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51. 发明授权

US4636333A Alkoxy-substituted polyhydroindan carboxaldehydes 失效
标题翻译：烷氧基取代的多羟基茚满羧醛
公开(公告)号：US4636333A
公开(公告)日：1987-01-13
申请号：US837386
申请日：1986-03-07
申请人： Mark A. Sprecker , William L. Schreiber , Futoshi Fujioka , Richard M. Boden , Manfred H. Vock , Patrick Whelan , Marie R. Hanna
发明人： Mark A. Sprecker , William L. Schreiber , Futoshi Fujioka , Richard M. Boden , Manfred H. Vock , Patrick Whelan , Marie R. Hanna
IPC分类号： C07C45/49 , C07C45/50 , C07C47/36 , C07C47/37 , C07C47/445 , C07C49/523 , C11B9/00 , A61K7/46
CPC分类号： C11B9/0042 , C07C45/49 , C07C45/50 , C07C47/36 , C07C47/37 , C07C47/445 , C07C49/523
摘要： Described is a mixture of polyhydroindan carboxaldehydes defined according to the structure: ##STR1## wherein R.sub.7 represents a moiety selected from the group consisting of methyl and isopropyl prepared by means of reacting bicyclopentadiene with a lower alkanol in the presence of a Lewis acid in order to form a mixture of compounds defined according to the structure: ##STR2## and then reacting the resulting ether with carbon monoxide and hydrogen in the presence of an "oxo" reaction catalyst.
摘要翻译：描述了根据以下结构定义的多羟基茚基甲醛的混合物：其中R 7表示选自甲基和异丙基的部分，其通过在路易斯酸存在下通过双环戊二烯与低级链烷醇反应制备，以便形成根据以下结构定义的化合物的混合物：，然后在“氧代”反应催化剂存在下，使所得的醚与一氧化碳和氢气反应。

52. 发明授权

US4616095A Isomer-directed process for producing asymmetric ketones using catalytic claisen rearrangement of allylic ethers, intermediates, and uses of products and intermediates of process in perfumery 失效
标题翻译：使用烯丙基醚的催化裂化重排，中间体以及香料中的产品和中间体的产物和中间体来生产不对称酮的异构体定向方法
公开(公告)号：US4616095A
公开(公告)日：1986-10-07
申请号：US765342
申请日：1985-08-13
申请人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
发明人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
IPC分类号： C07C43/305 , C07C45/51 , C07C49/21 , C07C49/217 , C11B9/00
CPC分类号： C07C403/16 , C07C43/305 , C07C45/515 , C11B9/0015 , C11B9/0034 , C11B9/0061 , C07C2101/14 , C07C2101/16
摘要： Described is an isomer-directed process for producing asymmetric ketones defined according to the generic structure: ##STR1## wherein one of Z.sub.1 or Z.sub.2 is the moiety: ##STR2## and the other of Z.sub.1 or Z.sub.2 is hydrogen; wherein R.sub.11 and R.sub.21 represent hydrogen or the same or different alkyl or alkenyl with the proviso that R.sub.11 and R.sub.21 are not both hydrogen or wherein R.sub.11 and R.sub.21 taken together:(i) complete a cycloalkyl, cycloalkenyl, bicycloalkyl, mono or polyalkyl cycloakyl or mono or polyalkyl cycloalkenyl ring, or(ii) represent alkylidene, cycloalkenyl alkylidene, aralkylidene, mono or polyalkyl cycloalkenyl alkylidene or mono or polyalkyl aralkylidene;and wherein R.sub.6, R.sub.7 and R.sub.8 are the same or different and each represents hydrogen or methyl, using a catalytic Claisen rearrangement of allylic ethers previously formed by reacting substituted or unsubstituted allylic alcohols defined according to the structure: ##STR3## with dialkyl ketals defined according to the structure: ##STR4## wherein R.sub.4 and R.sub.5 represent the same or different C.sub.1 -C.sub.4 alkyl.Also described are compounds and processes for using same in perfumery defined according the structures: ##STR5## Also described are certain diallylic ethers defined according to the generic structure: ##STR6##
摘要翻译：描述了根据通用结构定义的不对称酮的异构体定向方法：其中Z1或Z2之一为部分：Z1和Z2中的另一个为氢; 其中R11和R21表示氢或相同或不同的烷基或烯基，条件是R11和R21不同时为氢或其中R11和R21一起组合：（i）完成环烷基，环烯基，双环烷基，单或多烷基环烷基或单或聚烷基环烯基环，或（ii）代表亚烷基，环烯基亚烷基，亚烷叉基，单或多烷基环烯基亚烷基或单或多烷基亚烷基; 并且其中R 6，R 7和R 8相同或不同，并且各自表示氢或甲基，使用以前通过使根据以下结构定义的取代或未取代的烯丙基醇反应形成的烯丙基醚的催化Claisen重排：＆lt; IMAGE＆gt; 结构：其中R 4和R 5表示相同或不同的C 1 -C 4烷基。还描述了在根据以下结构定义的香料中使用它们的化合物和方法：其中描述了根据以下结构定义的某些二烯丙基醚：到通用结构：

