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51. 发明授权

US06534690B2 Process for the preparation of spherically shaped microcomposites 失效
标题翻译：制备球形微复合材料的方法
公开(公告)号：US06534690B2
公开(公告)日：2003-03-18
申请号：US09844236
申请日：2001-04-26
申请人： Mark Andrew Harmer , Qun Sun
发明人： Mark Andrew Harmer , Qun Sun
IPC分类号： C07C264
CPC分类号： B01J31/10 , B01J35/08 , B01J35/10 , B01J2231/12 , B01J2231/341 , B01J2231/52 , C07C5/2273 , C07C2531/08
摘要： A process for the preparation of at least one spherically shaped porous microcomposite is provided which microcomposite comprises a perfluorinated ion-exchange polymer containing pendant sulfonic and/or carboxylic acid groups entrapped within and highly dispersed throughout a network of inorganic oxide, wherein the weight percentage of the perfluorinated ion-exchange polymer in the microcomposite is from about 0.1 to about 90 percent, and wherein the size of the pores in the microcomposite is about 0.5 nm to about 75 nm; said process comprising the steps of: (a) combining a water-miscible inorganic oxide network precursor system, a water-miscible liquid composition comprising a perfluorinated ion-exchange polymer containing pendant sulfonic and/or carboxylic acid groups, and an organic liquid to form a two phase liquid system; (b) agitating the two phase liquid system sufficiently to sustain a dispersion of the water-miscible phase in the shape of spheres in the organic phase; (c) allowing the inorganic oxide network precursor system to form a network of inorganic oxide to yield at least one spherically shaped porous microcomposite having the above-described properties; and (d) recovering the at least one spherically shaped porous microcomposite.
摘要翻译：提供了制备至少一种球形多孔微复合材料的方法，该微复合材料包含全部含有离子交换聚合物的全氟化离子交换聚合物，所述全氟化离子交换聚合物包含在无机氧化物网络内并且高度分散在无机氧化物网络中的侧链磺酸和/或羧酸基团，其中重量百分数微复合材料中的全氟化离子交换聚合物为约0.1至约90％，并且其中微复合材料中的孔的尺寸为约0.5nm至约75nm; 所述方法包括以下步骤：（a）将水混溶性无机氧化物网络前体体系，包含含有侧链磺酸和/或羧酸基团的全氟化离子交换聚合物的水混溶性液体组合物和有机液体混合以形成两相液体系统; （b）充分搅拌两相液体系统以维持有机相中球混合物的水混溶相分散; （c）使无机氧化物网络前体体系形成无机氧化物网络，得到至少一种具有上述性质的球形多孔微复合材料; 和（d）回收至少一个球形多孔微复合物。

52. 发明授权

US06281400B1 Process for preparation of a catalytic microcomposite from a silicate and a highly fluorinated ion exchange resin 有权
标题翻译：由硅酸盐和高度氟化的离子交换树脂制备催化微复合物的方法
公开(公告)号：US06281400B1
公开(公告)日：2001-08-28
申请号：US09462970
申请日：2000-01-14
申请人： Mark Andrew Harmer , Qun Sun
发明人： Mark Andrew Harmer , Qun Sun
IPC分类号： C07C523
CPC分类号： C07C45/46 , B01J31/10 , B01J31/1633 , B01J2231/341 , B01J2231/4205 , B01J2231/52 , C07C2/66 , C07C5/2273 , C07C37/08 , C07C45/53 , C07C2521/08 , C07C2531/10 , Y02P20/52 , C07C49/786 , C07C49/08 , C07C39/04
摘要： The present invention relates to a process for preparing a microcomposite comprising a highly fluorinated ion-exchange polymer containing pendant sulfonate functional groups, said polymer existing as aggregated particles entrapped within and dispersed throughout a network of silica. Due to their high surface area and acid functionality, these microcomposites possess wide utility as improved solid acid catalysts, particularly in the substitution of aromatic compounds, in the decomposition of hydroperoxides, and in the isomerization of olefins.
摘要翻译：本发明涉及一种制备微复合材料的方法，该方法包括含有磺酸盐侧链官能团的高度氟化的离子交换聚合物，所述聚合物作为聚集的颗粒存在并分散在整个二氧化硅网内。由于它们的高表面积和酸官能度，这些微复合材料作为改进的固体酸催化剂具有广泛的用途，特别是在芳族化合物的取代，氢过氧化物的分解和烯烃的异构化中。

