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    • 51. 发明申请
    • MULTI-LAYER, MICROPOROUS POLYOLEFIN MEMBRANE, ITS PRODUCTION METHOD, BATTERY SEPARATOR, AND BATTERY
    • 多层,微孔聚烯烃薄膜,其生产方法,电池分离器和电池
    • US20090253032A1
    • 2009-10-08
    • US12296232
    • 2007-04-09
    • Kotaro TakitaShintaro Kikuchi
    • Kotaro TakitaShintaro Kikuchi
    • H01M2/18H01M2/16B29C55/00B32B37/20
    • H01M2/1653B29C48/08B29C48/90B29C48/906B29C48/91B29C48/914B29C55/065B29C55/12B29K2023/0683B29K2105/0061B29K2105/0088B29K2105/04C08L23/06C08L23/10C08L2205/02Y10T428/249978C08L2666/06
    • A multi-layer, microporous polyolefin membrane comprising first microporous layers constituting at least both surface layers and at least one second microporous layer disposed between both surface layers; said first microporous layer being made of a first polyolefin comprising (i) polypropylene, or (ii) a mixture of 50% or more by mass of polypropylene and a polyethylene resin; said second microporous layer being made of a second polyolefin comprising (i) a mixture of 7% or less by mass of ultra-high-molecular-weight polyethylene having weight-average molecular weight of 1×106 or more and the other polyethylene than said ultra-high-molecular-weight polyethylene, (ii) the other polyethylene than said ultra-high-molecular-weight polyethylene, or (iii) a mixture of 50% or less by mass of polypropylene and said mixture (i) or said polyethylene (ii); said second microporous layer having a larger average pore diameter than that of said first microporous layer; and the total thickness of said first microporous layers being 15-60% per 100% of the total thickness of said first and second microporous layers.
    • 一种多层微孔聚烯烃膜,包括构成至少两个表面层的第一微孔层和设置在两个表面层之间的至少一个第二微孔层; 所述第一微孔层由第一聚烯烃制成,所述第一聚烯烃包含(i)聚丙烯,或(ii)50质量%以上的聚丙烯和聚乙烯树脂的混合物; 所述第二微孔层由第二聚烯烃制成,所述第二聚烯烃包含(i)重均分子量为1×10 6以上的超高分子量聚乙烯的7质量%以下的混合物, 高分子量聚乙烯,(ii)除了所述超高分子量聚乙烯以外的其它聚乙烯,或者(iii)50质量%以下的聚丙烯和所述混合物(i)或所述聚乙烯(ii)的混合物 ); 所述第二微孔层的平均孔径大于所述第一微孔层的平均孔径; 并且所述第一微孔层的总厚度为所述第一和第二微孔层的总厚度的100%的15-60%。
    • 59. 发明申请
    • Process for producing polyolefin films
    • 生产聚烯烃薄膜的方法
    • US20070045894A1
    • 2007-03-01
    • US11217007
    • 2005-08-31
    • Michael McLeod
    • Michael McLeod
    • B29C47/06B29C55/06
    • B29C55/06B29C48/023B29C48/08B29C48/21B29C48/30B29C48/307B29C48/91B29C48/914B29C55/023B29C55/14B29K2023/12B29K2105/0014
    • Process for producing an oriented polyolefin film using a multi-component polymer composition provided by a primary polymer component comprising an isotactic propylene homopolymer produced by the polymerization of propylene in the presence of a Ziegler-Natta catalyst and a secondary polymer component comprising a metallocene polymerized isotactic propylene polymer having a xylene solubles content which is less than that of the primary polymer component. The secondary polymer component is a propylene homopolymer or an ethylene-propylene random copolymer having an ethylene content of about 0.5 wt. % or less. The polymer components are separately co-extruded to form a multilayer co-extrudate in which the primary polymer component is present in an amount greater than the secondary polymer component. The multilayer co-extrudate is oriented in at least one direction to form an oriented film.
    • 使用由主要聚合物组分提供的多组分聚合物组合物制备定向聚烯烃膜的方法,所述多组分聚合物组合物包含通过在齐格勒 - 纳塔催化剂存在下丙烯聚合制备的全同立构丙烯均聚物和包含茂金属聚合全同立构 丙烯聚合物的二甲苯可溶物含量小于初级聚合物组分的含量。 次级聚合物组分是乙烯含量为约0.5重量%的丙烯均聚物或乙烯 - 丙烯无规共聚物。 % 或更少。 聚合物组分分别共挤出以形成多层共挤出物,其中主要聚合物组分以大于次级聚合物组分的量存在。 多层共挤出物在至少一个方向取向以形成定向膜。