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51. 发明授权

US07226971B2 Polyester resin with carbamate functionality, a method of preparing the resin, and a coating composition utilizing the resin 有权
标题翻译：具有氨基甲酸酯官能团的聚酯树脂，制备树脂的方法和使用该树脂的涂料组合物
公开(公告)号：US07226971B2
公开(公告)日：2007-06-05
申请号：US10206418
申请日：2002-07-26
申请人： Swaminathan Ramesh , Marvin L Green
发明人： Swaminathan Ramesh , Marvin L Green
IPC分类号： C08G69/44
CPC分类号： B01F17/005 , C01P2004/61 , C01P2006/22 , C08G63/42 , C08G63/58 , C08G63/664 , C08G63/6854 , C09B67/009 , C09C1/3676 , C09C3/08 , C09C3/10 , C09D167/04 , C09D201/005 , C09D201/025
摘要： The present invention is directed to a polyester resin for use in a coating composition. The polyester resin is the reaction product of a first compound comprising a plurality of hydroxyl groups, a lactone compound, a carboxylic acid anhydride, an epoxy compound having at least one epoxy group, and a carbamate compound. The present invention is also directed to a coating composition including the polyester resin and to a method of preparing the resin.
摘要翻译：本发明涉及一种用于涂料组合物的聚酯树脂。聚酯树脂是包含多个羟基的第一化合物，内酯化合物，羧酸酐，具有至少一个环氧基的环氧化合物和氨基甲酸酯化合物的反应产物。本发明还涉及包含聚酯树脂的涂料组合物和制备树脂的方法。

52. 发明申请

US20070059532A1 Thermosetting coating compositions with multiple cure mechanisms 有权
标题翻译：具有多种固化机理的热固性涂料组合物
公开(公告)号：US20070059532A1
公开(公告)日：2007-03-15
申请号：US11227866
申请日：2005-09-15
申请人： Swaminathan Ramesh , Sunitha Grandhee
发明人： Swaminathan Ramesh , Sunitha Grandhee
IPC分类号： C08G18/00
CPC分类号： C09D201/025 , C08G18/3234 , C08G18/3831 , C08G18/672 , C08G18/718 , C08G18/728 , C08G18/792 , C09D175/12 , C09D175/16 , Y10T428/31551
摘要： A curable coating composition comprises (a) a compound having two types of functionality, functionality A and functionality B, that react in curing the coating, (b) a second material having functionality C that reacts with functionality A in curing the coating, and (c) a crosslinker having a plurality of functional groups D that react at least with functionality B in curing the coating. Functional groups D may also react with functionality C and/or with a functional group formed as a result of the reaction of functionality C with functionality A. The curable coating composition is applied to a substrate and cured under conditions appropriate for reactions of the functionalities A, B, C, and D.
摘要翻译：可固化涂料组合物包含（a）具有两种功能性的功能性官能团A和官能度B的化合物，其在固化涂层时反应，（b）具有官能度C的第二种材料，其与固化涂层中的官能度A反应，和 c）具有多个官能团D的交联剂，其在固化涂层中至少与官能团B反应。功能基团D也可与功能性C反应和/或与由官能度C与官能度A反应而形成的官能团反应。可固化涂料组合物施用于基材并在适合于官能度A的反应的条件下固化，B，C和D.

53. 发明申请

US20060047036A1 Clearcoat composition compatible with both waterborne and solventborne basecoats 有权
标题翻译：透明涂料组合物与水性和溶剂型底漆兼容
公开(公告)号：US20060047036A1
公开(公告)日：2006-03-02
申请号：US10929239
申请日：2004-08-30
申请人： Jun Lin
发明人： Jun Lin
IPC分类号： C08K5/24
CPC分类号： C08G18/792 , C08G18/2825 , C09D175/04 , C09D201/025 , C09D201/10 , C08L2666/16
摘要： A curable film-forming coating composition, typically a clearcoat, having improved compatibility over waterborne and solventborne basecoats. The composition includes a film-forming binder comprising a carbamate material, a curing agent, typically a monomeric melamine curing agent, and a hydroxy functional silane component. When used as a clearcoat over a standard pigmented basecoat, the resulting coating provides a substantially wrinkle free appearance and excellent adhesion to both waterborne and solventborne basecoats.
摘要翻译：一种可固化的成膜涂料组合物，通常为透明涂料，具有改善的相对于水性和溶剂型底涂层的相容性。组合物包括含有氨基甲酸酯材料，固化剂，通常为单体三聚氰胺固化剂和羟基官能的硅烷组分的成膜粘合剂。当用作标准着色底漆时的透明涂层时，所得涂层提供基本上无皱纹的外观和对水性和溶剂型底涂层的优异粘合性。

