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1. 发明授权

US6075089A Process for producing dispersions of water-soluble vinyl polymers and stabilizer for carrying out the process 失效
标题翻译：用于生产水溶性乙烯基聚合物和稳定剂分散体的方法，用于进行该方法
公开(公告)号：US6075089A
公开(公告)日：2000-06-13
申请号：US125181
申请日：1998-10-05
申请人： Werner Jaeger , Arvid Zimmermann , Mathias Hahn , Volker Hildebrandt , Karl Heinz Reichert
发明人： Werner Jaeger , Arvid Zimmermann , Mathias Hahn , Volker Hildebrandt , Karl Heinz Reichert
IPC分类号： B01F17/34 , C08F2/10 , C08F2/24 , C08F283/06 , C08K5/06 , C08F2/16 , C08L39/00
CPC分类号： C08F283/06 , C08F2/10
摘要： The present invention concerns a process for producing dispersions of watsoluble vinyl polymers and a stabilizer for carrying out this process. Such water-soluble, particularly cationic vinyl polymers, are employed on a large scale as process expediters for carrying out, for instance, separating processes in water treatment or waste-water purification, respectively, in the paper, coal and ore industries, in oil production or also in the food stuff industry, among others, for floculation, coagulation, retention or dewatering. According to the present invention, water-soluble vinyl polymers are homo- or copolymerized in the presence of a dispersion stabilizer of the invention. The stabilizer consists of a graft copolymer whose backbone is formed by polyethylene oxide and its grafted branches of cationic vinyl monomers. Among others, cationic, hydrophobically modified vinyl monomers can be advantageously employed. Copolymerizations can be carried out between cationic or non-ionic hydrophobically modified vinyl polymers and cationic or non-ionic, non-hydrophobically modified vinyl polymers.
摘要翻译： PCT No.PCT / DE97 / 00288 Sec。 371日期：1998年10月5日 102（e）日期1998年10月5日PCT提交1997年2月10日PCT公布。公开号WO97 / 30094 日期：1997年8月21日本发明涉及一种水溶性乙烯基聚合物的分散体的制造方法及其制造方法。大量使用这种水溶性，特别是阳离子乙烯基聚合物作为工艺加速器，用于在纸，煤和矿石工业，油中分别进行水处理或废水净化中的分离过程生产或在食品行业，其中包括絮凝，凝结，保留或脱水。根据本发明，水溶性乙烯基聚合物在本发明的分散稳定剂的存在下是均聚的或共聚合的。稳定剂由接枝共聚物组成，其主链由聚环氧乙烷及其接枝的阳离子乙烯基单体分支形成。其中，可以有利地使用阳离子，疏水改性的乙烯基单体。可以在阳离子或非离子疏水改性的乙烯基聚合物和阳离子或非离子，非疏水改性的乙烯基聚合物之间进行共聚。

2. 发明授权

US6133363A Process for producing dispersions of water-soluble vinyl polymers and stabilizer for implementing the process 失效
标题翻译：用于生产水溶性乙烯基聚合物和稳定剂的分散体的方法用于实施该方法
公开(公告)号：US6133363A
公开(公告)日：2000-10-17
申请号：US973814
申请日：1998-03-06
申请人： Werner Jaeger , Arvid Zimmermann , Karl-Heinz Reichert , Katrin Zeitz
发明人： Werner Jaeger , Arvid Zimmermann , Karl-Heinz Reichert , Katrin Zeitz
IPC分类号： C02F1/56 , C08F2/10 , C08F20/34 , C08F293/00 , C08F2/16
CPC分类号： C08F20/34 , C02F1/56
摘要： The invention relates to a method of manufacturing dispersions of water-sble cationic vinyl polymers which can be used as process aids for separation processes, e.g. as flocculation aids, coagulation agents, retention agents or dehydration accelerators. The dispersions are produced by radical homopolymerization of cationic, hydrophobically modified vinyl monomers or their copolymerization with water-soluble vinyl monomers in aqueous saline solutions. In this respect block copolymers are used as dispersion stabilizers, and which are formed from a cationic vinyl monomer and ethyleneoxide.
摘要翻译： PCT No.PCT / DE96 / 01063 Sec。 371日期1998年3月6日 102（e）1998年3月6日PCT PCT 1996年6月10日PCT公布。出版物WO96 / 41821 日期1996年12月27日本发明涉及一种制备水溶性阳离子乙烯基聚合物分散体的方法，其可用作分离方法的加工助剂，例如，作为絮凝助剂，凝结剂，保留剂或脱水促进剂。分散体是通过阳离子，疏水改性的乙烯基单体的自由基均聚或其与水溶性乙烯基单体在含水盐水溶液中的共聚来制备的。在这方面，嵌段共聚物用作分散稳定剂，并且由阳离子乙烯基单体和环氧乙烷形成。

