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51. 发明授权

US06262317B1 Process for preparing 1,4-butanediol by catalytic hydrogenation of 1,4-butinediol 有权
标题翻译：通过1,4-丁二醇的催化氢化制备1,4-丁二醇的方法
公开(公告)号：US06262317B1
公开(公告)日：2001-07-17
申请号：US09284209
申请日：1999-04-09
申请人： Rainer Becker , Franz Josef Bröcker , Gerd Kaibel , Rolf Pinkos , Joachim Wulff-Döring
发明人： Rainer Becker , Franz Josef Bröcker , Gerd Kaibel , Rolf Pinkos , Joachim Wulff-Döring
IPC分类号： C07C2700
CPC分类号： C07C29/172 , B01J8/025 , B01J8/0278 , B01J8/06 , B01J8/065 , B01J19/006 , B01J19/2465 , B01J19/249 , B01J19/26 , B01J2208/00283 , B01J2208/021 , B01J2219/00103 , B01J2219/0011 , B01J2219/00777 , B01J2219/185 , B01J2219/1943 , B01J2219/2462 , B01J2219/2469 , B01J2219/2474 , B01J2219/2477 , B01J2219/2479 , B01J2219/2481 , B01J2219/30 , B01J2219/30475 , C07C31/207
摘要： A process for preparing 1,4-butanediol by continuous catalytic hydrogenation of 1,4-butynediol comprises reacting 1,4-butynediol with hydrogen in the liquid continuous phase in the presence of a heterogeneous hydrogenation catalyst at from 20 to 300° C., a pressure of from 1 to 200 bar and values of the liquid-side volumetric mass transfer coefficient kLa of from 0.1 s−1 to 1 s−1 a) using a catalyst suspended in the reaction medium, where if a packed bubble column is employed this is operated in the upflow mode and at a ratio of gas leaving the reaction vessel to gas fed to the reaction vessel of from 0.99:1 to 0.4:1, or b) passing the liquid and gas in cocurrent in an upward direction through a fixed-bed reactor operated in the gas-circulation mode while maintaining a ratio of the gas fed to the reaction vessel to gas leaving the reaction vessel of from 0.99:1 to 0.4:1.
摘要翻译：通过1,4-丁炔二醇的连续催化氢化制备1,4-丁二醇的方法包括在非均相氢化催化剂存在下，在20-300℃下，使1,4-丁炔二醇与液体连续相中的氢反应，使用悬浮在反应介质中的催化剂，1至200巴的压力和液体侧体积传质系数kLa的值为0.1s-1至1s-1a），其中如果使用填充气泡塔，则在向上流动模式下操作，并且以从0.99:1至0.4:1的气体流入反应容器的气体的比率），使液体和气体沿向上的方向并流通过固定 - 在气体循环模式下操作的床反应器，同时保持供给反应容器的气体与离开反应容器的气体的比例为0.99:1至0.4:1。

52. 发明授权

US06204417B1 Method for producing aliphatic alcohols 有权
标题翻译：生产脂肪醇的方法
公开(公告)号：US06204417B1
公开(公告)日：2001-03-20
申请号：US09423876
申请日：1999-11-15
申请人： Rolf Fischer , Rolf Pinkos , Joachim Wulff-Döring
发明人： Rolf Fischer , Rolf Pinkos , Joachim Wulff-Döring
IPC分类号： C07C3118
CPC分类号： C07C29/149 , B01J23/56 , B01J23/6567 , B01J23/89 , C07C31/12 , C07C31/207 , C07C31/125 , C07C31/20
摘要： In a process for preparing aliphatic alcohols by hydrogenating aliphatic carboxylic acids or anhydrides or esters thereof or lactones in the presence of a catalyst comprising Pt and Re, in the form of the metal or an oxide in each case, the catalyst further comprises at least one further element from the groups 5 to 12 and 14 and the lanthanides of the Periodic Table of the Elements in the form of the metal or an oxide.
摘要翻译：在通过在包含Pt和Re的催化剂的存在下，在每种情况下以金属或氧化物的形式加氢脂族羧酸或其酸酐或其酯或内酯的方法中，催化剂还包含至少一种第5〜12和14族的元素，元素周期表的镧系元素为金属或氧化物。

