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1. 发明公开

US20240306647A1 COMPOSITIONS COMPRISING RECOMBIANANT BACILLUS CELLS AND AN INSECTICIDE 审中-公开
公开(公告)号：US20240306647A1
公开(公告)日：2024-09-19
申请号：US18400850
申请日：2023-12-29
申请人： BASF CORPORATION
发明人： Damian Curtis , Brian Thompson
IPC分类号： A01N63/23 , A01N37/40 , A01N37/52 , A01N41/10 , A01N43/12 , A01N43/24 , A01N43/40 , A01N43/56 , A01N43/653 , A01N43/713 , A01N47/06 , A01N47/22 , A01N47/24 , A01N47/34 , A01N51/00 , A01N55/00 , A01N57/08 , A01N57/14 , A01N57/28 , A01N63/50
CPC分类号： A01N63/23 , A01N37/40 , A01N37/52 , A01N41/10 , A01N43/12 , A01N43/24 , A01N43/40 , A01N43/56 , A01N43/653 , A01N43/713 , A01N47/06 , A01N47/22 , A01N47/24 , A01N47/34 , A01N57/08 , A01N57/14 , A01N57/28 , A01N63/50 , A01N51/00 , A01N55/00
摘要： The present invention relates to a composition comprising a) recombinant exosporium-producing Bacillus cells that express a fusion protein comprising: (i) at least one plant growth stimulating protein or peptide and (ii) a targeting sequence that localizes the fusion protein to the exosporium of the Bacillus cells; and b) at least one particular insecticide disclosed herein in a synergistically effective amount. Furthermore, the present invention relates to the use of this composition as well as a method for enhancing plant growth, promoting plant health, and/or reducing overall damage of plants and plant parts.

2. 发明申请

US20100234323A1 Antimicrobial Acids and Salts 审中-公开
标题翻译：抗菌酸和盐
公开(公告)号：US20100234323A1
公开(公告)日：2010-09-16
申请号：US12227674
申请日：2007-06-04
申请人： Werner Hölzl , Andrea Preuss
发明人： Werner Hölzl , Andrea Preuss
IPC分类号： A61K31/695 , C07F9/02
CPC分类号： A01N57/04 , A01N37/04 , A01N41/04 , A01N55/00 , A01N57/08 , C08L83/06
摘要： The invention relates to novel acidic siloxane derivatives, the use, methods of use or processes making use of siloxane derivatives of this type, especially to achieve an anti-microbial, preservative and/or antiadhesive effect, for the protection of articles and/or materials, and a process for the manufacture of the novel compounds. The siloxane acids (which may also be in salt form) have the formula (I), formula (II) and/or formula (III), wherein the symbols have the meanings given in the specification.
摘要翻译：本发明涉及新的酸性硅氧烷衍生物，使用，使用方法或使用这种类型的硅氧烷衍生物的方法，特别是为了获得用于保护制品和/或材料的抗微生物，防腐和/或抗粘附作用，以及制备新型化合物的方法。硅氧烷酸（其也可以是盐形式）具有式（I），式（II）和/或式（III）），其中符号具有说明书中给出的含义。

3. 发明授权

US4479946A Phosphorus esters of amidoximes, and compositions for and methods of controlling insects using them 失效
标题翻译：酰胺肟的磷酯，以及使用它们的昆虫的组合物和控制方法
公开(公告)号：US4479946A
公开(公告)日：1984-10-30
申请号：US378852
申请日：1982-06-17
申请人： Leonard E. Hodakowski , Dean F. Bushey
发明人： Leonard E. Hodakowski , Dean F. Bushey
IPC分类号： A01N57/08 , C07F9/6536 , A01N57/32 , C07F9/65
CPC分类号： C07F9/6536 , A01N57/08
摘要： Novel phosphorus esters of amidoximes and methods of preparing same. This invention is also directed to pesticidal compositions comprising an acceptable carrier and a pesticidally effective amount of a compound of this invention, as well as to a method of controlling pests which comprises subjecting the pests to a pesticidally effective amount of a compound of this invention.
摘要翻译：新型酰氨基磷酸酯及其制备方法。本发明还涉及包含可接受载体和杀虫有效量的本发明化合物的杀虫组合物，以及一种防治害虫的方法，其包括使害虫接种杀虫有效量的本发明化合物。

