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    • 52. 发明授权
    • Substrate processing method
    • 基板加工方法
    • US08608974B2
    • 2013-12-17
    • US13332531
    • 2011-12-21
    • Eiichi Nishimura
    • Eiichi Nishimura
    • C23F1/00
    • H01L21/02063C23F4/00H01J37/32091H01L21/02068H01L21/32136H01L21/32138H01L21/76805
    • There is provided a substrate processing method capable of increasing an etching rate of a copper member without using a halogen gas. A Cu layer 40 having a smoothened surface 50 is obtained, and then, a processing gas produced by adding a methane gas to a hydrogen gas is introduced into an inner space of a processing chamber 15. Plasma is generated from this processing gas. In the inner space of the processing chamber 15, there exist oxygen radicals 52 generated when an oxide layer 42 is etched, and carbon radicals 53 generated from methane. The oxygen radicals 52 and the carbon radicals 53 are compounded to generate an organic acid, and the organic acid makes a reaction with copper atoms of the Cu layer 40. As a result, a complex of the organic acid having the copper atoms is generated, and the generated organic acid complex is vaporized.
    • 提供了能够在不使用卤素气体的情况下提高铜构件的蚀刻速度的基板处理方法。 获得具有平滑表面50的Cu层40,然后将通过将甲烷气体加入到氢气中而产生的处理气体被引入到处理室15的内部空间中。由该处理气体产生等离子体。 在处理室15的内部空间中,当蚀刻氧化物层42时产生氧自由基52,以及由甲烷产生的碳自由基53。 将氧自由基52和碳基53混合以产生有机酸,并且有机酸与Cu层40的铜原子反应。结果,产生具有铜原子的有机酸的络合物, 产生的有机酸络合物蒸发。