53. 发明授权

US06204395B1 Process for the preparation of butane-1,4-diol, &ggr;-butyrolactone and tetrahydrofuran 有权
标题翻译：丁烷-1,4-二醇，γ-丁内酯和四氢呋喃的制备方法
公开(公告)号：US06204395B1
公开(公告)日：2001-03-20
申请号：US09554239
申请日：2000-06-29
申请人： Michael W. M. Tuck , Michael A. Wood , Andrew G. Hiles
发明人： Michael W. M. Tuck , Michael A. Wood , Andrew G. Hiles
IPC分类号： C07D30708
CPC分类号： C07D315/00 , C07C29/149 , C07C31/207
摘要： A process is described for the production of butane-1,4-diol, &ggr;-butyrolactone and/or tetrahydrofuran. A vaporous stream containing maleic anhydride, water, and carbon oxides is contact in an absorption zone with a high boiling ester as solvent to form a solution of maleic anhydride in the high boiling ester which has a boiling point at the atmospheric pressure at least about 30° C. higher than that of maleic anhydride and is selected from di-(C1 to C4 alkyl) esters of alkyl dicarboxylic acids containing up to 3 carbon atoms, mono- and di-(C10 to C18 alkyl) esters of maleic acid, fumaric acid, succinic acid, and mixtures thereof, (C1 to C4 alkyl) esters of naphthalene-monocarboxylic acids, tri-(C1 to C4 alkyl) esters of aromatic tricarboxylic acids, and di-(C1 to C4 alkyl) esters of isophthalic acid. The maleic anhydride in the solution is stripped with a gaseous stream containing hydrogen thereby forming a vaporous stream comprising hydrogen and maleic anhydride, which is contacted in a hydrogenation zone with a heterogeneous hydrogenation catalyst to convert maleic anhydride to at least one C4 compound selected from butane-1,4-diol, &ggr;-butyrolactone and tetrahydrofuran.
摘要翻译：描述了制备丁烷-1,4-二醇，γ-丁内酯和/或四氢呋喃的方法。含有马来酸酐，水和碳氧化物的气流在吸收区与高沸点酯作为溶剂接触，形成马来酸酐在高沸点酯中的溶液，其沸点在大气压至少约30℃ ℃，高于马来酸酐，并且选自含有至多3个碳原子的烷基二羧酸的二（C1-C4烷基）酯，马来酸的单 - 和二 - （C 10 -C 18烷基）酯，富马酸酸，琥珀酸及其混合物，萘 - 一元羧酸的（C1-C4烷基）酯，芳族三羧酸的三（C1-C4烷基）酯和间苯二甲酸的二（C1-C4烷基）酯。溶液中的马来酸酐用含有氢气的气流汽提，从而形成包含氢气和马来酸酐的蒸气流，其在氢化区与非均相氢化催化剂接触以将马来酸酐转化成至少一种选自丁烷的C 4化合物 -1,4-二醇，γ-丁内酯和四氢呋喃。

54. 发明授权

US06180838B2 Process for preparing alkanediols 失效
标题翻译：制备烷二醇的方法
公开(公告)号：US06180838B2
公开(公告)日：2001-01-30
申请号：US08618734
申请日：1996-03-20
申请人： Lynn Henry Slaugh , Paul Richard Weider , Joseph Broun Powell
发明人： Lynn Henry Slaugh , Paul Richard Weider , Joseph Broun Powell
IPC分类号： C07C2704
CPC分类号： B01J31/04 , B01J31/0268 , B01J31/20 , B01J31/2234 , B01J31/26 , B01J31/4046 , B01J2231/48 , B01J2531/822 , C07C29/141 , C07C29/16 , C07C45/58 , C07C45/80 , Y02P20/584 , C07C47/19 , C07C31/205 , C07C31/207
摘要： An alkanediol such as 1,3-propanediol is prepared in a process which involves reacting an alkylene oxide with carbon monoxide and hydrogen in an essentially non-water-miscible solvent in the presence of a non-phosphine-ligated rhodium catalyst and a catalyst promoter to produce an intermediate product mixture containing a hydroxyalkanal in an amount less than 15 wt %; extracting the hydroxyalkanal from the intermediate product mixture into an aqueous liquid at a temperature less than about 100° C. and separating the aqueous phase containing hydroxyalkanal from the organic phase containing rhodium catalyst; hydrogenating the hydroxyalkanal in the aqueous phase to an alkanediol; and recovering the alkanediol. The process enables the production of an alkanediol such as 1,3-propanediol in high yields and selectivity without the use of a phosphine ligand-modified rhodium catalyst.
摘要翻译：在包含非磷化氢连接的铑催化剂和催化剂促进剂的存在下，使烯化氧与一氧化碳和氢气在基本上不与水混合的溶剂中进行反应的方法制备了1,3-二醇，以产生含有小于15重量％的量的羟基卡那尔的中间产物混合物; 在低于约100℃的温度下将羟基卡那酸从中间产物混合物中提取成含水液体，并将含有羟基卡那酸的水相与含铑催化剂的有机相分离; 将水相中的羟基卡那酸氢化成链烷二醇; 并回收链烷二醇。该方法能够以高产率和选择性生产链烷二醇如1,3-丙二醇，而不需要使用膦配体改性的铑催化剂。

55. 发明授权

US3891511A Production of very pure butanediol 失效
标题翻译：生产非常纯的丁二醇
公开(公告)号：US3891511A
公开(公告)日：1975-06-24
申请号：US27236672
申请日：1972-07-17
申请人： BASF AG
发明人： DANNEIL AXEL , FLICKINGER ERICH , GRAEFJE HEINZ , PLASS REINHOLD , SCHNUR RUDOLF
IPC分类号： C07C29/80 , C07C31/20 , B01D3/00
CPC分类号： C07C29/80 , C07C31/207
摘要： Production of very pure butanediol-1,4 by separating in column 1 crude butanediol into a fraction A containing butanediol and lower boiling components and a fraction B containing higher boiling components, separating fraction A in column 2 into an overhead and a bottoms product consisting of very pure butanediol and separating fraction B in column 3 into butanediol of lower purity and components of higher boiling point.
摘要翻译：通过在第1列粗丁二醇中分离成含有丁二醇和低沸点组分的级分A和含较高沸点组分的级分B，生产非常纯的丁二醇-1,4，将第2列中的馏分A分离成塔顶馏出物和由非常纯的丁二醇和第3列中的分离馏分B为较低纯度的丁二醇和较高沸点的组分。

