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51. 发明申请

US20050043463A1 Preparation of multimodal polymer dispersions using polymeric stabilizer, and use thereof 有权
标题翻译：使用聚合物稳定剂制备多峰聚合物分散体及其用途
公开(公告)号：US20050043463A1
公开(公告)日：2005-02-24
申请号：US10918121
申请日：2004-08-12
申请人： Harmin Muller
发明人： Harmin Muller
IPC分类号： C08F2/24 , C08L1/00
CPC分类号： C08F2/24
摘要： A description is given of a process for preparing bimodal or multimodal polymers from olefinically unsaturated monomers in an aqueous medium. The process features the introduction as initial charge of selected mixtures of polymeric stabilizers and of at least one selected ionic comonomer. In the polymerization process the monomer is metered continuously or discontinuously into the said initial charge. In this way it is possible by means of simple process measures to prepare bimodal or multimodal dispersions.
摘要翻译：描述了在水性介质中由烯属不饱和单体制备双峰或多峰聚合物的方法。该方法的特征在于引入作为聚合物稳定剂和至少一种选择的离子共聚单体的所选混合物的初始电荷。在聚合过程中，将单体连续地或不连续地计量到所述初始电荷中。以这种方式，可以通过简单的过程措施来制备双峰或多峰分散体。

52. 发明申请

US20050020787A1 Method of emulsion polymerization 审中-公开
标题翻译：乳液聚合方法
公开(公告)号：US20050020787A1
公开(公告)日：2005-01-27
申请号：US10922179
申请日：2004-08-19
申请人： Huub Aert , Joan Vermeersch , Etienne Thillo , Jos Huybrechts
发明人： Huub Aert , Joan Vermeersch , Etienne Thillo , Jos Huybrechts
IPC分类号： C08F2/00 , C08F2/22 , C08F2/24 , C08F2/38
CPC分类号： C08F2/24 , C08F2/22 , C08F2/38
摘要： A method has been disclosed of preparing ultrafine hydrophobic latex particles of polymers and copolymers by free radical emulsion polymerization in a water-based system, making use therefor, in order to polymerize or copolymerize monomers or monomer mixtures respectively, of at least one compound selected from the group consisting of dimers and cobalt complexes, acting as a chain transfer agent (CTA), wherein said latex particles have an average particle size of less than 100 nm, being more than 10% lower than if prepared in the absence of said CTA, characterized in that said polymerization is conducted in a water-based reaction in the presence of a chain transfer agent and of a surfactant, wherein said surfactant is present in a concentration versus said monomer or monomer mixture of from 5 up to 25% by weight for a non-ionic surfactant or from 0.05 up to 10% by weight for an ionic surfactant, more particularly a surfactant in a concentration below twice its critical micelle concentration.
摘要翻译：已经公开了一种通过在水基体系中通过自由基乳液聚合制备聚合物和共聚物的超细疏水性胶乳颗粒的方法，其用途是分别使单体或单体混合物聚合或共聚至少一种选自由二聚体和钴配合物组成的组，用作链转移剂（CTA），其中所述胶乳颗粒具有小于100nm的平均粒度，比不存在所述CTA时制备的胶乳颗粒小10％以上，其特征在于所述聚合在链转移剂和表面活性剂的存在下在水基反应中进行，其中所述表面活性剂以相对于所述单体或单体混合物的浓度存在，其浓度为5至25重量％，用于非离子表面活性剂或0.05至10重量％的离子表面活性剂，更特别是浓度低于其临界胶束浓度两倍的表面活性剂 ation。

