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51. 发明授权

US06383319B1 Rocket fuels based on metal hydrides and poly-DCPD 失效
标题翻译：基于金属氢化物和聚-DCPD的火箭燃料
公开(公告)号：US06383319B1
公开(公告)日：2002-05-07
申请号：US09369051
申请日：1999-08-04
申请人： Ronald W. Humble , Robert H. Grubbs , Charles S. Woodson
发明人： Ronald W. Humble , Robert H. Grubbs , Charles S. Woodson
IPC分类号： C06B2700
CPC分类号： C06B27/00 , C06B45/10 , C06B47/02 , C06D5/00
摘要： Preferred embodiments of the present invention relate to rocket fuels comprising metal hydrides and poly-dicyclopentadiene (“poly-DCPD”). Although poly-DCPD also has physical and chemical properties that are compatible with being used as a rocket fuel in its own right, its primary function is as a binder for the metal hydride. Illustrative examples of metal hydrides include but are not limited to as aluminum hydrides, lithium hydrides, and lithium aluminum hydrides.
摘要翻译：本发明的优选实施方案涉及包含金属氢化物和聚二环戊二烯（“poly-DCPD”）的火箭燃料。虽然poly-DCPD也具有与其本身用作火箭燃料相容的物理和化学性质，但其主要功能是作为金属氢化物的粘合剂。金属氢化物的说明性实例包括但不限于氢化铝，氢化锂和氢化锂铝。

52. 发明授权

US06290911B1 Compositionally different polymer-based sensor elements and method for preparing same 失效
标题翻译：组成不同的基于聚合物的传感器元件及其制备方法
公开(公告)号：US06290911B1
公开(公告)日：2001-09-18
申请号：US09106791
申请日：1998-06-29
申请人： Nathan S. Lewis , Robert H. Grubbs , Robert D. Sanner , Eric J. Severin
发明人： Nathan S. Lewis , Robert H. Grubbs , Robert D. Sanner , Eric J. Severin
IPC分类号： G01N2702
CPC分类号： G01N27/126 , B01J19/0046 , B01J2219/00351 , B01J2219/00524 , B01J2219/00596 , B01J2219/00605 , B01J2219/00612 , B01J2219/00637 , B01J2219/00659 , B01J2219/00707 , B01J2219/00722 , C40B40/14 , C40B60/14 , G01N21/77 , G01N33/0031 , G01N2021/773 , Y10T436/2575
摘要： The present invention provides a combinatorial approach for preparing arrays of chemically sensitive polymer-based sensors which are capable of detecting the presence of a chemical analyte in a fluid in contact therewith. The described methods and devices comprise combining varying ratios of at least first and second organic materials which, when combined, form a polymer or polymer blend that is capable of absorbing a chemical analyte, thereby providing a detectable response. The detectable response of the sensors prepared by this method is not linearly related to the mole fraction of at least one of the polymer-based components of the sensors, thereby making arrays of these sensors useful for a variety of sensing tasks.
摘要翻译：本发明提供了一种用于制备化学敏感聚合物基传感器阵列的组合方法，其能够检测与其接触的流体中化学分析物的存在。所描述的方法和装置包括组合至少第一和第二有机材料的变化比例，其在组合时形成能够吸收化学分析物的聚合物或聚合物共混物，由此提供可检测的响应。通过该方法制备的传感器的可检测响应与传感器的至少一种基于聚合物的组分的摩尔分数没有线性关系，从而使得这些传感器的阵列可用于各种感测任务。

