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51. 发明授权

US4254229A Polyurethane plastics containing thio groups 失效
标题翻译：含硫基的聚氨酯塑料
公开(公告)号：US4254229A
公开(公告)日：1981-03-03
申请号：US106976
申请日：1979-12-26
申请人： Jurgen Schwindt , Gerhard Grogler , Paul Uhrhan
发明人： Jurgen Schwindt , Gerhard Grogler , Paul Uhrhan
IPC分类号： C08G18/10 , C08G18/38 , C08J5/18 , C08G18/14 , C07C149/40 , C08G18/32
CPC分类号： C08J5/18 , C08G18/10 , C08G18/3868 , C08J2367/02
摘要： The instant invention is directed to polyurethane plastics which may be cellular, produced by reaction of polyisocyanates with relatively high molecular weight polyhydroxyl compounds and, optionally, low molecular weight polyhydroxyl compounds, and diamines, said polyurethane plastic containing structural units corresponding to the general formula ##STR1## in which R' represents a straight or branched divalent aliphatic, cycloaliphatic or aromatic radicals containing from 2 to 20 carbon atoms andR" represents hydrogen, a straight or branched alkyl radical containing from 1 to 6 carbon atoms, an aryl radical containing from 6 to 15 carbon atoms, a cycloalkyl radical containing from 4 to 12 carbon atoms, halogen, --NO.sub.2, --CN, --OR'" or a radical ##STR2## where R"' represents a straight or branched alkyl radical containing from 1 to 6 carbon atoms.
摘要翻译：本发明涉及可通过多异氰酸酯与相对高分子量多羟基化合物和任选的低分子量多羟基化合物和二胺的反应制备的聚氨酯塑料，所述聚氨酯塑料含有对应于通式 IMAGE>其中R'表示含有2至20个碳原子的直链或支链二价脂族，脂环族或芳族基团，R“表示氢，含有1至6个碳原子的直链或支链烷基，含有 6至15个碳原子的环烷基，含有4至12个碳原子的环烷基，卤素，-NO 2，-CN，-OR“或其中R”'表示含有直链或支链烷基的基团 1至6个碳原子。

52. 发明授权

US4189542A Process for the production of foam moldings having an impervious outer skin using semi-prepolymer prepared from isocyanates such as isophorone diisocyanate 失效
标题翻译：使用由异氰酸酯如异佛尔酮二异氰酸酯制备的半预聚物生产具有不透水外皮的泡沫塑料制品的方法
公开(公告)号：US4189542A
公开(公告)日：1980-02-19
申请号：US930303
申请日：1978-08-02
申请人： Helmut Kleimann , Holger Meyborg , Hans-Jurgen Lienert , Gerhard Grogler
发明人： Helmut Kleimann , Holger Meyborg , Hans-Jurgen Lienert , Gerhard Grogler
IPC分类号： C08J9/02 , C08G18/10 , C08G18/75 , C08G18/80 , C08G18/14
CPC分类号： C08G18/8058 , C08G18/10 , C08G18/75 , C08G18/8032
摘要： The instant invention is directed to a process for the production of weather-resistant rigid molded foams based on polyurethanes having a dimensional stability under heat according to DIN 53 432 of at least 70.degree. C. and a compact surface, a cellular core and an integral density distribution throughout the cross-section of the moldings, comprising foaming a foamable reaction mixture of polyisocyanates, polyhydroxyl compounds, blowing agents and, optionally, other isocyanate-reactive compounds, activators and other auxiliaries in a closed mold under the conditions of in-mold foaming, the improvement wherein the polyisocyanates used are reaction products containing isocyanate groups and urethane groups, said reaction products formed by reacting diisocyanates containing at least one cycloaliphatically bound isocyanate group and no more than one aliphatically bound isocyanate group with sub-stoichiometric quantities of organic polyhydroxyl compounds.
摘要翻译：本发明涉及一种用于生产基于聚氨酯的耐候刚性模塑泡沫的方法，所述聚氨酯在根据DIN 53 432的加热条件下具有至少70℃的尺寸稳定性，以及紧凑的表面，多孔芯和积分包括在模制品的整个横截面处的密度分布，包括在模内的条件下，在封闭模具中发泡多异氰酸酯，多羟基化合物，发泡剂和任选的其它异氰酸酯反应性化合物，活化剂和其它助剂的可发泡反应混合物发泡，其中使用的多异氰酸酯是含有异氰酸酯基团和氨基甲酸酯基团的反应产物的改进，所述反应产物是通过使含有至少一个环脂族连接的异氰酸酯基团的二异氰酸酯和不超过一个脂族结合的异氰酸酯基团与亚化学计量的有机多羟基化合物。

