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51. 发明申请

US20050059782A1 Continuous bulk polymerization and esterification process and compositions 审中-公开
标题翻译：连续本体聚合和酯化过程及组合物
公开(公告)号：US20050059782A1
公开(公告)日：2005-03-17
申请号：US10964219
申请日：2004-10-13
申请人： Kevin Andrist , John Blasko , Glenn Calhoun , Frederick Hansen , Dean Hellwig , Kurt Hessenius , Steven Hurley , D. Jayasuriya , Matthew Lee , Stephen Maccani , H. Mills , Gregory Peterson , Paul Sandvick , Dennis Wilson , John Wiruth
发明人： Kevin Andrist , John Blasko , Glenn Calhoun , Frederick Hansen , Dean Hellwig , Kurt Hessenius , Steven Hurley , D. Jayasuriya , Matthew Lee , Stephen Maccani , H. Mills , Gregory Peterson , Paul Sandvick , Dennis Wilson , John Wiruth
IPC分类号： C08L23/00 , B01F17/00 , C08F2/02 , C08F20/04 , C08F22/06 , C08F220/06 , C08F220/18 , C09D133/04 , C09G1/16 , C09J133/04 , D21H17/28 , D21H17/37 , D21H21/16 , C08F8/14
CPC分类号： B01F17/0085 , B01F17/0028 , B01F17/005 , C08F2/02 , C08F20/04 , C08F22/06 , C08F220/06 , C08F220/18 , C09G1/16 , D21H17/28 , D21H17/37 , D21H21/16
摘要： A continuous bulk polymerization and esterification process includes continuously charging into a reaction zone at least one ethylenically unsaturated acid-functional monomer and at least one linear or branched chain alkanol having greater than 11 carbon atoms. The process includes maintaining a flow rate through the reaction zone sufficient to provide an average residence time of less than 60 minutes and maintaining a temperature in the reaction zone sufficient to produce a polymeric product incorporating at least some of the alkanol as an ester of the polymerized ethylenically unsaturated acid-functional monomer. The polymeric product is used in various processes to produce water-based compositions including emulsions and dispersions such as oil emulsions, wax dispersions, pigment dispersions, surfactants and coatings which contain the polymeric product. A polymeric surfactant includes at least one ethylenically unsaturated acid-functional monomer which has been radically incorporated into the polymeric surfactant and at least one ester of the incorporated ethylenically unsaturated acid-functional monomer which has a linear or branched chain alkyl group with greater than 11 carbon atoms. The molar critical micelle concentration of the polymeric surfactant is less than 1.0×10−2 moles/liter. Aqueous 2 percent solutions of certain polymeric surfactants have a surface tension of less than 45 mN/m at 30° C. and exhibit a decrease in surface tension of at least 5 mN/m as the temperature warms from 30° C. to 50° C.
摘要翻译：连续本体聚合和酯化方法包括将至少一种烯属不饱和酸官能单体和至少一种具有大于11个碳原子的直链或支链链烷醇连续地加入到反应区中。该方法包括保持通过反应区的流速足以提供小于60分钟的平均停留时间，并保持反应区中的温度足以产生聚合产物，该聚合物与至少一些烷醇作为聚合的烯键式不饱和酸官能单体。聚合物产品用于各种工艺中以生产水性组合物，包括乳液和分散体，例如油乳剂，蜡分散体，颜料分散体，表面活性剂和含有聚合产物的涂料。聚合物表面活性剂包括至少一种烯键式不饱和酸官能单体，其已经自由地掺入聚合物表面活性剂和至少一种具有直链或支链烷基与大于11个碳的烯键式不饱和酸官能单体的酯原子聚合物表面活性剂的摩尔临界胶束浓度小于1.0×10 -2摩尔/升。某些聚合物表面活性剂的2％水溶液在30℃下的表面张力小于45mN / m，并且随着温度从30℃升温到50℃，表面张力降低至少5mN / m C。