4. 发明授权

US4461764A Pesticidal phosphoryl- and phosphinyl-thioalkyl cyclic sufones 失效
标题翻译：杀虫磷酰基和氧膦基 - 硫代烷基环状磺酸酯
公开(公告)号：US4461764A
公开(公告)日：1984-07-24
申请号：US421178
申请日：1982-09-22
申请人： Philip S. Magee
发明人： Philip S. Magee
IPC分类号： A01N57/08 , C07D333/48 , C07F9/24 , C07F9/40 , C07F9/42 , C07F9/6553 , A01N57/32
CPC分类号： C07D333/48 , A01N57/08 , C07F9/2408 , C07F9/4075 , C07F9/425 , C07F9/655345
摘要： Compounds of the formula: ##STR1## wherein X is sulfur or oxygen; R.sub.1 is lower alkyl; R.sub.2 is lower alkyl, lower straight chain alkoxy, lower alkylthio, phenyl or the group --NR.sub.3 R.sub.4 where R.sub.3 and R.sub.4 are independently hydrogen or lower alkyl, provided that when X is oxygen, R.sub.2 is not phenyl, are pesticidal, exhibiting activity against pests such as plant fungal diseases and, in many cases, insects.
摘要翻译：下式的化合物：其中X是硫或氧; R1是低级烷基; R2是低级烷基，低级直链烷氧基，低级烷硫基，苯基或-NR3R4基团，其中R3和R4独立地是氢或低级烷基，条件是当X是氧时，R 2不是苯基，是杀虫剂，表现出对害虫的活性，作为植物真菌病，在许多情况下是昆虫。

5. 发明授权

US4357327A Heterocyclic substituted triazolyl phosphorous compounds and their use as insecticides 失效
标题翻译：杂环取代三唑基磷化合物及其作为杀虫剂的用途
公开(公告)号：US4357327A
公开(公告)日：1982-11-02
申请号：US260533
申请日：1981-05-04
申请人： Chester E. Pawloski
发明人： Chester E. Pawloski
IPC分类号： A01N57/08 , C07D213/77 , C07F9/6518 , C07F9/6558 , C07D237/28 , C07D237/30 , C07D241/40 , A61K31/495
CPC分类号： C07D213/77 , A01N57/08 , C07F9/65185 , C07F9/65583
摘要： Compounds are prepared which correspond to the formula ##STR1## wherein R represents a nitrogen containing heterocyclic radical corresponding to one of the formulae ##STR2## each X independently represents chloro, fluoro, bromo, nitro, alkyl of 1 to 4 carbon atoms, amino, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, cyano, trifluoromethyl, trichloromethyl, phenoxy or substituted phenoxy of the formula ##STR3## wherein each Z independently represents chloro, fluoro, bromo, nitro, cyano, alkoxy of 1 to 4 carbon atoms or alkylthio of 1 to 4 carbon atoms, with the proviso that when either n is 2 or 3, all X groups are sterically compatible with each other and all Z groups are sterically compatible with each other; Y represents oxygen or sulfur; each n can independently represent an integer of from 0 to 3, inclusive; R.sup.1 represents hydrogen, chloro, fluoro, bromo, alkyl of 1 to 4 carbon atoms, cycloalkyl of 3-6 carbon atoms, phenyl, phenylthio, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, thiocyanato, trifluoromethyl, trichloromethyl, amino, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms; R.sup.2 represents methyl, ethyl, propyl or isobutyl and R.sup.3 represents methoxy, ethoxy, propoxy, ethyl, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms or phenyl.
摘要翻译：制备符合下式的化合物：其中R表示与下式之一相对应的含氮杂环基，每个X独立地表示氯，氟，溴，硝基，1至4个碳原子的烷基，氨基，单 - 或二烷基氨基，其中每个烷基独立地含有1至4个碳原子，1至4个碳原子的烷氧基，1至4个碳原子的烷硫基，1至4个碳原子的烷基亚磺酰基 1至4个碳原子的烷基磺酰基，氰基，三氟甲基，三氯甲基，苯氧基或取代的苯氧基，其中每个Z独立地表示氯，氟，溴，硝基，氰基，1-4个碳原子的烷氧基或烷硫基具有1至4个碳原子，条件是当n为2或3时，所有X基彼此在空间上相容，并且所有Z基彼此在空间上相容; Y表示氧或硫; 每个n可以独立地表示0至3的整数，包括0和3; R 1表示氢，氯，氟，溴，1至4个碳原子的烷基，3-6个碳原子的环烷基，苯基，苯硫基，1至4个碳原子的烷氧基，1至4个碳原子的烷硫基，1至 4个碳原子，1至4个碳原子的烷基磺酰基，硫氰酸酯，三氟甲基，三氯甲基，氨基，一或二烷基氨基，其中每个烷基独立地含有1至4个碳原子; R 2表示甲基，乙基，丙基或异丁基，R 3表示甲氧基，乙氧基，丙氧基，乙基，单 - 或二烷基氨基，其中各烷基独立地含有1至4个碳原子，1至4个碳原子的烷硫基或苯基。