3. 发明申请

US20060142464A1 Polymer dispersion and process for preparing a polymer dispersion 有权
标题翻译：聚合物分散体和制备聚合物分散体的方法
公开(公告)号：US20060142464A1
公开(公告)日：2006-06-29
申请号：US11315967
申请日：2005-12-22
申请人： Mathias Hahn , Werner Jaeger , Andre Laschewsky , Bernd Paulke , Christian Przybyla , Achim Sieger
发明人： Mathias Hahn , Werner Jaeger , Andre Laschewsky , Bernd Paulke , Christian Przybyla , Achim Sieger
IPC分类号： C08F2/16
CPC分类号： C08F2/16 , C08F8/12 , C08F220/34 , C08F220/56 , C08F220/60 , C08F226/04 , C08F265/10 , C08F271/00 , C08F2800/10 , C08F2800/20 , C08L51/003 , D21H17/375 , D21H17/455 , D21H21/16 , C08L2666/02 , C08F226/02
摘要： The invention relates to a process for preparing an aqueous polymer dispersion comprising reacting, in the presence of a polymeric cationic co-stabiliser (A), one or more monomers (m), and a polymer (B) of a monomer mixture comprising at least one monomer (x) having a primary, secondary or tertiary amine or amide group and at least one olefinic unsaturation, and, at least one catonic monomer (y) having at least one olefinic unsaturation. The invention also relates to a polymer dispersion, a process for preparing a polymeric stabiliser (C), a polymeric stabiliser (C) and a process for producing paper.
摘要翻译：本发明涉及一种制备含水聚合物分散体的方法，包括在聚合物阳离子共稳定剂（A），一种或多种单体（m）和至少包含至少一种单体混合物的单体混合物的聚合物（B）的存在下，具有伯，仲或叔胺或酰胺基团和至少一个烯属不饱和基团的一种单体（x），和至少一种具有至少一个烯属不饱和键的单体（y）。本发明还涉及聚合物分散体，制备聚合物稳定剂（C），聚合物稳定剂（C）和生产纸的方法的方法。

4. 发明授权

US07122618B2 Quaternary polyamidoamines, the production thereof, corresponding agents and the use thereof 失效
标题翻译：第四纪聚酰胺胺，其制备，相应的试剂及其用途
公开(公告)号：US07122618B2
公开(公告)日：2006-10-17
申请号：US10485262
申请日：2002-08-12
申请人： Helmut Witteler , Axel Sanner , John-Bryan Speakman , Christian Drohmann , Mathias Hahn , Werner Jaeger
发明人： Helmut Witteler , Axel Sanner , John-Bryan Speakman , Christian Drohmann , Mathias Hahn , Werner Jaeger
IPC分类号： C08G69/26 , A61K7/00 , A61K31/74 , A61K47/48
CPC分类号： A61Q5/12 , A61K8/84 , A61Q5/06 , C08G73/0293
摘要： The present invention relates to quaternized polyamidoamines which have at least one structural unit of the formula VII in which R1, R2, R4 are straight-chain or branched organic radicals optionally containing heteroatoms; R5 is hydrogen or alkyl, R7 is hydrogen or alkyl or two radicals R7 together form a radical having a meaning given for R4, b is an integer from 0 to 50, and c is an integer from 1 to 50. The invention also relates to the preparation of the quaternary polyamidoamines, to compositions which comprise these compounds, and to the use thereof for cosmetic and pharmaceutical purposes, and in the fields of crop protection and textile dyeing. The present invention also relates to the use of quaternized polyamidoamines of the ionene type as biostatic or biocide and thus also biocidal compositions based on quaternized polyamidoamines.
摘要翻译：本发明涉及具有式VII中至少一个结构单元的季铵化聚酰胺胺，其中R 1，R 2，R 4，4，任选含有杂原子的直链或支链有机基团; R 5是氢或烷基，R 7是氢或烷基或两个基团R 7一起形成具有给定R 1的含义的基团， SUP> 4，b是0至50的整数，c是1至50的整数。本发明还涉及季戊聚酰胺胺的制备，包含这些化合物的组合物以及使用用于化妆品和药物目的，以及作物保护和纺织品染色领域。本发明还涉及紫罗烯类型的季铵化聚酰胺胺作为生物抑制剂或杀生物剂，因此也是基于季铵化聚酰胺胺的杀生物组合物的用途。

