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    • 4. 发明授权
    • Heterocyclic substituted triazolyl phosphorous compounds and their use
as insecticides
    • 杂环取代三唑基磷化合物及其作为杀虫剂的用途
    • US4357327A
    • 1982-11-02
    • US260533
    • 1981-05-04
    • Chester E. Pawloski
    • Chester E. Pawloski
    • A01N57/08C07D213/77C07F9/6518C07F9/6558C07D237/28C07D237/30C07D241/40A61K31/495
    • C07D213/77A01N57/08C07F9/65185C07F9/65583
    • Compounds are prepared which correspond to the formula ##STR1## wherein R represents a nitrogen containing heterocyclic radical corresponding to one of the formulae ##STR2## each X independently represents chloro, fluoro, bromo, nitro, alkyl of 1 to 4 carbon atoms, amino, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, cyano, trifluoromethyl, trichloromethyl, phenoxy or substituted phenoxy of the formula ##STR3## wherein each Z independently represents chloro, fluoro, bromo, nitro, cyano, alkoxy of 1 to 4 carbon atoms or alkylthio of 1 to 4 carbon atoms, with the proviso that when either n is 2 or 3, all X groups are sterically compatible with each other and all Z groups are sterically compatible with each other; Y represents oxygen or sulfur; each n can independently represent an integer of from 0 to 3, inclusive; R.sup.1 represents hydrogen, chloro, fluoro, bromo, alkyl of 1 to 4 carbon atoms, cycloalkyl of 3-6 carbon atoms, phenyl, phenylthio, alkoxy of 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms, alkylsulfinyl of 1 to 4 carbon atoms, alkylsulfonyl of 1 to 4 carbon atoms, thiocyanato, trifluoromethyl, trichloromethyl, amino, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms; R.sup.2 represents methyl, ethyl, propyl or isobutyl and R.sup.3 represents methoxy, ethoxy, propoxy, ethyl, mono- or dialkylamino wherein each alkyl group independently contains from 1 to 4 carbon atoms, alkylthio of 1 to 4 carbon atoms or phenyl.
    • 制备符合下式的化合物:其中R表示与下式之一相对应的含氮杂环基,每个X独立地表示氯,氟,溴,硝基 ,1至4个碳原子的烷基,氨基,单 - 或二烷基氨基,其中每个烷基独立地含有1至4个碳原子,1至4个碳原子的烷氧基,1至4个碳原子的烷硫基,1至4个碳原子的烷基亚磺酰基 1至4个碳原子的烷基磺酰基,氰基,三氟甲基,三氯甲基,苯氧基或取代的苯氧基,其中每个Z独立地表示氯,氟,溴,硝基,氰基,1-4个碳原子的烷氧基或烷硫基 具有1至4个碳原子,条件是当n为2或3时,所有X基彼此在空间上相容,并且所有Z基彼此在空间上相容; Y表示氧或硫; 每个n可以独立地表示0至3的整数,包括0和3; R 1表示氢,氯,氟,溴,1至4个碳原子的烷基,3-6个碳原子的环烷基,苯基,苯硫基,1至4个碳原子的烷氧基,1至4个碳原子的烷硫基,1至 4个碳原子,1至4个碳原子的烷基磺酰基,硫氰酸酯,三氟甲基,三氯甲基,氨基,一或二烷基氨基,其中每个烷基独立地含有1至4个碳原子; R 2表示甲基,乙基,丙基或异丁基,R 3表示甲氧基,乙氧基,丙氧基,乙基,单 - 或二烷基氨基,其中各烷基独立地含有1至4个碳原子,1至4个碳原子的烷硫基或苯基。
    • 5. 发明授权
    • Cyclic acetal-methyl-carbamoyl-methyl esters of phosphonic and
phosphoric acids, as herbicides
    • 作为除草剂的膦酸和磷酸的环状缩醛 - 甲基 - 氨基甲酰基 - 甲基酯
    • US4314840A
    • 1982-02-09
    • US164719
    • 1980-06-30
    • Leonard J. Stach
    • Leonard J. Stach
    • A01N57/08C07D317/28C07D319/06C07F9/165A01N43/24A01N43/30A01N43/32
    • C07D319/06A01N57/08C07D317/28C07F9/1651
