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51. 发明授权

US06897256B1 Polymer dispersions 失效
标题翻译：聚合物分散体
公开(公告)号：US06897256B1
公开(公告)日：2005-05-24
申请号：US09868903
申请日：2000-01-07
申请人： Stefan Dreher , Bernd Reck , Michael Seufert , Christian Pfaff
发明人： Stefan Dreher , Bernd Reck , Michael Seufert , Christian Pfaff
IPC分类号： C08J5/04 , C08F2/20 , C08F2/24 , C08L101/02 , C09D125/06 , C09J125/06 , C08K3/20
CPC分类号： C09D125/06 , C08L2201/50 , C08L2666/04 , C09J125/06
摘要： A description is given of a polymer dispersion comprising i) polymer particles dispersed in an aqueous medium and composed of units of ethylenically unsaturated monomers, ii) a water-soluble polymeric polyelectrolyte which along a polymeric backbone carries a large number of ionic groups of uniform charge character or groups which can be ionized to such groups, and iii) an ionic surfactant which carries an ionic group having a charge character opposite to that of the polymeric polyelectrolyte, or a group which can be ionized to such a group. The polymer dispersion can be coagulated by simple dilution with water.
摘要翻译：描述了聚合物分散体，其包含i）分散在水性介质中并由烯键式不饱和单体单元组成的聚合物颗粒，ii）沿着聚合物主链的水溶性聚合聚电解质携带大量均匀电荷的离子基团可以将这些基团离子化的特征或基团，以及iii）携带具有与聚合聚电解质电荷相反的电荷特性的离子基团的离子表面活性剂，或可以离子化成这种基团的基团。聚合物分散体可以通过用水简单稀释来凝结。

52. 发明申请

US20050107510A1 Dispersions containing perfluorovinyl ether homopolymers and use thereof 失效
标题翻译：含全氟乙烯基醚均聚物的分散体及其用途
公开(公告)号：US20050107510A1
公开(公告)日：2005-05-19
申请号：US11006259
申请日：2004-12-06
申请人： Lian Tan , Richard Buckanin , E. McAlister
发明人： Lian Tan , Richard Buckanin , E. McAlister
IPC分类号： C08F2/24 , C08F16/24 , C08F116/14 , D06M15/263 , D06M15/353 , D06M15/564 , C08F2/00 , B05D1/18 , B05D3/12
CPC分类号： C08F116/14
摘要： The present invention provides a method of preparing an aqueous dispersion of poly(perfluorovinyl ether) homopolymers. The present invention further relates to a method of making an aqueous fluoropolymer dispersion comprising bicomponent particles of poly(perfluorovinyl ether) homopolymers and a second fluoropolymer. The dispersions of the present invention may be used for rendering fibrous substrates oil repellent, water repellent and/or stain repellent.
摘要翻译：本发明提供了制备聚（全氟乙烯基醚）均聚物的水分散体的方法。本发明还涉及一种制备包含聚（全氟乙烯基醚）均聚物和第二含氟聚合物的双组分颗粒的含氟聚合物水分散体的方法。本发明的分散体可用于使纤维基材具有防油性，防水性和/或防污性。