5. 发明申请

US20060229401A1 Process for preparing a polymer dispersion 失效
标题翻译：制备聚合物分散体的方法
公开(公告)号：US20060229401A1
公开(公告)日：2006-10-12
申请号：US11450338
申请日：2006-06-12
申请人： Oliver Struck , Christian Przybyla , Achim Sieger , Mathias Hahn , Dirk Ruppelt , Werner Jaeger
发明人： Oliver Struck , Christian Przybyla , Achim Sieger , Mathias Hahn , Dirk Ruppelt , Werner Jaeger
IPC分类号： C08K3/20
CPC分类号： C08F2/10 , C08F2/24
摘要： The present invention relates to a process for preparing an aqueous polymer dispersion comprising: preparing a dispersant co-polymer of a monomer mixture (M) by polymerising the monomer mixture (M) in a reaction medium which is substantially free from organic solvents and/or substantially free from monomers which are not soluble in water, the monomer mixture (M) comprises at least one cationic vinyl monomer (m3) and at least one monomer (m4) which is tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, or a monomer of the general formula (I): wherein R1 is hydrogen or methyl, R2 is hydrogen or C1-C2 alkyl, R3 is hydrogen, C1-C4 alkyl, phenyl, or benzyl, n=1 to 4, and x=1 to 50, and then, polymerising one or more water-soluble monomers (m) in an aqueous solution of a salt in the presence of the obtained dispersant polymer. The invention also relates to an aqueous polymer dispersion, use of the dispersion and a process for the production of paper.
摘要翻译：本发明涉及一种制备含水聚合物分散体的方法，其包括：通过在基本上不含有机溶剂的反应介质中聚合单体混合物（M）和/或形成单体混合物（M）来制备单体混合物（M）的分散剂共聚物基本上不含不溶于水的单体，单体混合物（M）包含至少一种阳离子乙烯基单体（m 3/3）和至少一种单体（m 4）），其是丙烯酸四氢糠酯，甲基丙烯酸四氢糠酯或通式（I）的单体：其中R 1是氢或甲基，R 2是氢或C

6. 发明授权

US07091273B2 Process for preparing a polymer dispersion 失效
公开(公告)号：US07091273B2
公开(公告)日：2006-08-15
申请号：US10430422
申请日：2003-05-07
申请人： Oliver Struck , Christian Przybyla , Achim Sieger , Mathias Hahn , Dirk Ruppelt , Werner Jaeger
发明人： Oliver Struck , Christian Przybyla , Achim Sieger , Mathias Hahn , Dirk Ruppelt , Werner Jaeger
IPC分类号： C08F2/16 , C08F2/20 , C08F2/24 , D21H17/45
CPC分类号： C08F2/10 , C08F2/24
摘要： The present invention relates to a process for preparing an aqueous polymer dispersion comprising: preparing a dispersant co-polymer of a monomer mixture (M) by polymerising the monomer mixture (M) in a reaction medium which is substantially free from organic solvents and/or substantially free from monomers which are not soluble in water, the monomer mixture (M) comprises at least one cationic vinyl monomer (m3) and at least one monomer (m4) which is tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, or a monomer of the general formula (I): wherein R1 is hydrogen or methyl, R2 is hydrogen or C1–C2 alkyl, R3 is hydrogen, C1–C4 alkyl, phenyl, or benzyl, n=1 to 4, and x=1 to 50, and then, polymerising one or more water-soluble monomers (m) in an aqueous solution of a salt in the presence of the obtained dispersant polymer. The invention also relates to an aqueous polymer dispersion, use of the dispersion and a process for the production of paper.

7. 发明申请

US20050182222A1 Water soluble branched block copolymers 审中-公开
标题翻译：水溶性支链嵌段共聚物
公开(公告)号：US20050182222A1
公开(公告)日：2005-08-18
申请号：US10509138
申请日：2003-03-21
申请人： Werner Jaeger , Mathias Hahn , Antje Lieske , Heike Korth , Rainer Staeck , Angelo Scordialo
发明人： Werner Jaeger , Mathias Hahn , Antje Lieske , Heike Korth , Rainer Staeck , Angelo Scordialo
IPC分类号： C01B39/36 , C01B39/38 , C08F271/00 , C08F293/00 , C08L53/00
CPC分类号： C08L53/00 , C01B39/36 , C01B39/38 , C08F293/005 , C08L53/005 , Y10S423/21 , C08L2666/02
摘要： The invention pertains to water soluble branched block copolymers comprising quaternary ammonium compounds and poly(alkylene glycols), whereby the molecular building blocks, which contain the quaternary ammonium groups, form backbone chains that are linked together in a wide mesh manner by the poly(alkylene glycol) blocks.
摘要翻译：本发明涉及包含季铵化合物和聚（亚烷基二醇）的水溶性支链嵌段共聚物，由此含有季铵基团的分子结构单元形成主链，其以宽网格方式连接在一起，由聚（亚烷基乙二醇）块。