53. 发明授权

US6130287A Colloidally stabilized emulsion polymer 失效
标题翻译：胶体稳定的乳液聚合物
公开(公告)号：US6130287A
公开(公告)日：2000-10-10
申请号：US865440
申请日：1997-05-29
申请人： Venkataram Krishnan
发明人： Venkataram Krishnan
IPC分类号： C08L9/00 , C08F2/22 , C08F2/24 , C08F2/44 , C08F36/04 , C08F236/04 , C08K5/54 , C08L33/06 , C08L47/00 , C08L41/00 , C08G77/04
CPC分类号： C08K5/54 , C08F2/22 , C08F2/44 , C08F36/04
摘要： An emulsion polymer is disclosed by the present invention. In particular, the emulsion polymer comprises a protective colloid and a functionalized silane component which is of the formula: ##STR1## wherein R" is C.sub.1 -C.sub.5 alkyl, R' is C.sub.1 -C.sub.5 alkyl, R is SH, CH.sub.2 .dbd.CH--, CH.sub.2 .dbd.C(CH.sub.3)--C(O)O--, CH.sub.2 .dbd.CH--C(O)O--, and ##STR2## n is 1-10, and m is 2 or 3.
摘要翻译：本发明公开了一种乳液聚合物。特别地，乳液聚合物包含保护胶体和官能化的硅烷组分，其具有下式：其中R“为C 1 -C 5烷基，R'为C 1 -C 5烷基，R为SH，CH 2 = CH-，CH 2 = C（CH 3）-C（O）O-，CH 2 = CH-C（O）O-，n为1-10，m为2或3。

54. 发明授权

US6077903A Continuous process for producing rubbery polymer 失效
标题翻译：生产橡胶聚合物的连续工艺
公开(公告)号：US6077903A
公开(公告)日：2000-06-20
申请号：US076289
申请日：1998-05-12
申请人： Hung Dang Ngoc
发明人： Hung Dang Ngoc
IPC分类号： C08F2/00 , C08F2/24 , C08F2/26 , C08F220/18 , C08F265/04 , C08F283/00 , C08F285/00 , C08L51/00 , C08F267/00
CPC分类号： C08F285/00 , C08F265/04 , C08F283/00 , C08L51/003
摘要： There is a need for polymers which are utilized in automotive interiors which offer increased heat and ultraviolet light resistance. It is particularly critical for polymers which are utilized in making skin compounds for automotive instrument and door panels to display excellent heat and ultraviolet light resistance. This invention discloses a continuous process for preparing a rubbery polymer which can be blended with polyvinyl chloride to make leathery compositions having good heat and ultraviolet light resistance. This technique involves utilizing a multiple continuous reactor system wherein a first phase monomer solution containing butyl acrylate, an acrylic monomer, acrylonitrile and a crosslinking agent is continuously charged into at least three initial reactors. To attain a small particle size, it is necessary to limit the solids content in each of these initial reactors. Then, a second phase monomer solution containing styrene, additional acrylonitrile and additional crosslinking agent is continuously charged into a subsequent reactor. This technique can also be utilized to synthesize core/shell or IPN structures by using multistage emulsion polymerization in which the first stage latex contains a majority of the butyl acrylate with a small latex particle size being obtained.
摘要翻译：需要用于汽车内部的聚合物，其提供增加的耐热和耐紫外线性。对于用于汽车仪表和门板的皮肤化合物的聚合物，特别关键的是显示优异的耐热和耐紫外线性。本发明公开了一种制备橡胶状聚合物的连续方法，该方法可与聚氯乙烯共混以制备具有良好耐热和耐紫外线性的革质组合物。该技术涉及利用多连续反应器系统，其中将含有丙烯酸丁酯，丙烯酸单体，丙烯腈和交联剂的第一相单体溶液连续加入到至少三个初始反应器中。为了获得小的粒径，必须限制这些初始反应器中的每一个中的固体含量。然后，将含有苯乙烯，另外的丙烯腈和另外的交联剂的第二相单体溶液连续加入随后的反应器中。该技术也可用于通过使用多阶段乳液聚合来合成核/壳或IPN结构，其中第一阶段胶乳含有大部分获得的胶乳粒度小的丙烯酸丁酯。