53. 发明授权

US6107233A Process for the preparation of spherically shaped microcomposites 失效
标题翻译：制备球形微复合材料的方法
公开(公告)号：US6107233A
公开(公告)日：2000-08-22
申请号：US155261
申请日：1998-09-24
申请人： Mark Andrew Harmer , Qun Sun
发明人： Mark Andrew Harmer , Qun Sun
IPC分类号： B01J31/08 , B01J31/10 , B01J35/08 , B01J35/10
CPC分类号： B01J35/08 , B01J31/10 , B01J2231/4205 , B01J2231/52 , B01J35/10
摘要： A process for the preparation of at least one spherically shaped porous microcomposite is provided which microcomposite comprises a perfluorinated ion-exchange polymer containing pendant sulfonic and/or carboxylic acid groups entrapped within and highly dispersed throughout a network of inorganic oxide, wherein the weight percentage of the perfluorinated ion-exchange polymer in the microcomposite is from about 0.1 to about 90 percent, and wherein the size of the pores in the microcomposite is about 0.5 nm to about 75 nm; said processcomprising the steps of: (a) combining a water-miscible inorganic oxide network precursor system, a water-miscible liquid composition comprising a perfluorinated ion-exchange polymer containing pendant sulfonic and/or carboxylic acid groups, and an organic liquid to form a two phase liquid system; (b) agitating the two phase liquid system sufficiently to sustain a dispersion of the water-miscible phase in the shape of spheres in the organic phase; (c) allowing the inorganic oxide network precursor system to form a network of inorganic oxide to yield at least one spherically shaped porous microcomposite having the above-described properties; and (d) recovering the at least one spherically shaped porous microcomposite.
摘要翻译： PCT No.PCT / US97 / 04704 Sec。 371日期：1998年9月24日 102（e）1998年9月24日PCT 1997年3月24日PCT公布。公开号WO97 / 35662 日期1997年10月2日提供了制备至少一种球形多孔微复合材料的方法，该微复合材料包含全部含有离子交换聚合物的全氟化离子交换聚合物，该聚合物含有侧链磺酸和/或羧酸基团，并且高分散在整个无机氧化物网络中，其中所述微复合材料中全氟化离子交换聚合物的重量百分比为约0.1至约90％，并且其中所述微复合材料中的孔的尺寸为约0.5nm至约75nm; 所述方法包括以下步骤：（a）组合水混溶性无机氧化物网络前体体系，包含含有侧链磺酸和/或羧酸基团的全氟化离子交换聚合物的水混溶性液体组合物和有机液体，以形成两相液体系统; （b）充分搅拌两相液体系统以维持有机相中球混合物的水混溶相分散; （c）使无机氧化物网络前体体系形成无机氧化物网络，得到至少一种具有上述性质的球形多孔微复合材料; 和（d）回收至少一个球形多孔微复合物。