53. 发明申请

US20050070679A1 Copolymerizable emulsifiers and emulsion polymerization processes using the same 有权
标题翻译：可共聚乳化剂和使用其的乳液聚合方法
公开(公告)号：US20050070679A1
公开(公告)日：2005-03-31
申请号：US10929864
申请日：2004-08-30
申请人： Wolfgang Breuer , Patrick Tintillier
发明人： Wolfgang Breuer , Patrick Tintillier
IPC分类号： C08F2/24 , C08F222/20 , C08L1/00
CPC分类号： C08F222/20 , C08F2/24
摘要： Processes for the production of polymers by emulsion polymerization of olefinically unsaturated monomers, in which olefinically unsaturated esters corresponding to formula (I): HOOC—CH═CH—COO—(BO)z(PO)y(EO)xR1 (I) in which R1 is an alkyl group or alkenylphenol group containing 8 to 24 carbon atoms, BO is a butylene oxide unit, PO is a propylene oxide unit and EO is an ethylene oxide unit and the indices x, y and z independently of one another stand for 0 or for numbers of 1 to 50, with the proviso that at least one of the indices x, y and z is not 0, the carboxyl group of the compounds (I) being completely or partly present in neutralized form and the C═C double bond being cis- or trans-configured; are used as copolymerizable emulsifiers.
摘要翻译：通过烯属不饱和单体的乳液聚合制备聚合物的方法，其中对应于式（I）的烯属不饱和酯：HOOC-CH = CH-COO-（BO）z（PO）y（EO）xR I），其中R 1是含有8-24个碳原子的烷基或链烯基酚基，BO是环氧丁烷单元，PO是环氧丙烷单元，EO是环氧乙烷单元，并且x，y和z的指数相互独立地代表0或数字1至50，条件是指数x，y和z中的至少一个不为0，化合物（I）的羧基完全或部分存在于中和形式，并且C = C双键是顺式或反式构型的; 用作可共聚的乳化剂。

54. 发明申请

US20050059775A1 Shelf-stable silane-modified aqueous dispersion polymers 有权
标题翻译：稳定的硅烷改性水分散体聚合物
公开(公告)号：US20050059775A1
公开(公告)日：2005-03-17
申请号：US10881450
申请日：2004-06-30
申请人： Weizhen Cai , William Herdle , Jeffrey Cooke , Bruce Waldman
发明人： Weizhen Cai , William Herdle , Jeffrey Cooke , Bruce Waldman
IPC分类号： C08F2/24 , C08F8/42 , C08F220/12 , C08F230/08 , C08F263/04 , C08F265/04 , C08F283/12 , C08F290/06 , C08L43/04 , C08L51/00 , C08L51/08 , C09D143/04 , C08K5/15
CPC分类号： C08L51/003 , C08F8/42 , C08F220/12 , C08F230/08 , C08F263/04 , C08F265/04 , C08F283/12 , C08F290/06 , C08L43/04 , C08L51/085 , C09D143/04
摘要： Disclosed herein is a process for preparing a shelf-stable, one-pack, silane modified (meth)acrylic latex interpolymer composition, wherein the process comprises continuously adding at least a portion of a mixture comprising at least 0.5 mole percent of a vinyl silane comprising hydrolyzable groups and up to 99.5 mole percent of a (meth)acrylic monomer to water and a surfactant in a reaction vessel, wherein said addition is carried out in the presence of a polymerization initiator and buffer sufficient to maintain the pH of the reaction at a level of at least 6 throughout the reaction, while simultaneously hydrolyzing from about 10 to about 60% of the hydrolyzable groups of the vinyl silane.
摘要翻译：本文公开了一种制备搁置稳定的单组分硅烷改性（甲基）丙烯酸乳胶互聚物组合物的方法，其中该方法包括连续加入至少一部分包含至少0.5摩尔％的乙烯基硅烷的混合物，所述乙烯基硅烷包含可水解基团和至多99.5摩尔％的（甲基）丙烯酸单体与水和反应容器中的表面活性剂，其中所述加入在聚合引发剂和缓冲液存在下进行，足以将反应的pH保持在水平在整个反应中至少为6，同时水解约10至约60％的乙烯基硅烷的可水解基团。