54. 发明申请

US20060004150A1 Thermally curable, thixotropic blends containing carbamate and/or allophanate groups 失效
标题翻译：含有氨基甲酸酯和/或脲基甲酸酯基团的可热固化的触变性共混物
公开(公告)号：US20060004150A1
公开(公告)日：2006-01-05
申请号：US11213209
申请日：2005-08-26
申请人： Hubert Baumgart , Michael Gessner , Bruce Oermann , Paul Harris
发明人： Hubert Baumgart , Michael Gessner , Bruce Oermann , Paul Harris
IPC分类号： C08G63/91
CPC分类号： C09K3/10 , C08G71/00 , C09D5/04 , C09D201/025 , Y10S525/903
摘要： The invention provides heat-curable thixotropic mixtures containing carbamate and/or allophanate groups, including at least one oligomer and/or polymer containing at least one of carbamate and allophanate groups, and at least one thixotropic agent that is a urea derivative preparable by reacting at least one amine and/or water with at least one isocyanate in the presence of at least one amino resin. The invention further provides processes for preparing the mixtures and coating materials, adhesives and sealing compounds prepared from the mixtures.
摘要翻译：本发明提供含有氨基甲酸酯和/或脲基甲酸酯基团的热固化触变性混合物，包括至少一种含有氨基甲酸酯和脲基甲酸酯基团中的至少一种的低聚物和/或聚合物，以及至少一种触变剂，其是可通过在至少一种胺和/或水与至少一种异氰酸酯在至少一种氨基树脂的存在下进行。本发明还提供了由混合物制备混合物和涂料，粘合剂和密封化合物的方法。

55. 发明授权

US06962730B2 Coating composition containing crosslinkable monomeric difunctional compounds having at least thirty carbon atoms 有权
标题翻译：包含具有至少30个碳原子的可交联单体双官能化合物的涂料组合物
公开(公告)号：US06962730B2
公开(公告)日：2005-11-08
申请号：US10351079
申请日：2003-01-23
申请人： Walter H. Ohrbom , John A. Gilbert , Patricia A. Herrel , Marvin L. Green , Joanne Casale , Thomas G. Savino
发明人： Walter H. Ohrbom , John A. Gilbert , Patricia A. Herrel , Marvin L. Green , Joanne Casale , Thomas G. Savino
IPC分类号： C09D5/02 , C09D133/14 , C09D201/00 , C09D201/02 , B05D3/00
CPC分类号： C09D5/02 , C09D133/14 , C09D201/00 , C09D201/02 , C09D201/025
摘要： The invention provides coating compositions comprising a reactive component (a) which is substantially free of any heteratoms and is a not a crystalline solid at room temperature and which comprises from (i) 12 to 72 carbon atoms, and (ii) at least two functional groups, and (b) a crosslinking agent comprising a plurality of functional groups (iii) reactive with the functional groups (ii) of compound (a), wherein functional groups (ii) and (iii) are selected such that reaction there between produces a thermally irreversible chemical linkage. The coating compositions of the invention provide improved solids, chip resistance, flexibility and/or scratch & mar resistance while maintaining desirable and/or improved performance characteristics with regard to environmental etch, relative humidity, QCT, chip resistance, thermoshock resistance, cold crack resistance, adhesion and the like.
摘要翻译：本发明提供涂料组合物，其包含基本上不含任何杂原子的反应性组分（a），并且在室温下不是结晶固体，并且其包含（i）12至72个碳原子，和（ii）至少两个官能基团，和（b）包含与化合物（a）的官能团（ⅱ）反应的多个官能团（ⅲ）的交联剂，其中选择官能团（ⅱ）和（ⅲ），使得其中的反应产生热不可逆化学键。本发明的涂料组合物在环境蚀刻，相对湿度，QCT，芯片电阻，耐热裂纹性，耐寒裂纹性方面保持理想和/或改进的性能特征，提供了改进的固体，耐芯片性，柔性和/ ，粘合等。