54. 发明授权

US09790342B2 Closed-cell tannin-based foams without formaldehyde 有权
公开(公告)号：US09790342B2
公开(公告)日：2017-10-17
申请号：US14118916
申请日：2012-05-25
申请人： Mark Andrew Harmer , Vivek Kapur , Sharlene Renee Williams
发明人： Mark Andrew Harmer , Vivek Kapur , Sharlene Renee Williams
IPC分类号： B32B3/26 , C08J9/12 , B32B5/18 , B32B5/02 , B32B7/12 , B32B13/04 , B32B15/04 , B32B15/18 , B32B15/20 , B32B21/04 , B32B27/06 , B32B27/32 , B32B27/34 , B32B27/36 , B32B29/00 , C08G65/40 , C08J9/14
CPC分类号： C08J9/12 , B32B5/022 , B32B5/024 , B32B5/18 , B32B7/12 , B32B13/045 , B32B15/046 , B32B15/18 , B32B15/20 , B32B21/047 , B32B27/065 , B32B27/32 , B32B27/34 , B32B27/36 , B32B29/007 , B32B2250/40 , B32B2255/26 , B32B2266/02 , B32B2266/0214 , B32B2266/0228 , B32B2266/0278 , B32B2266/06 , B32B2266/08 , B32B2266/104 , B32B2266/126 , B32B2307/304 , B32B2419/00 , C08G65/40 , C08J9/141 , C08J9/146 , C08J2205/052 , C08J2397/00 , C08J2399/00 , C08J2459/00 , Y10T428/249976
摘要： Disclosed are foam compositions and processes to form closed-cell tannin-based foams. The foams comprises a continuous polymeric phase defining a plurality of cells, wherein the continuous polymeric phase comprises a tannin-based resin derived from a tannin and a monomer, wherein the monomer comprises furfural, glyoxal, acetaldehyde, 5-hydroxymethylfurfural, acrolein, levulinate esters, sugars, 2,5-furandicarboxylic acid, 2,5-furandicarboxylic aldehyde, urea, difurfural (DFF), furfuryl alcohol, glycerol, sorbitol, lignin, or mixtures thereof, and wherein the plurality of cells comprises a plurality of open-cells and a plurality of closed-cells with an open-cell content measured according to ASTM D6226-5, of less than 50%. The foam composition also comprises a discontinuous phase disposed in at least a portion of the plurality of closed-cells, the discontinuous phase comprising one or more blowing agents.

55. 发明申请

US20140093720A1 MIXED TANNIN-PHENOLIC FOAMS 有权
标题翻译：混合鞣革酚醛
公开(公告)号：US20140093720A1
公开(公告)日：2014-04-03
申请号：US14118940
申请日：2012-05-25
申请人： Michael W. Cobb , Mark Andrew Harmer , Vivek Kapur , Ann Y. Liauw , Sharlene Renee Williams
发明人： Michael W. Cobb , Mark Andrew Harmer , Vivek Kapur , Ann Y. Liauw , Sharlene Renee Williams
IPC分类号： C08J9/14 , B32B5/18
CPC分类号： C08J9/146 , B29C44/02 , B29C44/3415 , B29K2061/00 , B29K2105/046 , B29K2995/0015 , B29K2995/0016 , B29L2031/10 , B32B5/18 , C08J9/0061 , C08J9/14 , C08J9/141 , C08J2203/162 , C08J2361/06 , C08J2361/12 , C08J2497/00 , C08J2499/00 , E04C2/284 , Y10T428/249976
摘要： Disclosed are foam compositions and processes to form mixed tannin-phenolic foams. The foams comprises a continuous polymeric phase defining a plurality of cells, wherein the continuous polymeric phase comprises a mixed-resin derived from a phenol, a tannin, and a first monomer, and wherein the plurality of cells comprises a plurality of open-cells and a plurality of closed-cells with an open-cell content measured according to ASTM D6226-5, of less than 50%. The foam composition also comprises a discontinuous phase disposed in at least a portion of the plurality of closed-cells, the discontinuous phase comprising one or more blowing agents.
摘要翻译：公开了形成混合单宁 - 酚醛泡沫的泡沫组合物和方法。泡沫包括限定多个细胞的连续聚合物相，其中所述连续聚合物相包含衍生自苯酚，单宁和第一单体的混合树脂，并且其中所述多个细胞包含多个开放细胞和根据ASTM D6226-5测量的具有开孔含量的多个闭孔小于50％。所述泡沫组合物还包括设置在所述多个闭孔的至少一部分中的不连续相，所述不连续相包含一种或多种发泡剂。

