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    • 2. 发明授权
    • Photoimageable compositions having improved flexibility and stripping ability
    • 具有改善的柔韧性和剥离能力的可光成像组合物
    • US06322951B1
    • 2001-11-27
    • US09209353
    • 1998-12-11
    • Daniel E. LundyRobert K. BarrEdward J. Reardon
    • Daniel E. LundyRobert K. BarrEdward J. Reardon
    • G03F7033
    • G03F7/027C08G18/6725C08L53/00C08L53/005Y10S430/111C08L2666/02
    • A negative-acting photoimageable composition useful as a primary imaging resist in the manufacture of printed circuit boards comprises an acid-functional binder polymer, a photopolymerizable component, and a photoinitiator chemical system, in which all or a portion of the photopolymerizable component comprises a (meth)acrylate functional urethane oligomer, wherein the (meth)acrylate functionality is separated from the urethane linkage by at least two alkylene oxide groups and at least one ring-opened lactone group for improved flexibility, tenting strength, fine line adhesion, developer scumming, coupled with unexpectedly improved resistance to processing chemicals, such as alkaline developing solutions, acid etching solutions, and acid plating baths, and stripping ability in strong alkaline aqueous stripping solutions.
    • 在制造印刷电路板中用作主要成像抗蚀剂的负性光学成像组合物包括酸官能粘合剂聚合物,可光聚合组分和光引发剂化学体系,其中全部或部分可光聚合组分包含( 甲基)丙烯酸酯官能氨基甲酸酯低聚物,其中(甲基)丙烯酸酯官能团通过至少两个环氧烷基团与氨基甲酸酯键分离,并且至少一个开环内酯基团用于改善柔性,起绒强度,细线粘附性,显影剂浮渣, 再加上对处理化学品,如碱性显影溶液,酸蚀溶液和酸性电镀液以及在强碱性水性剥离溶液中的剥离能力方面的出色改进。