55. 发明申请

US20050043463A1 Preparation of multimodal polymer dispersions using polymeric stabilizer, and use thereof 有权
标题翻译：使用聚合物稳定剂制备多峰聚合物分散体及其用途
公开(公告)号：US20050043463A1
公开(公告)日：2005-02-24
申请号：US10918121
申请日：2004-08-12
申请人： Harmin Muller
发明人： Harmin Muller
IPC分类号： C08F2/24 , C08L1/00
CPC分类号： C08F2/24
摘要： A description is given of a process for preparing bimodal or multimodal polymers from olefinically unsaturated monomers in an aqueous medium. The process features the introduction as initial charge of selected mixtures of polymeric stabilizers and of at least one selected ionic comonomer. In the polymerization process the monomer is metered continuously or discontinuously into the said initial charge. In this way it is possible by means of simple process measures to prepare bimodal or multimodal dispersions.
摘要翻译：描述了在水性介质中由烯属不饱和单体制备双峰或多峰聚合物的方法。该方法的特征在于引入作为聚合物稳定剂和至少一种选择的离子共聚单体的所选混合物的初始电荷。在聚合过程中，将单体连续地或不连续地计量到所述初始电荷中。以这种方式，可以通过简单的过程措施来制备双峰或多峰分散体。

56. 发明申请

US20050020787A1 Method of emulsion polymerization 审中-公开
标题翻译：乳液聚合方法
公开(公告)号：US20050020787A1
公开(公告)日：2005-01-27
申请号：US10922179
申请日：2004-08-19
申请人： Huub Aert , Joan Vermeersch , Etienne Thillo , Jos Huybrechts
发明人： Huub Aert , Joan Vermeersch , Etienne Thillo , Jos Huybrechts
IPC分类号： C08F2/00 , C08F2/22 , C08F2/24 , C08F2/38
CPC分类号： C08F2/24 , C08F2/22 , C08F2/38
摘要： A method has been disclosed of preparing ultrafine hydrophobic latex particles of polymers and copolymers by free radical emulsion polymerization in a water-based system, making use therefor, in order to polymerize or copolymerize monomers or monomer mixtures respectively, of at least one compound selected from the group consisting of dimers and cobalt complexes, acting as a chain transfer agent (CTA), wherein said latex particles have an average particle size of less than 100 nm, being more than 10% lower than if prepared in the absence of said CTA, characterized in that said polymerization is conducted in a water-based reaction in the presence of a chain transfer agent and of a surfactant, wherein said surfactant is present in a concentration versus said monomer or monomer mixture of from 5 up to 25% by weight for a non-ionic surfactant or from 0.05 up to 10% by weight for an ionic surfactant, more particularly a surfactant in a concentration below twice its critical micelle concentration.
摘要翻译：已经公开了一种通过在水基体系中通过自由基乳液聚合制备聚合物和共聚物的超细疏水性胶乳颗粒的方法，其用途是分别使单体或单体混合物聚合或共聚至少一种选自由二聚体和钴配合物组成的组，用作链转移剂（CTA），其中所述胶乳颗粒具有小于100nm的平均粒度，比不存在所述CTA时制备的胶乳颗粒小10％以上，其特征在于所述聚合在链转移剂和表面活性剂的存在下在水基反应中进行，其中所述表面活性剂以相对于所述单体或单体混合物的浓度存在，其浓度为5至25重量％，用于非离子表面活性剂或0.05至10重量％的离子表面活性剂，更特别是浓度低于其临界胶束浓度两倍的表面活性剂 ation。

57. 发明授权

US6130287A Colloidally stabilized emulsion polymer 失效
标题翻译：胶体稳定的乳液聚合物
公开(公告)号：US6130287A
公开(公告)日：2000-10-10
申请号：US865440
申请日：1997-05-29
申请人： Venkataram Krishnan
发明人： Venkataram Krishnan
IPC分类号： C08L9/00 , C08F2/22 , C08F2/24 , C08F2/44 , C08F36/04 , C08F236/04 , C08K5/54 , C08L33/06 , C08L47/00 , C08L41/00 , C08G77/04
CPC分类号： C08K5/54 , C08F2/22 , C08F2/44 , C08F36/04
摘要： An emulsion polymer is disclosed by the present invention. In particular, the emulsion polymer comprises a protective colloid and a functionalized silane component which is of the formula: ##STR1## wherein R" is C.sub.1 -C.sub.5 alkyl, R' is C.sub.1 -C.sub.5 alkyl, R is SH, CH.sub.2 .dbd.CH--, CH.sub.2 .dbd.C(CH.sub.3)--C(O)O--, CH.sub.2 .dbd.CH--C(O)O--, and ##STR2## n is 1-10, and m is 2 or 3.
摘要翻译：本发明公开了一种乳液聚合物。特别地，乳液聚合物包含保护胶体和官能化的硅烷组分，其具有下式：其中R“为C 1 -C 5烷基，R'为C 1 -C 5烷基，R为SH，CH 2 = CH-，CH 2 = C（CH 3）-C（O）O-，CH 2 = CH-C（O）O-，n为1-10，m为2或3。