53. 发明授权

US4576741A Isomer-directed process for producing asymmetric ketones using catalytic Claisen rearrangement of allylic ethers, intermediates, and uses of products and intermediates of process in perfumery 失效
标题翻译：使用烯丙基醚的催化Claisen重排，中间体以及香料中产品和方法中间体的用途来生产不对称酮的异构体定向方法
公开(公告)号：US4576741A
公开(公告)日：1986-03-18
申请号：US671473
申请日：1984-11-14
申请人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
发明人： Mark A. Sprecker , Robert P. Belko , William L. Schreiber , Michael Licciardello
IPC分类号： C07C43/305 , C07C45/51 , C11B9/00 , C11D3/50 , A61K7/46
CPC分类号： C07C403/16 , C07C43/305 , C07C45/515 , C11B9/0015 , C11B9/0034 , C11B9/0061 , C07C2101/14 , C07C2101/16
摘要： Described in an isomer-directed process for producing asymmetric ketones defined according to the generic structure: ##STR1## wherein one of Z.sub.1 or Z.sub.2 is the moiety: ##STR2## and the other of Z.sub.1 or Z.sub.2 is hydrogen; wherein R.sub.11 and R.sub.21 represent hydrogen or the same or different alkyl or alkenyl with the proviso that R.sub.11 and R.sub.21 are not both hydrogen or wherein R.sub.11 and R.sub.21 taken together:(i) complete a cycloalkyl, cycloalkenyl, bicycloalkyl, mono or polyalkyl cycloalkyl or mono or polyalkyl cycloalkenyl ring, or(ii) represent alkylidene, cycloalkenyl alkylidene, aralkylidene, mono or polyalkyl cycloalkenyl alkylidene or mono or polyalkyl aralkylidene;and wherein R.sub.6, R.sub.7 and R.sub.8 are the same or different and each represents hydrogen or methyl, using a catalytic Claisen rearrangement of allylic ethers previously formed by reacting substituted or unsubstituted allylic alcohols defined according to the structure: ##STR3## with dialkyl ketals defined according to the structure: ##STR4## wherein R.sub.4 and R.sub.5 represent the same or different C.sub.1 -C.sub.4 alkyl.Also described are compounds and processes for using same in perfumery defined according the structures: ##STR5## Also described are certain diallylic ethers defined according to the generic structure: ##STR6##
摘要翻译：描述于根据通用结构定义的用于制备不对称酮的异构体定向方法：其中Z1或Z2之一为部分：Z1或Z2中的另一个为氢; 其中R11和R21表示氢或相同或不同的烷基或烯基，条件是R11和R21不同时为氢或其中R11和R21一起组合：（i）完成环烷基，环烯基，双环烷基，单或多烷基环烷基或单或聚烷基环烯基环，或（ii）代表亚烷基，环烯基亚烷基，亚烷叉基，单或多烷基环烯基亚烷基或单或多烷基亚烷基; 并且其中R 6，R 7和R 8相同或不同，并且各自表示氢或甲基，使用以前通过使根据以下结构定义的取代或未取代的烯丙基醇反应形成的烯丙基醚的催化Claisen重排：＆lt; IMAGE＆gt; 结构：其中R 4和R 5表示相同或不同的C 1 -C 4烷基。还描述了在根据以下结构定义的香水中使用该化合物的化合物和方法：还描述了根据通用物质定义的某些二烯丙基醚结构：