6. 发明授权

US4314840A Cyclic acetal-methyl-carbamoyl-methyl esters of phosphonic and phosphoric acids, as herbicides 失效
标题翻译：作为除草剂的膦酸和磷酸的环状缩醛 - 甲基 - 氨基甲酰基 - 甲基酯
公开(公告)号：US4314840A
公开(公告)日：1982-02-09
申请号：US164719
申请日：1980-06-30
申请人： Leonard J. Stach
发明人： Leonard J. Stach
IPC分类号： A01N57/08 , C07D317/28 , C07D319/06 , C07F9/165 , A01N43/24 , A01N43/30 , A01N43/32
CPC分类号： C07D319/06 , A01N57/08 , C07D317/28 , C07F9/1651
摘要： This invention discloses new compounds of the formula ##STR1## wherein X,Y,Z and Q are each independently selected from the group consisting of oxygen and sulfur; R.sup.1 is selected from the group consisting of alkyl, and ##STR2## wherein A may be different at different positions and is selected from the group consisting of alkyl, alkoxy, alkylthio, halogen, nitro and cyano, p is an integer from 0 to 5; R.sup.2 is selected from the group consisting of alkyl, alkoxy, alkylthio, amino, alkylamino, dialkylamino and ##STR3## wherein B may be different at different positions and is selected from the group consisting of alkyl, alkoxy, alkylthio, halogen, nitro and cyano, and q is an integer from 0 to 5; R.sup.3 is selected from the group consisting of hydrogen, alkyl and ##STR4## wherein D may be different at different positions and is selected from the group consisting of alkyl, alkoxy, alkylthio, halogen, nitro and cyano, and r is an integer from 0 to 5; R.sup.4 is selected from the group consisting of hydrogen, alkyl cycloalkyl and ##STR5## wherein E may be different at different positions and is selected from the group consisting of alkyl, alkoxy, alkylthio, halogen, nitro and cyano, and s is an integer from 0 to 5; R.sup.5, R.sup.6, R.sup.7, and R.sup.8 are each independently selected from the group consisting of hydrogen and alkyl; and n is an integer from 0 to 3.Further disclosed are herbicidal and insecticidal compositions utilizing the aforedescribed compounds.
摘要翻译：本发明公开了新的式（Ⅰ）化合物，其中X，Y，Z和Q各自独立地选自氧和硫; R1选自烷基和其中A可以在不同位置不同并且选自烷基，烷氧基，烷硫基，卤素，硝基和氰基，p是0至5的整数 ; R 2选自烷基，烷氧基，烷硫基，氨基，烷基氨基，二烷基氨基和其中B可以在不同位置不同，并且选自烷基，烷氧基，烷硫基，卤素，硝基和氰基 q为0〜5的整数， R 3选自氢，烷基和其中D可以在不同位置不同，并且选自烷基，烷氧基，烷硫基，卤素，硝基和氰基，并且r是0的整数至5; R 4选自氢，烷基环烷基和其中E可以在不同位置不同，并且选自烷基，烷氧基，烷硫基，卤素，硝基和氰基，s是从 0至5; R5，R6，R7和R8各自独立地选自氢和烷基; 并且n为0至3的整数。进一步公开了使用上述化合物的除草和杀虫组合物。