56. 发明申请

US20050080196A1 Carbamate functional addition polymers and method for their preparation 失效
标题翻译：氨基甲酸酯官能加成聚合物及其制备方法
公开(公告)号：US20050080196A1
公开(公告)日：2005-04-14
申请号：US10957556
申请日：2004-10-01
申请人： Swaminathan Ramesh , Paul Harris , Walter Ohrbom , Donald Campbell , Donald St. Aubin , Ulrike Rockrath
发明人： Swaminathan Ramesh , Paul Harris , Walter Ohrbom , Donald Campbell , Donald St. Aubin , Ulrike Rockrath
IPC分类号： C08F8/14 , C08F8/30 , C08F222/20 , C08F222/22 , C09D201/02 , C08L29/00
CPC分类号： C08F220/06 , C08F8/00 , C08F8/14 , C08F220/08 , C08F222/20 , C08F222/22 , C08L2312/00 , C09D133/14 , C09D201/025 , C08F265/06
摘要： Disclosed is a method for making nongelled addition polymers, especially carbamate functional additional polymers from linear unsaturated anhydrides. The method comprises reacting an unsaturated linear anhydride with an active hydrogen compound to provide two monomers comprising polymerizable C═C bonds, at least one of said monomers comprising an acid functional group; polymerizing the polymerizable C═C bonds of the two monomers to provide an acid functional polymerization product; and reacting the acid functional polymerization product with an epoxy functional compound to provide a nongelled addition polymer, wherein the disclosed method does not include a step comprising the physical removal of any acid functional monomers or polymerization products. Also disclosed is a curable coating composition containing the resulting carbamate functional polymer, as well as a coated substrate comprising a cured film resulting from the application and curing of the disclosed curable coating composition.
摘要翻译：公开了一种用于制备非线性加成聚合物，特别是来自线性不饱和酸酐的氨基甲酸酯官能的另外的聚合物的方法。该方法包括使不饱和直链酸酐与活性氢化合物反应以提供包含可聚合C = C键的两种单体，至少一种所述单体包含酸官能团; 聚合两种单体的可聚合C = C键以提供酸官能聚合产物; 并使酸官能聚合产物与环氧官能化合物反应以提供不通电的加成聚合物，其中所公开的方法不包括物理除去任何酸官能单体或聚合产物的步骤。还公开了含有所得氨基甲酸酯官能聚合物的可固化涂料组合物，以及包含由所公开的可固化涂料组合物的施用和固化产生的固化膜的涂布基材。

57. 发明授权

US06858674B2 Carbamate functional materials, a method of making said materials, and curable coating compositions containing said materials 失效
标题翻译：氨基甲酸酯官能材料，制备所述材料的方法和含有所述材料的可固化涂料组合物
公开(公告)号：US06858674B2
公开(公告)日：2005-02-22
申请号：US10285594
申请日：2002-10-31
申请人： Walter H. Ohrbom , Craig S. Schang
发明人： Walter H. Ohrbom , Craig S. Schang
IPC分类号： C07C217/12 , C08G18/28 , C08G18/38 , C09D201/02 , C08F8/32
CPC分类号： C08G18/3831 , C07C217/12 , C08G18/285 , C09D201/025 , Y10T428/31529 , Y10T428/31663
摘要： The invention provides a primary carbamate functional material of the formula: a method of making said materials and curable coating compositions comprising the primary carbamate functional material of the invention. The primary carbamate functional material comprises the reaction product of (1) at least one material P comprising one or more functional groups (i) which are reactive with a functional group Z but which are substantially nonreactive with a primary carbamate group X of monomeric reactive compound (2), and (2) a monomeric reactive compound comprising one or more structures of a particular formula.
摘要翻译：本发明提供下式的主要氨基甲酸酯官能材料：制备所述材料的方法和包含本发明的主要氨基甲酸酯官能材料的可固化涂料组合物。主要的氨基甲酸酯官能材料包括（1）至少一种包含一个或多个官能团（i）的材料P的反应产物，其与官能团Z反应，但是与单体反应性化合物的伯氨基甲酸酯基团X基本上不反应（2）和（2）包含一种或多种特定结构的单体反应性化合物。

