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1. 发明授权

US08552240B2 Process for producing propylene 有权
标题翻译：生产丙烯的方法
公开(公告)号：US08552240B2
公开(公告)日：2013-10-08
申请号：US12085704
申请日：2006-11-22
申请人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
发明人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
IPC分类号： C07C1/24
CPC分类号： C07C1/24 , C07C2521/08 , C07C2521/16 , C07C2527/173 , C07C2527/188 , C07C2527/19 , C07C2529/18 , Y02P20/582 , C07C11/06
摘要： Process for producing propylene from a propanol feedstock A2 by reacting the propanol feedstock A2 in a vapor phase dehydration reactor wherein the propanol is convened at a temperature comprised between 160 and 270° C. and at a pressure of above 0.1 MPa but less than 4.5 MPa, into a product stream B2 containing propylene, propyl ethers, water and unconverted and/or isomerized propanols, cooling the product stream B2, disengaging the cooled product stream B2 in a separation unit to give a first stream C2 containing propylene and propyl ethers, and a second product stream D2 containing water, propyl ethers and unconverted and/or isomerized propanols, feeding the product stream D2 to a dewatering unit wherein the water stream F2 is separated from the propyl ethers and unconverted and/or isomerised propanols stream E2, recycling the stream E2 into the dehydration reactor, cooling the product stream C2, feeding the cooled product stream C2 to a purification unit wherein the propyl ethers stream G2 is separated from the propylene stream H2, and optionally, recycling the propyl ethers stream G2 to either the dewatering unit or directly to dehydration reactor.
摘要翻译：通过丙醇原料A2在气相脱水反应器中反应生成丙烯的方法，其中丙醇在160-270℃的温度和高于0.1MPa但小于4.5MPa的压力下进行在含有丙烯，丙醚，水和未转化的和/或异构化的丙醇的产物流B2中，冷却产物流B2，使分离单元中的冷却的产物流B2脱离，得到含丙烯和丙醚的第一料流C2，将含有水，丙醚和未转化和/或异构化的丙醇的第二产物流D2，将产物流D2供给脱水单元，其中水流F2与丙醚和未转化的和/或异构化的丙醇流E2分离，将将流E2进入脱水反应器中，冷却产物流C2，将冷却的产物流C2进料到纯化单元，其中丙醚流G2与丙烯流H 2分离，并且任选地将丙醚流G2再循环到脱水单元或直接进入脱水反应器。

2. 发明申请

US20100329948A1 Stirring apparatus and method of use of said apparatus 审中-公开
公开(公告)号：US20100329948A1
公开(公告)日：2010-12-30
申请号：US12801962
申请日：2010-07-06
申请人： Stephen Roy Partington
发明人： Stephen Roy Partington
IPC分类号： B01J19/18
CPC分类号： B01F7/0065 , B01F15/027 , B01F2215/0427 , B01F2215/0431 , B01J8/382 , B01J19/0066 , B01J19/18 , B01J2208/00867 , B01J2219/00779
摘要： The present invention provides an apparatus comprising a vessel having a conduit extending therefrom, and a stirrer, a section of which is adapted to be located within the conduit and a section of which is adapted to be located within the vessel, said stirrer being adapted such that, in use, material within the conduit is conveyed in a direction towards the vessel and/or in a direction away from the vessel.

3. 发明申请

US20100249481A1 PROCESS FOR PREPARING ETHENE 有权
标题翻译：制备乙烯的方法
公开(公告)号：US20100249481A1
公开(公告)日：2010-09-30
申请号：US12734215
申请日：2008-10-08
申请人： Benjamin Patrick Gracey , Stephen Roy Partington
发明人： Benjamin Patrick Gracey , Stephen Roy Partington
IPC分类号： C07C1/24
CPC分类号： C07C1/20 , C07C2523/30 , Y02P20/52 , Y02P30/42 , C07C11/04
摘要： A process for the production of ethene by the vapour phased chemical dehydration of a feed comprising ethanol, water and ethoxyethane in a reactor at elevated temperature and pressure in the presence of a bed of catalyst comprising a supported heteropolytungstic acid characterised in that the reactor is maintained or configured so that it operates in a regime which satisfies the following parameters: 0.05
摘要翻译：在包含乙醇，水和乙氧基乙烷的进料的蒸气分级化学脱水的反应器中，在升高的温度和压力下，在包含负载型杂多钨酸的催化剂床的存在下，生产乙烯的方法，其特征在于反应器被维持或配置为使其在满足以下参数的状态下操作：0.05 <（Pwater / Pethanol + Pethoxyethane））/（8×10-5×GHSV + 0.75）（1）和-20

