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    • 56. 发明授权
    • Catalyst material recovery or concentration process
    • 催化剂材料回收或浓缩过程
    • US4845306A
    • 1989-07-04
    • US218017
    • 1988-07-12
    • Thomas A. Puckette
    • Thomas A. Puckette
    • B01J31/40C07C45/50C07C45/72C07C45/80
    • B01J31/04B01J31/24B01J31/2404B01J31/4046C07C45/50C07C45/72C07C45/80B01J2231/321B01J2531/822Y02P20/584
    • Disclosed is a process for recovering or concentrating active catalyst materials from a substantially homogeneous system comprising:(a) active catalyst materials which comprise(i) triorganophosphine-rhodium complexes, and(ii) free triorganophosphine;(b) oxidized triorganophosphine residues,(c) iron carboxylate salts,(d) pump oils, and(e) aldehydes and aldol condensation products thereof;said processing comprising:(1) admixing a portion of said homogeneous system with about 1 up to 100 volumes (relative to the volume of said portion) of at least one nonpolar hydrophobic hydrocarbon diluent selected from the group consisting of saturated or unsaturated aliphatic hydrocarbon having in the range of 3 up to 20 carbon atoms and aromatic or hydrocarbyl-substituted aromatic hydrocarbons having in the range of 6 up to 22 carbon atoms to produce a diluted homogeneous system,(2) contacting said diluted homogeneous system with 0.1 up to 20 volumes (relative to the volume of said nonpolar hydrophobic solvent) of at least one aqueous polar hydrophilic organic solvent selected from the group consisting of:aliphatic carboxylic acids having in the range of 1 up to 3 carbon atoms,aliphatic alcohols having in the range of 1 up to 3 carbon atoms,acetonitrile,acetone,dimethylformamide,dimethylacetamide,methyl ethyl ketone,1,4-dioxane,polyols having in the range of 2 up to 6 carbon atoms,glycol ethers having in the range of 4 up to 12 carbon atoms, as well as mixtures of any two or more thereof, and allowing the nonpolar hydrophobic hydrocarbon solvent and the aqueous polar hydrophilic organic solvent to separate into layers, and thereafter(3) separating the hydrocarbon layer from the aqueous polar hydrophilic organic layer.
    • 公开了一种从基本均匀的系统回收或浓缩活性催化剂材料的方法,包括:(a)活性催化剂材料,其包含(i)三有机膦 - 铑络合物和(ii)游离三有机膦; (b)氧化三有机膦残基,(c)羧酸铁盐,(d)泵油和(e)醛和醛醇缩合产物; 所述加工包括:(1)将所述均相体系的一部分与约1至多100体积(相对于所述部分的体积)混合至少一种非极性疏水性烃稀释剂,所述非极性疏水性烃稀释剂选自饱和或不饱和脂族烃,所述饱和或不饱和脂族烃具有 在3至20个碳原子的范围内和具有6至22个碳原子范围的芳族或烃基取代的芳族烃以产生稀释的均相体系,(2)使所述稀释均匀体系与0.1至20体积 (相对于所述非极性疏水溶剂的体积)至少一种极性亲水性有机溶剂水溶液,其选自:具有1至3个碳原子的脂族羧酸,脂族醇的范围为1 最多3个碳原子,乙腈,丙酮,二甲基甲酰胺,二甲基乙酰胺,甲基乙基酮,1,4-二恶烷,2至6个汽车范围内的多元醇 具有4至12个碳原子范围内的原子,二醇醚,以及它们的任何两种或多种的混合物,并使非极性疏水性烃溶剂和极性亲水性有机溶剂水分离成层,然后( 3)从含水极性亲水性有机层中分离烃层。