53. 发明授权

US06111121A High metathesis activity ruthenium and osmium metal carbene complexes 失效
标题翻译：高复分解活性钌和锇金属卡宾络合物
公开(公告)号：US06111121A
公开(公告)日：2000-08-29
申请号：US7498
申请日：1998-01-15
申请人： Robert H. Grubbs , Peter Schwab , Sonbinh T. Nguyen
发明人： Robert H. Grubbs , Peter Schwab , Sonbinh T. Nguyen
IPC分类号： B01J31/24 , B01J31/22 , C07F9/50 , C07F15/00 , C07F19/00 , C08F4/42 , C08F4/80 , C08F8/50 , C08F32/00 , C08G61/02 , C08G61/08
CPC分类号： C08F4/80 , B01J31/2265 , B01J31/24 , B01J31/2404 , C07F15/002 , C07F15/0046 , C08F32/00 , C08G61/08 , B01J2231/14 , B01J2231/543 , B01J2531/821 , B01J2531/825 , B01J31/18
摘要： Ruthenium and osmium carbene compounds that are stable in the presence of a variety of functional groups and can be used to catalyze olefin metathesis reactions on unstrained cyclic and acyclic olefins are disclosed. Also disclosed are methods of making the carbene compounds. The carbene compounds are of the formula ##STR1## where M is Os or Ru; R.sup.1 is hydrogen; R is selected from the group consisting of hydrogen, substituted or unsubstituted alkyl, and substituted or unsubstituted aryl; X and X.sup.1 are independently selected from any anionic ligand; and L and L.sup.1 are independently selected from any neutral electron donor. The ruthenium and osmium carbene compounds of the present invention may be synthesized using diazo compounds, by neutral electron donor ligand exchange, by cross metathesis, using acetylene, using cumulated olefins, and in a one-pot method using diazo compounds and neutral electron donors. The ruthenium and osmium carbene compounds of the present invention may be used to catalyze olefin metathesis reactions including, but not limited to, ROMP, RCM, depolymerization of unsaturated polymers, synthesis of telechelic polymers, and olefin synthesis.
摘要翻译：公开了在各种官能团存在下稳定并且可用于催化非限制性环状和无环烯烃上的烯烃复分解反应的钌和锇卡宾化合物。还公开了制备卡宾化合物的方法。卡宾化合物具有下式：其中M是Os或Ru; R1是氢; R选自氢，取代或未取代的烷基和取代或未取代的芳基; X和X 1独立地选自任何阴离子配体; L和L 1独立地选自任何中性给电子体。本发明的钌和锇卡宾化合物可以使用重氮化合物，通过中性电子给体配体交换，通过交叉复分解，使用乙炔，使用累积的烯烃，以及使用重氮化合物和中性电子给体的一锅法合成。本发明的钌和锇卡宾化合物可用于催化烯烃复分解反应，包括但不限于ROMP，RCM，不饱和聚合物的解聚，遥爪聚合物的合成和烯烃合成。

54. 发明授权

US5969170A High activity ruthenium and osmium metal carbene complexes for olefin metathesis reactions 失效
标题翻译：用于烯烃复分解反应的高活性钌和锇金属卡宾络合物
公开(公告)号：US5969170A
公开(公告)日：1999-10-19
申请号：US862615
申请日：1997-05-23
申请人： Robert H. Grubbs , SonBinh T. Nguyen , Lynda K. Johnson
发明人： Robert H. Grubbs , SonBinh T. Nguyen , Lynda K. Johnson
IPC分类号： B01J23/46 , B01J31/22 , C07C51/353 , C07C67/475 , C07F15/00 , C08F4/80 , C08F8/50 , C08F10/00 , C08F32/00 , C08F210/02 , C08G61/08 , C08G61/12 , C07F9/28
CPC分类号： B01J31/2265 , B01J31/24 , B01J31/2404 , C07C51/353 , C07C67/333 , C07C67/475 , C07F15/002 , C07F15/0046 , C08C19/08 , C08F10/00 , C08F32/00 , C08F8/50 , C08G61/08 , C08G61/128 , B01J2231/14 , B01J2231/543 , B01J23/462 , B01J23/466 , B01J2531/821 , B01J2531/825 , C07C2101/10 , C08C2019/09 , C08F210/02 , Y10S525/938
摘要： Disclosed are ruthenium and osmium carbene compounds which are stable in the presence of a variety of functional groups and which can be used to catalyze olefin metathesis reactions on strained and unstrained cyclic and acyclic olefins. Specifically, the present invention relates to carbene compounds of the formula ##STR1## wherein: M is Os or Ru; R and R.sup.1 are independently selected from hydrogen and substituent groups C.sub.2 -C.sub.20 alkenyl, C.sub.2 -C.sub.20 alkynyl, C.sub.1 -C.sub.20 alkyl, aryl, C.sub.1 -C.sub.20 carboxylate, C.sub.2 -C.sub.20 alkoxy, C.sub.2 -C.sub.20 alkenyloxy, C.sub.2 -C.sub.20 alkynyloxy, aryloxy, C.sub.2 -C.sub.20 alkoxycarbonyl, C.sub.1 -C.sub.20 alkylthio, C.sub.1 -C.sub.20 alkylsulfonyl or C.sub.1 -C.sub.20 alkylsulfinyl; each substituent group optionally substituted with C.sub.1 -C.sub.5 alkyl, a halogen, C.sub.1 -C.sub.5 alkoxy or with a phenyl group optionally substituted with a halogen, C.sub.1 -C.sub.5 alkyl or C.sub.1 -C.sub.5 alkoxy; X and X.sup.1 are independently selected from any anionic ligand; and L and L.sup.1 are each trialkyl phosphine ligands where at least one of the alkyl groups on the phosphine is a secondary alkyl or a cycloalkyl. A broad array of metathesis reactions are enabled including ring-opening metathesis polymerization of cyclic olefins, ring closing metathesis of acyclic dienes, cross metathesis involving at least one acyclic or unstrained cyclic olefin, depolymerization of unsaturated polymers and synthesis of telechelic polymers.
摘要翻译：公开了在各种官能团存在下稳定的钌和咔卡因化合物，其可用于催化在应变和未应变的环状和无环烯烃上的烯烃复分解反应。具体地说，本发明涉及下式的卡宾化合物其中：M是Os或Ru; R和R 1独立地选自氢和取代基C 2 -C 20烯基，C 2 -C 20炔基，C 1 -C 20烷基，芳基，C 1 -C 20羧酸酯，C 2 -C 20烷氧基，C 2 -C 20链烯氧基，C 2 -C 20炔氧基，芳氧基， C 2 -C 20烷氧基羰基，C 1 -C 20烷硫基，C 1 -C 20烷基磺酰基或C 1 -C 20烷基亚磺酰基; 任选被C 1 -C 5烷基，卤素，C 1 -C 5烷氧基或任选被卤素，C 1 -C 5烷基或C 1 -C 5烷氧基取代的苯基取代的取代基; X和X 1独立地选自任何阴离子配体; L和L1各自为三烷基膦配体，其中膦上的至少一个烷基是仲烷基或环烷基。可以进行广泛的复分解反应，包括环烯烃的开环易位聚合，无环二烯的闭环复分解，涉及至少一个无环或非应变的环烯烃的交叉复分解，不饱和聚合物的解聚和遥爪聚合物的合成。

