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1. 发明授权

US4024090A Process for molding polyurethane foams 失效
标题翻译：聚氨酯泡沫成型工艺
公开(公告)号：US4024090A
公开(公告)日：1977-05-17
申请号：US521425
申请日：1974-11-06
申请人： Wulf VON Bonin , Helmut Kleimann , Udo Post
发明人： Wulf VON Bonin , Helmut Kleimann , Udo Post
IPC分类号： C09J7/02 , B29C33/00 , B29C39/00 , B29C39/02 , B29C39/38 , B29C59/00 , C08G18/00 , C08J9/00 , C08L83/06 , C10M107/50 , C10M109/02 , C10N40/36 , C08K5/54
CPC分类号： C08J9/0061 , C08L83/06 , C08J2375/04 , C08J2483/00
摘要： The mold release properties of a molded polyurethane foam are improved by including in the foamable reaction mixture to be molded a reaction product of a polysiloxane and a monocarboxylic acid or polycarboxylic acid.
摘要翻译：通过在可发泡反应混合物中包含聚硅氧烷和一元羧酸或多元羧酸的反应产物，可以改善模塑聚氨酯泡沫的脱模性能。

2. 发明授权

US4007239A Aromatic diamines 失效
标题翻译：芳香二胺
公开(公告)号：US4007239A
公开(公告)日：1977-02-08
申请号：US620088
申请日：1975-10-06
申请人： Johannes Blahak , Erwin Muller , Helmut Kleimann
发明人： Johannes Blahak , Erwin Muller , Helmut Kleimann
IPC分类号： C08G18/10 , C08G18/32 , C08G18/38 , C07C153/07
CPC分类号： C08G18/3868 , C08G18/10 , C08G18/3243 , C08G18/3855
摘要： Novel aromatic diamines having the general formula ##STR1## WHEREIN N IS AN INTEGER OF FROM 2 TO 8, X is sulfur or oxygen, and R is an n-valent hydrocarbon radical which may be interrupted by O or S atoms and which is obtained by removing OH or SH groups from a polyol or polythiol having a molecular weight of less than 600, are prepared by reacting a compound having the formula (HX).sub.n R where X, n and R are as defined above with about n-equivalents of an isatoic acid anhydride in the presence of a strong base. The aromatic diamines of the invention are particularly useful as the active hydrogen containing component for reaction with polyisocyanates in the preparation of synthetic resins by the isocyanate-polyaddition process.
摘要翻译：具有通式为：其中N为2至8的整数的新型芳族二胺，X为硫或氧，R为可被O或S原子间隔的n价烃基，其由通过使具有式（HX）nR的化合物，其中X，n和R如上所定义的化合物与大约n当量的等离子体的化合物反应，从分子量小于600的多元醇或多硫醇中除去OH或SH基团酸酐在强碱存在下进行。本发明的芳族二胺在通过异氰酸酯加聚方法制备合成树脂时，特别适用于与多异氰酸酯反应的含活性氢成分。

3. 发明授权

US4098731A Process for the production of foams 失效
标题翻译：生产泡沫的过程
公开(公告)号：US4098731A
公开(公告)日：1978-07-04
申请号：US775090
申请日：1977-03-07
申请人： Wulf von Bonin , Helmut Kleimann , Jozsef Ivanyi
发明人： Wulf von Bonin , Helmut Kleimann , Jozsef Ivanyi
IPC分类号： C08G18/18 , C08J9/00
CPC分类号： C08J9/0028 , C08G18/1875 , C08J2375/04
摘要： The present invention relates to the production in closed molds, of foams with outstanding mold-release properties. These improved properties are obtained by including in the foamable mixture salts of saturated or unsaturated aliphatic or cycloaliphatic carboxylic acids having at least 8 carbon atoms and tertiary amines of the type in which the atom ratio of tertiary amine nitrogen to carbon in the molecule is between 1:3 and 1:12.
摘要翻译：本发明涉及封闭模具中生产具有出色脱模性能的泡沫。这些改进的性能是通过在具有至少8个碳原子的饱和或不饱和脂族或脂环族羧酸的可发泡混合物盐和在该分子中叔胺氮与碳的原子比在1之间的叔胺类型：3和1:12。