53. 发明授权

US5143987A Polyurethane reactive adhesive compounds containing finely dispersed polymers 失效
标题翻译：含有精细分散聚合物的聚氨酯类反应性胶粘剂
公开(公告)号：US5143987A
公开(公告)日：1992-09-01
申请号：US577979
申请日：1990-09-05
申请人： Eduard Hansel , Heinrich Hess , Gunter Arend , Gerhard Grogler , Richard Kopp
发明人： Eduard Hansel , Heinrich Hess , Gunter Arend , Gerhard Grogler , Richard Kopp
IPC分类号： C08G18/40 , C08G18/70 , C08G18/80 , C09J175/00 , C09J175/04
CPC分类号： C08G18/8038 , C08G18/40 , C08G18/409 , C08G18/707 , C09J175/04
摘要： The present invention is directed to a polyurethane reactive adhesive compound comprising:A) one or more polyisocyanates having an inactivated particle surface,B) at least one isocyanate reactive compound having a molecular weight MG.sub.w greater than 400, andC) finely dispersed polymer particles, wherein the polymer is solid at temperatures below 70.degree. C. and has a molecular weight MG.sub.w of at least 3000.
摘要翻译：本发明涉及一种聚氨酯反应性粘合剂化合物，其包含：A）一种或多种具有失活的颗粒表面的多异氰酸酯，B）至少一种分子量MGw大于400的异氰酸酯反应性化合物，和C）分散的聚合物颗粒，其中所述聚合物在低于70℃的温度下是固体，并且具有至少3000的分子量MGw。

54. 发明授权

US4720545A Process for the preparation of complexes of one mol of dimerized or low-oligodimerized 4,4'-diisocyanatodiphenylmethane and two to three mol of 4,4'-diisocyanatodiphenylmethane, corresponding complexes, and their use for polyurethane production 失效
标题翻译：制备一摩尔二聚或低二聚体4,4'-二异氰酸二苯基甲烷和2至3摩尔4,4'-二异氰酸二苯基甲烷，相应络合物及其用于聚氨酯生产的配合物的方法
公开(公告)号：US4720545A
公开(公告)日：1988-01-19
申请号：US829056
申请日：1986-02-13
申请人： Gerhard Grogler , Richard Kopp , Heinrich Hess
发明人： Gerhard Grogler , Richard Kopp , Heinrich Hess
IPC分类号： C08G18/00 , C07D229/00 , C08G18/72 , C08G18/76 , C08G18/79 , C07D403/14
CPC分类号： C07D229/00 , C08G18/798
摘要： The present invention relates to a process for the dimerization of 4,4'-diisocyanatodiphenylmethane from emulsion in apolar solvents with the formation of complexes and to the complexes obtainable for the first time by this process. The complexes consist of one mol of low molecular weight 4,4'-diisocyanato-diphenylmethane-uretdione or its low oligomers corresponding to the idealized formula (I) ##STR1## (n=0 to 0.5, where n is the average degree of oligomerization of the dimer) and 2 to 3 mol of 4,4'-diisocyanatodiphenylmethane (MDI) ##STR2## In the process according to the invention, 4,4'-diisocyanatodiphenylmethane (II) in the molten form is emulsified in apolar solvents. Dimerization is started in the presence of conventional dimerization catalysts at temperatures above the melting point of MDI, preferably up to an upper temperature limit of 50.degree. to 60.degree. C. The temperature is then lowered to
摘要翻译：本发明涉及一种在非极性溶剂中形成络合物的乳液中的4,4'-二异氰酸二苯基甲烷二聚作用的方法以及通过该方法首次获得的络合物。络合物由1mol低分子量的4,4'-二异氰酸酯基 - 二苯基甲烷脲二酮或其对应于理想化的式（I）的低聚物组成。（I）（n = 0至0.5，其中n 是二聚体的平均低聚度）和2〜3mol的4,4'-二异氰酸根合二苯基甲烷（MDI）。（II）在本发明的方法中，4,4'-二异氰酸根合二苯基甲烷熔融形式在非极性溶剂中乳化。在常规二聚催化剂存在下，在高于MDI熔点的温度下，优选开始二聚，最好达到50-60℃的上限温度。然后将温度降至<40℃。如果需要，二聚可以当异氰酸酯含量达到22.4％至26.9％时停止。然后将产物在低温下，优选0℃至25℃下处理。所得的络合物作为新物质被要求。还要求使用该复合物生产聚氨酯。