56. 发明申请

US20140079941A1 PHENOLIC FOAMS WITH BLOWING AGENT 1,1,1,4,4,4-HEXAFLUORO-2-BUTENE 审中-公开
标题翻译：具有发泡剂的1,1,1,4,4,4-HEXAFLUORO-2-BOTENE的PHENOLIC FOAMS
公开(公告)号：US20140079941A1
公开(公告)日：2014-03-20
申请号：US14118957
申请日：2012-05-25
申请人： Michael W. Cobb , Mark Andrew Harmer , Vivek Kapur , Ann Y. Liauw , Sharlene Renee Williams
发明人： Michael W. Cobb , Mark Andrew Harmer , Vivek Kapur , Ann Y. Liauw , Sharlene Renee Williams
IPC分类号： C08L61/06 , B32B5/18
CPC分类号： C08L61/06 , B32B5/18 , B32B2250/03 , B32B2250/40 , B32B2266/0285 , B32B2266/06 , B32B2266/08 , B32B2305/022 , B32B2307/304 , B32B2307/3065 , B32B2307/72 , C08J9/146 , C08J2203/162 , C08J2205/052 , C08J2361/06 , Y10T428/249976
摘要： Disclosed are foam compositions and processes to form closed-cell phenolic foams. The foams comprises a continuous polymeric phase defining a plurality of cells, wherein the continuous polymeric phase comprises a phenol-formaldehyde resole derived from a phenol and formaldehyde, and wherein the plurality of cells comprises a plurality of open-cells and a plurality of closed-cells with an open-cell content measured according to ASTM D6226-5, of less than 50%. The foam composition also comprises a discontinuous phase disposed in at least a portion of the plurality of closed-cells, the discontinuous phase comprising 1,1,1,4,4,4-hexafluoro-2-butene.
摘要翻译：公开了形成闭孔酚醛泡沫的泡沫组合物和方法。所述泡沫包括限定多个细胞的连续聚合物相，其中所述连续聚合物相包含衍生自苯酚和甲醛的苯酚 - 甲醛甲阶酚醛树脂，并且其中所述多个细胞包含多个开放细胞和多个封闭 - 具有根据ASTM D6226-5测量的开孔含量小于50％的细胞。所述泡沫组合物还包括设置在所述多个闭孔的至少一部分中的不连续相，所述不连续相包含1,1,1,4,4,4-六氟-2-丁烯。

57. 发明授权

US08304535B2 Sugar production by decrystallization and hydrolysis of polysaccharide enriched biomass 有权
标题翻译：通过多糖富集的生物质的去结晶和水解产糖
公开(公告)号：US08304535B2
公开(公告)日：2012-11-06
申请号：US12621591
申请日：2009-11-19
申请人： Mark Andrew Harmer , Subramaniam Sabesan
发明人： Mark Andrew Harmer , Subramaniam Sabesan
IPC分类号： C07H1/08 , C13K1/02 , C13K1/04
CPC分类号： C13K1/02 , C08H6/00 , C13K13/002 , D21C11/0007
摘要： Sugar solutions are obtained from polysaccharide enriched biomass by contacting biomass with water and at least one nucleophilic base to produce a polysaccharide enriched biomass comprising a solid fraction and a liquid fraction. The solid fraction is separated from the lignin-containing liquid fraction and contacted with an acid solution, the acid solution comprising about 70 weight percent to about 100 weight percent sulfuric acid or an acid mixture comprising phosphoric acid and sulfuric acid, at a temperature and for a reaction time sufficient to produce a decrystallized biomass mixture. Water is added and the diluted biomass mixture is then hydrolyzed to produce a saccharification product comprising sugars.
摘要翻译：通过将生物质与水和至少一个亲核碱接触以产生含有固体部分和液体部分的富含多糖的生物质，从多糖富集的生物质获得糖溶液。将固体部分与含木质素的液体部分分离，并与酸溶液接触，该酸溶液在一定温度下，包含约70重量％至约100重量％的硫酸或包含磷酸和硫酸的酸混合物足以产生非结晶生物质混合物的反应时间。加入水，然后将稀释的生物质混合物水解以产生包含糖的糖化产物。