58. 发明授权

US6077903A Continuous process for producing rubbery polymer 失效
标题翻译：生产橡胶聚合物的连续工艺
公开(公告)号：US6077903A
公开(公告)日：2000-06-20
申请号：US076289
申请日：1998-05-12
申请人： Hung Dang Ngoc
发明人： Hung Dang Ngoc
IPC分类号： C08F2/00 , C08F2/24 , C08F2/26 , C08F220/18 , C08F265/04 , C08F283/00 , C08F285/00 , C08L51/00 , C08F267/00
CPC分类号： C08F285/00 , C08F265/04 , C08F283/00 , C08L51/003
摘要： There is a need for polymers which are utilized in automotive interiors which offer increased heat and ultraviolet light resistance. It is particularly critical for polymers which are utilized in making skin compounds for automotive instrument and door panels to display excellent heat and ultraviolet light resistance. This invention discloses a continuous process for preparing a rubbery polymer which can be blended with polyvinyl chloride to make leathery compositions having good heat and ultraviolet light resistance. This technique involves utilizing a multiple continuous reactor system wherein a first phase monomer solution containing butyl acrylate, an acrylic monomer, acrylonitrile and a crosslinking agent is continuously charged into at least three initial reactors. To attain a small particle size, it is necessary to limit the solids content in each of these initial reactors. Then, a second phase monomer solution containing styrene, additional acrylonitrile and additional crosslinking agent is continuously charged into a subsequent reactor. This technique can also be utilized to synthesize core/shell or IPN structures by using multistage emulsion polymerization in which the first stage latex contains a majority of the butyl acrylate with a small latex particle size being obtained.
摘要翻译：需要用于汽车内部的聚合物，其提供增加的耐热和耐紫外线性。对于用于汽车仪表和门板的皮肤化合物的聚合物，特别关键的是显示优异的耐热和耐紫外线性。本发明公开了一种制备橡胶状聚合物的连续方法，该方法可与聚氯乙烯共混以制备具有良好耐热和耐紫外线性的革质组合物。该技术涉及利用多连续反应器系统，其中将含有丙烯酸丁酯，丙烯酸单体，丙烯腈和交联剂的第一相单体溶液连续加入到至少三个初始反应器中。为了获得小的粒径，必须限制这些初始反应器中的每一个中的固体含量。然后，将含有苯乙烯，另外的丙烯腈和另外的交联剂的第二相单体溶液连续加入随后的反应器中。该技术也可用于通过使用多阶段乳液聚合来合成核/壳或IPN结构，其中第一阶段胶乳含有大部分获得的胶乳粒度小的丙烯酸丁酯。

