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51. 发明授权

US09199845B2 Process for producing alkenes oxygenates by using supported heteropolyacid catalysts 有权
标题翻译：通过使用负载型杂多酸催化剂生产烯烃含氧化合物的方法
公开(公告)号：US09199845B2
公开(公告)日：2015-12-01
申请号：US12312589
申请日：2007-11-08
申请人： Benjamin Patrick Gracey , Gordon John Haining , Stephen Roy Partington
发明人： Benjamin Patrick Gracey , Gordon John Haining , Stephen Roy Partington
IPC分类号： C07C1/20 , C07C1/24 , B01J27/188 , C01B3/32 , B01J23/30 , B01J35/00 , B01J35/10 , B01J37/02 , C07C11/02 , B01J21/08 , B01J21/12
CPC分类号： C01B3/32 , B01J21/08 , B01J21/12 , B01J23/30 , B01J27/188 , B01J35/002 , B01J35/10 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/0201 , C01B2203/0227 , C01B2203/062 , C07C1/20 , C07C11/02 , C07C2521/08 , C07C2523/30 , Y02P20/582 , Y02P30/42
摘要： Process for producing alkene(s) from an oxygenate feedstock in a reactor by dehydration in the presence of a supported heteropolyacid catalyst. The pore volume of the supported heteropolyacid catalyst satisfies the following formula: PV>0.6−0.3[HPAloading/Surface Area of Dried Catalyst]where; PV is the Pore Volume of the dried supported heteropolyacid catalyst (measured in ml/g catalyst); HPA loading is the amount of heteropolyacid present in the dried supported heteropolyacid catalyst (measure in micro moles/g); and Surface Area of Dried Catalyst is the surface area of the dried supported heteropolyacid catalyst (measured in m2/g).
摘要翻译：在负载型杂多酸催化剂存在下通过脱水从反应器中的含氧化合物原料生产烯烃的方法。负载型杂多酸催化剂的孔体积满足下式：PV> 0.6-0.3 [HPA负载/干燥催化剂表面积]其中; PV是干燥的负载型杂多酸催化剂的孔体积（以ml / g催化剂测量）; HPA负载量是干燥的负载杂多酸催化剂中存在的杂多酸的量（以微摩尔/ g计）; 和干燥催化剂的表面积是干燥的负载型杂多酸催化剂的表面积（以m2 / g计）。

52. 发明授权

US09175396B2 Aluminum-containing substrate comprising a microporous layer of an aluminum phosphate zeolite, method for the production thereof, and use thereof 有权
标题翻译：含有磷酸铝沸石的微孔层的含铝基材，其制造方法及其用途
公开(公告)号：US09175396B2
公开(公告)日：2015-11-03
申请号：US12736807
申请日：2009-05-13
申请人： Jürgen Bauer , Ralph Herrmann , Wilhelm Schwieger , Abhijeet Avhale
发明人： Jürgen Bauer , Ralph Herrmann , Wilhelm Schwieger , Abhijeet Avhale
IPC分类号： B01J29/06 , B01J27/182 , C23C18/12 , B01J29/85 , B01J29/83 , B01J35/10 , B01J37/02
CPC分类号： C23C18/1212 , B01J29/83 , B01J29/85 , B01J35/10 , B01J35/1057 , B01J35/109 , B01J37/0215 , B01J37/0244 , B01J37/0246 , B01J2229/62 , B01J2229/66 , C23C18/1225 , C23C18/1241 , C23C18/1254
摘要： An aluminum-containing substrate is described that comprises at least one superficially applied microporous layer of an aluminum phosphate zeolite (ALPO) as well as other layers. Said aluminum-containing substrate is characterized in that the microporous layer of the aluminum phosphate zeolite represents a primer coating on which a microporous or mesoporous secondary material is located which differs from the material of the primer coating. Said aluminum-containing substrate is produced in a particularly advantageous manner according to a method in which 1. an aluminum-containing substrate is hydrothermally treated in an aqueous suspension containing at least phosphorus as a network-forming element, and a microporous primer coating of an aluminum phosphate zeolite is formed on the substrate by means of an in situ crystallization process, especially the molar ratio between the network-forming aluminum that is deficient in the aqueous suspension and the sum of all network-forming elements in the aqueous suspension being less than 0.5 such that the aluminum required for compensating the deficiency is removed from the aluminum-containing substrate, and 2.; a microporous or mesoporous secondary material is formed on the microporous primer coating by subjecting the aluminum-containing substrate that comprises the microporous primer coating to another treatment in an aqueous suspension containing the network-forming elements required for forming the porous secondary material. The described aluminum-containing substrate is particularly suitable as a heat exchanger, as a catalytic reactor, or as a component in heat transformation technology with an anti-corrosive or anti-fouling effect.
摘要翻译：描述了一种含铝衬底，其包括至少一个表面上施加的磷酸铝沸石（ALPO）的微孔层以及其它层。所述含铝基材的特征在于，磷酸铝沸石的微孔层代表与底漆涂层的材料不同的底涂层，其上定位有微孔或介孔二次材料。所述含铝基材以特别有利的方式根据以下方法制造：含铝基材在至少含有磷作为网络形成元素的水性悬浮液中进行水热处理，以及微孔底漆涂层通过原位结晶方法在基材上形成磷酸铝沸石，特别是水悬浮液中缺陷的网络形成铝与水悬浮液中所有网络形成元素的总和之间的摩尔比小于 0.5，使得从含铝基板除去补偿缺陷所需的铝，2。通过在包含形成多孔二次材料所需的网络形成元件的水性悬浮液中对包含微孔底漆涂层的含铝基材进行另外的处理，在微孔底漆涂层上形成微孔或介孔二次材料。所述含铝基材特别适合作为热交换器，催化反应器，或作为具有防腐蚀或防污效果的热转化技术中的成分。