4. 发明授权

US4070310A Process for the production of foams 失效
标题翻译：生产泡沫的过程
公开(公告)号：US4070310A
公开(公告)日：1978-01-24
申请号：US691057
申请日：1976-05-28
申请人： Heinz-Georg Schneider , Helmut Kleimann , Bruno Luckas
发明人： Heinz-Georg Schneider , Helmut Kleimann , Bruno Luckas
IPC分类号： C08G18/00 , C08G18/16 , C08J9/08 , C08J9/34 , C08G18/14
CPC分类号： C08J9/34 , C08J9/08 , C08J2375/04 , Y10S521/902
摘要： This invention relates to a process for the production of polyurethane foams in closed molds using mixtures of organic polyisocyanates with certain compounds which liberate carbon dioxide under the catalytic influence of basic compounds. In this process a mixture of polyisocyanates and compounds which liberate carbon dioxide under the catalytic influence of basic compounds is reacted with organic compounds containing hydrogen atoms which are reactive with isocyanate groups, which organic compounds are mixed with basic compounds and/or have basic compounds chemically built into them. The process is suitable for the production of any polyurethane foams in a closed mold, but is preferably applied to the production of semi-hard and particularly of hard polyurethane foams having a dense outer skin.
摘要翻译：本发明涉及一种在封闭模具中使用有机多异氰酸酯与某些在碱性化合物的催化作用下释放二氧化碳的化合物的混合物生产聚氨酯泡沫体的方法。在该方法中，在碱性化合物的催化作用下，释放二氧化碳的多异氰酸酯和化合物的混合物与含有与异氰酸酯基团反应的氢原子的有机化合物反应，该有机化合物与碱性化合物混合和/或化学上具有碱性化合物内置于其中该方法适用于在封闭模具中生产任何聚氨酯泡沫塑料，但优选用于生产具有致密外皮的硬硬聚氨酯泡沫塑料。

5. 发明授权

US4254228A Method of making foamed resins with internal mold-release agents 失效
标题翻译：用内部脱模剂制造泡沫树脂的方法
公开(公告)号：US4254228A
公开(公告)日：1981-03-03
申请号：US58571
申请日：1979-07-18
申请人： Helmut Kleimann , Wulf von Bonin , Heinz-Georg Schneider
发明人： Helmut Kleimann , Wulf von Bonin , Heinz-Georg Schneider
IPC分类号： C08G18/00 , C08G18/36 , C08G18/71 , C08G18/80 , C08J9/00 , C08G18/14
CPC分类号： C08J9/0061 , C08G18/36 , C08G18/71 , C08G18/80 , C08G18/8051 , C08G2101/0033 , C08G2125/00 , C08J2375/04 , C08J2475/00
摘要： A reaction product of a fatty acid ester and an organic polyisocyanate is included in a foamable reaction mixture containing an organic polyisocyanate to provide a molded product which can be removed from a mold whose surface has not been coated with conventional mold release agents.
摘要翻译：脂肪酸酯和有机多异氰酸酯的反应产物包括在含有机多异氰酸酯的可发泡反应混合物中，以提供可从表面未涂覆常规脱模剂的模具中除去的模塑产品。