58. 发明授权

US06852771B2 Dual radiation/thermal cured coating composition 有权
标题翻译：双辐射/热固化涂料组合物
公开(公告)号：US06852771B2
公开(公告)日：2005-02-08
申请号：US10454056
申请日：2003-06-04
申请人： Thomas C. Balch , Lyle A. Caillouette , Karl R. Gust
发明人： Thomas C. Balch , Lyle A. Caillouette , Karl R. Gust
IPC分类号： B05D3/02 , B05D3/06 , B05D7/00 , B05D7/02 , C08F283/00 , C08F283/01 , C08F290/14 , C08G18/42 , C08G18/48 , C08G18/62 , C08G18/79 , C08G59/18 , C08J3/24 , C09D175/06 , C09D175/16 , C09D201/02 , G11B5/702 , C08J3/28 , C09D5/03 , C09D167/00 , C09D171/00 , C09D175/14
CPC分类号： C09D175/16 , B05D3/0209 , B05D3/0254 , B05D3/067 , B05D7/02 , B05D7/53 , B05D7/54 , C08F283/006 , C08F283/01 , C08F290/141 , C08F290/147 , C08G18/4202 , C08G18/4208 , C08G18/4277 , C08G18/4854 , C08G18/6254 , C08G18/792 , C08G59/18 , C08J3/243 , C09D175/06 , C09D201/025 , G11B5/7021 , C08L75/04 , C08L2666/18
摘要： Coating composition comprising (a1) radiation curable component that polymerizes upon exposure to actinic radiation comprising at least two functional groups comprising at least one bond that is activatable upon exposure to actinic radiation, optionally, at least one isocyanate-reactive functional group, and optionally, at least one hydroxyl-reactive functional group; (a2) thermally curable binder component that polymerizes upon exposure to heat comprising at least two functional groups that are reactive with functional groups of component (a3), wherein at least 5% by weight based on a nonvolatile weight of component (a2) is component (X) that is a polymer with at least two functional groups (a21), a Tg of less than 0° C., and an equivalent weight of greater than 225; (a3) thermally curable crosslinking component comprising at least two functional groups that are reactive with functional groups of (a2); and (a4) optionally, at least one reactive diluent.
摘要翻译：包含（a1）暴露于光化辐射时聚合的可辐射固化组分的涂料组合物，其包含至少两个官能团，所述至少两个官能团包含至少一个在暴露于光化辐射下可活化的键，任选地至少一种异氰酸酯反应性官能团，至少一个羟基反应性官能团; （a2）可热固化的粘合剂组分，其在暴露于热下聚合包含至少两种与组分（a3）的官能团反应的官能团，其中基于组分（a2）的不挥发重量的至少5重量％是组分（X），其为具有至少两个官能团（a 21），Tg小于0℃，当量重量大于225的聚合物; （a3）可热固化的交联组分，其包含与（a2）的官能团反应的至少两个官能团; 和（a4）任选的至少一种反应性稀释剂。