7. 发明授权

US4299772A Xanthenone-yl esters of phosphoric and phosphonic acids 失效
标题翻译：磷酸和膦酸的呫吨酮基酯
公开(公告)号：US4299772A
公开(公告)日：1981-11-10
申请号：US127007
申请日：1980-03-04
申请人： James T. Traxler
发明人： James T. Traxler
IPC分类号： A01N57/16 , A01N57/08 , A01N57/24 , C07D311/86 , C07D335/16 , C07F9/09 , C07F9/24 , C07F9/38 , C07F9/40 , C07F9/655 , C07F9/6553
CPC分类号： C07F9/65522 , A01N57/08 , C07F9/655372
摘要： Disclosed are new compounds of the formula ##STR1## wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of halogen, alkyl, haloalkyl, nitro, alkylsulfinyl, alkylsulfonyl and cyano; k and m are integers from 0 to 3; Q is selected from the group consisting of oxygen and sulfur; Y is selected from the group consisting of oxygen and sulfur R.sup.3 is selected from the group consisting of alkyl and ##STR2## wherein R.sup.5 is selected from the group consisting of halogen, alkyl, haloalkyl, nitro and cyano; n is an integer from 0 to 3; R.sup.4 is selected from the group consisting of alkyl, alkoxy, alkylthio, amino, alkylamino, dialkylamino and ##STR3## wherein R.sup.6 is selected from the group consisting of halogen, alkyl, haloalkyl, nitro, and cyano; p is an integer from 0 to 3; and A and B are each independently selected from the group consisting of oxygen and sulfur, with the proviso that, if R.sup.4 is alkoxy, then one of A and B must be sulfur.Further disclosed is the insecticidal utility of the foregoing compounds.
摘要翻译：公开了式IMA的新化合物，其中R 1和R 2各自独立地选自卤素，烷基，卤代烷基，硝基，烷基亚磺酰基，烷基磺酰基和氰基; k和m是0至3的整数; Q选自氧和硫; Y选自氧和硫。R3选自烷基和卤素，其中R5选自卤素，烷基，卤代烷基，硝基和氰基; n为0〜3的整数。 R 4选自烷基，烷氧基，烷硫基，氨基，烷基氨基，二烷基氨基和其中R 6选自卤素，烷基，卤代烷基，硝基和氰基; p是0至3的整数; 并且A和B各自独立地选自氧和硫，条件是如果R 4是烷氧基，那么A和B之一必须是硫。进一步披露的是上述化合物的杀虫效用。

8. 发明授权

US4259235A Tricyclic nitrogenous compounds having string plant growth regulating properties 失效
标题翻译：具有串联植物生长调节性质的三环含氮化合物
公开(公告)号：US4259235A
公开(公告)日：1981-03-31
申请号：US941010
申请日：1978-09-11
申请人： Rolf Platz , Werner Fuchs , Norbert Rieber , Johann Jung , Bruno Wuerzer
发明人： Rolf Platz , Werner Fuchs , Norbert Rieber , Johann Jung , Bruno Wuerzer
IPC分类号： A01N43/02 , A01N43/44 , A01N43/48 , A01N43/62 , A01N43/78 , A01N43/80 , A01N43/90 , A01N57/08 , A01N57/28 , A01N57/30 , A01P21/00 , C07D205/12 , C07D229/00 , C07D231/54 , C07D417/12 , C07D487/08 , C07D487/10 , C07D491/08 , C07D495/04 , C07D495/08 , C07D498/08 , C07D519/00 , C07C107/04 , C07D261/20
CPC分类号： C07D487/08 , A01N43/44 , A01N43/62 , A01N43/90 , A01N57/08 , C07D205/12 , C07D229/00 , C07D487/10 , C07D491/08 , C07D495/08
摘要： Tricyclic nitrogenous compounds having strong plant growth regulating properties are disclosed. The compounds display the general formula ##STR1## wherein A is one of several nitrogen-containing radicals, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are selected from various recited aliphatic, aryl, araliphatic and heterocyclic groups. R.sup.3 and R.sup.4 may also together form one of a number of nitrogen, sulfur and oxygen containing radicals. These compounds have a variety of uses, including the reduction of plant growth height without harm to the plant.
摘要翻译：公开了具有强植物生长调节性质的三环含氮化合物。化合物显示通式为：其中A是若干含氮基团之一，R 1，R 2，R 3和R 4选自各种所列的脂族，芳基，芳脂族和杂环基。 R3和R4也可以一起形成多个氮，硫和含氧基团之一。这些化合物具有多种用途，包括降低植物生长高度而不损害植物。