    • This invention discloses new compounds of the formula ##STR1## wherein X,Y,Z and Q are each independently selected from the group consisting of oxygen and sulfur; R.sup.1 is selected from the group consisting of alkyl, and ##STR2## wherein A may be different at different positions and is selected from the group consisting of alkyl, alkoxy, alkylthio, halogen, nitro and cyano, p is an integer from 0 to 5; R.sup.2 is selected from the group consisting of alkyl, alkoxy, alkylthio, amino, alkylamino, dialkylamino and ##STR3## wherein B may be different at different positions and is selected from the group consisting of alkyl, alkoxy, alkylthio, halogen, nitro and cyano, and q is an integer from 0 to 5; R.sup.3 is selected from the group consisting of hydrogen, alkyl and ##STR4## wherein D may be different at different positions and is selected from the group consisting of alkyl, alkoxy, alkylthio, halogen, nitro and cyano, and r is an integer from 0 to 5; R.sup.4 is selected from the group consisting of hydrogen, alkyl cycloalkyl and ##STR5## wherein E may be different at different positions and is selected from the group consisting of alkyl, alkoxy, alkylthio, halogen, nitro and cyano, and s is an integer from 0 to 5; R.sup.5, R.sup.6, R.sup.7, and R.sup.8 are each independently selected from the group consisting of hydrogen and alkyl; and n is an integer from 0 to 3.Further disclosed are herbicidal and insecticidal compositions utilizing the aforedescribed compounds.
    • 本发明公开了新的式(Ⅰ)化合物,其中X,Y,Z和Q各自独立地选自氧和硫; R1选自烷基和其中A可以在不同位置不同并且选自烷基,烷氧基,烷硫基,卤素,硝基和氰基,p是0至5的整数 ; R 2选自烷基,烷氧基,烷硫基,氨基,烷基氨基,二烷基氨基和其中B可以在不同位置不同,并且选自烷基,烷氧基,烷硫基,卤素,硝基和氰基 q为0〜5的整数, R 3选自氢,烷基和其中D可以在不同位置不同,并且选自烷基,烷氧基,烷硫基,卤素,硝基和氰基,并且r是0的整数 至5; R 4选自氢,烷基环烷基和其中E可以在不同位置不同,并且选自烷基,烷氧基,烷硫基,卤素,硝基和氰基,s是从 0至5; R5,R6,R7和R8各自独立地选自氢和烷基; 并且n为0至3的整数。进一步公开了使用上述化合物的除草和杀虫组合物。
    • 6. 发明授权
    • Xanthenone-yl esters of phosphoric and phosphonic acids
    • 磷酸和膦酸的呫吨酮基酯
    • US4299772A
    • 1981-11-10
    • US127007
    • 1980-03-04
    • James T. Traxler
    • James T. Traxler
    • A01N57/16A01N57/08A01N57/24C07D311/86C07D335/16C07F9/09C07F9/24C07F9/38C07F9/40C07F9/655C07F9/6553
    • C07F9/65522A01N57/08C07F9/655372
    • Disclosed are new compounds of the formula ##STR1## wherein R.sup.1 and R.sup.2 are each independently selected from the group consisting of halogen, alkyl, haloalkyl, nitro, alkylsulfinyl, alkylsulfonyl and cyano; k and m are integers from 0 to 3; Q is selected from the group consisting of oxygen and sulfur; Y is selected from the group consisting of oxygen and sulfur R.sup.3 is selected from the group consisting of alkyl and ##STR2## wherein R.sup.5 is selected from the group consisting of halogen, alkyl, haloalkyl, nitro and cyano; n is an integer from 0 to 3; R.sup.4 is selected from the group consisting of alkyl, alkoxy, alkylthio, amino, alkylamino, dialkylamino and ##STR3## wherein R.sup.6 is selected from the group consisting of halogen, alkyl, haloalkyl, nitro, and cyano; p is an integer from 0 to 3; and A and B are each independently selected from the group consisting of oxygen and sulfur, with the proviso that, if R.sup.4 is alkoxy, then one of A and B must be sulfur.Further disclosed is the insecticidal utility of the foregoing compounds.