54. 发明授权

US4547594A Process for producing solanone, norsolanadione and intermediates therefor 失效
标题翻译：制备索罗酮，二酰甘油和其中间体的方法
公开(公告)号：US4547594A
公开(公告)日：1985-10-15
申请号：US636283
申请日：1984-07-31
申请人： Kenneth K. Light , William L. Schreiber , Joseph A. McGhie , Ronald P. Schreck , Takao Yoshida , Loren B. Schreiber , Ranya Muralidhara
发明人： Kenneth K. Light , William L. Schreiber , Joseph A. McGhie , Ronald P. Schreck , Takao Yoshida , Loren B. Schreiber , Ranya Muralidhara
IPC分类号： A23L27/20 , A24B15/32 , C07C45/51 , C07C45/59 , C07C45/66 , C07C309/28 , C07D295/02 , C07D295/03 , C07D295/145 , C07D295/155 , C07D317/30 , C07C45/63
CPC分类号： C07D295/03 , A23L27/202 , A24B15/32 , C07C255/00 , C07C309/28 , C07C45/516 , C07C45/59 , C07C45/66 , C07D295/145 , C07D295/155 , C07D317/30
摘要： Described is a process for preparing solanone and norsolanadione wherein in preparing solanone, the compound having the structure: ##STR1## or a mixture of compounds defined according to the structure: ##STR2## is reacted with methyl lithium and the resulting intermediate is hydrolyzed and the resulting compound is dehydrated and wherein in preparing norsolanadione this compound or mixture of compounds is reacted with ethylene glycol or propylene glycol thereby forming a ketal and the resulting ketal is reacted with methyl lithium and the resulting intermediate is then hydrolyzed in the presence of acid in which one of the dashed lines represents a carbon-carbon single bond and the other of the dashed lines represents a carbon-carbon double bond.
摘要翻译：描述了制备Solone和Norsolanadione的方法，其中在制备solone的情况下，将具有下列结构的化合物或其结构如下：＆lt; IMAGE＆gt;中定义的化合物的混合物与甲基锂反应，并将所得中间体水解，所得化合物脱水，并且其中在制备硝酰甘油的情况下，该化合物或化合物的混合物与乙二醇或丙二醇反应，从而形成缩酮，所得缩酮与甲基锂反应，然后在酸存在下将所得中间体水解，其中虚线之一表示碳 - 碳单键，另一个虚线表示碳 - 碳双键。

55. 发明授权

US4107066A Substituted acetonaphthones, processes for preparing same, uses of same in perfumery, and intermediates used in said processes 失效
公开(公告)号：US4107066A
公开(公告)日：1978-08-15
申请号：US819959
申请日：1977-07-28
申请人： William L. Schreiber , James N. Siano , Edward J. Shuster
发明人： William L. Schreiber , James N. Siano , Edward J. Shuster
IPC分类号： A61K8/35 , A61Q13/00 , C07C29/42 , C07C45/00 , C07C45/26 , C07C45/63 , C07C45/65 , C07C45/66 , C07C45/67 , C07C49/553 , C07C49/557 , C07C49/567 , C07C49/613 , C07C67/00 , C11B9/00 , C11D3/50
CPC分类号： C11D3/50 , C07C29/42 , C07C403/02 , C07C45/26 , C07C45/63 , C07C45/65 , C07C45/66 , C07C45/67 , C07C49/553 , C07C49/567 , C11B9/0053 , C07C2101/16 , C07C2102/28
摘要： Described are hexahydrotetramethyl acetonaphthones and mixtures of such substituted acetonaphthones having the generic formula: ##STR1## wherein one of the dashed lines is a carbon-carbon double bond and each of the other of the dashed lines is a carbon-carbon single bond, and, specifically, the novel isomer having the structure: ##STR2## and processes for the preparation of such mixtures and said novel isomer, as well as a known single component of said mixtures and compounds, by means of first forming 3-chloromesityl oxide from mesityl oxide and chlorine and then reacting the 3-chloromesityl oxide with myrcene via a Diels-Alder reaction thereby producing a chlorine containing Diels-Alder adduct and then either:(i) dehydrochlorinating the chlorine containing Diels-Alder adduct to form an acetyl conjugated cyclohexadiene and cyclizing the acetyl conjugated cyclohexadiene to produce a mixture of isomers having the generic formula: ##STR3## wherein one of the dashed lines is a carbon-carbon double bond and each of the other of the dashed lines is a carbon-carbon single bond; or (II) CYCLIZING THE CHLORINE CONTAINING Diels-Alder adduct to form an acetyl-chloro octahydronaphthalene and dehydrochlorinating the acetylchloro octahydronaphthalene to form a composition substantially composed of a compound having the structure: ##STR4## The products produced are useful as vetiver ingredients in perfumes and perfumed articles.