9. 发明授权

US4256902A Process for the preparation of 3-chloro-5-hydroxypyrazoles 失效
标题翻译：制备3-氯-5-羟基吡唑的方法
公开(公告)号：US4256902A
公开(公告)日：1981-03-17
申请号：US129724
申请日：1980-03-12
申请人： Pier M. Boschi , Franco Gozzo , Angelo Longoni
发明人： Pier M. Boschi , Franco Gozzo , Angelo Longoni
IPC分类号： A01N57/16 , A01N57/08 , A01N57/24 , A01N57/32 , A01P7/04 , C07D231/20 , C07D231/22 , C07F9/165 , C07F9/24 , C07F9/32 , C07F9/40 , C07F9/6503 , C07F9/6506 , C07F9/6509
CPC分类号： A01N57/08 , C07D231/20 , C07F9/650929
摘要： Phosphoric or thiophosphoric esters of 5(3)-hydroxypyrazoles are disclosed having the formula: ##STR1## wherein: R=H; alkyl with 1-7 carbon atoms optionally substituted with halogens, CN, and carboalkoxy groups; phenyl optionally substituted; benzyl; alkenyl; or alkynyl;X=halogen; --SR; --OR; --N(R).sub.2 ; or ##STR2## where Y is equal to or different from each other, and=H; C.sub.1 -C.sub.3 alkyl; halogen; --SR; --OR; or --N(R).sub.2 ;Z=S; or O; andR.sup.1 and R.sup.2, equal to or different from each other, are: alkoxyls; alkyls; phenyls; or alkylthio- or alkyl-amino-groups.These are useful as insecticides, acaricides and nematodacides.Also disclosed are 5(3)-hydroxypyrazoles having the formula: ##STR3## wherein: R=H; alkyl with 1-7 carbon atoms, optionally substituted with halogen atoms, CN, and carboalkoxy-groups; phenyl optionally substituted; benzyl; alkenyl; or alkynyl;X=halogen; --SR; --OR; --N(R).sub.2 ; or ##STR4## where Y is equal to or different from each other, and =H; C.sub.1 -C.sub.3 alkyl; halogen; --SR; or --OR; or --N(R).sub.2 ; and provided further that when in formula I, X=halogen or --N(R).sub.2 ; the R group, bound to the pyrazolic nitrogen, is different from phenyl.
摘要翻译：公开了5（3） - 羟基吡唑的磷或硫代磷酸酯，其具有下式：其中：R = H; 任选被卤素，CN和碳烷氧基取代的具有1-7个碳原子的烷基; 任选取代的苯基; 苄基; 烯基; 或炔基; X =卤素; -SR; -要么; -N（R）2; 或，其中Y彼此等于或不同，并且= H; C1-C3烷基; 卤素; -SR; -要么; 或-N（R）2; Z = S; 或O; R 1和R 2彼此相同或不同，为：烷氧基; 烷基; 苯基; 或烷硫基 - 或烷基 - 氨基。这些可用作杀虫剂，杀螨剂和杀线虫剂。还公开了具有下式的5（3） - 羟基吡唑：其中：R = H; 具有1-7个碳原子的烷基，任选被卤素原子取代，CN和烷氧羰基; 任选取代的苯基; 苄基; 烯基; 或炔基; X =卤素; -SR; -要么; -N（R）2; 或，其中Y彼此等于或不同，并且= H; C1-C3烷基; 卤素; -SR; 或-OR; 或-N（R）2; 并进一步提供，当在式I中，X =卤素或-N（R）2; 与吡唑氮结合的R基团与苯基不同。

10. 发明授权

US4233293A Insecticidal and acaricidal O-alkyl-O-[1-(2-cyanoalkyl)-5-halo-1,2,4-triazol(3)yl]-(thiono)(thiol)-p hosphoric(phosphonic) acid esters and ester-amides 失效
标题翻译：杀虫和杀螨剂O-烷基-O- [1-（2-氰基烷基）-5-卤代-1,2,4-三唑（3）基] - （硫醇）（硫醇） - 磷酸（膦酸）酯和酯酰胺类
公开(公告)号：US4233293A
公开(公告)日：1980-11-11
申请号：US680408
申请日：1976-04-26
申请人： Rainer A. Fuchs , Ingeborg Hammann , Wolfgang Behrenz
发明人： Rainer A. Fuchs , Ingeborg Hammann , Wolfgang Behrenz
IPC分类号： A01N57/24 , A01N57/08 , A01N57/16 , A01N57/32 , A01P7/02 , A01P7/04 , C07D249/12 , C07F9/6518 , C07F9/65
CPC分类号： C07F9/65183 , A01N57/08 , C07D249/12
摘要： O-Alkyl-O-[1-(2-cyanoalkyl)-5-halo-1,2,4-triazol(3)yl]-(thiono)(thiol)-phosphoric(phosphonic) acid esters and ester-amides of the formula ##STR1## in which R is alkyl with 1 to 6 carbon atoms,R.sub.1 is phenyl or alkyl, alkoxy, alkylthio, monoalkylamino or dialkylamino with 1 to 6 carbon atoms per alkyl or alkoxy,R.sub.2 is hydrogen or alkyl with 1 to 4 carbon atoms,Hal is halogen, andX is oxygen or sulfur,which possess insecticidal and acaricidal properties.
摘要翻译： O-（1-氰基烷基）-5-卤代-1,2,4-三唑（3）基] - （硫醇）（硫醇） - 磷酸（膦酸）酯和酯酰胺其中R为具有1至6个碳原子的烷基的式（I），R 1为苯基或烷基，烷氧基，烷硫基，单烷基氨基或每个烷基或烷氧基具有1至6个碳原子的二烷基氨基，R 2为氢或烷基， 1至4个碳原子，Hal是卤素，X是氧或硫，具有杀虫和杀螨的性质。

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