59. 发明授权

US6075089A Process for producing dispersions of water-soluble vinyl polymers and stabilizer for carrying out the process 失效
标题翻译：用于生产水溶性乙烯基聚合物和稳定剂分散体的方法，用于进行该方法
公开(公告)号：US6075089A
公开(公告)日：2000-06-13
申请号：US125181
申请日：1998-10-05
申请人： Werner Jaeger , Arvid Zimmermann , Mathias Hahn , Volker Hildebrandt , Karl Heinz Reichert
发明人： Werner Jaeger , Arvid Zimmermann , Mathias Hahn , Volker Hildebrandt , Karl Heinz Reichert
IPC分类号： B01F17/34 , C08F2/10 , C08F2/24 , C08F283/06 , C08K5/06 , C08F2/16 , C08L39/00
CPC分类号： C08F283/06 , C08F2/10
摘要： The present invention concerns a process for producing dispersions of watsoluble vinyl polymers and a stabilizer for carrying out this process. Such water-soluble, particularly cationic vinyl polymers, are employed on a large scale as process expediters for carrying out, for instance, separating processes in water treatment or waste-water purification, respectively, in the paper, coal and ore industries, in oil production or also in the food stuff industry, among others, for floculation, coagulation, retention or dewatering. According to the present invention, water-soluble vinyl polymers are homo- or copolymerized in the presence of a dispersion stabilizer of the invention. The stabilizer consists of a graft copolymer whose backbone is formed by polyethylene oxide and its grafted branches of cationic vinyl monomers. Among others, cationic, hydrophobically modified vinyl monomers can be advantageously employed. Copolymerizations can be carried out between cationic or non-ionic hydrophobically modified vinyl polymers and cationic or non-ionic, non-hydrophobically modified vinyl polymers.
摘要翻译： PCT No.PCT / DE97 / 00288 Sec。 371日期：1998年10月5日 102（e）日期1998年10月5日PCT提交1997年2月10日PCT公布。公开号WO97 / 30094 日期：1997年8月21日本发明涉及一种水溶性乙烯基聚合物的分散体的制造方法及其制造方法。大量使用这种水溶性，特别是阳离子乙烯基聚合物作为工艺加速器，用于在纸，煤和矿石工业，油中分别进行水处理或废水净化中的分离过程生产或在食品行业，其中包括絮凝，凝结，保留或脱水。根据本发明，水溶性乙烯基聚合物在本发明的分散稳定剂的存在下是均聚的或共聚合的。稳定剂由接枝共聚物组成，其主链由聚环氧乙烷及其接枝的阳离子乙烯基单体分支形成。其中，可以有利地使用阳离子，疏水改性的乙烯基单体。可以在阳离子或非离子疏水改性的乙烯基聚合物和阳离子或非离子，非疏水改性的乙烯基聚合物之间进行共聚。

60. 发明授权

US6037399A Microemulsion polymerization systems for the production of small melt-processible fluoropolymer particles 失效
标题翻译：用于生产小的可熔融加工的含氟聚合物颗粒的微乳液聚合体系
公开(公告)号：US6037399A
公开(公告)日：2000-03-14
申请号：US672779
申请日：1996-06-28
申请人： Huey Shen Wu , Jack Hegenbarth , Chen Xin-Kang , Chen Jian-Guo
发明人： Huey Shen Wu , Jack Hegenbarth , Chen Xin-Kang , Chen Jian-Guo
IPC分类号： C08F2/24 , C08F14/18 , C08F214/26 , C08F216/14 , C08L27/12 , C09D127/12 , C08K5/02
CPC分类号： C08F214/26 , C08F216/1408
摘要： An aqueous microemulsion polymerization procedure is described in which very small colloidal melt-processible fluoropolymer particles are produced from at least one gaseous monomer and optionally TFE. The polymerization procedure involves forming a microemulsion of at least one liquid organic compound; adding at least one gaseous free-radical polymerizable monomer to the microemulsion; and initiating polymerization by adding a free-radical initiator to the mixture.
摘要翻译：描述了一种水性微乳液聚合方法，其中由至少一种气态单体和任选的TFE制备非常小的胶体可熔融加工的含氟聚合物颗粒。聚合方法包括形成至少一种液体有机化合物的微乳液; 向微乳液中加入至少一种气态可自由基聚合的单体; 并通过向混合物中加入自由基引发剂引发聚合反应。

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