56. 发明授权

US4517385A Process for producing solanone, norsolanadione and intermediates therefor 失效
标题翻译：制备索罗酮，二酰甘油和其中间体的方法
公开(公告)号：US4517385A
公开(公告)日：1985-05-14
申请号：US636226
申请日：1984-07-31
申请人： Kenneth K. Light , William L. Schreiber , Joseph A. McGhie , Ronald P. Schreck , Takao Yoshida , Loren B. Schreiber , Ranya Muralidhara
发明人： Kenneth K. Light , William L. Schreiber , Joseph A. McGhie , Ronald P. Schreck , Takao Yoshida , Loren B. Schreiber , Ranya Muralidhara
IPC分类号： A24B15/32 , C07C45/42 , C07C45/59 , C07C45/66 , C07C49/12 , C07C49/203 , C07D295/02 , C07D295/03 , C07D295/145 , C07D295/155 , C07D309/28 , C07D317/28 , C07D317/30 , C07C49/16
CPC分类号： C07D295/03 , A24B15/32 , C07C255/00 , C07C45/42 , C07C45/59 , C07C45/66 , C07C49/203 , C07D295/145 , C07D295/155 , C07D309/28 , C07D317/28 , C07D317/30
摘要： Described is a process for preparing solanone and norsolanadione, both useful as tobacco flavorants.
摘要翻译：描述了一种制备可用作烟草香料的Solone和Norsolanadione的方法。

57. 发明授权

US4483995A Process for producing solanone, norsolanadione and intermediates therefor 失效
标题翻译：制备索罗酮，二酰甘油和其中间体的方法
公开(公告)号：US4483995A
公开(公告)日：1984-11-20
申请号：US511966
申请日：1983-07-08
申请人： Kenneth K. Light , William L. Schreiber , Joseph A. McGhie , Ronald P. Schreck , Takao Yoshida , Loren B. Schreiber , Ranya Muralidhara
发明人： Kenneth K. Light , William L. Schreiber , Joseph A. McGhie , Ronald P. Schreck , Takao Yoshida , Loren B. Schreiber , Ranya Muralidhara
IPC分类号： A23L27/20 , A24B15/32 , C07C45/51 , C07C45/59 , C07C45/66 , C07C49/203 , C07C309/28 , C07D295/02 , C07D295/03 , C07D295/145 , C07D295/155 , C07D317/30 , C07D317/00
CPC分类号： C07D295/03 , A23L27/202 , A24B15/32 , C07C255/00 , C07C309/28 , C07C45/516 , C07C45/59 , C07C45/66 , C07C49/203 , C07D295/145 , C07D295/155 , C07D317/30
摘要： The invention provides an organoleptically improved smoking tobacco product and additives therefor as well as methods of making the same.
摘要翻译：本发明提供一种感官改进的吸烟产品及其添加剂及其制备方法。

58. 发明授权

US4191660A Organoleptic uses of 1-(3,3-dimethyl-2-norbornyl)-2-propanone in cationic, anionic and nonionic detergents and soaps 失效
标题翻译：在阳离子，阴离子和非离子洗涤剂和肥皂中感官使用1-（3,3-二甲基-2-降冰片基）-2-丙酮
公开(公告)号：US4191660A
公开(公告)日：1980-03-04
申请号：US932615
申请日：1978-08-10
申请人： William L. Schreiber , James N. Siano , Manfred H. Vock , Edward J. Shuster
发明人： William L. Schreiber , James N. Siano , Manfred H. Vock , Edward J. Shuster
IPC分类号： C07C45/00 , C07C49/115 , C11B9/00 , C11D3/50 , C11D9/44
CPC分类号： C11D3/50 , C07C45/00 , C07C49/115 , C11B9/0046
摘要： Processes and compositions are described for the use in cationic, anionic and nonionic detergents and soaps of 1-(3,3-dimethyl-2-norbornyl)-2-propanone (hereinafter referred to as the "norbornylpropanone derivatives") having the structure: ##STR1## (which structure is intended to cover both the "endo" and the "exo" isomers thereof). Addition of the said "norbornylpropanone derivative" to soaps and cationic, anionic and nonionic detergents is indicated to produce sweet, berry, woody, piney, mint aroma notes with a damascenone-like character and buttery and minty nuances.
摘要翻译：描述了用于具有以下结构的1-（3,3-二甲基-2-降冰片基）-2-丙酮（以下称为“降冰片基丙酮衍生物”）的阳离子，阴离子和非离子洗涤剂和皂的方法和组合物，（该结构旨在涵盖“endo”和“exo”异构体）。将所述“降冰片基丙酮衍生物”加入到皂和阳离子，阴离子和非离子洗涤剂中可以产生甜味，浆果，木质，松树，薄荷香气，具有大马士革样特征和黄油和细小的细微差别。