52. 发明授权

US06846612B2 Organic anti-reflective coating compositions for advanced microlithography 有权
标题翻译：用于先进微光刻的有机抗反射涂料组合物
公开(公告)号：US06846612B2
公开(公告)日：2005-01-25
申请号：US10062790
申请日：2002-02-01
申请人： Shreeram V. Deshpande
发明人： Shreeram V. Deshpande
IPC分类号： C08F8/14 , C08G59/14 , C08G59/32 , C08G59/42 , C08G59/62 , C08G63/68 , C08G63/91 , C08G65/329 , C09D133/02 , C09D163/00 , C09D167/00 , C09D171/02 , G03F7/09 , G03C1/492 , C08L63/00
CPC分类号： C08G59/32 , C08F8/14 , C08G59/1438 , C08G59/42 , C08G59/625 , C08G63/68 , C08G63/91 , C08G65/329 , C09D133/02 , C09D163/00 , C09D167/00 , C09D171/02 , G03F7/091 , Y10S430/106
摘要： New polymers and new anti-reflective compositions containing such polymers are provided. The compositions comprise a polymer (e.g., epoxy cresol novolac resins) bonded with a chromophore (4-hydroxybenzoic acid, trimellitic anhydride). The inventive compositions can be applied to substrates (e.g., silicon wafers) to form anti-reflective coating layers having high etch rates which minimize or prevent reflection during subsequent photoresist exposure and developing.
摘要翻译：提供了新的聚合物和含有这种聚合物的新的抗反射组合物。组合物包含与发色团（4-羟基苯甲酸，偏苯三酸酐）结合的聚合物（例如环氧甲酚酚醛清漆树脂）。本发明的组合物可以施加到基底（例如，硅晶片）以形成具有高蚀刻速率的抗反射涂层，其在随后的光致抗蚀剂曝光和显影期间最小化或防止反射。

53. 发明授权

US06846564B1 Cross-linked acrylic microparticles, method for the production thereof and use thereof in coverings and moulding products 失效
标题翻译：交联丙烯酸类微粒，其制造方法及其在覆盖物和成型品中的应用
公开(公告)号：US06846564B1
公开(公告)日：2005-01-25
申请号：US09937551
申请日：2000-03-24
申请人： Jean-Pierre Pascault , Ludovic Valette , Philippe Barbeau , Benoit Magny
发明人： Jean-Pierre Pascault , Ludovic Valette , Philippe Barbeau , Benoit Magny
IPC分类号： C09D5/00 , C08F2/06 , C08F2/12 , C08F2/14 , C08F8/14 , C08F220/18 , C08F265/04 , C08L51/00 , C09D4/06 , C09D133/08 , C09D151/00 , C09D163/00 , B32B5/16 , B32B27/30
CPC分类号： C09D4/06 , C08F220/18 , C08F265/04 , C08L51/003 , C09D151/003 , Y10S526/909 , Y10T428/254 , Y10T428/265 , Y10T428/2927 , Y10T428/2982 , Y10T428/31645 , Y10T428/31667 , Y10T428/31696 , Y10T428/31917 , C08L2666/02 , C08F265/06
摘要： The invention relates to cross-linked acrylic microparticles, a method for the production thereof by polymerization in a dispersion in a non aqueous medium and to the uses thereof in covering or moulding compositions involving a favourable compromise between hardness, flexibility and adhesion. The micropparticles are obtained from a composition comprising: 50-99% mols of a constitutent (A) consisting of Cardura E 10 (meth)acrylate and optionally alkyl (meth)acrylate in C2-C8; a compound (B) consisting of at least one monomer or oligomer having at least 2 ethylenic unsaturations; a compound (C) consisting of at least one monomer or oligomer having in addition to one ethylenic unsaturation at least one second function (F1) with the possibility of at least partial chemical modification of the initial functions f1 into final functions f2.
摘要翻译：本发明涉及交联的丙烯酸微粒，其通过在非水介质中的分散体中聚合制备的方法及其在覆盖或模塑组合物中的用途，所述组合物涉及硬度，柔韧性和粘附性之间的有利折中。所述微粒子由包含：50-99％摩尔组合物（A）的组合物获得，所述组分（A）由Cardura E 10（甲基）丙烯酸酯和任选的C 2 -C 8烷基酯（甲基）丙烯酸酯组成; 由至少一种具有至少2个烯属不饱和度的单体或低聚物组成的化合物（B）由至少一种单体或低聚物组成的化合物（C），除了具有一个烯属不饱和度的至少一个第二官能（F1）外，还可以将初始功能f1至少部分化学修饰成最终功能f2。

