkoxy or C.sub.1 -C.sub.2 haloalkoxy,R.sub.6 is hydrogen, C.sub.1 -C.sub.3 alkyl or C.sub.1 -C.sub.3 alkoxy,X is oxygen or sulfur, andE is nitrogen or the methine group, andR.sub.7 is C.sub.1 -C.sub.4 alkyl which is substituted by halogen or C.sub.1 -C.sub.3 alkoxy or is C.sub.3 -C.sub.5 alkenyl,R.sub.8 is C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 haloalkyl or C.sub.2 -C.sub.6 alkoxyalkyl,R.sub.9, R.sub.10, R.sub.11, R.sub.12, R.sub.13 and R.sub.14, each independently of the other, are hydrogen or C.sub.1 -C.sub.3 alkyl,Q is oxygen, sulfur, the sulfinyl or sulfonyl bridge,Y is oxygen, sulfur or --NR.sub.16 --, wherein R.sub.16 is hydrogen or C.sub.1 -C.sub.3 alkyl,Z is oxygen, sulfur or --NR.sub.17 --, wherein R.sub.17 is hydrogen or C.sub.1 -C.sub.3 alkyl,m and n are each 0 to 1, andp is 0, 1 or 2, and to the salts of these compounds with amines, alkali metal bases or alkaline earth metal bases.These compounds have good pre- and postemergence selective herbicidal and growth regulating properties.
    • 本发明涉及通式为(I)的N-苯基磺酰基-N'-嘧啶基脲和N-苯基磺酰基-N-三嗪基脲,其中R 1是氢,卤素,硝基,氨基,C 1 -C 5烷基,C 1 -C 4卤代烷基或 -Q-R7,-CO-OR8或 - (CO)n-NR9R10基,R2是氢,C1-C4烷基,C1-C4烷氧基,C1-C4烷硫基,C1-C4卤代烷基,C1-C4卤代烷氧基,卤素或不大于 4个碳原子,R 3是被一个或多个氟或溴原子或一个或多个羟基,氰基,硝基, - (Y)m -CO-(Z)n -R 8,-SO 2 -NR 11 R 12取代的C 2 -C 10链烯基 ,-S(O)p-C 1 -C 3卤代烷基或-S(O)n -C 1 -C 3烷基,并且其可以另外被一个或多个氯原子取代,R 4是C 1 -C 3烷基,C 1 -C 3卤代烷基,C 1 -C 3烷氧基或 C1-C3卤代烷氧基,R5是氢,卤素,-NR13R14,C1-C3烷基,C1-C3卤代烷基,C1-C3烷氧基或C1-C2卤代烷氧基,R6是氢,C1-C3烷基或C1-C3烷氧基,X是氧或硫,E是 氮或次甲基,并且R 7为被所取代的C 1 -C 4烷基 卤素或C 1 -C 3烷氧基或C 3 -C 5链烯基,R 8为C 1 -C 4烷基,C 1 -C 4卤代烷基或C 2 -C 6烷氧基烷基,R 9,R 10,R 11,R 12,R 13和R 14各自独立地为氢或C 1 -C 3烷基, Q是氧,硫,亚磺酰基或磺酰基桥,Y是氧,硫或-NR 16 - ,其中R 16是氢或C 1 -C 3烷基,Z是氧,硫或-NR 17 - ,其中R 17是氢或C 1 -C 3烷基, m和n各自为0至1,p为0,1或2,以及这些化合物与胺,碱金属碱或碱土金属碱的盐。 这些化合物具有良好的芽前和芽后选择性除草和生长调节性质。
    • 9. 发明授权
    • N-phenylsulfonyl-N'-pyrimidinyl-ureas
    • N-苯基磺酰基-N'-嘧啶基 - 脲
    • US4759793A
    • 1988-07-26
    • US30529
    • 1987-03-27
    • Willy MeyerKonrad Oertle
    • Willy MeyerKonrad Oertle