    • 公开了式IMA的新化合物,其中R 1和R 2各自独立地选自卤素,烷基,卤代烷基,硝基,烷基亚磺酰基,烷基磺酰基和氰基; k和m是0至3的整数; Q选自氧和硫; Y选自氧和硫。R3选自烷基和卤素,其中R5选自卤素,烷基,卤代烷基,硝基和氰基; n为0〜3的整数。 R 4选自烷基,烷氧基,烷硫基,氨基,烷基氨基,二烷基氨基和其中R 6选自卤素,烷基,卤代烷基,硝基和氰基; p是0至3的整数; 并且A和B各自独立地选自氧和硫,条件是如果R 4是烷氧基,那么A和B之一必须是硫。 进一步披露的是上述化合物的杀虫效用。
    • 8. 发明授权
    • Process for the preparation of 3-chloro-5-hydroxypyrazoles
    • 制备3-氯-5-羟基吡唑的方法
    • US4256902A
    • 1981-03-17
    • US129724
    • 1980-03-12
    • Pier M. BoschiFranco GozzoAngelo Longoni
    • Pier M. BoschiFranco GozzoAngelo Longoni
    • A01N57/16A01N57/08A01N57/24A01N57/32A01P7/04C07D231/20C07D231/22C07F9/165C07F9/24C07F9/32C07F9/40C07F9/6503C07F9/6506C07F9/6509
    • A01N57/08C07D231/20C07F9/650929
    • Phosphoric or thiophosphoric esters of 5(3)-hydroxypyrazoles are disclosed having the formula: ##STR1## wherein: R=H; alkyl with 1-7 carbon atoms optionally substituted with halogens, CN, and carboalkoxy groups; phenyl optionally substituted; benzyl; alkenyl; or alkynyl;X=halogen; --SR; --OR; --N(R).sub.2 ; or ##STR2## where Y is equal to or different from each other, and=H; C.sub.1 -C.sub.3 alkyl; halogen; --SR; --OR; or --N(R).sub.2 ;Z=S; or O; andR.sup.1 and R.sup.2, equal to or different from each other, are: alkoxyls; alkyls; phenyls; or alkylthio- or alkyl-amino-groups.These are useful as insecticides, acaricides and nematodacides.Also disclosed are 5(3)-hydroxypyrazoles having the formula: ##STR3## wherein: R=H; alkyl with 1-7 carbon atoms, optionally substituted with halogen atoms, CN, and carboalkoxy-groups; phenyl optionally substituted; benzyl; alkenyl; or alkynyl;X=halogen; --SR; --OR; --N(R).sub.2 ; or ##STR4## where Y is equal to or different from each other, and =H; C.sub.1 -C.sub.3 alkyl; halogen; --SR; or --OR; or --N(R).sub.2 ; and provided further that when in formula I, X=halogen or --N(R).sub.2 ; the R group, bound to the pyrazolic nitrogen, is different from phenyl.
    • 公开了5(3) - 羟基吡唑的磷或硫代磷酸酯,其具有下式:其中:R = H; 任选被卤素,CN和碳烷氧基取代的具有1-7个碳原子的烷基; 任选取代的苯基; 苄基; 烯基; 或炔基; X =卤素; -SR; -要么; -N(R)2; 或,其中Y彼此等于或不同,并且= H; C1-C3烷基; 卤素; -SR; -要么; 或-N(R)2; Z = S; 或O; R 1和R 2彼此相同或不同,为:烷氧基; 烷基; 苯基; 或烷硫基 - 或烷基 - 氨基。 这些可用作杀虫剂,杀螨剂和杀线虫剂。 还公开了具有下式的5(3) - 羟基吡唑:其中:R = H; 具有1-7个碳原子的烷基,任选被卤素原子取代,CN和烷氧羰基; 任选取代的苯基; 苄基; 烯基; 或炔基; X =卤素; -SR; -要么; -N(R)2; 或,其中Y彼此等于或不同,并且= H; C1-C3烷基; 卤素; -SR; 或-OR; 或-N(R)2; 并进一步提供,当在式I中,X =卤素或-N(R)2; 与吡唑氮结合的R基团与苯基不同。