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    • 61. 发明申请
    • Sulfuric acid electrolytic cell and a sulfuric acid recycle type cleaning system applying the sulfuric acid electrolytic cell
    • 硫酸电解池和硫酸循环型清洗系统应用硫酸电解池
    • US20090321252A1
    • 2009-12-31
    • US12459134
    • 2009-06-26
    • Masaaki KatoYoshiyuki SeyaNaoya HayamizuMakiko TangeYoshiaki KurokawaNobuo Kobayashi
    • Masaaki KatoYoshiyuki SeyaNaoya HayamizuMakiko TangeYoshiaki KurokawaNobuo Kobayashi
    • C25B15/08C25B9/00
    • C25B1/285C25B9/00
    • In a sulfuric acid electrolytic cell to electrolyze sulfuric acid supplied to an anode compartment and a cathode compartment comprising a diaphragm, said anode compartment and said cathode compartment separated by said diaphragm, a cathode provided in said cathode compartment and a conductive diamond anode provided in said anode compartment, as said conductive diamond anode, a conductive diamond film is formed on the surface of said conductive substrate, the rear face of said conductive substrate is pasted, with conductive paste, on an current collector comprising a rigid body with size equal to, or larger than, said conductive substrate, an anode compartment frame constituting said anode compartment is contacted via gasket with the periphery on the side of the conductive diamond film of said diamond anode, said diaphragm is contacted with the front face of said anode compartment, further, with the front face of said diaphragm, the cathode compartment frame constituting said cathode compartment, a gasket, and said cathode are contacted in sequence, the rear face of said cathode is pasted with conductive paste to the current collector comprising a rigid body with size equal to, or larger than, said cathode and electric power is supplied from one current collector to the other current collector via said conductive paste.
    • 在硫酸电解池中,电解供给阳极室的硫酸和包含隔膜的阴极室,由所述隔膜隔开的所述阳极室和所述阴极室分别设置在所述阴极室中的阴极和设在所述阴极室中的导电金刚石阳极 阳极室,作为所述导电金刚石阳极,在所述导电衬底的表面上形成导电金刚石膜,所述导电衬底的背面用导电膏粘贴在集电器上,该集电器包括尺寸等于或等于的刚体, 或大于所述导电基底,构成所述阳极室的阳极室框架通过垫圈与所述金刚石阳极的导电金刚石膜侧面的周边接触,所述隔膜与所述阳极室的前表面接触 与所述隔膜的前面相连,阴极隔室框架构成所述阴极co 间隔件,垫圈和所述阴极按顺序接触,所述阴极的背面用导电膏粘贴到集电器,该集电器包括尺寸等于或大于所述阴极的刚体,并且电力从一个 集电器经由所述导电浆料到另一个集电器。
    • 63. 发明申请
    • Water electrolysis system
    • 水电解系统
    • US20080264780A1
    • 2008-10-30
    • US12149036
    • 2008-04-25
    • Masaaki KatoYusuke Ogawa
    • Masaaki KatoYusuke Ogawa
    • C25B9/10
    • C25B1/04C25B11/035C25B11/0489H01M4/8605H01M4/90H01M4/926Y02E60/366
    • In a water electrolysis system having an anode catalyst layer containing anode catalyst and a cathode catalyst layer containing cathode catalyst tightly attached, respectively, to each surface of a solid polymer electrolyte membrane comprising a cation exchange membrane, wherein at least one catalyst layer of said anode catalyst layer and cathode catalyst layer comprises a porous structure of anode catalyst or cathode catalyst dispersed in fluorine resin containing resin, featuring the surface of the anode catalyst layer or the cathode catalyst layer being hydrophobized and the water contact angle with the surface of the anode catalyst layer or the cathode catalyst layer of said porous structure being 90 degrees or more, whereby the transfer of gas to the counter electrode can be significantly suppressed, gas purity and current efficiency be improved, and safety operation of the electrolysis system be secured, without a major change in configuration of the water electrolysis system.
    • 在具有阳极催化剂层的阳极催化剂层和含有阴极催化剂层的阴极催化剂层的水电解系统分别紧密地连接在包含阳离子交换膜的固体高分子电解质膜的各表面上,其中所述阳极的至少一个催化剂层 催化剂层和阴极催化剂层包括分散在含氟树脂的树脂中的阳极催化剂或阴极催化剂的多孔结构,阳极催化剂层的表面或阴极催化剂层被疏水化,并且与阳极催化剂的表面的水接触角 所述多孔结构的层或阴极催化剂层为90度以上,由此可以显着地抑制气体向对置电极的转移,提高气体纯度和电流效率,并且可以确保电解系统的安全运行,而不需要 水电解系统配置发生重大变化。
    • 66. 发明申请
    • Ion exchange membrane electrolyzer
    • 离子交换膜电解槽
    • US20070235338A1
    • 2007-10-11
    • US11783322
    • 2007-04-09
    • Yoshiyuki KodamaShinichiro Yamamoto
    • Yoshiyuki KodamaShinichiro Yamamoto
    • B01D61/42
    • C25B9/08C25B11/02
    • An ion exchange membrane electrolyzer is provided, which is characterized in that a current is passed through at least one electrode in contact with a plate spring member formed at a portion of an electrode retainer member parallel with a flat plate form of electrode chamber partition, wherein said electrode retainer member is joined at a belt junction to the flat plate form of electrode chamber partition with a space between them, said electrode is provided with a floating mount means at a portion thereof other than a portion of contact with the plate spring member, and said floating mount means is provided with an engaging portion that is engaged with a fixed engaging member to enable said electrode to move in a perpendicular direction to an electrode surface and in a range of displacement of said plate spring member.