    • C07D249/16A01N43/70A01N47/36C07C20060101C07C67/00C07C301/00C07C309/86C07C311/15C07C311/16C07C311/17C07C311/29C07C311/39C07C311/53C07C311/65C07C325/00C07C331/16C07C331/32C07D239/42C07D239/46C07D239/47C07D239/48C07D239/52C07D239/56C07D239/69C07D251/16C07D251/18C07D251/22C07D251/46C07D251/52C07D521/00A01N43/54
    • C07C309/86A01N47/36C07C311/65C07D521/00
    • N-Phenylsulfonyl-N'-pyrimidinyl- and -triazinylureas of the formula I ##STR1## wherein A is 3,3,3-trifluoropropyl or 3,3-difluorobutyl,R.sup.1 is hydrogen, halogen, nitro, cyano, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl, C.sub.1 -C.sub.4 -alkylsulfonyl, --CO-R.sup.6, --NR.sup.7 R.sup.8, --CO--NR.sup.9 R.sup.10 or --SO.sub.2 --NR.sup.11 R.sup.12,R.sup.2 is hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -alkylsulfinyl or C.sub.1 -C.sub.4 -alkylsulfonyl,R.sup.3 and R.sup.4 independently of one another are each hydrogen, halogen, C.sub.1 -C.sub.4 -alkyl, C.sub.1 -C.sub.4 -haloalkyl, C.sub.2 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.1 -C.sub.4 -haloalkylthio, C.sub.2 -C.sub.4 -alkoxyalkyl, C.sub.1 -C.sub.4 -alkoxy or --NR.sup.12 R.sup.13,R.sup.5 is hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy,R.sup.6 is C.sub.1 -C.sub.4 -alkoxy, C.sub.1 -C.sub.4 -haloalkoxy, C.sub.1 -C.sub.4 -alkylthio, C.sub.2 -C.sub.6 -alkoxyalkoxy, hydrogen, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -haloalkyl,R.sup.7, R.sup.8, R.sup.9, R.sup.10, R.sup.11, R.sup.12 and R.sup.13 independently of one another are each hydrogen or C.sub.1 -C.sub.4 -alkyl,E is nitrogen or the methine bridge, andZ is oxygen or sulfur;and also the salts of these compounds.
    • 式I的N-苯基磺酰基-N'-嘧啶基 - 和 - 三嗪基脲其中A是3,3,3-三氟丙基或3,3-二氟丁基,R 1是氢,卤素,硝基,氰基,C 1 C 1-4烷基,C 1 -C 4 - 卤代烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4 - 烷基亚磺酰基,C 1 -C 4烷基磺酰基,-CO-R 6,-NR 7 R 8,-CO-NR 9 R 10或-SO 2 -NR 11 R 12,R 2是氢,卤素,C 1 -C 4 - 烷基,C 1 -C 4 - 烷氧基,C 1 -C 4 - 烷硫基,C 1 -C 4烷基亚磺酰基或C 1 -C 4烷基磺酰基,R 3和R 4彼此独立地各自为氢, 卤素,C 1 -C 4烷基,C 1 -C 4卤代烷基,C 2 -C 4卤代烷氧基,C 1 -C 4烷硫基,C 1 -C 4卤代烷硫基,C 2 -C 4烷氧基烷基,C 1 -C 4烷氧基或-NR 12 R 13, ,C 1 -C 4烷基或C 1 -C 4 - 烷氧基,R 6是C 1 -C 4 - 烷氧基,C 1 -C 4卤代烷氧基,C 1 -C 4 - 烷硫基,C 2 -C 6 - 烷氧基烷氧基,氢,C 1 -C 4烷基或C 1 -C 4 卤代烷基,R 7,R 8,R 9,R 10,R 11,R 12和R 13各自独立地为氢或C 1 -C 4烷基,E为氮或次甲基桥,Z为氧或硫; 以及这些化合物的盐。