53. 发明授权

US09174910B2 Method for producing acrylic acid with a fixed-bed multitubular reactor 有权
标题翻译：用固定床多管反应器生产丙烯酸的方法
公开(公告)号：US09174910B2
公开(公告)日：2015-11-03
申请号：US14383705
申请日：2013-03-28
申请人： Nippon Shokubai Co., Ltd.
发明人： Toshiya Nishiguchi
IPC分类号： C07C51/16 , C07C45/00 , C07C45/35 , B01J27/192 , C07C51/235 , B01J23/889 , B01J23/00 , B01J23/28 , B01J23/888 , B01J27/199 , C07C51/25
CPC分类号： C07C51/235 , B01J23/002 , B01J23/28 , B01J23/8885 , B01J23/8892 , B01J27/199 , B01J35/0006 , B01J35/10 , B01J35/1038 , B01J35/1066 , B01J35/1071 , B01J35/1076 , B01J35/108 , B01J37/0036 , B01J37/0045 , B01J37/0223 , B01J2523/00 , C07C51/252 , C07C57/04 , B01J2523/17 , B01J2523/53 , B01J2523/55 , B01J2523/68 , B01J2523/69 , B01J2523/845
摘要： This invention provides a method for producing acrylic acid by catalytic gas-phase oxidation, which method makes it possible to carry out a continuous operation steadily for a long period of time while a high yield is maintained.This method is characterized by comprising filling each of reaction tubes of a fixed-bed multitubular reactor with at least two species of catalysts each of which essentially comprises, as catalytically active components, oxide of molybdenum and oxide of vanadium and/or composite oxide of the same, said at least two species of catalysts being different in the ratio of D1/D2, D1 denoting the proportion of the total pore volume of pores whose pore diameter falls within the range of at least 0.03 μm and less than 0.4 μm to the total pore volume of the whole pores, and D2 denoting the proportion of the total pore volume of pores whose pore diameter fails within the range of at least 0.4 μm and at most 5 μm to the total pore volume of the whole pores, in such a manner that at least two reaction zones are formed axially in each of the reaction tubes.
摘要翻译：本发明提供了一种通过催化气相氧化制备丙烯酸的方法，该方法使得可以在保持高产率的情况下长时间稳定地进行连续操作。该方法的特征在于包括用至少两种催化剂填充固定床多管反应器的每个反应管，每种催化剂基本上包含钼的氧化物和钒的氧化物和/或复合氧化物的催化活性组分相同的是，至少两种催化剂的比例不同，D1 / D2，D1表示其孔径落入至少0.03μm且小于0.4μm的范围内的孔的总孔体积的比例相对于总量整个孔的孔体积，D2表示孔径在孔的总体积体积不小于0.4μm至最多5μm的孔的总孔体积的比例，以全孔的总孔体积在每个反应管中至少形成两个反应区域。