58. 发明授权

US08283492B2 Manufacture of hydrofluoroalkanesulfonic acids 有权
标题翻译：制造氢氟烷基磺酸
公开(公告)号：US08283492B2
公开(公告)日：2012-10-09
申请号：US13009887
申请日：2011-01-20
申请人： Mark Andrew Harmer , Christopher P. Junk , Zoe Schnepp
发明人： Mark Andrew Harmer , Christopher P. Junk , Zoe Schnepp
IPC分类号： C07C309/04 , C07C309/19
CPC分类号： C07C303/32 , C07C303/20 , C07C309/06
摘要： A process for manufacture of hydrofluoroalkanesulfonic acid with at least one hydrogen bonded to the carbon atom adjacent to the carbon atom bonded to the sulfonic acid group comprising: contacting a fluoroolefin with sulfite in an aqueous solution adjusted to about pH 4 to pH 12; removing water from the solution to form a solid; directly treating the solid with oleum; and distilling the hydrofluoroalkanesulfonic acid therefrom. Also a process for manufacture of potassium hydrofluoroalkanesulfonate in high purity is described.
摘要翻译：一种制备氢氟烷基磺酸的方法，所述氢氟烷基磺酸与至少一个与键合在磺酸基上的碳原子相邻的碳原子键合的氢包括：使氟烯烃与亚硫酸盐在调节至约pH4至pH12的水溶液中接触; 从溶液中除去水以形成固体; 用发烟硫酸直接处理固体; 并从其中蒸馏出氢氟烷基磺酸。还描述了制备高纯度的氢氟烷基磺酸钾的方法。

59. 发明申请

US20110296993A1 CARBON DIOXIDE REMOVAL AND IONIC LIQUID COMPOUNDS USEFUL THEREIN 有权
标题翻译：二氧化碳去除和离子液体化合物有用
公开(公告)号：US20110296993A1
公开(公告)日：2011-12-08
申请号：US13131079
申请日：2009-12-04
申请人： Thomas Foo , Mark Andrew Harmer , Keith W. Hutchenson , Christopher P. Junk , Berlyn R. Mellein , Aaron Minter , Mark Brandon Shiflett
发明人： Thomas Foo , Mark Andrew Harmer , Keith W. Hutchenson , Christopher P. Junk , Berlyn R. Mellein , Aaron Minter , Mark Brandon Shiflett
IPC分类号： B01D53/14 , B01D19/00
CPC分类号： B01D53/1493 , B01D2257/504 , Y02C10/04 , Y02C10/06
摘要： This invention relates to compounds useful as ionic liquids that are based on an N-substituted pyrrolidinone and incorporate a pendant ammonium cation that is spaced from the pyrrolidone ring by a variable length linker; and to methods of carbon dioxide removal in which they may be used.
摘要翻译：本发明涉及可用作离子液体的化合物，其基于N-取代的吡咯烷酮并掺入通过可变长度连接体与吡咯烷酮环间隔的侧铵阳离子; 以及可以使用它们的二氧化碳去除方法。

60. 发明授权

US07897807B2 Manufacture of hydrofluoroalkanesulfonic acids 有权
标题翻译：制造氢氟烷基磺酸
公开(公告)号：US07897807B2
公开(公告)日：2011-03-01
申请号：US12709531
申请日：2010-02-22
申请人： Mark Andrew Harmer , Christopher P. Junk , Zoe Schnepp
发明人： Mark Andrew Harmer , Christopher P. Junk , Zoe Schnepp
IPC分类号： C07C309/04 , C07C309/19
CPC分类号： C07C303/32 , C07C303/20 , C07C309/06
摘要： A process for manufacture of hydrofluoroalkanesulfonic acid with at least one hydrogen bonded to the carbon atom adjacent to the carbon atom bonded to the sulfonic acid group comprising: contacting a fluoroolefin with sulfite in an aqueous solution adjusted to about pH 4 to pH 12; removing water from the solution to form a solid; directly treating the solid with oleum; and distilling the hydrofluoroalkanesulfonic acid therefrom. Also a process for manufacture of potassium hydrofluoroalkanesulfonate in high purity is described.
摘要翻译：一种制备氢氟烷基磺酸的方法，所述氢氟烷基磺酸与至少一个与键合在磺酸基上的碳原子相邻的碳原子键合的氢包括：使氟烯烃与亚硫酸盐在调节至约pH4至pH12的水溶液中接触; 从溶液中除去水以形成固体; 用发烟硫酸直接处理固体; 并从其中蒸馏出氢氟烷基磺酸。还描述了制备高纯度的氢氟烷基磺酸钾的方法。

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