55. 发明授权

US5916983A Biologically active compounds by catalytic olefin metathesis 失效
标题翻译：通过催化烯烃复分解生物活性化合物
公开(公告)号：US5916983A
公开(公告)日：1999-06-29
申请号：US863872
申请日：1997-05-27
申请人： Richard L. Pederson , Robert H. Grubbs
发明人： Richard L. Pederson , Robert H. Grubbs
IPC分类号： C07C6/04 , C07C17/26 , C07C17/266 , C07C29/09 , C07C67/293 , C07C69/007 , C08F4/72 , C07C29/12 , C08F4/80 , C07F14/00
CPC分类号： C07C69/007 , C07C17/2632 , C07C17/266 , C07C29/095 , C07C6/04 , C07C67/11 , C07C67/26 , C07C67/293 , C07B2200/09 , C07C2531/24
摘要： Biologically active compounds such as pheromones and precursors thereof are produced by catalyzed cross metathesis of dissimilar terminal olefins or of a cyclodiene and a terminal olefin.
摘要翻译：通过异种末端烯烃或环二烯和末端烯烃的催化交叉复分解产生生物活性化合物如信息素及其前体。

56. 发明授权

US4883851A Ring opening metathesis polymerization of strained cyclic ethers 失效
标题翻译：应变环醚的开环复分解聚合
公开(公告)号：US4883851A
公开(公告)日：1989-11-28
申请号：US371982
申请日：1989-06-22
申请人： Robert H. Grubbs , Bruce M. Novak
发明人： Robert H. Grubbs , Bruce M. Novak
IPC分类号： C08G61/08
CPC分类号： C08G61/08
摘要： A process is provided for the polymerization of 7-oxanorbornene and its derivatives. The process involves the ring opening metathesis of 7-oxanorbornene and its derivatives, preferably using water as the solvent. Such materials may be homopolymerized or, alternatively, copolymerized with other cyclic olefins such as norbornene. The resulting polymers are also novel.
摘要翻译：提供了7-氧代降冰片烯及其衍生物聚合的方法。该方法涉及7-氧代降冰片烯及其衍生物的开环复分解，优选使用水作为溶剂。这些材料可以是均聚的，或者与其它环烯烃如降冰片烯共聚。所得聚合物也是新颖的。

57. 发明授权

US4567244A Ring opening polymerization of mono-olefin ring compounds 失效
标题翻译：单烯烃环化合物的开环聚合
公开(公告)号：US4567244A
公开(公告)日：1986-01-28
申请号：US594354
申请日：1984-03-28
申请人： Robert H. Grubbs , Laura R. Gilliom
发明人： Robert H. Grubbs , Laura R. Gilliom
IPC分类号： C08G61/08 , C08F4/64
CPC分类号： C08G61/08
摘要： A monomer containing a strained olefin ring such as cyclobutene or cyclopropene is polymerized by forming a complex of the monomer and Cp.sub.2 TiCH.sub.2 -(Cp is .eta..sup.5 -C.sub.5 H.sub.5) and heating the complex in the presence of excess monomer to above the decomposition point. A controlled, selective opening of the ring with the strained olefin forms a linear, soluble polymer.
摘要翻译：含有应变烯烃环如环丁烯或环丙烯的单体通过形成单体和Cp 2 TiCH 2 - （Cp为5-C 5 H 5）的络合物并在多余单体存在下将络合物加热至分解点而聚合。用应变烯烃控制选择性地开环，形成线性可溶性聚合物。