54. 发明申请

US20150290620A1 CATALYST COMPRISING IRON AND CARBON NANOTUBES 审中-公开
标题翻译：包含铁和碳纳米管的催化剂
公开(公告)号：US20150290620A1
公开(公告)日：2015-10-15
申请号：US14443245
申请日：2013-11-15
申请人： UNIVERSITY OF BATH
发明人： Matthew David Jones , Davide Mattia , Justin Patrick O'Byrne , Rhodri Ellis Owen , Daniel Minett , Pawel Plucinski , Sofia Ioana Pascu
IPC分类号： B01J21/18 , B01J35/00 , C10G2/00 , B01J37/14 , B01J37/18 , B01J37/02 , B01J23/745 , B01J35/04
CPC分类号： B01J21/185 , B01J23/745 , B01J35/0006 , B01J35/0013 , B01J35/0046 , B01J35/006 , B01J35/0073 , B01J35/04 , B01J35/10 , B01J37/0238 , B01J37/086 , B01J37/14 , B01J37/18 , B82Y30/00 , C01B32/168 , C10G2/332 , C10G2/50
摘要： Improved catalyst comprising iron and carbon nanotubes. The invention relates to a process for making a catalyst comprising carbon nanotubes and iron-based particles, the process comprising the steps of: a)preparing carbon nanotubes comprising iron-based particles by chemical vapour deposition of a vapour of a carbon-containing substance in the presence of an iron-containing substance; b) subjecting the carbon nanotubes comprising iron-based particles to oxidising conditions to selectively etch away graphite layers covering the iron-based particles, thereby exposing the iron-based particles at the surface of the carbon nanotubes and at least partially oxidising the iron-based particles; and c) subjecting the carbon nanotubes comprising iron-based particles to reducing conditions in order to at least partially reduce the iron-based particles. The catalyst may be used in the manufacture of hydrocarbons from carbon monoxide or carbon dioxide, or for carbon capture and utilization.
摘要翻译：改进的包含铁和碳纳米管的催化剂。本发明涉及一种制备包含碳纳米管和铁基颗粒的催化剂的方法，该方法包括以下步骤：a）通过化学气相沉积含碳物质的蒸气来制备包含铁基颗粒的碳纳米管含铁物质的存在; b）使包含铁基颗粒的碳纳米管经历氧化条件以选择性地蚀刻掉覆盖铁基颗粒的石墨层，从而使碳纳米管表面上的铁基颗粒暴露，并至少部分氧化铁基颗粒粒子; 和c）使包含铁基颗粒的碳纳米管经历还原条件以至少部分地还原铁基颗粒。催化剂可用于从一氧化碳或二氧化碳制造烃，或用于碳捕集和利用。

55. 发明申请

US20150246342A1 CATALYST FOR HYDROCARBON REFORMING, METHOD OF MANUFACTURING THE SAME, AND METHOD OF MANUFACTURING SYNTHESIS GAS 审中-公开
标题翻译：烃改性催化剂，其制备方法和制备合成气的方法
公开(公告)号：US20150246342A1
公开(公告)日：2015-09-03
申请号：US14631980
申请日：2015-02-26
申请人： SUMITOMO CHEMICAL COMPANY, LIMITED , SHOEI CHEMICAL INC. , NATIONAL UNIVERSITY CORPORATION OITA UNIVERSITY
发明人： Kazuro NAGASHIMA , Katsutoshi NAGAOKA , Katsutoshi SATO , Hideyuki HIGASHIMURA
IPC分类号： B01J23/755 , B01J23/75 , C01B3/40 , B01J37/02 , B01J37/08 , B01J37/00 , B01J23/02 , B01J35/02
CPC分类号： C01B3/40 , B01J23/78 , B01J35/002 , B01J35/008 , B01J35/023 , B01J35/10 , B01J37/0045 , B01J37/0236 , B01J37/08 , B01J37/18 , C01B2203/0238 , C01B2203/1052 , C01B2203/1058 , C01B2203/1082 , C01B2203/1241 , Y02P20/142 , Y02P20/52
摘要： There is provided a catalyst for hydrocarbon reforming having a high deposition suppressing effect with respect to a carbonaceous material on the catalyst surface even in a case where a reforming material including carbon dioxide, in particular, formed of only carbon dioxide is used in a reforming reaction, a method of manufacturing the same, and a method of manufacturing a synthesis gas using the catalyst. Specifically, there is provided a catalyst for hydrocarbon reforming which is a catalyst for reforming used for reforming hydrocarbons by a reaction of the hydrocarbons and a reforming material including carbon dioxide in which at least one type of metal particles selected from cobalt particles and nickel particles is supported on a support formed of magnesia in which an aluminum-containing component is segregated on the surface; and a method of manufacturing a synthesis gas in which using the catalyst for hydrocarbon reforming, a synthesis gas including carbon monoxide and hydrogen is obtained from a reforming material including hydrocarbons and carbon dioxide.
摘要翻译：提供了一种用于烃重整的催化剂，即使在重整反应中使用包括二氧化碳，特别是仅由二氧化碳形成的重整材料的情况下，在催化剂表面上对碳质材料具有高的沉积抑制效果，其制造方法和使用该催化剂的合成气的制造方法。具体地说，提供了一种用于烃重整的催化剂，其是用于通过烃的反应重整烃的重整催化剂和包括二氧化碳的重整材料，其中至少一种选自钴颗粒和镍颗粒的金属颗粒是支撑在由氧化镁形成的载体上，其中含铝组分在表面上分离; 以及使用烃重整用催化剂制造合成气的方法，由含有碳氢化合物和二氧化碳的重整材料得到包含一氧化碳和氢的合成气。

