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    • 5. 发明申请
    • Silica Nanoboxes, Method of Making and Use thereof
    • 二氧化硅纳米盒,其制造和使用方法
    • US20080227628A1
    • 2008-09-18
    • US12089811
    • 2006-10-12
    • Raymond Le Van Mao
    • Raymond Le Van Mao
    • B01J29/06C01B39/02C01B39/06B01J29/076
    • B01J29/041B01J20/18B01J20/2808B01J20/28083B01J29/082B01J29/087B01J29/40B01J29/7003B01J37/0009B01J2229/16B01J2229/22B01J2229/32B01J2229/38B01J2229/42C01B39/026C10G11/02C10G11/05
    • Disclosed herein are mesoporous material derived from a parent zeolite. In an embodiment of the invention, the mesoporous material derived from a parent zeolite, has an internal volume greater than about 0.35 cc/g and a surface area greater than about 250 m2/g, the mesoporous material comprises micropores having a surface area and mesopores, wherein the surface area of the micropores in the mesoporous material is less than about 25% of that in the parent zeolite, wherein less than about 3% of the internal volume of the mesoporous material is provided by micropores and wherein the mesopores are essentially homogeneously distributed and form an essentially interconnected network. In another embodiment of the invention, the mesoporous material derived from an alumina-rich parent zeolite has an internal volume greater than about 0.25 cc/g and a surface area greater than about 95 m2/g, the mesoporous material comprises micropores having a surface area and mesopores, wherein the surface area of the micropores in the mesoporous material is less than about 25% of that in the parent zeolite, wherein the mesopores are essentially homogeneously distributed and form an essentially interconnected network and wherein the mesoporous material further comprises at least one element selected for the group consisting of cerium, lanthanum and yttrium. Also disclosed are methods of manufacture and uses for the same.
    • 本文公开了衍生自母沸石的介孔材料。 在本发明的一个实施方案中,衍生自母沸石的介孔材料具有大于约0.35cc / g的内部体积和大于约250m 2 / g的表面积,介孔材料 包括具有表面积和中孔的微孔,其中介孔材料中的微孔的表面积小于母沸石中的微孔的约25%,其中介孔材料的内部体积的小于约3%由 微孔,其中介孔基本上均匀分布并形成基本上互连的网络。 在本发明的另一个实施方案中,衍生自富含氧化铝的母体沸石的介孔材料具有大于约0.25cc / g的内部体积和大于约95m 2 / g的表面积, 介孔材料包括具有表面积和介孔的微孔,其中介孔材料中的微孔的表面积小于母沸石中的微孔的约25%,其中介孔基本上均匀分布并形成基本上互连的网络,并且其中 介孔材料还包括选自铈,镧和钇的至少一种元素。 还公开了制造方法和用途。