55. 发明授权

US6075089A Process for producing dispersions of water-soluble vinyl polymers and stabilizer for carrying out the process 失效
标题翻译：用于生产水溶性乙烯基聚合物和稳定剂分散体的方法，用于进行该方法
公开(公告)号：US6075089A
公开(公告)日：2000-06-13
申请号：US125181
申请日：1998-10-05
申请人： Werner Jaeger , Arvid Zimmermann , Mathias Hahn , Volker Hildebrandt , Karl Heinz Reichert
发明人： Werner Jaeger , Arvid Zimmermann , Mathias Hahn , Volker Hildebrandt , Karl Heinz Reichert
IPC分类号： B01F17/34 , C08F2/10 , C08F2/24 , C08F283/06 , C08K5/06 , C08F2/16 , C08L39/00
CPC分类号： C08F283/06 , C08F2/10
摘要： The present invention concerns a process for producing dispersions of watsoluble vinyl polymers and a stabilizer for carrying out this process. Such water-soluble, particularly cationic vinyl polymers, are employed on a large scale as process expediters for carrying out, for instance, separating processes in water treatment or waste-water purification, respectively, in the paper, coal and ore industries, in oil production or also in the food stuff industry, among others, for floculation, coagulation, retention or dewatering. According to the present invention, water-soluble vinyl polymers are homo- or copolymerized in the presence of a dispersion stabilizer of the invention. The stabilizer consists of a graft copolymer whose backbone is formed by polyethylene oxide and its grafted branches of cationic vinyl monomers. Among others, cationic, hydrophobically modified vinyl monomers can be advantageously employed. Copolymerizations can be carried out between cationic or non-ionic hydrophobically modified vinyl polymers and cationic or non-ionic, non-hydrophobically modified vinyl polymers.
摘要翻译： PCT No.PCT / DE97 / 00288 Sec。 371日期：1998年10月5日 102（e）日期1998年10月5日PCT提交1997年2月10日PCT公布。公开号WO97 / 30094 日期：1997年8月21日本发明涉及一种水溶性乙烯基聚合物的分散体的制造方法及其制造方法。大量使用这种水溶性，特别是阳离子乙烯基聚合物作为工艺加速器，用于在纸，煤和矿石工业，油中分别进行水处理或废水净化中的分离过程生产或在食品行业，其中包括絮凝，凝结，保留或脱水。根据本发明，水溶性乙烯基聚合物在本发明的分散稳定剂的存在下是均聚的或共聚合的。稳定剂由接枝共聚物组成，其主链由聚环氧乙烷及其接枝的阳离子乙烯基单体分支形成。其中，可以有利地使用阳离子，疏水改性的乙烯基单体。可以在阳离子或非离子疏水改性的乙烯基聚合物和阳离子或非离子，非疏水改性的乙烯基聚合物之间进行共聚。

56. 发明授权

US6037399A Microemulsion polymerization systems for the production of small melt-processible fluoropolymer particles 失效
标题翻译：用于生产小的可熔融加工的含氟聚合物颗粒的微乳液聚合体系
公开(公告)号：US6037399A
公开(公告)日：2000-03-14
申请号：US672779
申请日：1996-06-28
申请人： Huey Shen Wu , Jack Hegenbarth , Chen Xin-Kang , Chen Jian-Guo
发明人： Huey Shen Wu , Jack Hegenbarth , Chen Xin-Kang , Chen Jian-Guo
IPC分类号： C08F2/24 , C08F14/18 , C08F214/26 , C08F216/14 , C08L27/12 , C09D127/12 , C08K5/02
CPC分类号： C08F214/26 , C08F216/1408
摘要： An aqueous microemulsion polymerization procedure is described in which very small colloidal melt-processible fluoropolymer particles are produced from at least one gaseous monomer and optionally TFE. The polymerization procedure involves forming a microemulsion of at least one liquid organic compound; adding at least one gaseous free-radical polymerizable monomer to the microemulsion; and initiating polymerization by adding a free-radical initiator to the mixture.
摘要翻译：描述了一种水性微乳液聚合方法，其中由至少一种气态单体和任选的TFE制备非常小的胶体可熔融加工的含氟聚合物颗粒。聚合方法包括形成至少一种液体有机化合物的微乳液; 向微乳液中加入至少一种气态可自由基聚合的单体; 并通过向混合物中加入自由基引发剂引发聚合反应。