56. 发明申请

US20150175898A1 METHOD FOR OXYGENATE CONVERSION 审中-公开
标题翻译：氧化转化方法
公开(公告)号：US20150175898A1
公开(公告)日：2015-06-25
申请号：US14560129
申请日：2014-12-04
申请人： Stephen J. McCarthy , Rohit VIJAY , Michael Francis RATERMAN , Brian PETERSON , Karlton J. HICKEY , Michel DAAGE , Brett LOVELESS , Ramesh GUPTA , Patricia A. BIELENBERG
发明人： Stephen J. McCarthy , Rohit VIJAY , Michael Francis RATERMAN , Brian PETERSON , Karlton J. HICKEY , Michel DAAGE , Brett LOVELESS , Ramesh GUPTA , Patricia A. BIELENBERG
IPC分类号： C10G3/00 , C10L1/06
CPC分类号： B01J29/405 , B01J21/04 , B01J23/06 , B01J27/14 , B01J29/061 , B01J29/40 , B01J29/7049 , B01J29/7057 , B01J29/90 , B01J35/10 , B01J35/1014 , B01J35/1019 , B01J35/1023 , B01J35/1038 , B01J35/1042 , B01J35/1057 , B01J35/108 , B01J35/109 , B01J37/0009 , B01J37/0201 , B01J37/28 , B01J38/02 , B01J38/12 , B01J2229/186 , B01J2229/20 , B01J2229/42 , C07C1/20 , C07C1/22 , C07C2523/06 , C07C2529/06 , C07C2529/40 , C07C2529/70 , C10G3/45 , C10G3/49 , C10G3/55 , C10L1/06 , C10L2200/0423 , C10L2200/0469 , C10L2270/023 , Y02P20/584 , Y02P30/20 , Y02P30/42 , C07C11/02 , C07C15/02
摘要： Methods for organic compound conversion are disclosed. Particular methods include providing a first mixture comprising ≧10.0 wt % of at least one oxygenate, based on the weight of the first mixture; contacting said first mixture in at least a first moving bed reactor with a catalyst under conditions effective to covert at least a portion of the first mixture to a product stream comprising water, hydrogen, and one or more hydrocarbons; and separating from said product stream (i) at least one light stream and ii) at least one heavy stream, wherein the method is characterized by a recycle ratio of ≦5.0.
摘要翻译：公开了有机化合物转化方法。具体方法包括提供基于第一混合物的重量的包含≥10.0wt％的至少一种含氧化合物的第一混合物; 在有效地将至少一部分第一混合物转化成包含水，氢和一种或多种烃的产物流的条件下，使至少第一移动床反应器中的第一混合物与催化剂接触; 和从所述产物流（i）分离至少一种轻质物流和ii）至少一种重质流，其中所述方法的特征在于再循环比为＆lt;