54. 发明授权

US6147036A Process for preparing compositions useful as intermediates for preparing lubricating oil and fuel additives and derivatives thereof 失效
标题翻译：制备用作制备润滑油和燃料添加剂及其衍生物的中间体的组合物的方法
公开(公告)号：US6147036A
公开(公告)日：2000-11-14
申请号：US43402
申请日：1998-03-23
申请人： Mark R. Baker
发明人： Mark R. Baker
IPC分类号： C07D307/33 , C07D309/30 , C08F8/00 , C08F8/14 , C08F10/00 , C08L23/26 , C10L1/14 , C10L1/16 , C10L1/18 , C10L1/198 , C10L1/20 , C10L1/22 , C10L1/224 , C10L1/232 , C10L1/238 , C10L1/2383 , C10L1/24 , C10L1/26 , C10L1/30 , C10L10/00 , C10L10/02 , C10L10/04 , C10L10/08 , C10M129/92 , C10M133/16 , C10M133/52 , C10M133/56 , C10M149/12 , C10M159/12 , C10M167/00
CPC分类号： C07D307/33 , C07D309/30 , C08F8/10 , C08F8/32 , C10L1/143 , C10L1/1817 , C10L1/198 , C10L1/221 , C10L1/224 , C10L1/232 , C10L1/238 , C10L1/303 , C10L10/02 , C10L10/04 , C10L10/06 , C10M129/92 , C10M133/52 , C10M133/56 , C10M159/12 , C10M167/00 , C10L1/1616 , C10L1/1641 , C10L1/1691 , C10L1/1802 , C10L1/1824 , C10L1/1832 , C10L1/1881 , C10L1/1883 , C10L1/1905 , C10L1/191 , C10L1/1985 , C10L1/201 , C10L1/2225 , C10L1/233 , C10L1/2383 , C10L1/2406 , C10L1/2456 , C10L1/2493 , C10L1/2691 , C10L1/306 , C10M2203/02 , C10M2203/022 , C10M2203/024 , C10M2203/04 , C10M2203/10 , C10M2203/102 , C10M2203/104 , C10M2203/106 , C10M2203/108 , C10M2205/022 , C10M2205/026 , C10M2205/06 , C10M2205/08 , C10M2207/023 , C10M2207/026 , C10M2207/027 , C10M2207/028 , C10M2207/08 , C10M2207/123 , C10M2207/124 , C10M2207/128 , C10M2207/129 , C10M2207/22 , C10M2207/26 , C10M2207/262 , C10M2207/287 , C10M2207/288 , C10M2207/289 , C10M2207/40 , C10M2207/402 , C10M2207/404 , C10M2209/086 , C10M2215/02 , C10M2215/04 , C10M2215/06 , C10M2215/064 , C10M2215/065 , C10M2215/066 , C10M2215/067 , C10M2215/068 , C10M2215/086 , C10M2215/24 , C10M2215/26 , C10M2215/28 , C10M2217/00 , C10M2217/02 , C10M2217/028 , C10M2217/04 , C10M2217/046 , C10M2217/06 , C10M2219/02 , C10M2219/046 , C10M2219/066 , C10M2219/084 , C10M2219/087 , C10M2219/088 , C10M2219/089 , C10M2223/02 , C10M2223/04 , C10M2223/042 , C10M2223/045 , C10M2223/047 , C10M2223/049 , C10M2223/10 , C10M2227/00 , C10M2227/061 , C10M2229/02 , C10M2229/04 , C10M2229/041 , C10M2229/042 , C10M2229/043 , C10M2229/044 , C10M2229/045 , C10M2229/046 , C10M2229/047 , C10M2229/048 , C10M2229/05 , C10N2210/02 , C10N2240/08 , C10N2270/02
摘要： A process for reacting certain carboxylic reactants with olefinic compounds then reacting the intermediate prepared thereby with ammonia, a hydrazine or an amine, and/or a reactive metal or reactive metal compound, products prepared thereby and, additive concentrates and lubricating oil and fuel compositions.
摘要翻译： PCT No.PCT / US97 / 14028 Sec。 371日期：1998年3月23日 102（e）1998年3月23日PCT PCT 1997年8月8日PCT公布。公开号WO98 / 05741 日本1998年2月12日一种使某些羧基反应物与烯烃化合物反应的方法，然后使由此制备的中间体与氨，肼或胺，和/或反应性金属或活性金属化合物，由此制备的产物，添加剂浓缩物和润滑剂油和燃料组成。

55. 发明授权

US6136916A Curable aqueous composition 失效
标题翻译：可固化的水性组合物
公开(公告)号：US6136916A
公开(公告)日：2000-10-24
申请号：US49541
申请日：1998-03-27
申请人： Charles Thomas Arkens , Robert David Gleim
发明人： Charles Thomas Arkens , Robert David Gleim
IPC分类号： C08G63/12 , C08F8/14 , C09J167/00 , C09J167/02 , D04H1/64 , D06M13/02 , D06M13/148 , D06M13/184 , D06M13/192 , D06M13/322 , D06M13/368 , D06M13/402 , D06M13/405 , D06M101/00 , C08L31/00
CPC分类号： C08F8/14 , D04H1/587 , D04H1/64
摘要： This invention relates to a formaldehyde-free curable aqueous composition containing a polyacid, a polyol and a phosphorous-containing accelerator. The composition may be used as a binder for heat resistant nonwovens such as nonwovens composed of fiberglass.
摘要翻译：本发明涉及含有多酸，多元醇和含磷加速剂的不含甲醛的可固化水性组合物。组合物可以用作耐热无纺布的粘合剂，例如由玻璃纤维组成的无纺布。