4. 发明授权

US07775703B2 Stirring apparatus and method of use of said apparatus 有权
标题翻译：所述装置的搅拌装置和使用方法
公开(公告)号：US07775703B2
公开(公告)日：2010-08-17
申请号：US10547846
申请日：2004-02-27
申请人： Stephen Roy Partington
发明人： Stephen Roy Partington
IPC分类号： B01F7/24
CPC分类号： B01F7/0065 , B01F15/027 , B01F2215/0427 , B01F2215/0431 , B01J8/382 , B01J19/0066 , B01J19/18 , B01J2208/00867 , B01J2219/00779
摘要： The present invention provides an apparatus comprising a vessel having a conduit extending therefrom, and a stirrer, a section of which is adapted to be located within the conduit and a section of which is adapted to be located within the vessel, said stirrer being adapted such that, in use, material within the conduit is conveyed in a direction towards the vessel and/or in a direction away from the vessel.
摘要翻译：本发明提供了一种装置，其包括具有从其延伸的导管的容器，以及搅拌器，其一部分适于位于导管内，其一部分适于位于容器内，所述搅拌器适于使用在使用中，导管内的材料沿着朝向容器的方向和/或远离容器的方向被输送。

5. 发明申请

US20090281362A1 Process for Producing Propylene 有权
标题翻译：生产丙烯的方法
公开(公告)号：US20090281362A1
公开(公告)日：2009-11-12
申请号：US12085704
申请日：2006-11-22
申请人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
发明人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
IPC分类号： C07C1/24 , C07C11/06 , C07C1/00
CPC分类号： C07C1/24 , C07C2521/08 , C07C2521/16 , C07C2527/173 , C07C2527/188 , C07C2527/19 , C07C2529/18 , Y02P20/582 , C07C11/06
摘要： The present invention relates to a process for the production of propylene from a feedstock comprising propanol.
摘要翻译：本发明涉及从包含丙醇的原料生产丙烯的方法。

6. 发明授权

US6165352A Process for dehydrogenating hydrocarbons and oxygenated hydrocarbons 失效
标题翻译：烃和含氧烃脱氢的方法
公开(公告)号：US6165352A
公开(公告)日：2000-12-26
申请号：US41309
申请日：1998-03-12
申请人： Jeremy Bernard Cooper , Jonathon Charles Frost , Stephen Roy Partington
发明人： Jeremy Bernard Cooper , Jonathon Charles Frost , Stephen Roy Partington
IPC分类号： B01J23/66 , B01J23/96 , B01J37/03 , C07B61/00 , C07C1/24 , C07C5/32 , C07C5/333 , C07C5/42 , C07C11/02 , C07C11/04 , C07C45/00 , C10G35/06
CPC分类号： C07C45/002 , B01J23/66 , B01J23/96 , B01J37/03 , C07C5/324 , C07C5/3335 , C07C5/42 , C07C2523/10 , C07C2523/52 , C07C2523/66 , Y02P20/52 , Y02P20/584 , C07C11/04
摘要： A continuous process for the dehydrogenation of a hydrocarbon and/or oxygenated hydrocarbon feed, comprising contacting the hydrocarbon and/or oxygenated hydrocarbon feed with a dehydrogenation catalyst at elevated temperature in a reaction zone characterised in that the catalyst is capable of retaining hydrogen and (a) is contacted with a feed to form a dehydrogenated product and hydrogen, at least some of the hydrogen formed being adsorbed by the catalyst and/or reacting therewith to reduce at least part of the catalyst; (b) the dehydrogenated product and any unadsorbed/unreacted hydrogen is removed from the reaction zone; (c) at least some of the adsorbed hydrogen is removed from the catalyst and/or at least some of the reduced catalyst is oxidised; and (d) reusing the catalyst from step (c) in step (a).
摘要翻译：一种用于烃和/或含氧烃进料脱氢的连续方法，包括使烃和/或含氧烃进料与脱氢催化剂在升高的温度下在反应区中接触，其特征在于催化剂能够保持氢和（a ）与进料接触以形成脱氢产物和氢，形成的至少一些形成的氢被催化剂吸附和/或与其反应以减少至少部分催化剂; （b）脱氢产物和任何未吸附的/未反应的氢从反应区除去; （c）从催化剂中除去至少一些吸附的氢气，和/或至少一些还原的催化剂被氧化; 和（d）在步骤（a）中重新使用来自步骤（c）的催化剂。