57. 发明申请

US20150175432A1 MAGNESIUM MODIFIED ULTRA-STABLE RARE EARTH Y-TYPE MOLECULAR SIEVE AND PREPARATION METHOD THEREFOR 有权
标题翻译：镁改性超稳定稀土Y型分子筛及其制备方法
公开(公告)号：US20150175432A1
公开(公告)日：2015-06-25
申请号：US14365432
申请日：2012-04-13
申请人： Xionghou Gao , Haitao Zhang , Hongchang Duan , Chaowei Liu , Di Li , Xueli Li , Zhengguo Tan , Yunfeng Zheng , Xiaoliang Huang , Jinjun Cai , Chenxi Zhang
发明人： Xionghou Gao , Haitao Zhang , Hongchang Duan , Chaowei Liu , Di Li , Xueli Li , Zhengguo Tan , Yunfeng Zheng , Xiaoliang Huang , Jinjun Cai , Chenxi Zhang
IPC分类号： C01B39/24 , B01J29/08 , B01J37/08 , C01B39/02
CPC分类号： C01B39/24 , B01J29/084 , B01J29/088 , B01J29/80 , B01J35/023 , B01J35/10 , B01J35/109 , B01J37/08 , B01J37/30 , B01J2229/18 , B01J2229/186 , B01J2229/40 , B01J2229/42 , C01B39/026 , C10G11/05
摘要： The present invention provides a magnesium-modified ultra-stable rare earth type Y molecular sieve and the preparation method thereof, which method is carried out by subjecting a NaY molecular sieve as the raw material to a rare earth exchange and a dispersing pre-exchange, then to an ultra-stabilization calcination treatment, and finally to a magnesium modification. The molecular sieve comprises 0.2 to 5% by weight of magnesium oxide, 1 to 20% by weight of rare earth oxide, and not more than 1.2% by weight of sodium oxide, and has a crystallinity of 46 to 63%, and a lattice parameter of 2.454 nm to 2.471 nm. In contrast to the prior art, in the molecular sieve prepared by this method, rare earth ions are located in sodalite cages, which is demonstrated by the fact that no rare earth ion is lost during the reverse exchange process. Moreover, the molecular sieve prepared by such a method has a molecular particle size D(v,0.5) of not more than 3.0 μm and a D(v,0.9) of not more than 20 μm. Such a molecular sieve has both high stability and high selectivity for the target product, while cracking catalysts using the molecular sieve as an active component is characterized by a high heavy-oil-conversion capacity and a high yield of valuable target products.
摘要翻译：本发明提供一种镁改性超稳定稀土类Y分子筛及其制备方法，该方法是以NaY分子筛为原料进行稀土交换和分散预交换，然后进行超稳定化煅烧处理，最后进行镁改性。分子筛含有0.2〜5重量％的氧化镁，1〜20重量％的稀土氧化物和1.2重量％的氧化钠，结晶度为46〜63％，晶格参数为2.454 nm至2.471 nm。与现有技术相反，在通过该方法制备的分子筛中，稀土离子位于钠盐网箱中，这通过在反向交换过程中没有稀土离子损失的事实来证明。此外，通过这种方法制备的分子筛具有不大于3.0μm的分子粒度D（v，0.5）和不大于20μm的D（v，0.9）。这种分子筛对于目标产物具有高稳定性和高选择性，而使用分子筛作为活性组分的裂化催化剂的特征在于高重油转化能力和高产率的有价值的目标产物。

58. 发明申请

US20150158018A1 HYDROCRACKING CATALYST AND PROCESS FOR PRODUCING LUBE BASE STOCKS 审中-公开
标题翻译：水裂化催化剂及其制备方法
公开(公告)号：US20150158018A1
公开(公告)日：2015-06-11
申请号：US14100239
申请日：2013-12-09
申请人： Bi-Zeng ZHAN
发明人： Bi-Zeng ZHAN
IPC分类号： B01J29/16 , C10G65/12 , C10G67/04
CPC分类号： B01J29/166 , B01J21/12 , B01J23/882 , B01J23/883 , B01J23/888 , B01J29/084 , B01J35/0006 , B01J35/002 , B01J35/10 , B01J35/1019 , B01J35/1023 , B01J35/1042 , B01J35/1047 , B01J35/1061 , B01J37/04 , C10G65/12 , C10G67/04 , C10G2400/10
摘要： Hydrocracking catalysts and hydrocracking processes for the selective production of lube base stocks are disclosed. The hydrocracking catalyst contains a low acidity, highly dealuminated USY zeolite having a zeolite acid site density of from 1 to 100 micromole/g, a catalyst support, and one or more metals. The hydrocracking catalysts can maximize lube base stock yield while providing for effective impurity removal and VI enhancement at lower hydrocracking conversions.
摘要翻译：公开了用于选择性生产润滑基料的加氢裂化催化剂和加氢裂化方法。加氢裂化催化剂含有沸石酸位密度为1-100微摩尔/ g，催化剂载体和一种或多种金属的低酸度，高脱铝USY沸石。加氢裂化催化剂可以最大限度地提高润滑油基础油料产量，同时提供有效的杂质去除和VI增强在较低的加氢裂化转化率。