56. 发明授权

US6083585A Oxygen scavenging condensation copolymers for bottles and packaging articles 失效
公开(公告)号：US6083585A
公开(公告)日：2000-07-04
申请号：US717370
申请日：1996-09-23
申请人： Paul J. Cahill , Stephen Y. Chen
发明人： Paul J. Cahill , Stephen Y. Chen
IPC分类号： B65D65/40 , B32B27/00 , B32B27/08 , B32B27/28 , B32B27/34 , B32B27/36 , B65D20060101 , B65D1/02 , B65D5/70 , B65D30/08 , B65D30/10 , B65D33/02 , B65D77/06 , B65D81/02 , B65D81/24 , B65D81/26 , C08F20060101 , C08F8/14 , C08F299/00 , C08G20060101 , C08G10/00 , C08G63/46 , C08G63/91 , C08G65/00 , C08G69/02 , C08G81/02 , C08J5/18 , C08K5/07 , C08K5/09 , C08K5/098 , C08K5/12 , C08L20060101 , C08L77/00 , C08L101/00 , C09D20060101 , C09D5/02 , C09D5/08 , C09D163/00 , B29D22/00
CPC分类号： B32B27/36 , B65D1/0215 , B65D81/266 , Y10T428/1352 , Y10T428/31725
摘要： Compositions for scavenging oxygen are disclosed. These compositions comprise condensation copolymers comprising predominantly polyester segments and an oxygen scavenging amount of polyolefin oligomer segments. The polyester segments comprise segments derived from typical bottling and packaging polyesters such as PET and PEN. The copolymers are preferably formed by transesterification during reactive extrusion and typically comprise about 0.5 to about 12 wt % of polyolefin oligomer segments. The copolycondensates are capable of absorbing at least 0.4 cc of oxygen per gram of copolymer in the solid state at ambient temperatures and are typically used as layers in films, liners, cups, wraps, bottles, etc. Use of these oxygen scavenging compositions in bottles provides a clear and rigid bottle similar in appearance to unmodified polyester bottles. In a series of preferred embodiments, bottles fabricated with the oxygen scavenging copolycondensates of this invention are over 99.4 wt % polyester and suitable for recycle with other polyester bottles.

57. 发明授权

US6054541A Process of manufacturing precursor of an absorbing agent 失效
标题翻译：制造吸收剂前体的方法
公开(公告)号：US6054541A
公开(公告)日：2000-04-25
申请号：US45827
申请日：1998-03-23
申请人： Katsuyuki Wada , Kinya Nagasuna , Shin-ichi Fujino , Yoshihiko Masuda
发明人： Katsuyuki Wada , Kinya Nagasuna , Shin-ichi Fujino , Yoshihiko Masuda
IPC分类号： A61F13/15 , A61L15/60 , C08F220/00 , C08F220/06 , C08F8/14
CPC分类号： A61F13/53 , A61F13/15203 , A61L15/60 , C08F220/00 , C08F220/06
摘要： An absorbing agent has a diffusing absorbency under pressure of not less than 25 g/g when 60 minutes elapsed after absorption is started, and a water-soluble content is above 0 percent by weight and not more than 7 percent by weight. The absorbing agent is prepared by surface-crosslinking a precursor of the absorbing agent obtained by performing an aqueous solution polymerization of a hydrophilic unsaturated monomer having not less than 50 mole percent neutralized acrylic acid as a main component using a specific crosslinking agent having a main component composed of an ester compound of a specific polyhydroxy alcohol and an unsatuated carboxylic acid, and a high-boiling component having at least two alcohol structures in a molecule as a specific ratio. As a result, an absorbing agent having excellent properties such as the diffusing absorbency under pressure is high, the water soluble content is small, and the amount of wet back of the aqueous liquid after a long period of time is small, water absorbency under pressure can be stably maintained for a long period of time can be achieved.
摘要翻译：吸收剂在吸收开始60分钟后具有不低于25g / g的压力下的扩散吸收性，并且水溶性成分高于0重量％且不大于7重量％。吸收剂是通过使用具有主成分的特定交联剂进行以不少于50摩尔％中和的丙烯酸为主成分的亲水性不饱和单体的水溶液聚合而获得的吸收剂的前体进行表面交联而制备的。由特定的多羟基醇和不饱和羧酸的酯化合物和分子中具有至少两个醇结构的高沸点组分作为特定比例组成。结果，具有优异性能的吸收剂如压力下的扩散吸收性高，水溶性量小，长时间后的水性液体的湿润量少，压力下的吸水性可以长期稳定地维持可以实现。