58. 发明授权

US4147725A Process for preparing aniline compounds from amides with rhodium 失效
标题翻译：从含铑的酰胺制备苯胺化合物的方法
公开(公告)号：US4147725A
公开(公告)日：1979-04-03
申请号：US888892
申请日：1978-03-22
申请人： Kathryn A. Eickholt , Robert H. Grubbs
发明人： Kathryn A. Eickholt , Robert H. Grubbs
IPC分类号： B01J23/74 , C07C85/12
CPC分类号： C07C209/62
摘要： A vapor-phase process for preparing aniline or a substituted aniline, the process comprising contacting vaporous benzamide or a vaporous substituted benzamide with a metal catalyst, is improved by using rhodium as the metal catalyst.
摘要翻译：通过使用铑作为金属催化剂，改进了制备苯胺或取代苯胺的气相方法，该方法包括使蒸气性苯甲酰胺或蒸气取代的苯甲酰胺与金属催化剂接触。

59. 发明授权

US08877936B2 Ruthenium olefin metathesis catalysts bearing N-heterocyclic carbene ligands with substituted backbone 有权
标题翻译：含有取代基的N-杂环卡宾配体的钌烯烃复分解催化剂
公开(公告)号：US08877936B2
公开(公告)日：2014-11-04
申请号：US12936917
申请日：2009-04-09
申请人： Robert H. Grubbs , Cheol Keun Chung , Jean-Baptiste Bourg , Kevin Kuhn
发明人： Robert H. Grubbs , Cheol Keun Chung , Jean-Baptiste Bourg , Kevin Kuhn
IPC分类号： C07F15/00 , C07D233/06 , C07C6/04 , C07C67/475 , C08G61/08 , C07C67/333
CPC分类号： C07D233/06 , C07C67/333 , C07C67/475 , C07C2601/10 , C07F15/0046 , C08G61/08 , C07C69/74 , C07C69/007 , C07C69/157
摘要： This invention relates generally to olefin metathesis, more particularly, to tri- or tetra-substituted imidazolinium salts which are precursors to N-heterocyclic carbene (NHC) ligands with tri- or tetra-substituted imidazolinium rings, organometallic ruthenium complexes comprising gem di-substituted imidazolinium NHC ligands, organometallic ruthenium complexes comprising tri- or tetra-substituted imidazolinium NHC ligands, and to olefin metathesis methods using them. The catalysts and methods of the invention have utility in the fields of catalysis, organic synthesis, and industrial chemistry.
摘要翻译：本发明一般涉及烯烃复分解，更具体地涉及作为具有三取代或四取代的咪唑啉环的N-杂环卡宾（NHC）配体的前体的三取代或四取代的咪唑啉鎓盐，有机金属钌络合物包括双取代咪唑啉NHC配体，包含三取代或四取代的咪唑啉NHC配体的有机金属钌络合物，以及使用它们的烯烃复分解方法。本发明的催化剂和方法可用于催化，有机合成和工业化学领域。

60. 发明授权

US08512722B2 Antimicrobial materials 有权
标题翻译：抗菌材料
公开(公告)号：US08512722B2
公开(公告)日：2013-08-20
申请号：US12842593
申请日：2010-07-23
申请人： Choon Woo Lee , Robert H. Grubbs , Mark Humayun
发明人： Choon Woo Lee , Robert H. Grubbs , Mark Humayun
IPC分类号： A01N25/10
CPC分类号： C09D5/14 , A01N33/12 , C08G73/0206 , C08G73/0226 , C09D5/1637 , C09D179/02 , D06M16/00 , Y10T428/31721 , Y10T428/31725 , A01N25/34 , A01N2300/00
摘要： The disclosure provides methods and materials suitable for preparing coating layers on substrates. The coatings comprise quaternary amine groups and therefore impart anti-bacterial properties to the substrate. In one embodiment, for example, there is provided a quaternary amine-containing polymeric coating comprising propylene and ethylene repeat units.
摘要翻译：本公开提供了适合于在基底上制备涂层的方法和材料。涂层包含季胺基，因此赋予基底抗菌性能。在一个实施方案中，例如，提供了包含丙烯和乙烯重复单元的含季铵的聚合物涂层。

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