57. 发明授权

US6028135A Preparation of aqueous polymer dispersions of low viscosity with polymer volume concentrations of at least 50% 失效
标题翻译：聚合物体积浓度至少为50％的低粘度水性聚合物分散体的制备
公开(公告)号：US6028135A
公开(公告)日：2000-02-22
申请号：US877499
申请日：1997-06-17
申请人： Peter Keller , Bernhard Schuler , Bernd Stanger
发明人： Peter Keller , Bernhard Schuler , Bernd Stanger
IPC分类号： B01F17/52 , C08F2/22 , C08F2/24 , C08F2/44 , C08F291/00 , C09D109/00 , C09D123/00 , C09D125/04 , C09D129/10 , C09D131/02 , C09D133/04 , C09D133/20 , C09D135/02 , C09D151/00 , C09J109/00 , C09J123/00 , C09J125/04 , C09J129/10 , C09J131/02 , C09J133/04 , C09J133/20 , C09J135/02 , C09J151/00 , C14C11/00 , C08K3/20
CPC分类号： C14C11/003 , C08F291/00 , C09D151/003 , C09J151/003
摘要： A process for the preparation of aqueous polymer dispersions of low viscosity with polymer volume concentrations of at least 50% by volume, based on the polymer dispersion, by free-radical emulsion polymerization of ethylenically unsaturated monomers, with the exception of vinyl halides and vinylidene halides, in the presence of at least one initiator and at least one initial polymer involves emulsifying the major proportion of the monomers in an aqueous dispersion of the initial polymer and supplying this emulsion continuously to the polymerization reaction.
摘要翻译：基于聚合物分散体，通过乙烯基卤化物和亚乙烯基卤化物除外的烯键式不饱和单体的自由基乳液聚合制备低粘度的聚合物体积浓度为至少50体积％的聚合物水分散体的方法在至少一种引发剂存在下，并且至少一种初始聚合物包括将初始聚合物的水分散体中的主要比例的单体乳化，并将该乳液连续地供给聚合反应。

58. 发明授权

US5990342A Surfactant, emulsifier for emulsion polymerization, dispersant for suspension polymerization and modifier for resin modification 失效
标题翻译：表面活性剂，乳液聚合乳化剂，悬浮聚合用分散剂和树脂改性改性剂
公开(公告)号：US5990342A
公开(公告)日：1999-11-23
申请号：US683776
申请日：1996-07-16
申请人： Masahide Tsuzuki , Kaoru Komiya
发明人： Masahide Tsuzuki , Kaoru Komiya
IPC分类号： B01F17/42 , B01F17/52 , C08F2/18 , C08F2/20 , C08F2/24 , C08F2/26 , C07C69/73 , C07C69/52
CPC分类号： C08F2/26
摘要： A surfactant, an emusifier for emulsion polymerization, a dispersant for suspension polymerization and a modifier for modification of resin properties are disclosed, each of these agents being comprised of a novel compound having a dibasic carboxyl group. The compound is represented by Formula (1)[X--O--(R.sup.1 O).sub.m --OC--R.sup.2 --COO].sub.y M (1)where M is a hydrogen atom, a metal atom or a quaternary nitrogen-containing group, y is equal to the valence of M, R.sup.1 is at least one hydrocarbon group, R.sup.2 is a moiety of a dibasic acid or a moiety of its anhydride, m is 0 or an integer of 1 to 1,000, and X is a hydrocarbon group having at least one polymerizable double bond of carbon--ncarbon which may contain an oxygen atom and a fluorine atom.
摘要翻译：公开了一种表面活性剂，用于乳液聚合的乳化剂，用于悬浮聚合的分散剂和用于改性树脂性质的改性剂，这些试剂均由具有二元羧基的新化合物组成。该化合物由式（1）[XO-（R1O）m-OC-R2-COO] yM（1）表示，其中M是氢原子，金属原子或含季氮的基团，y等于 M的价数，R 1是至少一个烃基，R 2是二元酸的部分或其酸酐的部分，m是0或1〜1000的整数，X是具有至少一个可聚合双键的烃基可以含有氧原子和氟原子的碳 - 碳的键。