58. 发明授权

US6054252A Photoimageable compositions having improved chemical resistance and stripping ability 有权
公开(公告)号：US6054252A
公开(公告)日：2000-04-25
申请号：US364494
申请日：1999-07-30
申请人： Daniel E. Lundy , Robert K. Barr , Edward J. Reardon
发明人： Daniel E. Lundy , Robert K. Barr , Edward J. Reardon
IPC分类号： G03F7/039 , C08F8/14 , C08F257/02 , C08F267/04 , C08F290/06 , C08L51/00 , G03F7/033 , G03F7/038 , G03C1/73 , C08K5/10
CPC分类号： G03F7/0388 , C08F257/02 , C08F267/04 , C08F290/06 , C08F8/14 , C08L51/003 , G03F7/033 , C08F2810/30
摘要： A negative-acting photoimageable composition useful as a primary imaging resist in the manufacture of printed circuit boards comprises an acid-functional binder polymer, a photopolymerizable component, and a photoinitiator chemical system, in which the binder polymer has an anhydride functional backbone half-esterified with a meth(acrylate) functional hydroxy-terminated oligomer, wherein the meth(acrylate) functionality is separated from the half-ester linkage by at least two alkoxylate groups and at least one ring opened lactone group for improved stripping ability in strong alkaline aqueous stripping solutions, while maintaining good chemical resistance to other processing chemicals, such as alkaline developing solutions, acid etching solutions, and acid plating baths.

59. 发明授权

US06005056A Modified acryl copolymer 失效
标题翻译：改性丙烯酸共聚物
公开(公告)号：US06005056A
公开(公告)日：1999-12-21
申请号：US913142
申请日：1997-11-03
申请人： Stephan Neis , Matthias Masonne
发明人： Stephan Neis , Matthias Masonne
IPC分类号： C08G59/16 , C08F8/14 , C08F20/26 , C09D133/06
CPC分类号： C08F8/14
摘要： A modified acrylic copolymer obtained by modifying an epoxy groups-containing copolymer by a carboxyl group-containing polycycloaliphatic substance having at least two cycles and a refractive index at 20.degree. C. of at least 1.460 as well as the use for lacquers with higher gloss.
摘要翻译： PCT No.PCT / DE96 / 00393 Sec。 371日期：1997年11月3日 102（e）日期1997年11月3日PCT 1996年3月6日PCT公布。 WO96 / 28478 PCT出版物日本1996年9月19日通过具有至少两个循环并且在20℃下的折射率至少为1.460的含羧基的多环脂族物质改性含环氧基的共聚物而获得的改性丙烯酸共聚物，以及用于漆光泽度较高。

60. 发明授权

US5985989A Method of making a water reducing additive for cement 失效
标题翻译：制造水泥减水剂的方法
公开(公告)号：US5985989A
公开(公告)日：1999-11-16
申请号：US890092
申请日：1997-07-09
申请人： Edward T. Shawl , Xinhau Zhou
发明人： Edward T. Shawl , Xinhau Zhou
IPC分类号： C04B24/28 , C04B24/26 , C04B24/32 , C04B103/32 , C08F2/44 , C08F8/14 , C08G81/02 , C08L71/02 , C08K5/06
CPC分类号： C04B24/2647 , C04B24/267 , C08L71/02 , C04B2103/302 , C04B2103/32
摘要： Substances useful as water reducing and superplasticizer additives for cement compositions are formed by in situ polymerization of one or more ethylenically unsaturated acid monomers such as acrylic acid or maleic anhydride in a reaction medium comprising a polyether such as polypropylene glycol or a copolymer of ethylene oxide and propylene oxide to form a carboxylic acid polymer, followed by reaction of the polyether and carboxylic acid polymer. The composition and properties of the resulting additives may be readily varied as desired through the use of different acid monomers, polyethers, reaction conditions, reagent proportions and the like.
摘要翻译：用作水泥组合物的减水剂和超增塑剂添加剂的物质通过一种或多种烯属不饱和酸单体如丙烯酸或马来酸酐在包含聚醚如聚丙二醇或环氧乙烷和环氧丙烷以形成羧酸聚合物，随后聚醚和羧酸聚合物反应。通过使用不同的酸单体，聚醚，反应条件，试剂比例等，所得添加剂的组成和性质可根据需要容易地变化。

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