6. 发明授权

US4201847A Process of preparing foams with internal mold-release agents 失效
标题翻译：用内部脱模剂制备泡沫体的方法
公开(公告)号：US4201847A
公开(公告)日：1980-05-06
申请号：US924260
申请日：1978-07-13
申请人： Helmut Kleimann , Wulf von Bonin , Heinz-Georg Schneider
发明人： Helmut Kleimann , Wulf von Bonin , Heinz-Georg Schneider
IPC分类号： C08G18/36 , C08G18/71 , C08G18/80 , C08J9/00 , C08G18/14
CPC分类号： C08J9/0061 , C08G18/36 , C08G18/71 , C08G18/8051 , C08G2101/0033 , C08G2125/00 , C08J2375/04 , C08J2475/00
摘要： A reaction product of a fatty acid ester and an organic polyisocyanate is included in a foamable reaction mixture containing an organic polyisocyanate to provide a molded product which can be removed from a mold whose surface has not been coated with conventional mold release agents.
摘要翻译：脂肪酸酯和有机多异氰酸酯的反应产物包括在含有机多异氰酸酯的可发泡反应混合物中，以提供可从表面未涂覆常规脱模剂的模具中除去的模塑产品。

7. 发明授权

US4033912A Process for molding polyurethane foams 失效
标题翻译：聚氨酯泡沫成型工艺
公开(公告)号：US4033912A
公开(公告)日：1977-07-05
申请号：US521426
申请日：1974-11-06
申请人： Helmut Kleimann , Wulf VON Bonin
发明人： Helmut Kleimann , Wulf VON Bonin
IPC分类号： B29C33/00 , B29C33/64 , B29C39/00 , B29C39/02 , B29C59/00 , C08G18/00 , C08G18/61 , C08J9/00 , C08J9/02 , C08J9/12 , C08G18/14 , C08G18/77 , C08K5/54
CPC分类号： C08J9/0028 , B29C33/64 , C08G18/61 , B29K2075/00 , B29K2105/04 , C08G2125/00 , C08J2375/04
摘要： The mold release properties of a molded polyurethane foam are improved by including the foamable mixture to be molded, a reaction product of a polysiloxane and an organic monoisocyanate or polyisocyanate.
摘要翻译：通过包括待模塑的可发泡混合物，聚硅氧烷和有机单异氰酸酯或多异氰酸酯的反应产物来改善模塑聚氨酯泡沫的脱模性能。

8. 发明授权

US4320067A Process for the preparation of modified polyisocyanates 失效
标题翻译：制备改性多异氰酸酯的方法
公开(公告)号：US4320067A
公开(公告)日：1982-03-16
申请号：US228513
申请日：1981-01-26
申请人： Wulf von Bonin , Helmut Kleimann , Hans-Albrecht Freitag
发明人： Wulf von Bonin , Helmut Kleimann , Hans-Albrecht Freitag
IPC分类号： C07D251/34 , C07C67/00 , C07C239/00 , C07C273/18 , C07C275/00 , C07D295/13 , C08G18/00 , C08G18/32 , C08G18/78 , C08G18/80 , C07C119/042 , C07C119/045 , C07C119/048
CPC分类号： C07D295/13 , C07C273/1827 , C08G18/3228 , C08G18/8038
摘要： A process for preparing modified polyisocyanates in which an organic polyisocyanate is reacted with a polyamine present in less than stoichiometric amount. Polyamines suitable to this process include (a) polyamines having more than three nonaromatically bound, basic nitrogen atoms of which at least two are primary and/or secondary amino nitrogen atoms, and (b) polyamine mixtures having an average of more than three nonaromatically bound, basic nitrogen atoms of which at least two are primary and/or secondary amino nitrogen atoms. These modified polyisocyanates are particularly useful starting materials for production of polyurethane plastics by the isocyanate-polyaddition process.
摘要翻译：制备改性多异氰酸酯的方法，其中有机多异氰酸酯与少于化学计量的多胺反应。适用于该方法的多胺包括（a）具有多于三个非结合的碱性氮原子的多胺，其中至少两个是伯和/或仲氨基氮原子，和（b）平均多于三个非结合的多胺混合物，其中至少两个为碱性氮原子和/或仲氨基氮原子的碱性氮原子。这些改性的多异氰酸酯是通过异氰酸酯加聚方法生产聚氨酯塑料的特别有用的起始原料。