59. 发明授权

US09045410B2 Nickel hydrogenation catalyst 有权
标题翻译：镍加氢催化剂
公开(公告)号：US09045410B2
公开(公告)日：2015-06-02
申请号：US14350889
申请日：2012-10-12
申请人： BASF Corporation
发明人： Hermanus Johannes Bouwman , Robert Johan Andreas Maria Terörde , Tjalling Rekker
IPC分类号： C07C51/36 , B01J37/03 , B01J21/08 , B01J23/755 , B01J35/10 , C11C3/12 , C07C5/02
CPC分类号： C07C51/36 , B01J21/08 , B01J23/755 , B01J35/10 , B01J37/03 , C07C5/02 , C11C3/123
摘要： The invention relates to a catalyst comprising nickel and a solid silica support, to a process for preparing such a catalyst and to a process for the hydrogenation of an unsaturated fatty material. According to the invention there is provided a catalyst comprising nickel on a solid silica support, wherein said catalyst has a specific pore volume of at least 0.4 ml/g and a TPR peak maximum within the range of 360-420° C.
摘要翻译：本发明涉及包含镍和固体二氧化硅载体的催化剂，涉及一种制备这种催化剂的方法和用于氢化不饱和脂肪材料的方法。根据本发明，提供了一种在固体二氧化硅载体上包含镍的催化剂，其中所述催化剂具有至少0.4ml / g的比孔容积和在360-420℃范围内的TPR峰值最大值。

60. 发明授权

US08969233B2 Hydrocracking process using a zeolite modified by basic treatment 有权
标题翻译：加氢裂化工艺采用经基础处理改性的沸石
公开(公告)号：US08969233B2
公开(公告)日：2015-03-03
申请号：US13684264
申请日：2012-11-23
申请人： IFP Energies Nouvelles
发明人： Laurent Simon , Emmanuelle Guillon
IPC分类号： B01J29/06 , C01B39/00 , B01J29/08 , B01J29/14 , B01J29/16 , B01J35/10 , B01J37/10 , C10G45/08 , C10G45/12 , C10G47/20 , C10G65/12 , B01J37/20
CPC分类号： C01B39/00 , B01J29/084 , B01J29/146 , B01J29/166 , B01J35/10 , B01J35/1038 , B01J35/1061 , B01J37/10 , B01J37/20 , B01J2229/16 , B01J2229/22 , B01J2229/36 , B01J2229/38 , B01J2229/40 , C10G45/08 , C10G45/12 , C10G47/20 , C10G65/12 , C10G2300/1007 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/4018 , C10G2400/02 , C10G2400/04
摘要： The present invention describes a hydrocracking and/or hydrotreatment process using a catalyst comprising an active phase containing at least one hydrogenating/dehydrogenating component selected from the group VIB elements and the non-precious elements of group VIII of the periodic table, used alone or in a mixture, and a support comprising at least one dealuminated zeolite Y having an overall initial atomic ratio of silicon to aluminum between 2.5 and 20, an initial weight fraction of extra-lattice aluminum atoms greater than 10%, relative to the total weight of aluminum present in the zeolite, an initial mesopore volume measured by nitrogen porosimetry greater than 0.07 ml·g−1 and an initial crystal lattice parameter a0 between 24.38 Å and 24.30 Å, said zeolite being modified by a) a stage of basic treatment comprising mixing said dealuminated zeolite Y with a basic aqueous solution, and at least one stage c) of thermal treatment.
摘要翻译：本发明描述了使用催化剂的加氢裂化和/或加氢处理方法，所述催化剂包含活性相，所述活性相含有至少一种选自元素周期表中VIB族元素和VIII族非贵金属的氢化/脱氢组分，混合物和包含至少一种脱铝沸石Y的载体，其具有2.5至20的硅与铝的总初始原子比，相对于铝的总重量，超晶格铝原子的初始重量分数大于10％存在于沸石中，通过氮气孔隙度法测量的初始中孔体积大于0.07ml·g -1，初始晶格参数a0在24.38埃至24.30埃之间，所述沸石通过以下步骤进行修饰：a）碱性处理阶段，包括将所述脱碱沸石Y与碱性水溶液和至少一个阶段c）进行热处理。

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