59. 发明授权

US5932651A Silicone/organic copolymer emulsions 失效
标题翻译：有机硅/有机共聚物乳液
公开(公告)号：US5932651A
公开(公告)日：1999-08-03
申请号：US552022
申请日：1995-11-02
申请人： Donald Taylor Liles , David Logan Murray
发明人： Donald Taylor Liles , David Logan Murray
IPC分类号： C08F2/22 , C08F2/24 , C08F20/10 , C08F30/08 , C08F220/10 , C08F220/12 , C08F220/28 , C08F230/08 , C08F246/00 , C08F283/12 , C08F290/14 , C08L83/04 , C08L83/16
CPC分类号： C08F283/124 , C08F230/08 , C08F290/148
摘要： Emulsion copolymerizing a particular crosslinker, i.e., either a siloxane or silazane, with an organic monomer, results in new and novel emulsions. An emulsion can be formed having particles consisting of polymer chains formed from organic monomer. Depending on the crosslinker and reaction conditions, these emulsion polymer chains can be either crosslinked or uncrosslinked. The uncrosslinked polymer chains can be crosslinked at a later point by the addition of a suitable catalyst.
摘要翻译：将特定交联剂（即硅氧烷或硅氮烷）与有机单体共聚的乳液导致新的和新颖的乳液。可以形成具有由有机单体形成的聚合物链构成的颗粒的乳液。根据交联剂和反应条件，这些乳液聚合物链可以是交联的或未交联的。未交联的聚合物链可以通过加入合适的催化剂在稍后交联。

60. 发明授权

US5922789A Redispersible powder compositions for preparing photographic recording materials 失效
标题翻译：用于制备照相记录材料的可再分散粉末组合物
公开(公告)号：US5922789A
公开(公告)日：1999-07-13
申请号：US58328
申请日：1998-04-09
申请人： Klaus Kohlhammer , Wolfgang Roth-Greiner , Reiner Figge , Reinhard Haerzschel
发明人： Klaus Kohlhammer , Wolfgang Roth-Greiner , Reiner Figge , Reinhard Haerzschel
IPC分类号： G03C1/047 , B41M5/00 , B41M5/50 , B41M5/52 , C08F2/24 , C08L57/04 , G03C1/04 , G03C1/053
CPC分类号： B41M5/52 , C08L57/04 , G03C1/04 , B41M5/5236 , B41M5/5254
摘要： The invention is a ready-to-use, water-redispersible powder composition useful for preparing photographic recording materials or inkjet recording materials, which comprises a mixture containing polymers made from ethylenically unsaturated monomers and gelatin, wherein the polymers are prepared by emulsion polymerization in the presence of at least one emulsifier selected from emulsifiers with ionic and nonionic groups and if exclusively ionic emulsifiers are used, the copolymerization is carried out in the presence of comonomers which contain one or more groups selected from --COOH, --OH, SO.sub.3.sup.-, NCH.sub.2 OH and --C.dbd.O.
摘要翻译：本发明是可用于制备照相记录材料或喷墨记录材料的即用型水可再分散粉末组合物，其包含含有由烯属不饱和单体和明胶制成的聚合物的混合物，其中聚合物通过在存在至少一种选自具有离子和非离子基团的乳化剂的乳化剂，并且如果使用专门的离子乳化剂，则共聚合在含有一个或多个选自-COOH，-OH，SO 3 - ，NCH 2 OH的基团的共聚单体存在下进行和-C = O。

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