55. 发明授权

US4667008A Process for the production of solid polyisocyanates of retarded reactivity, polymer-coated, finely divided polyisocyanates and their use 失效
公开(公告)号：US4667008A
公开(公告)日：1987-05-19
申请号：US732039
申请日：1985-05-08
申请人： Gerhard Grogler , Richard Kopp , Heinrich Hess
发明人： Gerhard Grogler , Richard Kopp , Heinrich Hess
IPC分类号： C08G18/00 , C08G18/70 , C08G18/72 , C08L75/04 , C09D175/00 , C09D175/04 , C14C11/00 , D06N3/14 , C08G18/32 , C08G18/48
CPC分类号： C08G18/8019 , C07C263/18 , C08G18/3206 , C08G18/3234 , C08G18/4825 , C08G18/5024 , C08G18/703 , C08G18/725 , C08G18/755 , C08G18/7621 , C08G18/7831 , C08G18/8038 , Y10T428/2991
摘要： This invention relates to the production of polymer-coated, finely divided polyisocyanates by mixing(A) solid, finely divided polyisocyanates (preferably dimeric diisocyanates or urea diisocyanates) with(B) polyisocyanates differing in composition from those mentioned under (A) (preferably (cyclo) aliphatic polyisocyanates, such as biuretized diisocyanates or trimers or NCO-prepolymers),in quantities of from 0.05 to 50 parts by weight, and preferably in quantities of from 0.2 to 25 parts by weight, of (B) per 100 parts by weight of (A). The solid polyisocyanate particles surface-modified by covering with polyisocyanates (B) and then reacted with(D) isocyanate-reactive compounds containing reactive hydrogen atoms or with compounds free from active hydrogen atoms which form polymers with isocyanates in sub-equivalent to substantially equivalent quantities (preferably 0.5 to 1.0 equivalent per NCO-equivalent), in the presence of(C) inert, weakly polar organic solvents, (for example aliphatic hydrocarbons or relatively long chain dialkyl ethers), plasticizers, polyols or aromatic polyamines.A polymer coating is formed by the reaction of (B) and (D) around the solid polyisocyanate cores (A).The present invention also relates to the polyisocyanate particles covered with polyisocyanates (B) on the surface of the solid polyisocyanates (A) and, in particular, to the foreign-polymer coated, finely particulate polyisocyanates of retarded reactivity obtained by reaction with (D).The present invention also relates to the use of the polyisocyanate-covered and, more particularly, polymer-coated polyisocyanates, optionally in suspension in polyols and/or plasticizers, for the production of polyurethanes, more particularly in one-component polyurethane reactive systems having a long shelf life and a high thickening point.