59. 发明授权

US3988487A Foodstuff flavoring compositions comprising alkylidene alkenals and processes for preparing same as well as flavoring compositions for use in such foodstuff 失效
标题翻译：包含亚烷基烯的食品调味组合物及其制备方法以及用于这种食品的调味组合物
公开(公告)号：US3988487A
公开(公告)日：1976-10-26
申请号：US603932
申请日：1975-08-12
申请人： Anne Sanderson , Gerard Mosciano , Alan O. Pittet , Louis J. Strasburger , William L. Schreiber , Michel Van Praag , Edward J. Shuster , Bernard J. Rutkowsky , William J. Evers
发明人： Anne Sanderson , Gerard Mosciano , Alan O. Pittet , Louis J. Strasburger , William L. Schreiber , Michel Van Praag , Edward J. Shuster , Bernard J. Rutkowsky , William J. Evers
IPC分类号： A23L27/20 , C11B9/00 , A23L1/235
CPC分类号： C07C45/004 , A23L27/2024 , C07C45/45 , C07C45/515 , C07C45/62 , C11B9/0015
摘要： Methods for altering, modifying or enhancing the organoleptic properties of foodstuffs and perfumes comprising incorporating with such materials a small but effective amount (from 0.02 ppm up to about 150 ppm) of at least one 2-alkylidene-cis-3-alkenal or at least one 2-alkylidene-trans-3-alkenal or a mixture having at last one 2-alkylidene-trans-3-alkenal and one 2-alkylidene-cis-3-alkenal represented by the formula: ##SPC1##Or di-lower alkyl acetal thereof wherein one of R.sub.1 and R.sub.2 is hydrogen and the other is lower alkyl; and one of R.sub.3 and R.sub.4 is hydrogen and the other is lower alkyl; together with compositions containing the said 2-alkylidene-3-alkenals or acetals thereof for use in altering such organoleptic properties.
摘要翻译：用于改变，改良或增强食品和香料的感官特性的方法，包括与这些物质一起掺入至少一种2-亚烷基 - 顺-3-烯醛或至少含有少量（从0.02ppm至高达150ppm）的少量有效量一个2-亚烷基 - 反式-3-链烯酸或具有最后一个2-亚烷基 - 反式-3-链烯酸和一个2-亚烷基 - 顺式-3-烯醛的混合物，其由下式表示：+ q，10 OR DI-LOWER 其中R1和R2中的一个是氢，另一个是低级烷基; R3和R4之一是氢，另一个是低级烷基; 以及含有所述2-亚烷基-3-链烯或其缩醛的组合物，用于改变这种感官特性。

60. 发明授权

US4489009A Process for producing solanone, norsolanadione and intermediates therefor 失效
标题翻译：制备索罗酮，二酰甘油和其中间体的方法
公开(公告)号：US4489009A
公开(公告)日：1984-12-18
申请号：US511944
申请日：1983-07-08
申请人： Kenneth K. Light , William L. Schreiber , Joseph A. McGhie , Ronald P. Schreck , Takao Yoshida , Loren B. Schreiber , Ranya Muralidhara
发明人： Kenneth K. Light , William L. Schreiber , Joseph A. McGhie , Ronald P. Schreck , Takao Yoshida , Loren B. Schreiber , Ranya Muralidhara
IPC分类号： A23L27/20 , A24B15/32 , C07C45/51 , C07C45/59 , C07C45/66 , C07C309/28 , C07D295/02 , C07D295/03 , C07D295/145 , C07D295/155 , C07D317/30 , C07C121/34 , C07C121/30
CPC分类号： C07D295/03 , A23L27/202 , A24B15/32 , C07C255/00 , C07C309/28 , C07C45/516 , C07C45/59 , C07C45/66 , C07D295/145 , C07D295/155 , C07D317/30
摘要： Described is a process for preparing solanone and norsolanadione using chemical intermediates: which provide an organoleptically improved smoking tobacco product and additives therefor.
摘要翻译：描述了使用化学中间体制备Solone和Norsolanadione的方法：其提供感官改进的吸烟产品及其添加剂。 + PG]

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