8. 发明申请

US20050182181A1 Water soluble-polymer dispersion and method of producing a water-soluble polymer dispersion 有权
标题翻译：水溶性聚合物分散体和水溶性聚合物分散体的制造方法
公开(公告)号：US20050182181A1
公开(公告)日：2005-08-18
申请号：US10514854
申请日：2003-05-15
申请人： Oliver Struck , Christian Przybyla , Werner Jaeger , Mathias Hahn , Dirk Ruppelt
发明人： Oliver Struck , Christian Przybyla , Werner Jaeger , Mathias Hahn , Dirk Ruppelt
IPC分类号： C08L33/00 , C02F1/56 , C02F11/14 , C08F2/10 , C08F290/06 , C08L71/02 , D21H21/10 , C08K3/00
CPC分类号： C08F290/062 , C02F1/56 , C02F11/14 , C08F2/10 , D21H21/10
摘要： The present invention relates to a water-soluble polymer dispersion comprising:a dispersed polymer made up of at least one water-soluble monomer A and at least one water-soluble cationic monomer B, at least one stabiliser C, and at least one cationic polyelectrolyte as co-stabiliser D. It also relates to a method of producing a polymer dispersion and to a paper-making process.
摘要翻译：本发明涉及一种水溶性聚合物分散体，其包含：由至少一种水溶性单体A和至少一种水溶性阳离子单体B，至少一种稳定剂C和至少一种阳离子聚电解质作为共稳定剂D.它还涉及一种制备聚合物分散体和造纸过程的方法。

9. 发明授权

US06423801B1 Branched polyammonium compounds of high molecular weight and processes for producing said compounds 失效
标题翻译：高分子量的支化聚铵化合物和用于制备所述化合物的方法
公开(公告)号：US06423801B1
公开(公告)日：2002-07-23
申请号：US09029002
申请日：1999-02-08
申请人： Mathias Hahn , Werner Jaeger , Jeffrey R. Cramm
发明人： Mathias Hahn , Werner Jaeger , Jeffrey R. Cramm
IPC分类号： C08F2606
CPC分类号： C02F1/56 , C07D207/08 , C08F226/02
摘要： The invention is concerned with water soluble high-molecular weight quaternary ammonium graft polymer, wherein ammonium salt side chains are grafted onto a polyamine backbone under free radical conditions, and wherein the initiator system comprises a free radical-producing oxidizing agent and the polyamine backbone polymer.
摘要翻译：本发明涉及水溶性高分子量季铵接枝聚合物，其中铵盐侧链在自由基条件下接枝到多胺骨架上，并且其中引发剂体系包含产生自由基的氧化剂和多胺主链聚合物。

10. 发明授权

US6124396A Branched water-soluble acrylamide copolymers of high molecular weight and process for manufacturing them 失效
标题翻译：高分子量的支链水溶性丙烯酰胺共聚物及其制造方法
公开(公告)号：US6124396A
公开(公告)日：2000-09-26
申请号：US42
申请日：1998-03-23
申请人： Mathias Hahn , Werner Jaeger , Jeffrey R. Cramm , Wesley L. Whipple
发明人： Mathias Hahn , Werner Jaeger , Jeffrey R. Cramm , Wesley L. Whipple
IPC分类号： C02F1/56 , C08F271/00 , C08F3/32 , C08L37/00 , C08J41/00
CPC分类号： C08F271/00 , C02F1/56
摘要： This invention concerns comb-like branched, water-soluble cationic acrylamide copolymers, prepared from 1-40 mole % of a water-soluble cationic prepolymer backbone of formula I--[A--B--NR].sub.n -- Iwhere A is an unsaturated ammonium compound or acrylamide and B--NR-- is selected from the group consisting of olefinically unsaturated, functional amine-group-containing monomers, triethanolamine, and diethanolalkylamine, and the amount of B--NR is 1 mole % to 50 mole % and n represents a degree of polymerization which leads to molecular weights in the range from 1000 to 200,000 g/mole, and 60 to 99 mole % acrylamide by graft polymerization of the acrylamide onto the amine-group-containing cationic prepolymer backbone with a water-in-oil emulsion technique, and the comb-like branched acrylamide copolymers have a molecular weight of >1 million.
摘要翻译： PCT No.PCT / DE96 / 01273。 371日期：1998年3月23日 102（e）1998年3月23日PCT 1997年1月30日PCT PCT。出版物WO97 / 03098 日本1997年1月30日本发明涉及由1-40摩尔％的式I [AB-NR] n-1的水溶性阳离子预聚物主链制备的梳状支链型水溶性阳离子丙烯酰胺共聚物，其中A为不饱和铵化合物或丙烯酰胺和B-NR-选自烯属不饱和，含官能胺基单体，三乙醇胺和二乙醇烷基胺，B-NR的量为1摩尔％至50摩尔％，n 表示通过将丙烯酰胺接枝聚合到含胺基的阳离子预聚物主链上的水溶性聚合，其分子量为1000至200,000g / mol，和60至99mol％的丙烯酰胺，油乳液技术，梳状支链丙烯酰胺共聚物的分子量> 100万。

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