59. 发明授权

US06777090B2 Substance mixture which can be cured thermally and by using actinic radiation, and the use thereof 有权
标题翻译：能够热固化并通过使用光化辐射的物质混合物及其用途
公开(公告)号：US06777090B2
公开(公告)日：2004-08-17
申请号：US10130934
申请日：2002-06-19
申请人： Hubert Baumgart , Uwe Meisenburg , Heinz-Peter Rink , Paul J. Harris , Reinhold Schwalm
发明人： Hubert Baumgart , Uwe Meisenburg , Heinz-Peter Rink , Paul J. Harris , Reinhold Schwalm
IPC分类号： B32B3126
CPC分类号： C09D201/025 , C08G18/3831 , C08G18/672 , C09J201/025 , Y10T428/31511 , Y10T428/31551 , Y10T428/31938
摘要： Composition curable thermally and with actinic radiation (dual-cure composition) comprising A) at least one constituent containing on average per molecule at least one primary or secondary carbamate group and at least one bond which can be activated with actinic radiation and preparable by from polyfunctional compounds containing at least two isocyanate-reactive, acid-reactive or epoxide-reactive functional groups and suitable monoisocyanates, monoacids or monoepoxides or from polyisocyanates, polyacids or polyepoxides and suitable compounds which contain an isocyanate-reactive, acid-reactive or epoxide-reactive functional group; and B) at least one constituent containing on average per molecule at least one carbamate-reactive functional group and also, where appropriate, at least one bond which can be activated with actinic radiation; and its use as adhesive, sealing compound and coating material.
摘要翻译：包含可热固化和与光化辐射（双重固化组合物）组合的组合物，其包含：A）每分子平均含有至少一个伯或仲氨基甲酸酯基团和至少一个可以用光化辐射活化并可由多官能化合物制备的键的至少一种成分含有至少两种异氰酸酯反应性，酸反应性或环氧化物反应性官能团和合适的单异氰酸酯，单酸或单环氧化物或由多异氰酸酯，多元酸或聚环氧化物和含有异氰酸酯反应性，酸反应性或环氧化物反应性官能团的合适化合物 ; 和B）每分子平均含有至少一个氨基甲酸酯反应性官能团的至少一种组分，并且在适当的情况下还可以使用至少一种可用光化辐射活化的键;以及其用作粘合剂，密封剂和涂料。

60. 发明授权

US06710138B2 Carbamate functional polymers and oligomers 有权
标题翻译：氨基甲酸酯官能聚合物和低聚物
公开(公告)号：US06710138B2
公开(公告)日：2004-03-23
申请号：US10342897
申请日：2003-01-15
申请人： Walter H Ohrbom , John W. Rehfuss
发明人： Walter H Ohrbom , John W. Rehfuss
IPC分类号： C08F830
CPC分类号： C08G18/285 , C09D201/025
摘要： The instant invention provides carbamate functional polymers and/or oligomers and coating compositions containing such which have improved levels of nonvolatile solids yet demonstrate good sprayability and etch resistance. The carbamate functional polymers and/or oligomers of the invention comprise the polymerization reaction product of (a) a polymer or oligomer comprising a plurality of functional groups reactive with an active hydrogen group, and (b) a monomeric compound of the formula: wherein at least one of Y and Z is an active hydrogen containing group and the other is a primary carbamate group, and R is of the formula: —(L)n—R′ wherein L is a linking group of one or more carbons containing heteratoms selected from the group consisting of O, N, and mixtures thereof, R′ is an alkyl group free of heteratoms and selected from the group consisting of branched alkyl groups having from 5 to 30 carbons, straight chain alkyl groups of more than 2 carbons, and mixtures thereof, and n is a number from 0 to 1.
摘要翻译：本发明提供了含有这样的氨基甲酸酯官能聚合物和/或低聚物和涂料组合物，其具有改进的非挥发性固体含量，但表现出良好的喷涂性和耐蚀刻性。本发明的氨基甲酸酯官能聚合物和/或低聚物包含（a）包含多个与活性氢基团反应的官能团的聚合物或低聚物的聚合反应产物，和（b）下式的单体化合物：其中在 Y和Z中的至少一个是含氢活性基团，另一个是伯氨基甲酸酯基，R是下式的化合物： - （L）nR'其中L是一个或多个含有杂原子的碳的连接基团，选自由O，N及其混合物组成的基团，R'是不含杂原子的烷基，选自碳原子数5〜30的支链烷基，碳原子数2以上的直链烷基及其混合物，n为0〜1的数。

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