56. 发明授权

US4546165A Process for the production of stabilized polyisocyanates of retarded reactivity and their use in the production of polyurethanes 失效
标题翻译：用于生产延迟反应性稳定的多异氰酸酯及其在生产聚氨酯中的用途的方法
公开(公告)号：US4546165A
公开(公告)日：1985-10-08
申请号：US694566
申请日：1985-01-24
申请人： Gerhard Grogler , Heinrich Hess , Richard Kopp
发明人： Gerhard Grogler , Heinrich Hess , Richard Kopp
IPC分类号： C08G18/00 , C07C265/00 , C08G18/08 , C08G18/70 , C08G18/72 , C08G18/80 , C08G18/18
CPC分类号： C08G18/6648 , C08G18/089 , C08G18/10 , C08G18/5045 , C08G18/6685 , C08G18/705 , C08G18/7825 , C08G18/798 , C08G18/80
摘要： The present invention relates to a process for the production of solid polyisocyanates of retarded reactivity stabilized by surface modification by reacting solid, finely divided polyisocyanates, and particularly dimeric tolylene diisocyanate, dimeric diphenylmethane diisocyanate and 3,3'-diisocyanato-4,4'-dimethyl-N,N'-diphenyl urea, with acyclic, mono- or bicyclic compounds having an amidine or guanidine structure and which do not contain any hydrogen atoms reactive to isocyanates at room temperature in a quantity of from 0.1 to 25 equivalent percent of "amidine" or "guanidine" per isocyanate equivalent. The reaction may be carried out directly in a liquid medium selected from the group consisting of active hydrogen compounds, plasticizers, water, and solvents to form a suspension of polyadduct-coated, stabilized polyisocyanates in the liquid medium.
摘要翻译：本发明涉及通过使固体，细分散的多异氰酸酯，特别是二聚甲苯二异氰酸酯，二聚二苯基甲烷二异氰酸酯和3,3'-二异氰酸根合-4,4'-二异氰酸酯二异氰酸酯反应，通过表面改性而稳定的延迟反应性固体聚异氰酸酯的制备方法，二甲基-N，N'-二苯基脲，其具有脒或胍结构的无环，单或双环化合物，并且在室温下不含任何与异氰酸酯反应的氢原子，其量为0.1至25当量的“ 脒“或”胍“。反应可以直接在选自活性氢化合物，增塑剂，水和溶剂的液体介质中进行，以在液体介质中形成多加成膜包被的稳定化多异氰酸酯的悬浮液。

57. 发明授权

US4387057A New diisocyanates containing sulfur and a process for their preparation 失效
标题翻译：含有硫的新型二异氰酸酯及其制备方法
公开(公告)号：US4387057A
公开(公告)日：1983-06-07
申请号：US136624
申请日：1980-04-02
申请人： Jurgen Schwindt , Gerhard Grogler , Otto Ganster , Johannes Koster
发明人： Jurgen Schwindt , Gerhard Grogler , Otto Ganster , Johannes Koster
IPC分类号： C08G18/00 , C07C67/00 , C07C313/00 , C07C315/04 , C07C317/32 , C07C323/36 , C08G18/77 , C07C119/048
CPC分类号： C08G18/775
摘要： The invention is directed to new sulfur-containing diisocyanates in which a mercapto, sulfoxo or sulfone group joins two aromatic nuclei together or joins an aromatic nucleus to an aliphatic group and in which at least one of the aromatically bound isocyanate groups is in the ortho-position to the sulfur atom. The invention is also directed to a process for the preparation of these new sulfur-containing diisocyanates and to their use in the isocyanate polyaddition process for the production of polyurethanes.
摘要翻译：本发明涉及新的含硫二异氰酸酯，其中巯基，磺基或砜基团将两个芳香核团连接在一起或将芳香核连接到脂族基团上，其中至少一个芳族结合的异氰酸酯基团在邻位 - 位置到硫原子。本发明还涉及一种制备这些新的含硫二异氰酸酯的方法及其在用于生产聚氨酯的异氰酸酯加聚方法中的用途。

58. 发明授权

US4377644A Mixed anhydrides of isocyanates and carboxylic acids, mixtures thereof with carboxylic acids, and the use thereof as blowing agents for the production of cellular plastics 失效
标题翻译：异氰酸酯和羧酸的混合酸酐，其与羧酸的混合物及其作为泡沫塑料生产发泡剂的用途
公开(公告)号：US4377644A
公开(公告)日：1983-03-22
申请号：US312034
申请日：1981-10-16
申请人： Richard Kopp , Gerhard Grogler , Max Mann
发明人： Richard Kopp , Gerhard Grogler , Max Mann
IPC分类号： C08J9/08 , C08G18/14
CPC分类号： C08J9/08
摘要： This invention relates to solid reaction products of aliphatic, cycloaliphatic or araliphatic mono- and/or polyisocyanates and organic, weakly acid mono- and/or polycarboxylic acids for the production of cellular plastics articles and particularly polyurethane foams. The products of the present invention may also be in the form of mixtures with carboxylic acids. The products are suitable for the production of cellular or porous plastics articles, but are preferably used in the preparation of cellular thermoplastic polyurethanes and semi-rigid and particularly rigid polyurethane integral skin foams having a compact outer skin formed by foaming the reaction mixture in closed molds.
摘要翻译：本发明涉及脂肪族，脂环族或芳脂族单 - 和/或多异氰酸酯和有机，弱酸单 - 和/或多元羧酸的固体反应产物，用于生产细胞塑料制品，特别是聚氨酯泡沫。本发明的产品也可以是与羧酸的混合物的形式。该产品适用于生产细胞或多孔塑料制品，但优选用于制备细胞热塑性聚氨酯和半刚性和特别硬的聚氨酯整体皮肤泡沫，其具有通过将闭合模具中的反应混合物发泡而形成的致密外皮。