7. 发明授权

US08426664B2 Process for producing ethylene 有权
标题翻译：生产乙烯的方法
公开(公告)号：US08426664B2
公开(公告)日：2013-04-23
申请号：US12085703
申请日：2006-11-22
申请人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
发明人： Craig Bailey , Leslie William Bolton , Benjamin Patrick Gracey , Michael Keith Lee , Stephen Roy Partington
IPC分类号： C07C1/24
CPC分类号： C07C1/24 , C07C2521/08 , C07C2521/16 , C07C2527/188 , C07C2527/19 , C07C2529/18 , Y02P20/582 , C07C11/04
摘要： Process for producing ethylene from an ethanol feedstock A by (1) reacting the ethanol feedstock A in a vapor phase reactor wherein the ethanol is converted at a temperature between 160 and 270° C. and at a pressure of above 0.1 MPa but less than 4.5 MPa, into a product stream B containing ethylene, diethyl ethers, water and unconverted ethanol, (2) cooling the product stream B, (3) disengaging the cooled product stream B in a separation unit to give a first stream C containing ethylene and diethyl ethers, and a second product stream D containing water, diethyl ethers and unconverted ethanol, (4) feeding the product stream D to a dewatering unit wherein the water stream F is separated from the diethyl ethers and unconverted ethanol stream E, (5) recycling the stream E into the dehydration reactor of step 1, (6) cooling the product stream C, and (7) feeding the cooled product stream C to a purification unit wherein the diethyl ethers stream G is separated from the ethylene stream H. Optionally, the ethyl ethers stream G is recycled to either the dewatering unit of step (4) or directly to dehydration reactor of step (1).
摘要翻译：通过（1）使乙醇原料A在气相反应器中反应，其中乙醇在160-270℃之间的温度和在0.1MPa以上但小于4.5的压力下进行转化，从乙醇原料A生产乙烯的方法 MPa，加入含有乙烯，二乙醚，水和未转化乙醇的产物流B中，（2）冷却产物流B，（3）在分离单元中使冷却的产物流B脱离，得到含有乙烯和二乙基醚和含有水，二乙醚和未转化乙醇的第二产物流D，（4）将产物流D供给脱水单元，其中水流F与二乙醚和未转化的乙醇流E分离，（5）回收将流E进入步骤1的脱水反应器，（6）冷却产物流C，和（7）将冷却的产物流C供给到纯化单元，其中二乙醚流G与乙烯流H分离。乙醚流G被再循环到步骤（4）的脱水单元或直接转移到步骤（1）的脱水反应器中。

8. 发明授权

US07148304B2 Polymerization catalysts 有权
标题翻译：聚合催化剂
公开(公告)号：US07148304B2
公开(公告)日：2006-12-12
申请号：US10667859
申请日：2003-09-23
申请人： Brian Stephen Kimberley , Peter James Maddox , Stephen Roy Partington
发明人： Brian Stephen Kimberley , Peter James Maddox , Stephen Roy Partington
IPC分类号： C08F210/02
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/04 , Y10S526/943 , C08F4/61904 , C08F4/60089 , C08F4/6541 , C08F4/025 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F210/14 , C08F2500/10 , C08F2500/26 , C08F2500/03 , C08F4/7042
摘要： A catalyst for the polymerization of 1-olefins is disclosed, which comprises (1) a compound of Formula B wherein M is Fe[II], Fe[III], Co[I], Co[II], Co[III], Mn[I], Mn[II], Mn[III], Mn[IV], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R1, R2, R3, R4, R5, R6 and R7 are independently selected from hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; and when any two or more of R1–R7 are hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; and (2) a further catalyst. Copolymers made using the catalyst having specific physical properties are also disclosed
摘要翻译：公开了用于1-烯烃聚合的催化剂，其包括（1）式B化合物，其中M为Fe [II]，Fe [III]，Co [I]，Co [II]，Co [III] Mn [I]，Mn [II]，Mn [III]，Mn [IV]，Ru [II]，Ru [III]或Ru [IV] X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R 1，R 2，R 3，R 4，R 5， R 6和R 7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基; 当R 1〜R 2中的任意两个以上为烃基，取代烃基，杂烃基或取代的杂烃基时，所述两个或多个可以连接形成一个或多个环状取代基; 和（2）另外的催化剂。还公开了使用具有特定物理性质的催化剂制备的共聚物