9. 发明授权

US4317791A Process for the production of non-cellular molded articles 失效
标题翻译：用于生产非细胞模制品的方法
公开(公告)号：US4317791A
公开(公告)日：1982-03-02
申请号：US812946
申请日：1977-07-05
申请人： Heimo Ludke , Peter Gunther , Helmut Kleimann
发明人： Heimo Ludke , Peter Gunther , Helmut Kleimann
IPC分类号： C08J9/02 , B29B7/00 , B29C31/00 , B29C39/00 , B29C39/10 , B29C39/24 , C08G18/02 , C08G18/09 , B29C5/00 , C08G18/08
CPC分类号： C08G18/092 , C08G18/022 , Y10S521/902
摘要： A process is described for the successive production of at least two non-cellular molded articles differing in their mechanical properties. Both articles are based on organic polyisocyanates which are trimerized in the presence of compounds which are reactive with isocyanate groups where the equivalent ratio of NCO groups to groups reactive with NCO groups is varied within the range of 1:0.8 to 1:0. In a second embodiment, a uniform article is produced having anisotropic mechanical characteristics varying continuously and/or stepwise.
摘要翻译：描述了连续生产其机械性能不同的至少两个非多孔模塑制品的方法。两种制品均基于有机多异氰酸酯，它们在与异氰酸酯基团反应的化合物存在下进行三聚，其中NCO基团与NCO基团反应的基团的当量比在1:0.8至1:0的范围内变化。在第二实施例中，制造具有连续和/或逐步变化的各向异性机械特性的均匀制品。

10. 发明授权

US4189542A Process for the production of foam moldings having an impervious outer skin using semi-prepolymer prepared from isocyanates such as isophorone diisocyanate 失效
标题翻译：使用由异氰酸酯如异佛尔酮二异氰酸酯制备的半预聚物生产具有不透水外皮的泡沫塑料制品的方法
公开(公告)号：US4189542A
公开(公告)日：1980-02-19
申请号：US930303
申请日：1978-08-02
申请人： Helmut Kleimann , Holger Meyborg , Hans-Jurgen Lienert , Gerhard Grogler
发明人： Helmut Kleimann , Holger Meyborg , Hans-Jurgen Lienert , Gerhard Grogler
IPC分类号： C08J9/02 , C08G18/10 , C08G18/75 , C08G18/80 , C08G18/14
CPC分类号： C08G18/8058 , C08G18/10 , C08G18/75 , C08G18/8032
摘要： The instant invention is directed to a process for the production of weather-resistant rigid molded foams based on polyurethanes having a dimensional stability under heat according to DIN 53 432 of at least 70.degree. C. and a compact surface, a cellular core and an integral density distribution throughout the cross-section of the moldings, comprising foaming a foamable reaction mixture of polyisocyanates, polyhydroxyl compounds, blowing agents and, optionally, other isocyanate-reactive compounds, activators and other auxiliaries in a closed mold under the conditions of in-mold foaming, the improvement wherein the polyisocyanates used are reaction products containing isocyanate groups and urethane groups, said reaction products formed by reacting diisocyanates containing at least one cycloaliphatically bound isocyanate group and no more than one aliphatically bound isocyanate group with sub-stoichiometric quantities of organic polyhydroxyl compounds.
摘要翻译：本发明涉及一种用于生产基于聚氨酯的耐候刚性模塑泡沫的方法，所述聚氨酯在根据DIN 53 432的加热条件下具有至少70℃的尺寸稳定性，以及紧凑的表面，多孔芯和积分包括在模制品的整个横截面处的密度分布，包括在模内的条件下，在封闭模具中发泡多异氰酸酯，多羟基化合物，发泡剂和任选的其它异氰酸酯反应性化合物，活化剂和其它助剂的可发泡反应混合物发泡，其中使用的多异氰酸酯是含有异氰酸酯基团和氨基甲酸酯基团的反应产物的改进，所述反应产物是通过使含有至少一个环脂族连接的异氰酸酯基团的二异氰酸酯和不超过一个脂族结合的异氰酸酯基团与亚化学计量的有机多羟基化合物。

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