59. 发明授权

US4336180A Solvent-free polyurethanes with fibrous reinforcing agents 失效
标题翻译：无溶剂的聚氨酯与纤维增强剂
公开(公告)号：US4336180A
公开(公告)日：1982-06-22
申请号：US246816
申请日：1981-03-23
申请人： Klaus Recker , Gerhard Grogler
发明人： Klaus Recker , Gerhard Grogler
IPC分类号： C08G18/00 , C08G18/08 , C08G18/10 , C08K3/34 , C08K7/02 , C08L67/00 , C08L75/00 , C08L77/00 , C08L75/12
CPC分类号： C08G18/10 , C08G18/0838 , C08K7/02
摘要： The instant invention is directed to a substantially solvent-free molding material, comprising(A) from 92 to 30% by weight, of an active-hydrogen containing prepolymer containing: from 0.3 to 4% by weight, based on the prepolymer, of free primary and/or secondary amino groups, from 1.5 to 10% by weight, based on the prepolymer, of urethane groups, and from 1.5 to 10% by weight, based on the prepolymer, of urea groups;(B) from 24 to 1% by weight of a polyisocyanate having a melting point above 120.degree. C.; and(C) from 5 to 69% by weight of an organic or inorganic fibrous material with a fiber length of from 0.1 to 100 mm, the equivalent ratio between NCO groups, including masked NCO groups, and active H-atoms of components (A) and (B) is between 1:1 and 1:1.75. The instant invention is also directed to a process for the production of the substantially solvent-free molding material.
摘要翻译：本发明涉及基本无溶剂的模塑材料，其包含（A）92至30重量％的含活性氢的预聚物，其包含：基于预聚物的0.3至4重量％的游离初级和/或仲氨基，基于预聚物的1.5至10重量％的氨基甲酸酯基，和基于预聚物的基于预聚物的1.5至10重量％的脲基; （B）24〜1重量％的熔点高于120℃的多异氰酸酯。和（C）5至69重量％的纤维长度为0.1至100mm的有机或无机纤维材料，NCO基团（包括掩蔽的NCO基团）和组分的活性H原子（A ）和（B）在1:1至1: 1.75之间。本发明还涉及生产基本上无溶剂的成型材料的方法。

60. 发明授权

US4006124A Amidine-metal complexes and their use as catalysts for isocyanate polyaddition reactions 失效
标题翻译：脒金属络合物及其用作异氰酸酯加聚反应的催化剂
公开(公告)号：US4006124A
公开(公告)日：1977-02-01
申请号：US590768
申请日：1975-06-26
申请人： Rainer Welte , Gerhard Grogler
发明人： Rainer Welte , Gerhard Grogler
IPC分类号： C07D249/08 , C07D213/74 , C07D471/04 , C07D487/04 , C07F1/00 , C07F3/06 , C07F7/22 , C07F9/6512 , C07F19/00 , C08G18/00 , C08G18/18 , C08G18/22
CPC分类号： C07F7/22 , C07F19/005 , C08G18/22
摘要： The instant invention is directed to a process for the production of novel amidine-metal complexes and to the use thereof as catalysts for isocyanate polyaddition reactions. The novel amidine-metal complexes of the instant invention are generally produced by mixing an amidine with a metal salt.
摘要翻译：本发明涉及一种制备新型脒基金属络合物的方法及其作为异氰酸酯加聚反应催化剂的用途。本发明的新型脒基金属络合物通常通过将脒与金属盐混合来制备。

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