9. 发明授权

US06657026B1 Polymerization catalysts 有权
标题翻译：聚合催化剂
公开(公告)号：US06657026B1
公开(公告)日：2003-12-02
申请号：US09659589
申请日：2000-09-11
申请人： Brian Stephen Kimberley , Peter James Maddox , Stephen Roy Partington
发明人： Brian Stephen Kimberley , Peter James Maddox , Stephen Roy Partington
IPC分类号： C08F442
CPC分类号： C07D213/53 , C07F13/005 , C07F15/0053 , C07F15/025 , C07F15/065 , C08F4/65912 , C08F4/65916 , C08F4/65925 , C08F10/00 , C08F10/02 , C08F110/02 , C08F210/16 , C08F2410/04 , Y10S526/943 , C08F4/61904 , C08F4/60089 , C08F4/6541 , C08F4/025 , C08F2500/04 , C08F2500/07 , C08F2500/12 , C08F210/14 , C08F2500/10 , C08F2500/26 , C08F2500/03 , C08F4/7042
摘要： A catalyst for the polymerization of 1-olefins which includes (1) a compound of Formula B wherein M is Fe[II], Fe[III], Co[I], Co[II], Co[III], Man[I], Man[II], Mn[III], Mn[IV], Ru[II], Ru[III] or Ru[IV]; X represents an atom or group covalently or ionically bonded to the transition metal M; T is the oxidation state of the transition metal M and b is the valency of the atom or group X; R1, R2, R3, R4, R5, R6 and R7 are independently selected form hydrogen, halogen, hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl; and when any two ore more of R1-R7 are hydrocarbyl, substituted hydrocarbyl, heterohydrocarbyl or substituted heterohydrocarbyl, said two or more can be linked to form one or more cyclic substituents; and (2) a further catalyst.
摘要翻译：一种用于1-烯烃聚合的催化剂，其包括（1）式B化合物，其中M是Fe [II]，Fe [III]，Co [I]，Co [II]，Co [III]，Mn [I ]，Mn [II]，Mn [III]，Mn [IV]，Ru [II]，Ru [III]或Ru [IV] X表示与过渡金属M共价或离子键合的原子或基团; T是过渡金属M的氧化态，b是原子或基团X的化合价; R 1，R 2，R 3，R 4，R 5，R 6和R 7独立地选自氢，卤素，烃基，取代的烃基，杂烃基或取代的杂烃基; 并且当R 1 -R 7中的任何两个或更多个是烃基，取代的烃基，杂烃基或取代的杂烃基时，所述两个或更多个可以连接形成一个或多个环状取代基; 和（2）另外的催化剂。

10. 发明授权

US06300437B1 Polymerization process 失效
标题翻译：聚合过程
公开(公告)号：US06300437B1
公开(公告)日：2001-10-09
申请号：US08904437
申请日：1997-07-31
申请人： Philip Howard , Peter James Maddox , Stephen Roy Partington
发明人： Philip Howard , Peter James Maddox , Stephen Roy Partington
IPC分类号： C08F442
CPC分类号： C08F210/16 , C08F4/65912 , C08F4/65916 , C08F4/65927 , C08F10/00 , Y10S526/901 , Y10S526/943 , C08F210/14 , C08F2500/09 , C08F2500/20 , C08F2500/12 , C08F2500/26
摘要： A process for preparing polyolefins having at least 0.01 long chain branches (LCB)/1000 carbon atoms along the polymer backbone as measured by flow activation and a molecular weight distribution greater than 2.5 comprises polymerization in the presence of a metallocene complex having the formula: wherein Cp1, Cp2 are independently a substituted or unsubstituted indenyl or hydrogenated indenyl group, Y is a univalent anionic ligand, M is zirconium, titanium or hafnium, and Z is a bridging group comprising an alkylene group having 1 to 20 carbon atoms or a dialkyl silyl- or germyl- group, or alkyl phophine or amine radical. Polyolefins prepared from such a process show specific flow activation energy/LCB relationships.
摘要翻译：通过流动活化和大于2.5的分子量分布测量，制备沿着聚合物主链具有至少0.01个长支链（LCB）/ 1000个碳原子的聚烯烃的方法包括在具有下式的茂金属络合物存在下聚合：其中Cp1 ，Cp2独立地是取代或未取代的茚基或氢化茚基，Y是一价阴离子配体，M是锆，钛或铪，Z是包含具有1至20个碳原子的亚烷基的桥连基或二烷基甲硅烷基或甲锗烷基或烷基磷或胺基。从这种方法制备的聚烯烃显示出特定的流动活化能/ LCB关系。

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