56. 发明授权

US3818043A Cuprous chloride as a catalyst for the reaction of an aldehyde with an olefin 失效
标题翻译：氯化铝作为催化剂与烯烃反应的催化剂
公开(公告)号：US3818043A
公开(公告)日：1974-06-18
申请号：US24911372
申请日：1972-05-01
申请人： CONTINENTAL OIL CO
发明人： STARKS C
IPC分类号： C07C29/38 , C07D319/06 , C07D15/04
CPC分类号： C07D319/06 , C07C29/38 , C07C33/03 , C07C31/20 , C07C31/207
摘要： An olefin and an aldehyde may be reacted in the presence of an aqueous solution of a strong acid and cuprous chloride in a twophase reaction system to produce unsaturated 1-alcohols and diols which are readily converted into compounds useful as detergents, polyesters and the like and dioxanes which may be used as solvents.
摘要翻译：烯烃和醛可以在两相反应体系中的强酸和氯化亚铜的水溶液的存在下反应，以产生不饱和的1-醇和二醇，其易于转化为可用作洗涤剂，聚酯和可以用作溶剂的类似物和二氧杂环己烷。

57. 发明授权

US3816549A Purification of alkylene glycols 失效
标题翻译：烷基甘氨酸的纯化
公开(公告)号：US3816549A
公开(公告)日：1974-06-11
申请号：US11064171
申请日：1971-01-28
申请人： CELANESE CORP
发明人： PRINZ R
IPC分类号： C07C29/86 , C07C31/20
CPC分类号： C07C29/86 , C07C31/20 , C07C31/205 , C07C31/207
摘要： PROCESS FOR IMPROVING THE TASTE AND/OR ODOR CHARACTERISTICS OF A CRUDE ALKYLENE GLYCOL BY SUBJECTING THE GLYCOL TO DUAL SOLUTION EXTRACTION WHEREIN WATER AND A DIALKYL ETHER ARE THE DUAL SOLVENTS, THE IMPURITIES BEING PREFERENTIALLY DISSOLVED IN THE ETHER PHASE WHILE THE PURIFIED GLYCOL IS PREFERENTIALLY DISSOLVED IN THE WATER PHASE.

58. 发明授权

US3772395A Process for increasing selectivity of tetramethylene glycol 失效
标题翻译：增加四乙基甘氨酸选择性的方法
公开(公告)号：US3772395A
公开(公告)日：1973-11-13
申请号：US17535971
申请日：1971-08-26
申请人： MITSUBISHI CHEM IND
发明人： YAMAGUCHI M , KAGEYAMA Y
IPC分类号： C07C29/136 , B01J23/00 , B01J23/70 , B01J37/02 , C07B61/00 , C07C27/00 , C07C29/149 , C07C67/00 , C07C31/18
CPC分类号： C07C29/149 , B01J23/70 , B01J37/0201 , C07C31/207
摘要： THE SELECTIVITY OF TETRAMETHYLENE GHYCOL, BY THE HYDROGENATION OF Y-BUTYROLACTONE, IS INCREASED BY USING A CATALYTICALLY ACTIVE METALLIC NICKEL-METALLIC COBALT-OXIDE OF THORIUM.

59. 发明授权

US3414588A Condensation of aldehydes with unsaturated compounds 失效
标题翻译：醛与不饱和化合物的缩合
公开(公告)号：US3414588A
公开(公告)日：1968-12-03
申请号：US34109464
申请日：1964-01-29
申请人： MOBIL OIL CORP
发明人： JONES DANIEL G
IPC分类号： C07C2/86 , C07C29/00 , C07C29/04 , C07C29/38 , C07D319/06
CPC分类号： C07D319/06 , C07C2/867 , C07C29/44 , C07C2529/08 , C07C2529/18 , C07C11/18 , C07C31/20 , C07C31/207 , C07C29/00 , C07C31/12 , C07C29/04 , C07C31/10 , C07C29/38

60. 发明授权

US3201478A Method of producing a tertiary monohydric alcohol 失效
标题翻译：叔一元醇的制造方法
公开(公告)号：US3201478A
公开(公告)日：1965-08-17
申请号：US3340160
申请日：1960-06-02
申请人： TEXACO INC
发明人： HARRY CHAFETZ
IPC分类号： C07C29/00
CPC分类号： C07C29/00 , C07C67/08 , C07C67/283 , C07C67/297 , C07C31/125 , C07C31/207 , C07C31/20 , C07C33/03 , C07C69/16 , C07C69/145 , C07C69/14

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