    • 提供了一种离子交换膜电解器,其特征在于,电流通过与形成在与电极室隔板的平板形式平行的电极保持器部件的部分处形成的板簧构件接触的至少一个电极,其中 所述电极保持构件在带结处连接到电极室隔板的平板形式,其间具有空间,所述电极在除了与板簧构件接触的部分之外的部分处设置有浮动安装装置, 并且所述浮动安装装置设置有与固定的接合构件接合的接合部分,以使所述电极能够在垂直于电极表面的方向上移动并且在所述板簧构件的位移范围内。
    • 68. 发明申请
    • Ion exchange membrane electrolyzer
    • 离子交换膜电解槽
    • US20030155232A1
    • 2003-08-21
    • US10368380
    • 2003-02-20
    • CHLORINE ENGINEERS CORP., LTD.
    • Shinji KatayamaMasaru MoriMasakazu Kameda
    • C25C007/00C25B009/00C25D017/00
    • C25B9/20
    • The invention provides an ion exchange membrane electrolyzer ensuring a satisfactory circulation of electrolyte, high electrolytic efficiency and great ridigity. An anode chamber partition in a flat sheet form is joined to a cathode chamber partition in a flat sheet form. An electrode retainer member in a sheet form is joined to at least one partition at a belt-like junction. A projecting strip with an electrode joined thereto is located between adjacent junctions. A space on an electrode surface side of the electrode retainer member defines a path through which a fluid goes up in the electrode chamber, and a space that spaces away from the space defines a path through which an electrolyte separated from a gas at a top portion of the electrode goes down.
    • 本发明提供了一种离子交换膜电解槽,确保了电解液的良好循环,电解效率高,电位大。 平板形式的阳极室隔板以平板形式接合到阴极室隔板。 片状形式的电极保持构件以带状连接部连接至至少一个隔板。 连接有电极的突出条被定位在相邻的接合点之间。 电极保持构件的电极表面侧上的空间限定了流体在电极室中上升的路径,并且与空间隔开的空间限定了电解质与顶部的气体分离的路径 的电极下降。
    • 70. 发明授权
    • Brine treatment method
    • 盐水处理方法
    • US5578218A
    • 1996-11-26
    • US514624
    • 1995-08-14
    • Terumi MatsuokaMasahiro OharaIzumi Kawamura
    • Terumi MatsuokaMasahiro OharaIzumi Kawamura
    • B01D15/04B01J41/04C01D3/16C01F5/30C01F11/32C02F1/42
    • C01D3/16C01F11/32C01F5/30
    • In a brine treatment method of removing sulfate ions from sulfate-ion contained brine, sulfate-ion contained brine is brought into dispersive contact with granular ion exchange resin carrying zirconium hydrous oxide thereon in a fluid state under an acidic condition to thereby cause the sulfate ions to be adsorbed by the ion exchange resin and removed from the brine, then the granular ion exchange resin is washed with aqueous solution whose pH value is equal to or lower than a pH value in the adsorbing step, thereby removing chloride ions from the granular ion exchange resin, then in a fluid state, the granular ion exchange resin adsorbing the sulfate ions is brought into dispersive contact with aqueous solution of pH value higher than the pH value in the adsorbing step, thereby desorbing the adsorbed sulfate ions from the granular ion exchange resin, and then the granular ion exchange resin is washed with water.
    • 在从含有硫酸根离子的盐水中除去硫酸根离子的盐水处理方法中,在酸性条件下,将含有硫酸根离子的盐水与流动状态的载有氧化锆水的粒状离子交换树脂分散接触,从而使硫酸根离子 被离子交换树脂吸附并从盐水中除去,然后用吸附步骤中pH值等于或低于pH值的水溶液洗涤粒状离子交换树脂,从而从颗粒离子中除去氯离子 在流体状态下,吸附硫酸根离子的粒状离子交换树脂与吸附工序中pH值以上的pH值分散接触,从而从粒状离子交换器吸附硫酸根离子 树脂,然后用水洗涤颗粒状离子交换树脂。